233 results about "Hexafluorophosphoric acid" patented technology

The room temperature ionic liquid containing unsaturated double bond has the general expressino of A+B-, where A+ contains R1 being hydroxyl with 1-4 carbon atoms and R2 containing 2-20 carbon atoms and at least one double bond; and B- is one of anions, including chlorate radical, bromate radical, iodate radical, acetate radical, sulfate radical, nitrate radical, tetrafluorobromate radical, etc. Its preparation is to mixture and react olefin halide R1X and N-alkyl imidazole to obtain ionic liquid dialkyl imidazolium halide. The present invention also relates to the application of the ionic liquid in dissolving cellulose and preparing cellulose derivative.

Use is made, for selectively hydrogenating the olefinic double bonds of block copolymers, at least one block of which comprises olefinic double bonds, using a catalyst based on a metal from Group VIII in a medium comprising an organic solvent for the copolymer and an ionic liquid as solvent for the catalyst, of a water-immiscible ionic liquid, preferably an ionic liquid for which the anion is the hexafluorophosphate anion and the cation is the 1-butyl-3-methylimidazolium (bmim⁺) or 1-ethyl-3-methylimidazolium (emim⁺) cation.

Applied to poly(styrene)-b-poly(butadiene)-b-poly(methyl methacrylate) block copolymers, the poly(butadiene) block of which predominantly possesses a 1,4-microstructure, this process results in copolymers for which the degree of hydrogenation is at least equal to 50% and which exhibit a melting point of greater than 30 °C.

The invention discloses an iridium complex phosphor material taking a phthalazine derivative as a ligand. The structure of the material is shown as formulas (I) and (II), wherein Ar represents aryl, substituted aryl, heterocycle aryl and substituted heterocycle aryl; R can be one of a halogen atom, alkyl, substituted alkyl, alkoxyl, aryloxy, an alkylthio group, arylthio, aromatic amino, aliphatic amino or a heterocyclic substituent; L^Y can be one of N-COOH, 8-hydroxyquinoline, beta-diketone, N^NH and the like; N^N can be bipyridyl, diquinoline, 1,10-phenanthroline, a derivative of the 1,10-phenanthroline and the like; and Z can be hexafluorophosphate and perchlorate. A dicyclic or ionic iridium complex phosphorescent electroluminescent device taking the phthalazine derivative as the ligand obtained with the preparation method has high internal and external quantum yields, high luminance and high stability. A dicyclic iridium complex is shown as a formula (I), i.e., (C^N)2Ir(L^Y); and an ionic iridium complex is shown as a formula (II), i.e., (C^N)2Ir(N^N)<+>Z<->.

A process for the preparation of anhydrous high purity phosphorus pentafluoride in high yield. The process uses an excess of hydrogen fluoride in a reaction with a phosphoric acid to form hexafluorophosphoric acid followed by reaction with a sulfur based acid reactant in a reaction medium containing an excess of hydrogen fluoride.

The invention discloses an ionic liquid mixed electrolyte for a lithium ion battery. The ionic liquid mixed electrolyte comprises lithium salt, ionic liquid and a non-aqueous organic solvent, wherein the lithium salt is one or mixture of two of lithium bis borate and lithium difluoroborate; cations in the ionic liquid are selected from one of imidazole cations, piperidine cations, pyridine cations, pyrrole cations, quaternary ammonium cations and quaternary phosphine cations; anions in the ionic liquid are selected from one of tetrafluoroborate radicals, hexafluorophate radicals, difluorosulfimide anions and diperfluoroalkylsulfimide anions; and the non-aqueous organic solvent is selected from any one or mixture of several of linear carbonate, cyclic carbonate, linear ether and cyclic ether. The ionic liquid mixed electrolyte is high in thermal stability, wide for an electrochemical stability window, high in conductivity, low in viscosity and good in compatibility with an anode material and a cathode material of the lithium ion battery at the same time.

The invention discloses a multihole gel polymer electrolytic thin film, which comprises the following steps: comprising polyvinylidene fluoride with mass percent at 33-54%, acrylon-methacrylic acid macrogol single dimethyl ether ester copolymer and 43-52% 1M hexafluorophosphoric acid lithium carbonic ester ionogen; synthesizing metyl group acroleic acid carbowax single dimethyl ether ester and acrylic nitrile copolymer; blending and dissolving to N, N-dimethyl acetamine dissolvent with polyvinylidene fluoride; getting multihole thin film through immersed deposition method; absorbing hexafluorophosphoric acid lithium carbonic ester ionogen; getting the product. This invention possesses simple method and high film strength, which possesses good application prospect in polymer lithium ion battery.

The invention discloses an epoxy adhesive for OLED frame encapsulation and a preparation method of the epoxy adhesive. The epoxy adhesive is prepared from the following components in parts by weight:50-80 parts of epoxy resin, 5-10 parts of epoxy diluents, 5-10 parts of flexibilizer, 20-40 parts of filler, 1-5 parts of photoinitiator, 0.1-1 part of antioxidant and 0.3-3 parts of additive. The epoxy resin is one or a mixture of more of cycloaliphatic epoxy resin and bisphenol F epoxy resin. The epoxy diluent is one or a mixture of more of oxetane and aliphatic glycidyl ether. The photoinitiator is a cationic photoinitiator which comprises an iron-arene photoinitiator and a hexafluorophosphate photoinitiator. The epoxy adhesive adopts a curing way that ultraviolet exposure and heating are conducted in sequence, has the advantages of less curing agent residue, less volatile component residue, low curing temperature, strong bonding force, boiling resistance, water vapor resistance, oxygenbarrier performance and the like, and reaches the halogen-free standard.

The invention relates to a method for preparing lithium hexafluorophosphate. The method comprises the following steps: (1), enabling anhydrous hydrogen fluoride and phosphorus pentoxide to react underthe protection of inert gas to prepare hexafluorophosphoric acid; (2), adding oleum to the hexafluorophosphoric acid under cooling stirring to prepare phosphorus pentafluoride gas; (3), dissolving high-pure lithium fluoride in an anhydrous hydrogen fluoride solution to form an anhydrous hydrogen fluoride solution containing the lithium fluoride; (4), cooling the phosphorus pentafluoride gas at 40DEG C below zero, guiding the phosphorus pentafluoride gas to the anhydrous hydrogen fluoride solution containing the lithium fluoride, and reacting, crystallizing, separating and drying the phosphorus pentafluoride gas to obtain a pure lithium hexafluorophosphate product; and (5), continuously pumping the unreacted cooled phosphorus pentafluoride gas after a reaction to the other anhydrous hydrogen fluoride solution containing the lithium fluoride and continuously reacting to obtain a lithium hexafluorophosphate finished product. The invention has rich material resources and easily obtainable raw materials, low production cost, high reaction rate, high product quality and thorough reaction and can realize semi-continuous production by the series connection of double kettles.

The invention discloses a benzotriazole group-containing ionic liquid and its preparation method and use. The benzotriazole group-containing ionic liquid is characterized in that cations are imidazolium cations; anions are hexafluorophosphate radical, tetrafluoroborate radical or bis(trifluoromethylsulfonyl)imide anions; and an imidazole ring-substituted end group contains a benzotriazole group. The benzotriazole group-containing ionic liquid can be used as a lubricant additive or a lubricating grease additive.

The invention relates to a method for spearing butane from butylene with the multicomponent compound of ionic liquid, saline, ethyl methyl ketone and N-formylmorpholine. The content of ionic liquid in the multicomponent compound is 1.0 to 95 percent; the content of the saline in the multicomponent compound is 0.5 to 20 percent; the electropositive ion of the ionic liquid is iminazole electropositive ion, alkyl imidazole electropositive ion or alkyl quaternary ammonium ion, or the compound thereof; the electronegative ion is tetrafluoroborate electronegative ion, hexafluorophosphoric acid electronegative ion, nitrate ion, tetrachloro aluminic acid iron, heptachlor bi aluminic acid iron, chloride ion, bromine electronegative ion or the mixture; and the ionic liquid can be dimethylformamide potassium thiocyanate compound salt, dimethylformamide sodium sulfocyanate compound salt, or the compound; the saline is potassium thiocyanate, sodium sulfocyanate, ammonium thiocyanate, sodium nitrate, potassium nitrate, sodium iodide, potassium iodide, zinc chloride, copper chloride, zinc chloride, potassium bromide, or the compound thereof.

The invention provides a preparation method of a lithium hexafluorophosphate, which comprises the following steps: firstly, reacting a phosphorus pentachloride with an anhydrous hydrogen fluoride to form mixed liquid of the phosphorus pentachloride and the anhydrous hydrogen fluoride; secondly, preparing anhydrous hydrogen fluoride solution of lithium fluoride; and finally, adding the anhydrous hydrogen fluoride solution of the lithium fluoride into the mixed liquid of the phosphorus pentachloride and the anhydrous hydrogen fluoride, and sequentially performing reaction, crystallization, separation and drying to obtain a pure lithium hexafluorophosphate product. The preparation method of the invention has the advantages of mild reaction, high safety and purity of the lithium hexafluorophosphate product of over 99.9 percent; and the mother liquor can be reclaimed and reused so that the cost is reduced.

The invention discloses a phosphorescence iridium complex by taking a quinazoline derivative as a ligand and an organic electroluminescent device thereof. The structure of the phosphorescence iridium complex disclosed by the invention is represented by the formula (I) or the formula (II) described in the specification, wherein Ar represents aryl, substituted aryl, heterocyclic aryl and substituted heterocyclic aryl; R can be one of a halogen atom, alkyl, substituted alkyl, alkoxy, aryloxy, alkyl sulphanyl, aryl sulphanyl, aromatic amino, fatty amino and heterocyclic substituent; L^Y can be one of N^COOH, N^OH, beta-diketone, N^NH and the like; N^N can be bipyridyl, biquinolyl, phenanthroline and derivatives thereof and the like; and Z can be a hexafluorophosphoric acid radical, a perchloric acid radical and the like. A light-emitting layer of the electroluminescent device disclosed by the invention is prepared by adopting a spin coating and film-preparing method under a specified condition, has the advantages of being low in cost, simple for operation and steady in chemical property, and is beneficial to preparing large-screen electroluminescent devices.

The invention discloses an ionic liquid polymer electrolyte and a preparation method thereof. An ionic liquid polymer is synthesized through using a polymer chemical functionalization process, and the structure of the ionic liquid polymer is represented by formula (1) shown in the specification. The ionic liquid polymer is formed through connecting N-methylimidazole with a polymer by chemical bonds, wherein the polymer can be a linear polymer and a hyperbranched polymer, the linear polymer is polyethylene oxide and polyepoxy chloropropane preferably, and the hyperbranched polymer is hyperbranched polyether preferably; and anion a can be halogen, tetrafluoroborate, hexafluorophosphate and ditrifluoromethyl sulfimide, and N-methylimidazole in the formula (1) can be substituted by a pyridine ring, tributyl amine and a pyrrole ring. The ionic liquid polymer electrolyte is composed of the ionic liquid polymer and a lithium salt, and contains no volatile solvents, and the conductivity at room temperature of the ionic liquid polymer electrolyte can reach 3.5*10<-4>Scm<-1>. The polymer electrolyte can be used in lithium ion secondary batteries, electrochromic devices, supercapacitors and other electrochemical devices.

This invention discloses a method for catalyzing alcohol acid esterification by using an ionic liquid. The ionic liquid A+B- is used as catalyst and solvent, wherein: A+ has the following structural formula, and R could be an alkyl group or alkene group with more than one carbons; B- is selected from the following negative ions: chlorin, bromine, iodine, acetate, sulfate radical, hydrogensulfate radical, phosphate radical, hydrogen phosphate radical, nitrate radical, tetrafluoroboric radical, hexafluorophosphoric radical, p-toluenesulfonic radical, and trifluoromethanesulfonic radical; the catalyst amount added is 0.01%-50% of the total mole of the alcohol and acid added, reaction temperature 20-140Deg C, normal pressure reaction time 0.5-12h.

The invention relates to a morpholine quaternary ammonium salt ionic liquid and a preparation method. The ionic liquid has the following structural general formula: A ⁺B^-, wherein, the A⁺ has the structural general formula as the right, in the general formula: R₁ is the saturated or unsaturated alkyl containing 1 to 4 carbon atoms, and the R₂ is in line with the following rules: a) at least 2 carbon atoms are contained; b) not more than 20 carbon atoms are contained; the B^- is selected from one the following anions: chlorine, bromine, iodine, acetate, sulfate, nitrate, tetrafluoroborate, thiocyanate, hexafluorophosphate, p-toluenesulfonic and trifluoromethanesulfonic.

The present invention relates to a new type diacetone acryloamide type ionic liquid and its preparation method. It is made up by using diacetone acryloamide and respectively making it and sulfuric acid, hydrochloric acid, acetic acid, trifluoroacetic acid, tetrafluoroboric acid or phosphofluoric acid undergo the processes of acid and alkali neutralization and separation. Said invention is low in cost, simple in preparation, has no secondary pollution and is suitable for industrial production and application.

The invention relates to a preparation method of lithium hexafluorophosphate. The preparation method is characterized by comprising the following steps of: (1) enabling hexafluorophosphate MPF6 to react with a raw material, namely, halogenated lithium salt LiF to obtain fluoride MF and lithium hexafluorophosphate LiPF6, wherein M is Li, Na, K, NH4 and Ag; (2) performing a reaction under a closed condition and in a dry inert gas atmosphere of which the water content is smaller than 10ppm, and stirring for 2-24 hours to generate a lithium hexafluorophosphate solution, wherein the water content of a solvent is smaller than 10ppm, and the reaction temperature is between 0 DEG C and 15 DEG C; and (3) dissolving the MF in the solvent by using the solubility of the MF in the solvent, precisely filtering, removing undissolved substances including the fluoride MF and the like in a filtering manner, condensing and crystallizing to obtain a lithium hexafluorophosphate solid, and drying the lithium hexafluorophosphate solid to obtain a lithium hexafluorophosphate product.

This invention describes a one pot, single-step process for the preparation of halide-free hydrophobic salts comprising polyalkylated imidazolium cations and various anions in accordance with the following structure, where R¹ and R³ represent the either the same or different alkyl groups, and R², R⁴, and R₅ represent either hydrogen atoms, or the same or different alkyl group substituents; X represents a polyatomic anion that is the conjugate base of an acid. By simply mixing aqueous formaldehyde with an alkyl amine such as methylanune, ethylamine, n-propyl oriso-propylamine, or n-butyl-, iso-butyl, or t-butylamine, or by mixing aqueous formaldehyde with two alkyl amines (preferably one being methylamine, ethylamine, n-propyl- or iso-propylamine, or n-butyl-, isobutyl, or t-butylamine) and another being n-propyl- or isopropylaine, or n-butyl-, isbutyl, or t-butylamine), an acid (such as hexafluorophosphoric acid, trifluoroacetic acid, pentafluoropropionic, heptafluorobutyric acid, or the free acid of a bis(perfluoroalkylsulfonyprnide or tris(perfluoroalkylsulfonyl)methide as the source of the anion) and aqueous glyoxal solution, the hydrophobic ionic salts or mixtures thereof thus formed may be conveniently separated directly from the aqueous byproduct layer. Like the single cation hydrophobic salts, these mixed hydrophobic ionic liquids are non-flammable and manifest no detectable vapor pressure up to their decomposition temperature of greater than 300° C. We have also discovered that, surprisingly, ternary mixtures of dialkylated ionic liquids manifest higher ionic conductivities than a single ionic liquid of the mixture alone. This property benefits electrochemical power source applications such as batteries and capacitors. Furthermore, we have discovered that ternary mixtures of dialkylated ionic liquids absorb microwave radiation more efficiently than a single ionic liquid of the mixture alone. This property benefits microwave-induced synthetic reactions. Such physical and chemical properties make it possible to employ inexpensive mixtures of polyalkylated imidazolium cations in an advantageous manner as thermal transfer fluids, high temperature lubricants, and plasticizers, and as solvents in the areas of electrochemistry, synthetic chemistry, catalysis, and separations chemistry.

The invention relates to preparation of a cobalt adsorbent. The cobalt adsorbent is prepared by introducing bis(pentamethylcyclopentadienyl)cobalticinium hexafluorophosphate, (S,S)-(+)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt and 1-vinyl-3-buthylimidazolium bis[(trifluoromethyl)sulfonyl]imide in polymerization to be polymerized.

The invention discloses a molecularly imprinted polymer for detecting ofloxacin and a preparing method and application thereof. A carrier, a template molecule, a functional monomer and a crosslinking agent are polymerized under the action of an initiating agent to form a composite material, and the template molecule is removed from the composite material to obtain the molecularly imprinted polymer; graphene/rhodium nano particles serve as the carrier, the template molecule is ofloxacin, the functional monomer is methyl ferrocenyl methacrylate, and the crosslinking agent is 3,3'-(1',4'-butane)-bi-1-vinyl imidazole hexafluorophosphoric acid. The invention further discloses application of an electrochemical transducer made of the molecularly imprinted polymer to ofloxacin detection. The electrochemical transducer made of the molecularly imprinted polymer has good adsorptive property to ofloxacin and is high in selectivity, not prone to interference and wide in detection linear range, and the lower detection limit can reach 0.06 micrometer.

The invention discloses an electrolyte for a lithium battery. The electrolyte contains a pyridine ionic liquid, and the pyridine ionic liquid contains cations and anions; the cations are N-alkylpyridine; the anions are one kind of the anions of a group consisting of aluminum tetrachloride acid radical ions, gallium tetrachloride acid radical ions, tetrafluoroboric acid anions, hexafluorophosphoric acid anions, bis(trifluoromethanesulphonyl)imine anions, lactic acid anions, p-methyl benzene sulfonate acid radical anions, acetyl sulfonyl imide anions, saccharin anions, amino acids anions, sulfuric acid ester anions, succinic acid diisooctyl ester sulfonate radical anions, 4,5-dimetridazloe anions, and 5-nitrotetrazolato anions. The electrolyte can inhabit increasement of a metal lithium surface passivatin layer (an SEI film) in the lithium battery, and can significantly improve storage performance of the battery. Furthermore, the invention further discloses a preparation method for the electrolyte and the lithium battery containing the electrolyte.

The invention relates to a functional ionic liquid and a preparation method thereof. The structural formula of the ionic liquid is disclosed in the specification, wherein X<-> is Cl<-> (chloride ion), [BF4]<-> (tetrafluoroborate ion), [PF6]<-> (hexafluorophosphate ion) or [Tf2N]<-> (bistrifluoromethanesulfonimide ion), and n=0-15. After being introduced to the cation alkyl side chain of the ionicliquid, a phenanthroline group can coordinate with some metallic ions to form metallic coordination compounds, and can absorb energy and transfer the absorbed energy to the metallic ions so as to coordinate with rare earth ions, thereby being used for preparing a rare earth compound/ionic liquid material. The prepared material has the advantages of colorful emitted light, high color purity, long fluorescence lifetime and high quantum efficiency, and is applicable to the fields of display, new light sources, X-ray intensifying screens and the like.

The invention discloses a method for catalyzing and esterifying sulfoacid basal functional ion liquid in the formula (1), wherein, n equals to 2, 3 and 4; R is H or C1 to C4 saturated or unsaturated alkyl of straight chain or branched chain; negative ion B- is chlorine, bromine, iodine, sulfate radical, hydrogen sulfate radical, nitric acid radical, dihydrogen phosphate radical, tetrafluoride boric acid radical, hexaflurate phosphoric acid radical, acetic acid radical, methyl sulfoacid radical, paratoluenesulfonic acid radical, fluoroform sulfoacid radical and trifluoroacetic acid radical. The adding dosage of the ion liquid is 0.5 to 100 percent of the total mol of the alcohol and acid, reacting for 0.5 to 12 hours under the normal pressure and the temperature of 20 to 140 DEG C, the esterifying reaction is catalyzed to produce the ester. Compared with the traditional acidic catalyst, the ion liquid simplifies the separation of the product of the esterifying reaction and provides higher selectivity. The invention is distinctly characterized in that the phase separation between the produced ester and the catalyst is automatically finished, and the ion liquid is reusable after simple or non treatment.

The invention discloses lithium ion battery flame-retardant electrolyte which comprises raw materials of an electrolyte lithium salt, an organic solvent and a flame-retardant additive, wherein the organic solvent is prepared from the following components in parts by volume: 15-40 parts of an organic basic solvent with a high dielectric constant, 5-45 parts of a low-vapor pressure solvent, 10-55 parts of a low-viscosity solvent and 2-35 parts of an indoor temperature ionic liquid; the anion of the indoor temperature ionic liquid is prepared from at least one ion of tetrafluoroborate, hexafluoroborate, trifluoromethanesulfonate, bi-trifluoro sulfonamide and trifluoroacetic acid; the cation of the indoor temperature ionic liquid is ammonium cation; the flame-retardant additive is at least one of fluoroproplylene carbonate, di-fluoroproplylene carbonate, trifluoroproplylene carbonate, fluorobenzene ether, fluoro ether and propyl-2,2,2-trifluoro-ethyl carbonate; the mass of the flame-retardant accounts for 1-20% of the total mass of the electrolyte. By adopting the lithium ion battery flame-retardant electrolyte, not only is the flame-retardant property of the electrolyte remarkably improved, but also the charge and discharge property of a battery is slightly affected.

The invention discloses a preparation method of difluorophosphoric acid alkali metal salt. In the method, the difluorophosphoric acid alkali metal salt is produced through a reaction of hexafluorophosphates of alkali metals and corresponding phosphates of the alkali metals in a solid phase or in a non-aqueous solvent, wherein the reaction equation is MPF6+M3PO4=2MPO2F2+2MF (M=Li, Na, K, Rb, Cs), the molar ratio of MPF6 to M3PO4 is 0.8-1.5:1, preferably 1.1-1.2:1, namely, the hexafluorophosphates of alkali metals is excessive properly to ensure reaction of the phosphates to be carried completely. The method can be used for preparing the difluorophosphoric acid alkali metal salt under safe situations, thereby improving safety of the preparation process and ensuring safety of preparation operators. The difluorophosphoric acid alkali metal salt is produced through a reaction of the hexafluorophosphates and the phosphates of the alkali metals, and the target product can be produced whether the reaction is carried out in solid phases or liquid phases under mild conditions without dangerous gas raw materials and generation of acidic gas or water which may damage performances of an electrolyte.