476 results about "Perchloric acid" patented technology

The invention belongs to the technical field of electrochemical energy storage, and particularly relates to a low-temperature aqueous electrolyte for anchoring I < + > ions based on a double-coordination structure and a low-temperature four-electron aqueous zinc-iodine battery. The low-temperature aqueous electrolyte is a mixed solution of a zinc salt, an electrolyte additive and water, and the low-temperature aqueous electrolyte comprises 2-5 mol / L of the zinc salt and 0.3-0.6 mol / L of the electrolyte additive; the zinc salt is zinc perchlorate or zinc tetrafluoroborate. The low-temperature four-electron aqueous zinc-iodine battery comprises the low-temperature aqueous electrolyte. Compared with the prior art, the invention at least has the following beneficial effects: (1) the corrosion risk caused by chloride ion concentration is reduced; (2) efficient four-electron iodine positive electrode reaction is realized; and (3) obtaining the low-temperature four-electron aqueous zinc-iodine battery.

The invention discloses a two-dimensional metal oxide composite reduced graphene oxide burning rate catalyst, which is prepared by the following steps: uniformly grinding glucose, ammonium nitrate and transition metal nitrate, calcining at high temperature to generate a two-dimensional metal oxide nanosheet, mixing the two-dimensional metal oxide nanosheet with surfactant modified reduced graphene oxide powder, and sintering at high temperature to obtain the two-dimensional metal oxide composite reduced graphene oxide burning rate catalyst. And transferring into a high-pressure hydrothermal kettle for solvothermal reaction, so that the reduced graphene oxide and the two-dimensional metal oxide nanosheet are compounded to form the composite burning rate catalyst with a 2D-2D structure. Two two-dimensional materials are compounded through a solvothermal method, the defects of accumulation of reduced graphene oxide and aggregation of the two-dimensional metal oxide due to high surface energy are effectively avoided, meanwhile, the high conductivity of the reduced graphene oxide is utilized, the synergistic catalysis effect of the metal oxide and the carbon material is enhanced, and the performance of the composite material is improved. The composite material has a good catalytic effect on the thermal decomposition process of ammonium perchlorate.

The invention discloses a preparation method and application of octahedral cuprous oxide containing defects, and belongs to the technical field of material preparation. In order to solve the problems that in existing cuprous oxide preparation, a defect structure is difficult to accurately regulate and control, and the crystal form uniformity is insufficient, the method comprises the steps that a copper source solution, a glucose solution, a sodium citrate solution and an ammonium fluoride solution with specific concentrations are mixed according to the volume ratio, the pH is adjusted to 10.5-11, then a hydrothermal reaction is conducted, and a target product is obtained through centrifugation, filtration, washing and drying. The method comprises the following specific steps: mixing solutions, reacting in a high-pressure reaction kettle at 140-165 DEG C for 4-6 hours, and realizing octahedral crystal form construction and defect regulation and control by controlling the raw material ratio and reaction conditions. The preparation method is simple in process and high in controllability, and the prepared octahedral cuprous oxide containing defects can serve as a catalyst to be applied to the fields of catalytic decomposition of ammonium perchlorate and the like and has good industrial application prospects.

The invention belongs to the technical field of drying, and relates to an ammonium perchlorate drying system and method. The drying system comprises a drying box, a hopper and a drying assembly. A connecting frame is arranged in the drying box, and the drying assembly comprises two transmission rollers rotationally mounted on the connecting frame and a drying belt wound between the two transmission rollers; a feed opening is formed in the hopper, and ammonium perchlorate in the hopper falls onto the drying belt through the feed opening; and a driving assembly is mounted on the drying box. Along with operation of the feeding roller and the drying belt, ammonium perchlorate evenly falls onto the drying belt, ammonium perchlorate accumulation is avoided, ammonium perchlorate can be continuously added to the drying belt along with drying, the drying efficiency can be improved, and dried ammonium perchlorate automatically falls into a collecting box. And the connecting frame vibrates in the length direction of the drying box and swings around the connecting column, so that the ammonium perchlorate on the drying belt is turned over, and the ammonium perchlorate is fully and comprehensively dried.

The utility model relates to the technical field of a high-temperature combustion infrared thermal conductivity combined measurement method, in particular to a gas filtering structure of the high-temperature combustion infrared thermal conductivity combined measurement method, which comprises a mounting shell, one side of the mounting shell is communicated with a gas inlet pipe, the inner side of the mounting shell is fixedly connected with a filter screen which is arranged in an inclined manner, and the filter screen is fixedly connected with a gas outlet pipe. One side, far away from the air inlet pipe, of the mounting shell is communicated with a through pipe, the outer side of the through pipe is provided with a second valve, and the inner side of the mounting shell is fixedly connected with a positioning plate penetrating through one side of the mounting shell. One of the adsorption bottles is filled with asbestos, the other one of the adsorption bottles is filled with a magnesium perchlorate solution, solid particles in the gas are filtered out by the filter screen, then the alkali asbestos and the magnesium perchlorate solution in the adsorption bottles can adsorb CO2 and H2O respectively, and the filtered gas can flow out from the through pipe after the second valve is opened.

The invention provides a sample dissolving method of a nickel-based alloy, and belongs to the technical field of analytical chemistry, and the nickel-based alloy comprises the following components in percentage by mass: 0.15-0.20% of C, 0.15-0.20% of B, 0.15-0.20% of C, and the balance of Fe and inevitable impurities. Comprising the following steps: preliminarily dissolving a sample through concentrated hydrochloric acid and concentrated nitric acid; adding perchloric acid, and preserving heat for 1-2 minutes at the temperature of 100-120 DEG C to obtain a yellow insoluble substance, the ratio of the adding volume of the perchloric acid to the mass of the sample being (110-130) mL: 1g; transferring the liquid and the yellow insoluble substance into a second reaction cup, adding hydrofluoric acid, and keeping the temperature at 50-60 DEG C for 2-4 minutes; and fixing the volume after dissolving. Firstly, concentrated hydrochloric acid and concentrated nitric acid are adopted for dissolution, due to the fact that the content of Cr, Mo and W is high, and detection of Ce, Si and other metals cannot be affected, the adding mode of the concentrated nitric acid and the concentrated hydrochloric acid is limited, then perchloric acid is added, fuming of the perchloric acid is controlled, and the content of the perchloric acid and the content of the concentrated nitric acid which are added in the earlier stage are combined; the method has the advantages that low Cr content due to generation of CrO2Cl2 is avoided while metal carbides are dissolved, undissolved yellow substances are dissolved in combination with hydrofluoric acid, and low Si content due to generation of SiF4 is avoided.

The invention provides a hydrated eutectic electrolyte as well as a preparation method and application thereof. The electrolyte comprises water-soluble zinc salt, deionized water and a deep eutectic solution, the deep eutectic solution is formed by mixing zinc perchlorate and a polar deep eutectic solvent and performing deep eutectic crystallization. The electrolyte has the characteristics of low water activity, low freezing point and efficient induction of uniform deposition of zinc, can be compatible with an iodine-loaded positive electrode and can inhibit dissolution of iodine, and the characteristics are beneficial to inhibition of hydrogen evolution reaction, polyiodine shuttling and other side reactions in the battery circulation process, promote uniform deposition of zinc, protect the integrity of an iodine electrode, and improve the electrochemical performance of the battery. The stable operation of the zinc-iodine battery is ensured; the electrolyte is a zinc sulfate solution containing a ZnClO4 / dimethyl sulfoxide deep eutectic solvent, the solution is combined with free water to form a eutectic structure, the eutectic structure participates in construction of a Zn < 2 + > ion solvation shell, extra intramolecular hydrogen bonds are introduced for the electrolyte, meanwhile, hydrogen bonds among water molecules are weakened, so that the internal energy of the electrolyte is enhanced, the freezing point is reduced, and the flowability is improved.

The invention belongs to the technical field of optical glass. The invention relates to an electrochromic glass device, in particular to a preparation method of the electrochromic glass device. The preparation method comprises the following specific preparation steps: cleaning the surface of a glass substrate, and depositing an indium tin oxide transparent conductive layer on the surface of the glass substrate by adopting magnetron sputtering; the preparation method comprises the following steps: by taking nano spherical silicon dioxide as a template, dispersing the nano spherical silicon dioxide in an ethanol solution, then adding a sodium tungstate solution, then adjusting the pH value to 2-3, carrying out a stirring reaction, and then cleaning with a sodium hydroxide solution to remove the template so as to obtain a hollow spherical precursor dispersion liquid; coating the hollow spherical precursor dispersion liquid on the surface of the transparent conductive layer in a spin coating mode, drying and annealing; preparing a liquid electrolyte: taking propylene carbonate as a solvent, and taking lithium perchlorate as an electrolyte lithium salt; niO is deposited on the surface of the WO3 electrochromic layer to serve as a counter electrode through magnetron sputtering; epoxy resin is adopted to package the edge, after liquid electrolyte is injected, internal residual bubbles are removed through hot pressing, and the product is obtained.

The invention belongs to the technical field of metal material surface treatment, and discloses a composite preparation method of an ultrahigh-resolution-rate alpha + beta phase region thermal deformation high-strength titanium alloy EBSD sample, which comprises the following steps: mechanically grinding a to-be-tested surface of the alpha + beta phase region thermal deformation high-strength titanium alloy EBSD sample; performing electrolytic polishing in an electrolytic polishing solution which is prepared from perchloric acid and absolute ethyl alcohol and is naturally cooled to room temperature, and then performing four-stage short-time ion beam etching to obtain an ultrahigh-resolution-rate alpha + beta phase region thermal deformation high-strength titanium alloy EBSD sample; and ion beam etching parameters of each stage of the four-stage short-time ion beam etching are given. The technical problem that in the prior art, a preparation method of an alpha + beta phase region thermal deformation high-strength titanium alloy EBSD sample with the ultrahigh resolution rate (the resolution rate is 98% or above) does not exist is solved.

The invention discloses a preparation method of an ammonium perchlorate microrod with a uniform morphology. The preparation method comprises the following steps: firstly, heating a triethylene glycol saturated solution of ammonium perchlorate under a room temperature condition to a preset high temperature; then adding the high-temperature ammonium perchlorate saturated solution into an acetic acid anti-solvent at a certain temperature at a certain feeding rate for recrystallization; and finally, standing, separating, washing and drying the product to obtain the ammonium perchlorate microrod. The obtained ammonium perchlorate microrod is regular in morphology, good in dispersity and uniform in size, the length is 40-60 microns, and the width is about 10 microns. The method has the advantages of being high in operability, good in repeatability, easy to industrialize and the like.

The invention relates to the technical field of element detection, in particular to a method for measuring the manganese content in copper concentrate, which comprises the following steps: weighing a copper concentrate sample with the mass of m in a tetrafluoroethylene beaker, and adding a small amount of water to soak the sample; adding nitric acid and hydrochloric acid, and heating at 200-300 DEG C for 5-10 minutes; then adding perchloric acid and hydrofluoric acid, heating at 200-300 DEG C until the copper concentrate sample is completely dissolved, and cooling to room temperature; adding dilute nitric acid, and heating to dissolve the separated salt crystals to obtain a to-be-detected pre-solution; transferring the to-be-detected pre-solution to a volumetric flask, adding water to dilute the pre-solution to a scale line, and uniformly shaking to obtain a to-be-detected solution; according to the method, a nitric acid-hydrochloric acid-perchloric acid-hydrofluoric acid mixed acid digestion system is adopted, so that the manganese element in the copper concentrate is completely dissolved, and the interference of a complex matrix on manganese determination is effectively solved; by combining the high sensitivity and multi-element analysis capability of the inductively coupled plasma emission spectrometer, a linear standard curve of a manganese element characteristic spectral line and concentration is established, and the accuracy and precision of quantitative analysis are remarkably improved.

The invention relates to the technical field of metal material transmission electron microscope sample preparation, in particular to a method for removing an oxide layer on the surface of a silicon steel transmission electron microscope film sample. The metal wafer is subjected to electrolysis double-spraying, and the double faces are evenly thinned; the electrolyte is formed by mixing perchloric acid and an absolute ethyl alcohol solution; liquid nitrogen is used for cooling the electrolytic cell; cleaning the metal wafer in absolute ethyl alcohol; and the cleaned metal wafer is vacuumized. The method has the advantages that the electrolytic double-spraying thinning method is combined with the ion thinning method, reasonable working parameters are selected and an oxide layer on the surface of the sample is cleaned by utilizing ion thinning on the basis that the electrolytic double-spraying sample is perforated to obtain a good thin area, so that a high-quality and high-precision metal film sample is obtained; powerful support is provided for silicon steel product mechanism research; the sample preparation speed is high, and the sample preparation cost is low; the thin area is large, the oxide layer is removed, the thin area of the cut sample is very small, the ion thinning is the second time, and the electrolytic double-spraying thin area is the largest.

The present invention discloses a copper-containing hydrogen-bond organic framework material, a preparation method, and an application thereof. The method comprises the following steps: mixing trimesic acid, melamine, and a copper salt and dispersing them in a solvent to obtain a mixed suspension; transferring the mixed suspension to a reactor for reaction to obtain a copper-containing hydrogen-bond organic framework material solution; cooling the copper-containing hydrogen-bond organic framework material solution, centrifuging it, and then post-treating the copper-containing hydrogen-bond organic framework material solid obtained by centrifugation to obtain a copper-containing hydrogen-bond organic framework material with a one-dimensional rod-shaped structure. When used in the thermal decomposition catalysis of ammonium perchlorate, the copper-containing hydrogen-bond organic framework material prepared by the present invention can exhibit high catalytic activity and stability, thereby concentrating the exothermic temperature range and heat release of ammonium perchlorate.

This invention discloses a method for dissolving NiCrPSi nickel alloy samples for ICP-OES detection, comprising the following steps: mixing the NiCrPSi nickel alloy sample to be tested with hydrochloric acid aqueous solution, concentrated nitric acid, and hydrofluoric acid aqueous solution, digesting at 120-140℃ for 1.5-2.5h, and then evaporating the solution to dryness at 220-260℃; then adding nitric acid aqueous solution and heating until the solid is completely dissolved, and then diluting with water to obtain the NiCrPSi nickel alloy test solution. The dissolution method of this invention can completely dissolve NiCrPSi nickel alloy powder without elemental loss, providing an accurate sample solution for ICP-OES detection; and it eliminates the need for specialized equipment such as microwave digesters or electrothermal digesters, as well as special reagents such as perchloric acid and tartaric acid, using only conventional acid reagents and general experimental equipment, thus reducing costs, simplifying operation, and enhancing versatility.

This invention relates to a method for synthesizing an acid-base indicator from cellulose. The method involves mixing a cellulose raw material with a non-volatile acid, heating and carbonizing the mixture in high-temperature air, washing the carbonized material with water, neutralizing the suspension with alkali, filtering to remove inorganic salts, and evaporating the water to obtain the acid-base indicator. The cellulose raw material is cellulose and / or materials containing cellulose, and the non-volatile acid includes one or more of sulfuric acid, phosphoric acid, perchloric acid, benzenesulfonic acid, p-toluenesulfonic acid, and benzoic acid. This invention utilizes non-toxic, harmless, and low-cost cellulose as a raw material to prepare the acid-base indicator through a simple and environmentally friendly production process. The synthesis technology has advantages such as low raw material price and easy availability, simple preparation process, no environmental pollution, and easy product separation.

A quantitative detection method of thallium content in converter graphite ball, steps include: 1) the pretreatment of converter graphite ball; 2) the preparation of standard solution series; 3) the detection of thallium content in converter graphite ball.The application finds that the suitable pretreatment method of converter graphite ball is carbon removal by burning, and then high-chloric acid and dilute nitric acid are used to dissolve salt, by which the converter graphite ball can be completely dissolved, thereby the stability of quantitative determination of thallium content in converter graphite ball is improved, the pretreatment method is simple, fast and operable; the method is suitable for the quantitative detection of thallium content in converter graphite ball with thallium content not less than 0.0062 μg / L, the recovery rate of thallium is as high as 99.1%, the analysis accuracy is high, the detection lower limit is as low as ppb level, the sensitivity is high, and the method has the advantages of simple operation, simple analysis condition and low labor intensity.Therefore, the application has significant economic benefits and the advantages of simplicity and economy.

This invention provides a temperature-resistant shape memory polymer plugging agent, its preparation method, and its application, belonging to the field of oil and gas drilling technology. The preparation method of this plugging agent includes the following steps: mixing acetic acid and perchloric acid to obtain a mixed acid, then adding bromate, potassium permanganate, and natural flake graphite, and stirring to obtain low-temperature expanded graphite; mixing cyanate ester, linear aliphatic epoxy resin, and an active diluent, then adding low-temperature expanded graphite, organotin compounds, and amine catalysts, and carrying out a curing reaction to obtain a temperature-resistant shape memory polymer material; testing the glass transition temperature (Tg) of the synthesized temperature-resistant shape memory polymer material, compressing it at (Tg+5)~(Tg+10)℃, and then cooling, pulverizing, and granulating to obtain the final product. The plugging agent of this invention can rapidly recover its original shape at high temperatures, accumulate and seal leakage channels, and form a high-strength sealing layer in fractures, meeting the requirements of safe and efficient drilling.

A method for recovering ammonium perchlorate from a solid composite propellant, the method being carried out at a temperature of less than 50° C. involving maceration of solid composite propellant fragments in the form of an aqueous suspension, the method being terminated when the ionic conductivity in the aqueous suspension reaches a stabilized value, of less than 60 mS / cm.

The invention belongs to the technical field of chemical analysis, and particularly relates to an ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometry) method for synchronously determining the contents of multiple components of primary and secondary quantities of nickel, silicon, chromium, phosphorus, copper, lead and arsenic in a nickel-iron alloy. According to the performance of each component of the ferro-nickel alloy, concentrated nitric acid, concentrated hydrochloric acid and perchloric acid are specifically dissolved and diluted to a certain volume in batches, the emission spectral line intensity of the to-be-detected component is determined by an ICP-AES spectrometer, and the component content is calculated according to the characteristic spectral line intensity and a working curve established by a calibration curve solution. According to the method, the analysis precision and accuracy are improved, and the detection speed of the primary and secondary multiple components in the ferro-nickel alloy is also greatly increased.

This invention discloses a method for determining the arsenic content in ores, belonging to the field of ore element detection technology, comprising the following steps: (1) weighing the ore sample, adding hydrochloric acid-nitric acid mixed acid for acid hydrolysis, then adding hydrofluoric acid and perchloric acid for auxiliary digestion, evaporating to near dryness, and dissolving the residue with hydrochloric acid; (2) adding a thiourea-ascorbic acid-citric acid mixed reducing masking agent to reduce and mask interfering ions; (3) using an atomic fluorescence spectrometer to determine the fluorescence intensity of arsenic in the sample solution, and calculating the arsenic content according to the standard curve. This method achieves accurate and stable determination of arsenic in various ores such as phosphate rock and iron ore by optimizing sample pretreatment conditions, improving the reduction system and matrix interference suppression strategy.

The invention relates to the field of glass detection, and particularly discloses a method for testing the content ratio of ferrous iron to ferric iron in glass. The method specifically comprises the following steps: washing a to-be-detected glass sample, grinding into micro powder, drying, respectively taking the same amount of glass micro powder, and marking as a sample 1 and a sample 2; divalent iron can be converted into ferric iron by adding perchloric acid into the sample 1, and the test result is the content of total iron in the glass. And dimethyl silicone oil is added into the sample 2 so as to isolate air and prevent ferrous iron from being oxidized into ferric iron in the testing process to influence the experiment result. According to the method, the proportion of Fe < 2 + > to Fe < 3 + > in an unknown glass sample can be simply and quickly obtained, the result is accurate and reliable, the test period is short, and the working efficiency is greatly improved.

The invention provides an energetic complex K-BTE and a continuous preparation method and application thereof.The continuous preparation method comprises the steps that 1, 2-bis (tetrazole-5-yl) ethane serves as an initial raw material, a ligand solution and a metal ion salt solution are continuously injected into a continuous flow reaction unit through an injection pump, and energetic complex crystals are obtained through filtering, washing and drying; a novel energetic complex preparation method which is simple and continuous in process and mild in reaction condition is developed, the energetic complex K-BTE which is novel in structure and excellent in comprehensive performance is prepared for the first time, and the energetic complex K-BTE has the characteristic of high thermal stability and also has the advantages of being simple and efficient in process method and safe and controllable in process; the thermal decomposition temperature of K-BTE reaches up to 366.5 DEG C, the actually measured impact sensitivity is greater than 40J, the friction sensitivity is between 240N and 360N, and meanwhile, the thermal decomposition of ammonium perchlorate is catalyzed. Due to the excellent performance of the K-BTE, the K-BTE has huge application potential in the field of catalyzing the combustion efficiency of solid propellants as an energetic complex.

The invention relates to the field of spiral conveying equipment, in particular to a spiral conveyor for perchloric acid production, and solves the problems that the internal temperature of the spiral conveyor is uniform, the phenomenon that the stability and efficiency of the whole reaction process are affected due to the fact that the reaction rates of different parts are inconsistent is avoided, and the stirring angle can be adjusted so as to adapt to different reaction rates. Comprising a conveying pipe and a driving motor, the outer wall of the conveying pipe is slidably connected with a sliding plate, and the sliding plate is connected with the output end of the driving motor. The phenomenon that water drops on the outer wall of the conveying pipe are hung on the wall unevenly can be avoided, the phenomenon that the reaction rates of all areas are different due to the difference of the internal temperature is prevented, the driving motor can synchronously drive the sliding plate to scrape the outer wall of the conveying pipe when driving the spiral shaft to conduct spiral conveying, the situation that heat dissipation is affected by water drop gathering is avoided, and the service life of the conveying pipe is prolonged. And meanwhile, automatic adjustment can be performed through the stirring blades, so that stirring at different reaction rates is met.

The invention discloses a two-dimensional carbon-based catalyst material as well as a preparation method and application thereof, and belongs to the technical field of catalyst preparation. The preparation method comprises the following steps: by taking aniline as a carbon source and a nitrogen source, initiating oxidative polymerization by ammonium persulfate in a perchloric acid solution containing a metal precursor to generate metal-doped polyaniline; and heating the polymer to induce an explosion reaction so as to realize rapid stripping and carbonization of polyaniline and finally obtain the two-dimensional carbon-based material. The method provided by the invention has the advantages of low initiation temperature, extremely short reaction time and remarkable energy-saving advantage, the obtained material shows excellent catalytic performance and good stability in various systems such as energy conversion and electro-catalytic synthesis as an electrode catalyst, and the preparation process is low in raw material cost, simple to operate, low in energy consumption, small in environmental pollution and suitable for industrial production. And the method has a good large-scale application prospect.

The invention discloses a rapid detection method for talcum powder in food, and relates to the technical field of element analysis and detection. The detection method comprises the following steps: uniformly mixing a to-be-detected sample with nitric acid, perchloric acid and sulfuric acid, heating and digesting, supplementing nitric acid and continuing digesting, and increasing the heating and digesting temperature until the to-be-detected sample is completely digesting to obtain a digesting solution; adding the digestion solution into a colorimetric tube, adding water to a scale, and uniformly shaking to obtain a to-be-detected sample colorimetric solution; mixing another to-be-detected sample with the same mass with talcum powder to obtain a control sample, and treating according to the same method to obtain a control sample colorimetric solution; performing oscillation treatment on the to-be-detected sample colorimetric solution and the control sample colorimetric solution, and performing turbidity comparison under a black background through turbidimetry to obtain a detection result. The method is quick and simple to operate, high in sensitivity, high in accuracy, safe, efficient and energy-saving, the detection period is shortened by half compared with that of a national standard method, and the talcum powder in batch food can be detected at the same time.

The application belongs to the technical field of drying devices, and relates to an ammonium perchlorate filtering and drying device and a drying method thereof. The drying device comprises a drying box, a heating element is arranged in the drying box, a filtering assembly is arranged in the drying box, rotating plates are rotatably arranged at two ends of the drying box, and two mounting plates of the filtering assembly are slidably connected in the drying box. One of the two mounting plates of the same filtering assembly is fixedly connected with the corresponding rotating plate, and the other mounting plate is rotatably connected with the rotating plate. The rotating plate drives the filtering assembly to rotate, filters the ammonium perchlorate, and makes the caked ammonium perchlorate stay on the filter screen. The filtering assembly is folded, and then the caked ammonium perchlorate is preliminarily extruded and crushed. The ammonium perchlorate is dispersed into the folds of the filtering assembly, the ammonium perchlorate is prevented from being accumulated together, and the crushing efficiency is improved. The filtering assembly is twisted and deformed, the ammonium perchlorate is extruded and crushed, and the drying efficiency and drying effect are improved.

This invention provides a method for the simultaneous and rapid detection of four oxidative stress-related biomarkers and its application. The detection method includes: (S1) pretreatment of samples using a protein precipitation extract to simultaneously extract four target compounds: 8-hydroxydeoxyguanosine, 8-isoprostaglandin F2β, 8-isoprostaglandin F2α, and acetyllysine, and preparing a test solution; the protein precipitation extract is a methanol-acetonitrile-perchloric acid mixed solution containing formic acid, wherein the volume ratio of methanol, acetonitrile, and perchloric acid is (8-10):(8-10):(0.5-1), and the volume concentration of formic acid is 0.1-0.5%; (S2) detection of the test solution and standard solution using liquid chromatography-tandem mass spectrometry, and matrix calibration using an internal standard method; plotting a standard curve with the peak area ratio of the target compound to the internal standard as the ordinate and the concentration as the abscissa; and calculating the concentration of the target compound in the test solution based on the standard curve.

The invention relates to the technical field of new energy and mining and blasting, in particular to a preparation method of a biomass instantaneous cracking agent. The preparation method comprises the following steps: mixing biomass powder, pulverized coal, an oxidant, a catalyst and a release agent to obtain mixed powder; mixing the adhesive, the water and the preservative to prepare a glue solution; the glue solution and the mixed powder are kneaded, granulated and dried, and the biomass instantaneous cracking agent is obtained, the biomass powder accounts for 4-55 parts by mass, the pulverized coal accounts for 0-48 parts by mass, the oxidizing agent accounts for 0-45 parts by mass, the catalyst accounts for 0-20 parts by mass, the release agent accounts for 0-2.5 parts by mass, the adhesive accounts for 2-10 parts by mass, the preservative accounts for 0-0.15 part by mass, and the oxidizing agent and the catalyst are not 0 at the same time; the oxidizing agent is potassium peraluminate powder and / or ammonium perchlorate powder; the catalyst is potassium nitrate powder and / or sodium nitrate powder. The biomass instantaneous cracking agent prepared by the invention solves the problems of long stone cracking time, low efficiency and environmental pollution of the existing stone cracking agent.

The application discloses a separation method of tetrafluoropropylene and tetrafluoroethane mixture, mainly comprising the following steps: taking the tetrafluoropropylene and tetrafluoroethane mixture as raw materials, adding ionic liquid in an extractive rectification tower, and performing extractive rectification on the raw materials, wherein the cation of the ionic liquid has the structure of formula (I), and the anion is one of perchlorate ion [ClO4] or fluorosulfonylimide [FSI] ion. In formula (I), R and R' are respectively selected from C1-C4 alkyl. The specified ionic liquid is added in the extractive rectification tower, high-efficiency separation of the tetrafluoropropylene and tetrafluoroethane mixture is realized, high-purity tetrafluoropropylene and tetrafluoroethane can be obtained, the mass purity of the tetrafluoropropylene and tetrafluoroethane products can be as high as 99.6%, and compared with other ionic liquids, the ionic liquid used in the application has smaller energy consumption in the extractive rectification separation process under the condition of obtaining products with the same purity, and the annual economic cost is lower.

The invention belongs to the technical field of ammonium perchlorate modification, and particularly relates to a low-sensitivity ammonium perchlorate composite material and a preparation method thereof. The preparation method of the composite material comprises the following steps: (1) mixing diethanol amine and an insensitive material to obtain a coating material; (2) adding a part of ammonium perchlorate into a stirrer according to a sandwich type feeding method, spreading the bottom of the stirrer, adding a coating material, finally adding the rest ammonium perchlorate, lifting a stirrer material cylinder, and starting a stirring reaction when the bottom of a stirring paddle is about to touch the material; and (3) after the reaction is finished, stirring and cooling the reaction system to obtain the ammonium perchlorate composite material with low friction sensitivity and impact sensitivity. The process provided by the invention is suitable for preparing low-sensitivity ammonium perchlorate with various particle sizes, has the advantages of simple process flow, good reproducibility, easiness in amplification and almost no pollution to the environment, and does not influence the performance of ammonium perchlorate while reducing the sensitivity of ammonium perchlorate.