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74 results about "Cation composition" patented technology

Method for preparing liquid alkylated diphenylamine compound by ionic liquid catalyst

The invention discloses a method for preparing liquid alkylated diphenylamine compound by an ionic liquid catalyst. Alkylate reaction is carried out on diphenylamine and alkene under the action of the catalyst; the catalyst is separated and recovered after the reaction finishes; steps of washing, pressure distillation for removing excessive alkene and water post treatment are carried out on the product; and then light yellow liquid alkylated diphenylamine compound is obtained. Pressure of the alkylated reaction is 1 atmospheric pressure and temperature thereof is 80-150 DEG C. The catalyst is ironic liquid catalyst, which is composed of metal halogenide anions and quaternary cations. Dioctyl diphenylamine content in liquid alkylated diphenylamine compound is less than 25% wt and diphenylamine content therein is less than 1%wt. Residual diphenylamine content in the obtained product is less than 1%wt and the ioctyl diphenylamine in the product is less than 25%wt; color and luster of the product is light and stable. The invention has simple and easy post-processing, does not generate a large amount of aluminiferous waste water and is easy to carry out industrialized promotion; in addition, the invention has high catalyst efficiency, repeatable use and easy separation from the product.
Owner:JIANGSU UNIV OF SCI & TECH

Metal coordination polycation gene vector and preparation method and application thereof

The invention discloses a metal coordination polycation gene vector. The metal coordination polycation gene vector consists of a coordinated metal, a coordinated unit, a stimuli-responsive unit and polycations, and the structural general formula of the metal coordination polycation gene vector is as shown in the specification, wherein M represents the coordinated metal; a dimethyl pyridylamine component represents the coordinated unit; a disulfide bond component represents the stimuli-responsive unit; a ball represents the polycations; n represents the quantity of metal ion ligands grafted by one polycation molecule, n is 1 to 200; and the metal coordination polycation gene vector is used for non-virus gene vectors. The metal coordination polycation gene vector has the advantage that the metal ion ligands containing stimuli-responsive radicals are modified on the polycations, so that the DNA binding capacity of the polycations and the acting force with cytomembranes are greatly improved; after the compound enters cells, the metal ion ligands and the polycations are disconnected, DNAs are released and expressed so as to show extremely high transfection efficiency, so that the application of the polycations in the aspect of the non-virus gene vectors is greatly expanded due to metal coordination monomers in the invention.
Owner:NANKAI UNIV
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