The invention relates to a heavy
metal waste liquid electro-deposition cyclic utilization treatment method which comprises the following steps: establishing an interface charge migration model based on waste liquid
ion composition and a polarization curve, and quantifying migration impedance characteristics of Cu < 2 + >, Zn < 2 + > and Ni < 2 + >. Through progressive potential scanning, ions are subjected to gradient deposition according to migration resistance,
preferential adsorption and reduction are induced through
pulse frequency adjustment, and a
metal reduction potential window is matched. A movable
electrode structure is adopted to transversely move a deposition reaction area on a microscale, and reverse high-frequency pulses are applied in a deposition intermittent period or an
electrode migration period to trigger stripping and
crystallization of a
metal deposition layer and removal of a
passivation layer. And continuously depositing the
electrode to form a dynamic circulation
closed loop. A micro
conductivity /
ion selective electrode
sensor array is integrated, and the concentration and intensity distribution of residual heavy metal ions in the waste liquid are evaluated. The concentration mode is switched according to the sensing result, and the optimized concentration reaches a redeposition threshold value. The AI
scheduling system controls the
reflux proportion of the concentrated solution, ensures the concentration matching
reflux, improves the treatment efficiency and reduces the waste.