5411 results about "Sodium hydroxide" patented technology

A fireproof magnesium oxide board is prepared by mixing the following raw materials, the raw material names and weight parts are as follows: 80-100 parts of magnesium oxide; 20-30 parts of anhydrous magnesium chloride; 10-20 parts of modified expanded vermiculite foaming agent; 20-30 parts of aluminum silicate fiber; 5-10 parts of sawdust; 10-15 parts of fly ash; 8-12 parts of glass magnesium board crushed powder; 1.5-5 parts of non-woven fabric; 10-20 parts of water; wherein the modified expanded vermiculite is prepared by the following steps: (1) Vermiculite is incompletely expanded and calcined; (2) acrylic acid monomer, sodium hydroxide, acrylamide monomer, initiator potassium persulfate, crosslinking aid pentaerythritol polyglycidyl ether, incompletely expanded vermiculite, and water are taken, stirred evenly and ultrasonically dispersed to obtain a first reaction solution, which is placed in a reactor for reaction to obtain a gel material; (3) the gel material is preliminarily crushed and dried, and then further crushed in a ball mill to obtain a fire-resistant expanded vermiculite with water absorption performance.

The invention relates to a comprehensive utilization method of fluosilicic acid containing hydrogen fluoride, which comprises the following steps: 1) reacting a stock solution containing fluosilicic acid with a potassium fluoride raw material, and carrying out solid-liquid separation to obtain potassium fluosilicate and a hydrofluoric acid solution; 2) reacting potassium fluosilicate with a sodium hydroxide raw material, and carrying out solid-liquid separation to obtain a mixture of a potassium fluoride solution, sodium fluoride and silicon dioxide; and returning the potassium fluoride solution to the step 1) to be recycled as a potassium fluoride raw material. According to the scheme, hydrofluoric acid is prepared from fluosilicic acid containing hydrogen fluoride, sodium fluoride and water glass products are produced at the same time, no other byproduct waste is produced, and the raw material utilization rate is high. And meanwhile, the method has the advantages of low raw material cost, low equipment cost and low energy consumption cost, can generate remarkable economic benefits, and is suitable for popularization and application.

According to the invention, biomass rice hull ash and a sodium hydroxide solution are reacted to obtain water glass and carbon mud. And reacting the water glass with CO2 generated by calcining the limestone to produce a white carbon black product and a mixed waste liquid of sodium carbonate and sodium bicarbonate. Meanwhile, quick lime obtained by calcining limestone is digested and then reacts with sodium carbonate and sodium bicarbonate mixed waste liquid to generate a light calcium carbonate product and dilute sodium hydroxide waste liquid. And finally, the dilute sodium hydroxide waste liquid is concentrated and reused for water glass production, so that the waste liquid is recycled, and a complete process closed loop is formed. According to the process method disclosed by the invention, two leading-edge innovative processes, namely production of white carbon black by renewable resource biomass rice hull ash and production of white carbon black by a carbonization method, are organically combined and are coupled with production of light calcium carbonate by a limestone calcination process, so that the problem that a large amount of sodium sulfate-containing wastewater is discharged in a traditional process is solved; meanwhile, the carbon footprint of white carbon black and calcium carbonate products is greatly reduced.

Disclosed in the present invention are a fluorosilicone-modified low-surface-energy antifouling coating and a preparation method therefor. The coating comprises the following components in parts by weight: 11-15 parts of butyl acrylate, 3-4 parts of dodecafluoroheptyl methacrylate, 3-4 parts of vinyl-terminated polydimethylsiloxane, 3-4 parts of 2-hydroxy-4-acryloyloxybenzophenone, 30-38 parts of methyl isobutyl ketone, 0.15-0.25 parts of azobisisobutyronitrile, 0.1-0.2 parts of sodium hydroxide, 2-3 parts of modified titanium dioxide nanoparticles, and 0.5-1.5 parts of 3-aminopropyltriethoxysilane. In the present invention, vinylpentamethyldisiloxane reacts with decamethylcyclopentasiloxane to prepare vinyl-terminated polydimethylsiloxane; a titanium dioxide precursor is mixed with polydopamine nanoparticles for modification to prepare modified titanium dioxide nanoparticles; and then the components above are mixed to prepare the fluorosilicone-modified low-surface-energy antifouling coating. The coating has low surface energy and good adhesion and ultraviolet resistance.

The invention discloses a mixed gas-imitating gel fiber as well as a preparation method and application thereof, and belongs to the technical field of fiber materials. The mixed gas-imitating gel fiber is prepared from the following components: cellulose dispersion liquid, a silane coupling agent and viscose in a mass ratio of (1-3): (0.2-0.8): (5-10), comprising the following steps: adding sodium hydroxide into a cellulose dispersion liquid, adjusting the pH value to be alkaline, adding viscose and a silane coupling agent, and carrying out ultrasonic stirring to prepare a mixed spinning solution; the mixed spinning solution is extruded into a coagulating bath through a wet spinning device to be drafted, wet fibers are obtained, and the mixed gas-imitating gel fibers are obtained after freeze drying. The aerogel fiber disclosed by the invention has low heat conductivity coefficient, high mechanical strength and extreme temperature resistance, can solve the problem that the densification and porosity of a traditional fiber structure are difficult to balance, and effectively expands the application prospect of the aerogel fiber in the fields of cold protection, warm keeping and the like.

The invention relates to a preparation method and application of a Janus structure photo-thermal-piezoelectric hydrogel dressing for infected wound repair, and the preparation method comprises the following steps: respectively dissolving phenylboronic acid grafted methacrylamide gelatin and dopamine grafted hyaluronic acid in deionized water, adding MXene coated CeO2 heterojunction, and ultrasonically dispersing uniformly, so as to obtain the Janus structure photo-thermal-piezoelectric hydrogel dressing for infected wound repair. After mixing, sodium hydroxide is used for adjusting the pH value to alkalescence, and a Janus structure inner layer is formed; respectively dissolving phenylboronic acid grafted gelatin and o-nitrobenzyl alcohol grafted hyaluronic acid in deionized water, adding BaTiO3, ultrasonically dispersing uniformly, and mixing to form a Janus structure outer layer; the Janus structure photo-thermal-piezoelectric hydrogel dressing prepared by the invention has the characteristic of space-time release so as to adapt to the wound repair process, in addition, the Janus structure photo-thermal-piezoelectric hydrogel dressing also has excellent photo-thermal conversion performance, bacteria infecting the wound are killed through photo-thermal heating, physiological electric signals are effectively simulated through the piezoelectric effect, cell behaviors are regulated and controlled, and the Janus structure photo-thermal-piezoelectric hydrogel dressing can be used for wound infection repair.

The invention discloses a method for recovering lithium phosphate from lithium iron phosphate black powder. The method comprises the following steps: mixing black powder recovered from waste lithium iron phosphate batteries with sodium persulfate, and calcining; adding water into the obtained calcined product, dissolving, filtering to obtain water extract A and leaching residues, washing the leaching residues with water, and calcining at high temperature to obtain battery-grade iron phosphate; adding a sodium hydroxide solution into the water extract A, and reacting to obtain a water extract B; adding a trisodium phosphate solution into the water immersion liquid B, fully reacting, performing suction filtration to obtain lithium phosphate and filtrate, and cleaning and drying the lithium phosphate to obtain battery-grade lithium phosphate; and freezing and denitrifying the filtrate to obtain a denitrified solution, and adding the denitrified solution into the sodium hydroxide solution for recycling. The method does not generate wastes, recycles the filtrate in the whole process, theoretically realizes zero loss of the lithium element, prevents the iron element from entering the solution, simplifies the preparation steps of the lithium phosphate, and has the advantages of cost reduction and environmental protection.

The invention provides a continuous purification method of crude acetonitrile, and belongs to the field of acetonitrile purification. The continuous purification method of the crude acetonitrile comprises the following steps: rectification light component removal, membrane separation impurity removal, adsorption impurity removal and rectification purification. According to the continuous purification method of the crude acetonitrile, continuous purification of the crude acetonitrile can be realized, and meanwhile, the problems that new impurities are introduced by side reactions, the rectification efficiency and the rectification stability are influenced by treated products and the device is influenced by over-high alkalinity of the treated secondary rectification liquid due to the fact that sodium hydroxide and formaldehyde are adopted to treat the rectification liquid are avoided; the acetonitrile product with the purity meeting the requirement is prepared by continuously purifying the crude acetonitrile.

The invention belongs to the field of coal gangue resource utilization, and particularly discloses a method for preparing fiber-reinforced coal gangue-based composite functional aerogel. After being activated, the coal gangue is put into an acid leaching solution to be leached, and an aluminum-rich solution is obtained; adding ammonia water into the aluminum-rich solution to adjust the pH to obtain hydroxide precipitate; adding a sodium hydroxide solution into the precipitate to react to obtain a sodium aluminate solution; neutralizing the sodium aluminate solution with hydrochloric acid to obtain an aluminum chloride solution, stirring to obtain aluminum sol, and adding ceramic fibers into the aluminum sol; violently stirring the sol, and adding epoxypropane to obtain wet gel; after aging the wet gel, carrying out surface modification to obtain hydrophobic coal gangue-based aluminum oxide and composite wet gel of the hydrophobic coal gangue-based aluminum oxide; and drying the modified wet gel at normal pressure to obtain the hydrophobic coal gangue-based aluminum oxide and the composite aerogel thereof. Ceramic fibers are introduced as a reinforcing phase, so that the compressive strength and toughness of the material are improved; the composite aerogel is subjected to surface modification, uniform modification is ensured, the contact angle is remarkably increased, the hygroscopicity is reduced, and the stability of the material is enhanced.

The invention relates to hybrid fiber reinforced ultrahigh-performance geopolymer concrete as well as a preparation method and application thereof. Slag, metakaolin and silica fume are used as precursor materials of geopolymer concrete, a sodium hydroxide-water glass solution is adopted to compound an alkali activator, and steel fibers, polyvinyl alcohol fibers and modified glass chopped fibers of different sizes are mixed and doped, so that the brittleness of the geopolymer concrete is remarkably improved, and the service life of the geopolymer concrete is prolonged. The early strength and the high temperature resistance are improved. The hybrid fiber reinforced ultrahigh-performance geopolymer concrete has the characteristics of low carbon emission, ultrahigh strength, high temperature resistance, high durability and the like, and can meet the use of the geopolymer concrete in actual engineering. According to the ultrahigh-performance geopolymer concrete, solid waste resources are utilized at the same time, carbon emission in the concrete production process is reduced, and the ultrahigh-performance geopolymer concrete is environmentally friendly, low in carbon, ultrahigh in strength, easy to prepare and capable of being suitable for complex environmental engineering structures such as tunnels, bridges and high-rise buildings.

The invention provides steam-cured alkali-activated fly ash concrete and a preparation method thereof. The steam-cured alkali-activated fly ash concrete is prepared from the following components in parts by mass: 30 to 40 parts of fly ash, 10 to 15 parts of slag, 10 to 20 parts of water glass, 60 to 80 parts of fine aggregate, 110 to 140 parts of coarse aggregate, 2 to 6 parts of water, 1 to 3 parts of nano SiO2 and 0.1 to 0.5 part of basalt fiber. The content of alkali in the water glass is 8.5-9.5%, and the modulus of the water glass is adjusted to 1.3-1.5 by using sodium hydroxide; the mass ratio of short fibers with the length of 6-12mm to long fibers with the length of 12-24mm in the basalt fibers is (0.5-2): 1. The alkali content, the water glass modulus and steam curing parameters are optimized, and meanwhile, nano SiO2 and basalt fibers are added for synergistic enhancement, so that the concrete has good crack resistance and compressive strength.

The utility model belongs to the field of chemical raw material recovery, and discloses a continuous resourceful treatment system for photovoltaic fluorine-containing wastewater. The system comprises a first-stage fluorine removal unit, a second-stage fluorine removal unit and a silicon removal unit. According to the utility model, the fluorine element is subjected to resource recovery in the form of high-purity calcium fluoride with the purity of more than 95%, meanwhile, the consumption of a fresh sodium hydroxide solution is avoided, the purpose of treating waste with waste is realized, and the residual fluorine quantity in the effluent of the system is reduced to be less than 5mg / L.

The invention belongs to the technical field of desiliconized fly ash, and particularly relates to a high-alumina-silica-ratio material capable of replacing bauxite as well as a preparation method and application of the high-alumina-silica-ratio material. The preparation method comprises the following steps: S1, crushing coal gangue, and grinding the crushed coal gangue until the particle size is less than 40 meshes to obtain a ground material; s2, mixing the ground material and a catalyst according to a weight ratio of 100: (1-2), roasting, and cooling to obtain activated coal gangue; the catalyst comprises sodium carbonate, calcium oxide and aluminum oxide in a weight ratio of 1: (0.3-0.5): (1.4-1.6); s3, mixing a sodium hydroxide solution, the activated coal gangue and a surfactant, and reacting at 50-90 DEG C for 1-6 hours to obtain desiliconized slurry; and S4, filtering the desiliconized slurry, collecting a solid phase, washing with water, and drying to obtain desiliconized fly ash, namely the high alumina-silica ratio material capable of replacing bauxite. The method is high in desiliconization rate.

The present invention generally relates to a system for producing activated carbon from cow dung. The process begins with a drying and washing unit to pre-treat the raw material. Dried cow dung is then milled and sieved to a specific particle size. A second drying step prepares the sieved material for carbonization in a nitrogen atmosphere. The resulting carbonized material undergoes chemical activation using a sodium hydroxide solution. Subsequent pyrolysis in a nitrogen environment further develops the pore structure of the activated carbon. The pyrolyzed material is then washed with hydrochloric acid to remove impurities. A final drying step yields the desired activated carbon product, which is then crushed. This system provides a controlled and efficient method for converting cow dung into valuable activated carbon, offering a sustainable waste management solution and a source of high-quality material for various applications.

The invention discloses a high-temperature-resistant lignite resin and a preparation method thereof, and belongs to the field of drilling fluids, and the preparation method comprises the following steps: obtaining and preparing an extracting solution containing humic acid from lignite; adding hydrochloric acid into the extracting solution, separating, filtering and precipitating, dissolving the precipitating in a sodium hydroxide solution to obtain a humic acid solution, adding formaldehyde and sodium pyrosulfite into the humic acid solution, preheating to 80 DEG C, adding the extracting solution, heating to 110-130 DEG C, continuously stirring, reacting for 1-3 hours, and cooling to 60 DEG C or below to obtain a reaction product; transferring a reaction product to a neutralizing tank, dropwise adding a NaOH solution, adjusting the pH value to 10-11, and controlling the temperature below 55 DEG C; the mass ratio of the dry basis mass of sulfonated humic acid to ECH is 1: (0.05-0.15), the temperature is kept at 45-55 DEG C, the stirring speed is 400-600 rpm, and the reaction is performed for 2-4 hours; meanwhile, a NaOH solution is continuously added, and the pH is kept at 10-11. Adjusting the pH value of the reaction liquid to 7-8 by using dilute HCl, and terminating the reaction; and obtaining a resin product.

The invention discloses a preparation method of a green high-performance industrial solid waste-based grouting material, and belongs to the field of industrial solid waste treatment and grouting reinforcement, and the preparation method comprises the following steps: performing dry mixing on red mud, slag, fly ash and cement which are dried and ground to specified fineness according to a preset proportion to obtain a uniform dry material; preparing a composite alkali activator from water glass and sodium hydroxide according to a molar ratio of 3: 1, premixing the composite alkali activator with water, and adding the dry material in batches to form wet slurry; and carrying out high-speed shearing and stirring on the wet slurry, and standing and curing to obtain the solid waste-based slurry which can be directly used for grouting. The method obviously improves the solid waste utilization rate, relieves the environmental pressure, and is suitable for related projects such as stratum settlement control, gushing water blocking, mine roadway broken rock mass supporting and underground cavity concrete lining crack repairing in tunnel and subway projects.

The invention provides loofah sponge nanocellulose hydrogel and a preparation method thereof.The preparation method comprises the following steps that anhydrous citric acid, choline chloride and water are mixed to react, and a ternary eutectic solvent is obtained; dispersing loofah sponge purified cellulose in a ternary eutectic solvent, washing and filtering a product to be neutral, dispersing the product in water, and performing ultrasonic treatment to obtain loofah sponge nanocellulose turbid liquid; dissolving sodium lignin sulfonate and lithium chloride in a sodium hydroxide solution to obtain a precursor solution; mixing the loofah sponge nanocellulose suspension with water, polyacrylamide, ammonium persulfate and N, N-methylene bisacrylamide, pouring the precursor solution into the loofah sponge nanocellulose suspension, uniformly stirring the mixture, pouring the mixture into a mold, and sealing the mold; and forming to obtain the loofah sponge nanocellulose hydrogel. The invention also provides an application of the hydrogel. The hydrogel disclosed by the invention has excellent biocompatibility, mechanical property and conductivity, has a wide application prospect in the field of flexible electronics, and is simple in preparation process, low in cost, green and environment-friendly.

The invention relates to the technical field of vanadium pentoxide preparation, and particularly discloses a preparation method of high-purity vanadium pentoxide, which comprises the following steps: S1, vanadium slag pretreatment: carrying out microwave activation on vanadium slag, and then carrying out ball milling and roasting to obtain clinker; the sulfuric acid-oxalic acid composite acid and the clinker are mixed and leached, the pH is adjusted after leaching is completed, and vanadium-containing leachate is obtained through filtering; s3, vanadium enrichment: heating the vanadium-containing leachate, adding a sodium carbonate solution while stirring, adjusting the pH value, preserving heat and curing, and then carrying out hot filtration to obtain vanadium-rich filter residues; s4, vanadium purification: mixing the vanadium-rich filter residues with a sodium hydroxide solution, stirring, introducing compressed air while stirring, and carrying out hot filtration after the reaction is finished, so as to obtain vanadium-rich filtrate; and S5, calcining: carrying out two-stage calcining on the ammonium metavanadate precursor to obtain high-purity V2O5. The preparation method is high in vanadium recovery rate, and the purity of the prepared V2O5 is 99% or above.

The invention discloses an insulating tape for a new energy battery and a preparation method of the insulating tape, and relates to the technical field of new energy battery assemblies. The insulating tape for the new energy battery is prepared by coating pretreated glass fiber cloth with a coating, the coating is prepared from the following raw materials in parts by weight: 15 to 20 parts of modified polyimide resin, 2 to 4 parts of epoxy resin E-51, 71 to 77 parts of an ethanol / butanone mixed solvent, 3 to 5 parts of modified nano silicon dioxide, 0.2 to 0.4 part of a silane coupling agent KH-550, 0.1 to 0.3 part of polydimethylsiloxane, 0.1 to 0.2 part of paraffin-based mineral oil and 0.3 to 0.5 part of triethylene tetramine. The glass fiber cloth pretreatment material comprises deionized water and a 5%-8% sodium hydroxide solution. The insulating adhesive tape for the new energy battery contains the modified polyimide resin, so that the high temperature resistance and electrolyte resistance of the adhesive tape can be enhanced, the insulativity is improved, and the modified nano silicon dioxide is good in dispersity. The preparation process is fine, the glass fiber cloth is fully pretreated, the preparation process is standard, and the use requirements of new energy batteries can be met.

The invention discloses a carbon / nano zero-valent iron composite material based on coal gasification slag and a preparation method of the carbon / nano zero-valent iron composite material. The method comprises the following steps: performing component separation on the coal gasification slag to obtain an iron-rich residual carbon component, mixing and grinding the iron-rich residual carbon component and sodium hydroxide according to a specific mass ratio, performing high-temperature calcination treatment in a nitrogen protective atmosphere, and performing hydrothermal activation reaction, solid-liquid separation, washing and drying to obtain the carbon / nano zero-valent iron composite material. The material shows excellent hexavalent chromium removal performance, can realize efficient removal of Cr (VI) in water within 5 minutes (the removal rate reaches 78.9%), and has remarkable structural stability. Synergistic activation of the endogenous iron-carbon components in the industrial solid waste is creatively achieved, a green and environment-friendly novel functional material solution is provided for heavy metal pollution treatment, and the method has important environmental benefits and industrial application value.

Adhesive compositions including a multivalent metal salt, an multidentate acidic organic compound, and an aqueous medium are disclosed. The multivalent metal salt and multidentate acidic organic compound can include, as a mixture, a carbonate salt and / or carbonic acid. The aqueous medium can include pH adjusting agent such as sodium hydroxide. The adhesive composition, upon curing, can have a porosity of 10-50%. The adhesive composition, upon curing, can include a plurality of pores. The adhesive composition can be porous, and upon curing can have a plurality of pores having a pore size of between 20 μm to 200 μm. Methods of producing the adhesive composition are disclosed. Methods of using the adhesive composition are further disclosed.

The invention relates to the technical field of composite catalyst materials, in particular to a ferrocobalt bimetal hydroxide / BCN composite material and a preparation method and application thereof.The preparation method comprises the steps that cobalt nitrate and ferric nitrate are used for preparing a metal salt solution, sodium carbonate and sodium hydroxide are used for preparing a precipitant solution, a B-doped carbon nitride BCN material is added into the metal salt solution to form a uniform suspension, and the suspension is dried to obtain the ferrocobalt bimetal hydroxide / BCN composite material; dropwise adding the precipitant solution into the suspension to obtain a precursor solution, performing hydrothermal reaction on the precursor solution, and performing centrifugal impurity removal and drying to construct a heterostructure between layered double hydroxide and BCN in situ to obtain the Co-Fe LDH-coated BCN composite material. Through boron doping and heterostructure construction, the charge separation capacity of graphite carbon nitride is enhanced, the electron migration efficiency is improved through a heterointerface structure, the metal ion release amount and the cycle stability are controlled, and the catalytic performance is remarkably improved.

The invention provides a preparation method and application of polypyrrole graphene oxide hydrogel with an anisotropic structure. The preparation method comprises the following steps: adding sodium hydroxide and urea into water according to a certain proportion, adding microcrystalline cellulose into an alkali urea solution, uniformly stirring, and repeatedly freezing and thawing to obtain a cellulose solution; adding graphene oxide into water for cell disruption and dispersion to obtain a uniform graphene oxide solution; adding the graphene oxide solution into the cellulose solution, then adding an epichlorohydrin cross-linking agent, and carrying out stirring treatment, centrifugation and low-temperature standing to form gel; and pre-stretching the hydrogel to a certain length, immersing the hydrogel into a dilute sulphuric acid solution, taking out the hydrogel, adding pyrrole, carrying out polymerization growth in a closed environment, taking out the hydrogel, soaking the hydrogel in water, and washing the hydrogel to obtain the anisotropic polypyrrole graphene oxide hydrogel. The anisotropic polypyrrole graphene oxide cellulose hydrogel disclosed by the invention has excellent solar photo-thermal water evaporation performance and also has excellent thermal management performance.

The invention provides a synthesis method of a bromide ion adsorbent for salt lake bromine extraction, and belongs to the technical field of adsorbent preparation, a mixed solution of strontium chloride and manganese chloride and a mixed solution of sodium phosphate and sodium hydroxide are subjected to precipitation reaction to obtain A-Sr4Mn6 (PO4) 6 (OH) 2; the preparation method comprises the following steps: reacting A-Sr4Mn6 (PO4) 6 (OH) 2 with a sodium bromide solution to obtain B-Sr4Mn6 (PO4) 6Br2; and reacting the B-Sr4Mn6 (PO4) 6Br2 with a sodium hydroxide solution to obtain Sr4Mn6 (PO4) 6 (OH) 2, namely the bromide ion adsorbent. The prepared adsorbent can selectively adsorb bromide ions from high-salt brine, and has the advantages of high adsorption capacity, high selectivity, high recyclability and the like; in brine with extremely high chloride ion concentration, low-concentration bromide ions can be selectively adsorbed without being influenced by high-concentration chloride ions; in a high-salt water body, the adsorption capacity on bromide ions is higher; the selective adsorption separation of the chloride ions and the bromide ions is realized.

The invention discloses a molasses-based biomass sulfonated carbon catalyst preparation method, which comprises: grinding and mixing solid molasses and sodium hydroxide, calcining at 500-650 DEG C in an inert atmosphere to obtain activated carbon, and carrying out a sulfonation reaction on the activated carbon and concentrated sulfuric acid to obtain the catalyst. According to the method, by-product molasses in the sugar industry is taken as a raw material, a carbon source is rich in source, low in price and easy to obtain, the process is simple, the catalyst has relatively high specific surface area and conversion rate, the by-product can be utilized in a high-valued manner, and the method has certain industrial practical value.

The invention discloses an optical-grade PET release film and a preparation method and application thereof, and belongs to the technical field of PET release liners.The preparation method comprises the steps that organic silicon resin, polyacrylate and functional silicone oil serve as raw materials, hexadecafluorophthalocyanine copper serves as a catalyst, sodium hydroxide provides hydroxyl anions, and hydroxyl-containing fluorinated hydroxyaniline is obtained; amino groups on the surface of fluorinated hydroxyaniline react with carboxyl groups of graphene oxide and are grafted on the surface of graphene oxide, then hydroxyl groups in the fluorinated hydroxyaniline and carboxyl groups of acrylic acid are subjected to esterification reaction under the action of a catalyst, so that acrylic acid is grafted on fluorinated modified graphene oxide, and the fluorinated modified graphene oxide is obtained. Therefore, hydroxyl and epoxy functional groups on the surface of the graphene oxide are consumed, hindering of electron transmission is reduced, the conductivity of the release film is improved, and the antistatic requirement of the release film is met.

The invention relates to the technical field of functional polymer composite materials, and provides diatomite modified composite super absorbent and rapid absorbent resin and a preparation method thereof. The preparation raw materials of the diatomite modified composite high-water-absorption and rapid-water-absorption resin provided by the invention comprise acrylic acid, acrylamide, sodium hydroxide, N, N '-methylene bisacrylamide, ammonium persulfate and modified diatomite. The diatomite is modified by the silane coupling agent, the agglomeration problem of the diatomite is solved, the compatibility with organic monomers is improved, and the modified diatomite, acrylic acid and acrylamide are utilized to construct an organic-inorganic synergistic three-dimensional porous network structure, so that the resin has ultrahigh water absorption rate, rapid water absorption performance and good water retention stability. Meanwhile, the preparation method disclosed by the invention does not need nitrogen protection, has the advantages of simple process, controllable raw material cost and easiness in industrial mass production, and is suitable for multiple fields such as water-saving agriculture, soil moisturizing, landscaping and the like.

The invention discloses a method for preparing MHP by cyclic utilization of manganese precipitation post-solution, which comprises the following steps: mixing sodium hydroxide, magnesium oxide and manganese precipitation post-solution to obtain compound alkali slurry; mixing the laterite-nickel ore liquid subjected to iron and aluminum removal with the compound alkali slurry, and carrying out precipitation reaction to obtain MHP slurry; carrying out thickening treatment on the MHP slurry to obtain a dense underflow; filtering the dense underflow to obtain an MHP filter cake and filtrate; directly carrying out manganese precipitation treatment on the filtrate to obtain manganese slag and manganese-precipitated liquid; and reusing the manganese-deposited liquid in the preparation of the compound alkali slurry. According to the invention, a sodium hydroxide and magnesium oxide compounded system is utilized, so that the MHP precipitation process can be simplified to one step. And meanwhile, part of the manganese-deposited liquid is recycled to the alkali preparation process, so that the wastewater treatment cost is reduced, and the magnesium content in the MHP can be reduced by controlling the circulation amount of the manganese-deposited liquid, and the cost of preparing crystals through subsequent fine extraction of the MHP is reduced.

The invention relates to the field of concrete, and particularly discloses anti-crack concrete and a preparation method thereof. The anti-crack concrete is prepared from the following raw material components in parts by weight: 400 parts of cement; 1000 to 1100 parts of coarse aggregate; 730 to 800 parts of fine aggregate; 40 to 50 parts of modified rubber particles; 20 to 25 parts of basalt fiber; 5-6 parts of a water reducing agent; 1.3 to 1.5 parts of SAP resin; 0.015 to 0.02 part of an air entraining agent; 130 to 140 parts of water; a modifier used for preparing the modified rubber particles is sodium hydroxide and a silane coupling agent. The anti-crack concrete disclosed by the invention has good anti-crack capability, the total cracking area does not exceed 35mm < 2 > / m < 2 >, and the 28d compressive strength is not lower than 40MPa.

The invention relates to the technical field of lithium ion battery fire extinguishing agents, in particular to a lithium ion battery fire extinguishing agent and a preparation process. The preparation process comprises the following steps: S1, biomass pretreatment: mixing 40-50 parts of chitin powder with a 2wt% sodium hydroxide solution according to a mass volume ratio of 1: 10, stirring at 60 DEG C for 1-2 hours, and centrifuging and freeze-drying to obtain a chitin crude product; dispersing the chitin crude product in deionized water, and carrying out ultrasonic treatment to obtain a cellulose suspension with the solid content of 1%; s2, cellulose modification: adding 15-20 parts of povidone into the cellulose suspension, and mixing and stirring at 60 DEG C for 1 hour to obtain a modified cellulose suspension; s3, introducing nano silicon dioxide; s4, preparing modified gel; and S5, cross-linking and drying.