579 results about "Glyoxylic acid" patented technology

The preparation of novel vehicle alcohols environment-friendly fuel aims to overcome a plurality of defects caused by replacing alcohols fuel with gasoline. The invention discloses the novel vehicle alcohols environment-friendly fuel which comprises the following components of 50-95 parts of main alcohols fuel, 3-30 parts of low-temperature ignition auxiliary material, 0.1-20 parts of burning value reinforcing agent, 0-15 parts of dispersant, 0-0.05 part of smoke abatement burning agent, 0-5 parts of ignition accelerating agent, 0-0.04 part of antioxidant, 0-0.3 part of emulsification dispersing agent, 0-0.08 part of metal anticorrosion inhibiter, 0-0.8 part of rubber plastic anti-dissolving additive, 0-8 parts of air-resistance regulating agent, 0-6 parts of fuel lubricating agent and 0-0.7 part of glyoxylic acid neutralizer. According to the novel vehicle alcohols environment-friendly fuel, low temperature ignitability is improved, dynamic performance is enhanced, burning is sufficient, discharging is environment-friendly and free form pollution, corrosivity of the alcohols fuel on metal can be controlled, swelling performance of the alcohols fuel on rubber can be controlled and the air resistance phenomenon can be effectively prevented.

alpha-keto acids and certain precursors and derivatives thereof, particularly those selected from the group which consists of glyoxylic acid, 2-oxo-propanoic acid, 2-oxo-butanoic acid, 3-methyl-2-oxo butanoic acid, 3-methyl-2-oxo pentanoic acid, 4-methyl-2-oxo pentanoic acid, 3-hydroxy-2-oxo-propanoic acid, oxalacetic acid, 2-oxo-glutaric acid, 2-oxo-3-phenyl-propanoic acid, 3-(4-hydroxy-phenyl)-2-oxo-propanoic acid, 2-oxo-1H-indole-3-propanoic acid, 2-oxo-1H-imidazole-4-propanoic acid, 4-methylthio-2-oxo-butanoic acid, 3-mercapto-2-oxo-propanoic acid, 3-hydroxy-2-oxo-butanoic acid, 6-amino-2-oxo-hexanoic acid and 5-guanido-2-oxo-pentanoic acid, and precursors and derivatives thereof that are capable of being formed from or releasing said acids in the use medium, are useful as flavouring ingredients. Such ingredients are useful for preparing flavouring compositions and a wide variety of flavoured foodstuffs to which they impart greater creaminess and bulkiness so that they have heightened effect in the mouth and generally an enhanced mouthfeel. They are also useful for enhancing the sweetness of foods sweetened with natural or artificial sweeteners, and giving it a more natural character.

The invention relates to acid solution used for processing the magnesium alloy surface. The acid solution is water solution which contains acids, inhibitor and wetting agent, wherein, the acids are first acids or mixture of first acids and second acids; the first acids are selected from one type or a plurality of types among citric acids, oxalic acids, tartaric acids, methanoic acids, acetic acids, metacetonic acids, butyric acids, glutaric acids, phenylformic acids, benzene dicarboxylic acids, lactic acids, glycolic acids, glyoxylic acids and amino acids; and the second acids are hydrochloric acids and/or nitric acids. By adoption of the acid solution, the magnesium alloy surface can be fully activated; the membranous layer of a converting film which is formed on the magnesium alloy surface after chemical conversion process is compact, has erosion resistance and good binding force with a paint film. Moreover, the method is a environment-friendly method for processing the magnesium alloy surface.

The present invention relates to ALD processes for deposition of a metal selected from Pd, Rh, Ru, Pt and Ir wherein a layer including the metal is formed on a surface composed of a material selected from W, Ta, Cu, Ni, Co, Fe, Mn, Cr, V Nb, tungsten nitride, tantalum nitride, titanium nitride, dielectrics and activated dielectrics at a temperature ranging from >60° C. to <260° C. The layer is formed by sequentially pulsing into a chamber containing the surface a precursor for the metal and a reducing gas selected from hydrogen, glyoxylic acid, oxalic acid, formaldehyde, 2-propanol, imidazole and plasma-activated hydrogen.

The present disclosure relates to degradable superabsorbent materials based on acetals of glyoxylic acid and derivatives thereof with polyvinyl alcohol, and methods of making the polymers. The polymers are used to make superabsorbent particles, coatings, sheets, and fibers. Formulations and articles including the superabsorbent polymers, particles, coatings, sheets, and fibers are also disclosed.

Metal alloy barrier layers formed of a group VII metal alloyed with boron (B) and/or phosphorous (P) and an at least one element from glyoxylic acid, such as carbon (C), hydrogen (H), or carbon and hydrogen (CH) formed by electoless plating are described. These barrier layers may be used as a barrier layer over copper bumps that are soldered to a tin-based solder in a die package. Such barrier layers may also be used as barrier layer liners within trenches in which copper interconnects or vias are formed and as capping layers over copper interconnects or vias to prevent the electromigration of copper.

The invention discloses a productive technology of vanlillin by a glyoxylic acid method. The productive technology comprises a synthesis process, a fractionation process and a purification process, wherein the synthesis process comprises condensation treatment, oxidation treatment and decarboxylation treatment of methyl catechol and glyoxylic acid. The productive technology particularly comprisesthe following steps: respectively converting the methyl catechol and the glyoxylic acid into guaiacol sodium and sodium glyoxylate in a sodium hydroxide system; carrying out condensation treatment onthe guaiacol sodium and the sodium glyoxylate; after recovering the unreacted methyl catechol in a condensation liquid, carrying out oxidation treatment, namely carrying out catalytic oxidation on anethanol group in 4-hydroxy-3-methoxybenzene sodium glycolate by using copper oxide in the sodium hydroxide system to form a ketone group, thereby generating a corresponding ketonic acid compound; after separating red copper oxide particles from an oxidation liquid, carrying out decarboxylation treatment, namely using sulfuric acid to acidize the oxidation liquid, and simultaneously converting an acid group in the ketonic acid compound into carbon dioxide so as to generate 4-hydroxy-3- methoxybenzaldehyde; and carrying out the fractionation process and the purification process to obtain the vanlillin.

A treatment method and a treatment system of tail gas from glyoxylic acid production by nitric acid oxidation of glyoxal belong to the fields of environmental protection, energy saving and consumption reduction. The method comprises the following steps: introducing air to oxidize NO in tail gas generated by nitric acid oxidation of glyoxal into NO2; performing six-grade water absorption continuously to absorb gas of NOx and HCl in the tail gas; absorbing the tail gas after six-grade water absorption by a NaOH or Na2CO3 solution to remove residual NO2 and HCl gas and to generate an alkaline solution containing NaNO3, NaNO2, and trace NaCl; discharging the treated tail gas by an induced draft fan; performing neutralization, concentration, crystallization, centrifugation and separation of the generated alkaline solution to obtain a mixed sodium salt containing NaNO3, NaNO2, and trace NaCl, returning the mixed sodium salt to an oxidation vessel to be used as a catalyst for recycle. The treatment system comprises: an oxidation reaction vessel, water absorbing towers from grade one to grade six, a seventh grade alkaline solution absorbing tower, a concentration and crystallization vessel, a centrifuge, and a induced draft fan.

The invention provides colloid palladium activation solution which comprises colloid palladium, sodium chloride, glyoxylic acid, hydrochloric acid, stannous chloride and stabilizer for stabilizing the stannous chloride, wherein the glyoxylic acid has strong reducibility and can avoid that divalent tin ions in the activation solution are oxidized, and prolong the service life of the action solution; simultaneously, the glyoxylic acid is adsorbed on the periphery of colloid palladium particles, thereby leading the dispersion of the colloid palladium to be more uniform, avoiding the gel coagulation among the colloid particles and enhancing the activity of the activation solution. The invention provides a preparation method of the colloid palladium, and the process is simple. In addition, the adoption of the colloid palladium activation solution for activating the surface of a non-metal substrate can firstly adsorb the glyoxylic acid in the activation solution on the surface of the non-metal substrate, enhance the bonding force between the colloid palladium particles and the non-metal substrate, leading a plated coating after chemical plating to have uniform thickness and flat surface, and leading the adhesion between the plated coating and the substrate to be very high.

The invention provides a preparation method for a graphene/nano-silver composite antibacterial material and belongs to the technical field of new materials. The preparation method is characterized in that graphene oxide provided with silver ions in an adsorption manner is put into a reduction agent solution to be heated, the graphene/nano-silver composite material is obtained through centrifugal separation, and a reduction agent is glyoxylic acid. The method has the beneficial effects that reduction of the graphene oxide and the silver ions is sufficient, operation is simple, the process is controllable, and the obtained material has good antibacterial activity on common bacteria.

The present invention is directed to novel pharmaceutical compositions comprising nano- and micro-particulate formulations of poorly water soluble tubulin inhibitors of the indole chemical class, preferably N-substituted indol-3-glyoxyamides, and more preferably N-(Pyridin-4-yl)-[1-(4-chlorobenzyl)-indol-3-yl]glyoxylic acid amide (D-24851), also known as “Indibulin,” and methods of making and using such compositions for the treatment of anti-tumor agent resistant cancers and other diseases.

The invention relates to a multi-effect membrane distillation device with efficient internal heat reclamation function and a method. The middle part of a membrane shell is provided with a cavity, two ends of the membrane shell are provided with an inlet and an outlet respectively, hollow fibrous membranes and hollow fiber pipes arranged uniformly are arranged in the cavity of the membrane shell, joints at two ends of the hollow fibrous membranes and the hollow fiber pipes are connected with the inlet and the outlet respectively, the lower end of the membrane shell is provided with a distillate outlet, and an external heat exchanger is connected in series between the inlet and the outlet of the water return end of a membrane assembly. The device has compact structure, simple and mild operating condition, low energy consumption and high water making rate, and can be used for small-scale dispersed implementation and integrated application; the method can be used in the fields of sea water desalinization, bitter water desalinization, concentration treatment of aqueous solution of nonvolatile or semi-volatile solutes, environmental protection and the like; and particularly when the method is used for concentration of aqueous solution of nonvolatile and semi-volatile solutes such as sodium chloride, ammonium sulfate, ammonium nitrate, sodium nitrate, sodium carbonate, sodium hydroxide, sulfuric acid, hydrochloric acid, glucose, xylitol, urea, glycerol, ethylene glycol, lactic acid, glyoxylic acid, dimethyl sulfoxide, sulfolane and the like, normal pressure steam or hot water is used as a heat source, and the highest water making rate can reach 13.7.

A post-dry etching cleaning liquid composition for cleaning a substrate after dry etching is provided, the cleaning liquid composition containing at least one type of fluorine compound, glyoxylic acid, at least one type of organic acid salt, and water. With regard to the fluorine compound, ammonium fluoride may be used. With regard to the organic acid salt, at least one of ammonium oxalate, ammonium tartarate, ammonium citrate, and ammonium acetate may be used.

A process for preparing piperonal, characterized by comprising the three successive steps: (A) the addition step of reacting 1,2-methylenedioxybenzene with glyoxylic acid in the presence of a strong acid to form 3,4-methylenedioxymandelic acid, (B) the extraction step of adding an organic solvent to the reaction fluid and then neutralizing the resulting fluid with a base to thereby extract 3,4-methylenedioxymandelic acid into the organic solvent and separate the fluid into an organic solvent layer and an aqueous layer, and (C) the oxidation step of removing the aqueous layer, concentrating the organic solvent layer, adding nitric acid to the concentrate, and then making the 3,4-methylenedioxymandelic acid react with the nitric acid to form piperonal.

The invention relates to preparation methods of glyoxylic acid L-menthyl alcohol ester and a monohydrate of the glyoxylic acid L-menthyl alcohol ester, and belongs to the technical field of fine chemical industry. The glyoxylic acid L-menthyl alcohol ester is prepared by the following steps: reacting L-menthol with monohalogen or dihalogen acetyl halide or anhydride to generate monohalogen or dihalogen acetic acid L-menthyl alcohol ester; and reacting in the presence of a pro-oxidant to obtain the glyoxylic acid L-menthyl alcohol ester. The monohydrate of the glyoxylic acid L-menthyl alcohol ester is prepared by the following steps: cooling and diluting a reaction solution using monohalogen acetic acid L-menthyl alcohol ester as a raw material; treating by using a dimethylsulfoxide (DMSO) solution of P2O5 and triethylamine to obtain the glyoxylic acid L-menthyl alcohol ester; washing, extracting and concentrating a reaction solution using dihalogen acetic acid L-menthyl alcohol ester as a raw material to obtain the glyoxylic acid L-menthyl alcohol ester; and treating by using sodium hydrogen sulfite and formaldehyde to obtain the monohydrate of the glyoxylic acid L-menthyl alcohol ester. The total yield of the glyoxylic acid L-menthyl alcohol ester synthesized by the technology can reach over 72 percent; the total yield of the monohydrate of the glyoxylic acid L-menthyl alcohol ester can reach over 80 percent; the purity can reach over 99.5 percent; the technical process is simple and convenient; the raw materials are available; the yield is high; the product purity is high; and the process is suitable for industrial production.

The invention relates to a chemical bronze plating liquid of mixing type non-formaldehyde reducer for electronic printing circuit board, wherein the constituents include copper sulfate, EDTA, reducing agent and stabilizing agent, the reducing agent is prepared by mixing two non-formaldehyde reducing agents, which can be hypophosphites, glyoxylic acid and methyl aldehyde addition compound, any two of them can be combined. The advantages of the non-formaldehyde reducing agent include reduced environmental pollution, fast rate of deposition, high copper sedimentary deposit, and good copper deposition compactness.

The invention provides a catalyst used in catalytic oxidation of glyoxal for preparing glyoxylic acid. The catalyst is V2O5/SBA-15, wherein SBA-15 is used as a carrier to load V2O5. According to the preparation method, the SBA-15 is used as the carrier, oxalic acid solution of ammonium metavanadate is used as impregnation precursor, and the catalyst is prepared by using an equivalent-volume impregnation method. Compared with the noble metal catalyst, the V2O5/SBA-15 provided by the invention is low in price, the glyoxylic acid can be obtained from the glyoxal under the action of the V2O5/SBA-15 catalyst without maintaining a certain pH value of a reaction system; only a small amount of oxalic acid is detected from a product; and the catalyst has high glyoxylic acid selectivity and less byproducts.

A chemical copper plating solution for micropore filling. 1 L of the chemical copper plating solution comprises 5-20 g of copper sulfate pentahydrate, 10-50 g of disodium ethylene diamine tetraacetate, 1.0-1.5 g of formaldehyde or glyoxylic acid, 0.001-0.02 g of mercapto heterocyclic compounds, 0.02-0.04 g of polyether with an average molecular weight of 3650, 1.5-3.5 g of NaOH, and the balance of distilled water; the mercapto heterocyclic compounds are 2-mercapto benzimidazole, 2- mercapto benzoxazole, 1-phenyl-5-mercapto-tetrazole or 2-mercapto benzothiazole. By simultaneously adding mercapto heterocyclic compounds and polyether with an average molecular weight of 3650 into the chemical copper plating solution, the invention realizes no cavity, no gap of micropores, and perfect chemicalcopper filling; the chemical copper plating solution is stable; and the deposited copper film has good quality.