798 results about "Phosphonium salt" patented technology

The present invention relates to one kind of high activity catalyst for catalyzing and activating CO2 to react with alkane epoxide to synthesize polycarbonate. The high activity catalyst is tetradentate Schiff base metal complex with double function, i. e., it has both electrophlic center originated from the metal ion in the complex and nucleophilic center originated from the quaternary ammonium salt or quaternary phosphonium salt connected to the benzene ring in the complex. The catalyst can catalyze the reaction of CO2 and alkane epoxide effectively to prepare polycarbonate.

A biodegradable resin composition and an object molded or formed from the composition. The resin composition comprises: 100 parts by weight of a biodegradable polyester resin comprising not smaller than 50% by weight of polylactic acid having a melting point of not lower than 160° C., the biodegradable polyester resin having a melt flow rate of 0.1 to 50 g/10 min as measured under a load of 21.2 N at 190° C.; and 0.1 to 20 parts by weight of a phyllosilicate containing a primary, secondary or tertiary amine salt, a quaternary ammonium salt or a phosphonium salt ionically bonded between layers thereof.

A process for the preparation of alkylene glycols by reacting an alkylene oxide with water in the presence of at least one ionic composition of a quaternary phosphonium cation of the general formula R1R2R3R4P+Whereby each of R1, R2, R3 and R4, independently, may be an alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl group having from 1 to 10 carbon atoms, each of which may carry one or more substituents, or be attached to a polymer and an anion other than metalate or halogen.

Provided are a solid catalyst which gives a cyclic carbonate at a high yield and a high selectivity, which is stable and which may be readily separated after reaction; and a method of industrially advantageous, inexpensive and safe production of a cyclic carbonate by the use of the catalyst. The catalyst contains an inorganic solid substance having a surface modified with an ionic substance containing a Group 15 element; or contains an ionic substance containing a Group 15 element, and an inorganic solid substance. The modifying group for surface modification of an inorganic solid substance is an ionic substance containing a Group 15 element. The ionic substance containing a Group 15 element is at least one substance selected from organic phosphonium salts, organic ammonium salts, organic arsonium salts and organic antimonium salts.

Water-fastness in aqueous ink-jet inks containing water-soluble dyes is achieved by using a specific ionic species having a charge opposite to that on the dye molecule. Anionic dyes typically contain sulfonate (or carboxylate) anionic groups. Using at least one specific ionic species of opposite charge, specifically, phosphonium salts, causes the colorant components to "crash" or precipitate out of the water-based ink onto the print medium due to the formation of a suitable charge complex between the ionic parts of the dye and the opposite charge of the counter-ion species. Other positively charged salts, such as quaternary ammonium salts, carbonium salts, iodonium salts, sulfonium salts, and pyrillium salts may be used to improve aqueous dispersion stability and thus printability. Such additional cationic salt partially replaces the phosphonium salt(s). Alternatively, certain surfactants, such as aromatic ethoxylates, polyethylene oxide ethers, or polypropylene oxide ethers may be used to improve print quality.

A composition for removing metals from masrolar D contains chelating agent, precipitant, optional surfactant and demulsifier, and at least one of mono-alcohol or biol polymer, quaternary ammonium salt, quaternary phosphonium salt and crown ether.

A catalyst system that may reduce polymeric fouling may include at least one titanate compound, at least one aluminum compound, and an antifouling agent. The antifouling agent may be chosen from one or more of a phosphonium or phosphonium salt; a sulfonate or a sulfonate salt; a sulfonium or sulfonium salt; an ester including a cyclic moiety; an anhydride; a polyether; and a long-chained amine-capped compound. The catalyst system may further include a non-polymeric ether compound.

A flame resistant textile is provided. The textile is a sateen weave fabric containing cellulosic fibers, where the sateen weave fabric has a thickness of at least 19.5 mils, a thickness of at least 25 mils after 3 home washes at 120° F., an air permeability of at least 60 cfm, and a weight of less than about 7 oz/yd². The sateen weave fabric also contains a treatment, where the treatment contains a tetramethylhydroxy phosphonium salt or its condensate and chemical selected from the group consisting of urea, guanidines, guanyl urea, glycoluril, and polyamines. When the sateen weave fabric to which the treatment has been applied has been heat-cured and oxidized at least a portion of the cellulosic fibers have a pentavalent phosphate compound polymerized therein. The method for producing the flame resistant textile is also provided.

The invention provides a mineralized collagen artificial periosteum. The artificial periosteum is prepared from mineralized collagen in which nano calcium phosphonium salt and collagen fibers are arranged in order, has substances and micro and macro structures, which are the same as a natural periosteum, also has a favorable mechanical property and biodegradation properties, and can be used for replacing and restoring the periosteum. The artificial periosteum can limit other bone grafting materials in the bone fracture parts in the restoring process to prevent the bone grafting materials from coming out and muscles, fat and other tissues from being extruded into the bone fracture parts, so that the restoring effect cannot be influenced. The pore structure of the artificial periosteum facilitates revascularization and conveying of nutrient substances, thereby benefiting restoring of bone fractures. Since the mineralized collagen artificial periosteum consists of nano calcium phosphonium salt and the collagen fibers, the artificial periosteum can be gradually degraded along with regeneration of bone tissues and the periosteums in the body. The invention also provides a preparation method of the artificial periosteum.

The present invention relates to polycarbonate compositions comprising

• • A) from 10 to 99 parts by weight, in each ease based on the sum of components A+B+C, of aromatic polycarbonate and/or aromatic polyester carbonate,
  • B) from 1 to 35 parts by weight, in each case based on the sum of components A+B+C, of rubber-modified graft polymer of
    • B.1 from 5 to 95 wt. % of at least one vinyl monomer on
    • B.2 from 95 to 5 wt. % of one or more graft bases having a glass transition temperature <10° C.,
  • C) from 0 to 40 parts by weight, in each case based on the sum of components A+B+C, of vinyl (co)polymer and/or polyalkylene terephthalate,
  • D) from 0 to 50 parts by weight, in each case based on the sum of components A+B+C, of phosphorus-containing flameproofing agent,
  • E) from 0 to 1.0 part by weight, in each case based on the sum of components A+B+C, of acidic additives, and
  • F) from 0 to 50 parts by weight, in each case based on the sum of components A+B+C, of additives,
  • wherein component B is obtainable by reacting component B.1 with the graft base B.2 by means of emulsion polymerization, with the proviso that in those compositions that are free of components D) and E), the graft polymer dispersion in the spray drying or in the precipitation has a pH value of less than 7,
  • characterized in that there are used in the graft reaction from 0.1 to 5 parts by weight (based on the sum of the parts by weight of the monomers B.1 and of the graft base B.2 that are used=100 parts by weight) of at least one emulsifier selected from the group consisting of alkali, alkaline earth, ammonium and phosphonium salts of a saturated fatty acid having from 10 to 50 carbon atoms, wherein the emulsifier or emulsifiers remains or remain in component B,

and also to a process for the preparation of these polycarbonate compositions and to the use of the polycarbonate compositions in the production of molded bodies, and to the molded bodies themselves.

The invention discloses a method for improving the performance of a large-power high-light-transmittance LED packaging epoxy resin composition. The composition is composed of a component A and a component B. The composition has excellent UV resistance and yellowing resistance. The composition is advantaged in good manufacturability, good light transmittance, and low light failure. The composition can be used in white-light and blue-light LED packaging. Compared with organosilicon, the composition is advantaged in low price. Innovatively, the component A of the composition is composed of liquid cycloaliphatic epoxy resin, solid cycloaliphatic epoxy resin, and hydrogenated bisphenol A epoxy resin. An anti-forming agent, a color complementary agent, and a dispensing agent are adopted in auxiliary. The system does not contain benzene ring, and yellowing is not easy to occur. The component B is prepared through the steps that: methyl hexahydrophthalic anhydride and hexahydrophthalic anhydride are subjected to a polymerization reaction with promoting agents or cationic initiators such as quaternary phosphonium salt, quaternary ammonium salts, DBU salt, and imidazole; with added phosphate antioxidant, a thermal yellowing capacity is improved. With the applications of an ultraviolet absorber and a light stabilizer, a UV yellowing resisting effect is further improved.

The invention discloses a method for preparing poly(monothiocarbonate). According to the method, carbon oxysulfide and oxygen-containing monomers are used as raw materials; a catalysis system consisting of initiators and Lewis acid is used; after the bulk polymerization or solution polymerization, poly(monothiocarbonate) is obtained; the oxygen-containing monomers are selected from at least one kind of materials of epoxy compounds, oxetane and 3-substituted oxetane; the initiators are selected from quaternary ammonium salt, quaternary phosphonium salts or organic alkali. The preparation method of synthesizing the poly(monothiocarbonate) through anion ring-opening polymerization by using a catalytic system formed by at least one kind of materials from quaternary ammonium salt, quaternary phosphonium salts or organic alkali, and the Lewis acid; the poly(monothiocarbonate) with the specific chain structures can be obtained through preparation. The catalysis system can be obtained only through compounding; the metal residue and color residue problems do not exist.

The invention discloses a high polymer quaternary phosphonium salt antibacterial material and a preparation method thereof. The high polymer quaternary phosphonium salt antibacterial material is prepared by bonding halogenacylhalide type monomers onto macromolecules of an ethylene-vinyl alcohol copolymer (EVOH) through grafting reaction and further performing quaternary phosphonium reaction with trialkylphosphine. The high polymer quaternary phosphonium salt antibacterial material disclosed by the invention has the advantages of broad-spectrum, high-efficient and lasting antibacterial function and good safety, can be shaped and processed into products with the antibacterial function alone, and mixed with polyethylene, polypropylene and other non-polar resin and other types of resin for being shaped and processed into the products with the antibacterial function, and further has broad application prospects. The sterilization efficiency of the high polymer quaternary phosphonium salt antibacterial material prepared by the preparation method disclosed by the invention against escherichia coli, staphylococcus aureus and a variety of bacteria is more than 99%, and the mildew-resistant grade against aspergillus niger, aspergillus terreus and a variety of mildew is 1-0 grade.

A method for reducing the effects of biological contamination in a hydrocarbon-containing system comprising the steps of continuously adding a formulation comprising tris(hydroxymethyl)phosphine or a tetrakis(hydroxymethyl)phosphonium salt to the system for one day or more; monitoring the efficacy of the continuous treatment by an assessment of the extent to which there is any effect on the environment that is attributable to metabolic activity of active microbes present in the system; wherein the tris(hydroxymethyl)phosphine or tetrakis(hydroxymethyl)phosphonium salt is added at a concentration of from 1 to 30 ppm based on the total volume of aqueous fluid added to the system, and wherein the formulation is added to the system at a stage to minimize incompatibility with any other chemicals that are added to the aqueous fluid. The treatment disrupts the microbial activity of active microbes in the hydrocarbon-containing system and can prevent or reduce detrimental effects arising from the presence of active microbes in the system.

A method for the manufacture of a polyetherimide composition includes catalyzing the reaction of a dianhydride and an organic diamine with a catalyst selected from guanadinium salts, pyridinium salts, imidazolium salts, tetra(C_6-24)aryl ammonium salts, tetra(C_7-24 arylalkylene)ammonium salts, dialkyl heterocycloaliphatic ammonium salts, bis-alkyl quaternary ammonium salts, (C_7-24arylalkylene)(C_1-16alkyl)phosphonium salts, (C_6-24aryl)(C_1-16alkyl)phosphonium salts, phosphazenium salts and combinations thereof, optionally in the presence of a solvent.

The invention provides semi-clathrate hydrate compositions formed from water, a semi-clathrate hydrate forming compound and a gas. The semi-clathrate hydrate forming compounds can be ammonium salts, sulphonium salts, phosphonium salts or amines. The semi-clathrate hydrate compositions can be used to store gases including hydrogen, methane and carbon dioxide. Methods of manufacture of the compositions and their uses in energy storage and generation, and for the separation of gases are also described.

The invention provides a vulcanized rubber laminate obtained by firmly bonding an unvulcanized epichlorohydrin rubber layer and an organic peroxide-containing fluororubber layer. The laminate is obtained by thermal adhesion a layer of an unvulcanized epichlorohydrin rubber composition to a layer of an unvulcanized fluororubber composition. The epichlorohydrin rubber composition comprises 1) an unvulcanized epichlorohydrin rubber containing 3 to 15 mol % of allyl glycidyl ether unit, 2) quinoxaline-based vulcanizing agents, mercaptotriazine-based vulcanizing agents or bisphenol-based vulcanizing agents, and 3) 1,8-diazabicyclo(5,4,0)undecene-7 salts, 1,5-diazabicyclo(4,3,0)nonene-5 salts, quaternary ammonium salts, quaternary phosphonium salts, basic white carbons or an alkaline metal salt of higher fatty acid the fluororubber composition comprises an fluororubber and an organic peroxide-based vulcanizing agent.

The present invention provides an electrolyte composition used in a charge storage device, which comprises an ionic liquid that has high ionic conductivity and is highly safe with no risks of inflammation and the like. It is an electrolyte composition used in a charge storage device, which comprises a quaternary phosphonium salt ionic liquid represented by general formula (1) as described below. The viscosity at 25° C. of this ionic liquid is preferably 200 mPa·sec or less. In the general formula (1), it is preferable that the alkoxyalkyl group be a methoxymethyl group and that all the alkyl groups be ethyl groups.

wherein R₁ represents a linear or branched alkyl group containing 1 to 3 carbon atoms; R₂ represents a methyl group or an ethyl group; n represents an integer between 1 and 3; and X represents N(SO₂CF₃)₂.

The invention relates to a preparation method of a flame resistance core-shell type aqueous acrylic ester resin coating. Water, emulsifiers, methacrylic acid and a monomer A are added and emulsified, an initiator starts to be added dropwise for 1-3 hours when the temperature is 75 DEG C, reaction is carried out for 3-5 hours with the temperature kept at 75 DEG C, quaternary phosphonium salt is added to react for 1-3 hours, and core layer emulsion is obtained; a monomer B and an initiator are added into the core layer emulsion dropwise for 1-3 hours at the same time and react for 2 hours with the temperature kept at 75-85 DEG C, borane is added dropwise, reaction is carried out for 1-3 hours with the temperature kept at 75-85 DEG C, then cross-linking agents are added dropwise, reaction is carried out for 1-2 hours with the temperature kept at 75-85 DEG C, the temperature is decreased to be 50 DEG C, an emulsifier is added into a reaction system, the reaction time is 30 minutes, ammonium hydroxide is added to adjust the pH value to be 7-8, and the flame resistance core-shell type aqueous acrylic ester resin coating is obtained. The flame resistance of obtained flame resistance core-shell type aqueous acrylic ester resin can be greatly improved, and the defect that traditional acrylic ester resin is sticky at high temperature and crisp at low temperature is also overcome.