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226results about How to "Reduce passivation" patented technology

Preparation method for tantalum-contained interlayer metallic oxide electrode

The invention belongs to the electrochemical technical field, and relates to a preparation method for a tantalum-contained interlayer metallic oxide electrode. The electrode is suitable for occasions including steel plate high-speed electroplating, seawater electrolysis marine life pollution and damage prevention devices, sodium hypochlorite electrolysis production devices, sewage treatment, cathode protection and the like in the electrochemistry industrial field. The main process comprises three steps, namely substrate pretreatment, tantalum-contained interlayer preparation and oxide coatingpreparation: firstly, a tantalum-contained interlayer is prepared on a titanium substrate by adopting a thermal decomposition method, and then a mixed metallic oxide electro-catalysis coating is prepared on the tantalum-contained interlayer; the mass percent purity of the metallic titanium substrate is larger than 99%; and the process is simple and convenient to carry out, the metallic oxide electrode with larger size or more complicated structure can be prepared, and the tantalum-contained interlayer can better protect the titanium substrate, delay the titanium substrate inactivation, improve the stability of the oxide electrode and prolong the service life.
Owner:725TH RES INST OF CHINA SHIPBUILDING INDAL CORP

Method for preparing citrate nano zero-valent iron and method of activated persulfate thereof for treating organic wastewater

The invention discloses a method for preparing citrate nano zero-valent iron and a method of activated persulfate thereof for treating organic wastewater. The method for treating organic wastewater comprises the following steps: adding persulfate and stable citrate nano zero-valent iron into wastewater containing organic pollutants; uniformly mixing the stable citrate nano zero-valent iron with the persulfate, wherein the stable citrate nano zero-valent iron releases ferrous ions to react with zero-valent iron and the persulfate to generate free radicals with oxidizability, the free radicals degrade the organic pollutants in the wastewater, and the method is used for solving the problem in the prior art that activating conditions of activating the persulfate via heating activation and optical radiation activation are complicated; when the ferrous ions are used for activating the persulfate, the ferrous ions react with the active free radicals to reduce the utilization rate of peroxydisulfate and generate a large amount of iron sludge; the technical problem that the nano zero-valent iron is unlikely to recover when the nano zero-valent iron is used for activating the persulfate is at least partially overcome.
Owner:重庆地大工业技术研究院有限公司

Method and device for treating high-concentration nonbiodegradable organic wastewater

The invention discloses a method and device for treating high-concentration nonbiodegradable organic wastewater. The method comprises the following steps: (1) adjusting pH (Potential of Hydrogen) of the wastewater to be 3; (2) feeding the adjusted wastewater into an Fenton reactor, and simultaneously adding an Fenton agent to perform Fenton reaction; (3) enabling the wastewater containing the Fenton agent to flow through an electric flocculation device; continuously performing Fenton reaction under the effect of a pulsed power electric field, and simultaneously performing electrochemical reaction and electric catalytic oxidation reaction, in order to further degrade organic matters in the wastewater as well as generate flocculates and precipitates; scrapping the flocculates through a slag scraper in an air flotation area of the electric flocculation device; and (4) enabling the wastewater with the precipitates to flow into a precipitation tank, adjusting the pH to be 7 to 8, and then removing the precipitated wastewater from the precipitation tank. Compared with the prior art, the method for treating the high-concentration nonbiodegradable organic wastewater, disclosed by the invention, can improve the removal efficiency of nonbiodegradable organic pollutants.
Owner:SICHUAN KAIWO ENVIRONMENTAL PROTECTION TECHCO

Microwave electro-Fenton method for processing organic wastewater and device thereof

The invention relates to a microwave electro-Fenton method for processing organic wastewater and a device thereof. Under the action of microwave, a boron-doped diamond film electrode is used as an anode material for electrochemical degradation processing, and organic pollutant containing wastewater is processed efficiently by an electrochemical method. According to the invention, the boron-doped diamond film electrode is utilized to continuously generate hydroxyl radical with strong oxidation capacity in a wastewater system containing divalent iron ions, and in-situ activation of the boron-doped diamond film electrode is carried out by means of thermal effect and non-thermal effect of microwave so as to increase activity of the electrode and promote mass transfer process during the degradation process of organic pollutants. Therefore, the oxidation capacity of the electro-Fenton reaction is enhanced, and mineralization reaction rate is effectively accelerated. In comparison with traditional Fenton and electro-Fenton methods, the processing effect of the microwave electro-Fenton method provided by the invention is effectively enhanced. The method provided by the invention is simple to operate, has a good effect of processing organic wastewater, and has a wide application prospect as well as development potential.
Owner:TONGJI UNIV

Eutrophication water body in-situ electromagnetic coupling flocculation precipitation device

InactiveCN105084633AEliminate endogenous pollutionMitigate aging and passivationWater/sewage treatmentEnergy based wastewater treatmentFertilizerSewage
An eutrophication water body in-situ electromagnetic coupling flocculation precipitation device comprises a storage battery, a solar cell panel and a buoy connected with the solar cell panel. The solar cell panel is connected with the storage battery, a sewage pump, a sludge pump, the storage battery, an air compressor and a magnetic seed feeder are arranged on the upper portion of the buoy, the sewage pump, the sludge pump, the air compressor and the magnetic seed feeder are connected with the storage battery, a flocculation reaction zone is arranged in the middle of the buoy, a sludge settling zone is located below the flocculation reaction zone, a precipitation separation zone is located at the two sides of the sludge settling zone, an eutrophication water body outside the buoy is pumped into the flocculation reaction zone through the sewage pump, the flocculation reaction zone is provided with multiple pairs of anodes and cathodes which are used for electric flocculation, a perforated pipe sparger which is connected with the air compressor is installed on the lower portion of the flocculation reaction zone, the magnetic seed feeder is used for feeding magnetic seeds into the flocculation reaction zone, and powerful magnets are installed on the two side surfaces of the sludge settling zone. According to the eutrophication water body in-situ electromagnetic coupling flocculation precipitation device, the running cost is low, the maintenance is simple, pharmaceutical pollution and solid waste are not produced, the magnetic seeds are easy to recycle, and concentrated sediment can be used as fertilizer directly.
Owner:CHANGJIANG RIVER SCI RES INST CHANGJIANG WATER RESOURCES COMMISSION

Device and process for preparing liquid ferrate through electrolysis method

The invention relates to a device for preparing liquid ferrate through an electrolysis method. The device is characterized in that an electrolyzer is a U-shaped pipe electrolyzer, an alkali liquor inlet of an alkali liquor storage tank is communicated with the alkali liquor inlet of the U-shaped pipe electrolyzer through an alkali liquor delivery pump and an alkali liquor control valve which are arranged on a pipeline, the liquid ferrate outlet of the U-shaped pipe electrolyzer is communicated with a liquid ferrate storage tank through a liquid ferrate control valve and a liquid ferrate delivery pump which are arranged on the pipeline, a side pipeline of the alkali liquor inlet of the U-shaped pipe electrolyzer is a cathode chamber, a cathode electrode is arranged in the cathode chamber of the U-shaped pipe electrolyzer, a side pipeline of the liquid ferrate outlet of the U-shaped pipe electrolyzer is an anode chamber, at least one anode electrode is arranged in an enlarged containing groove of the anode chamber of the U-shaped pipe electrolyzer, and the cathode electrode and the anode electrode are connected with a direct current power source. The device is simple in structure, economical and applicable, scientific and reasonable in technologic process, and low in operation cost, has high current efficiency and good effect, and can be widely used for interval or continuous production.
Owner:NORTHEAST DIANLI UNIVERSITY

Preparation method of crystalline silicon solar cell

The invention discloses a preparation method of a crystalline silicon solar cell. In the passivation process technology of the back surface of a silicon wafer, because aluminum oxide has constant negative charge, the composition of the back surface can be lowered, and the same time, because silicon nitride in rich in hydrogen, passivation can be realized effectively, and in addition, the passivation overlapping layers of aluminum oxide and silicon nitride act as a back reflector, the absorption of long beam waves can be improved greatly, the passivation overlapping layers are positioned between a back surface electrode and the silicon wafer, the warping degree of the crystalline silicon solar cell can be lowered greatly, and the influence on the lifetime of a minority carrier in the silicon wafer can be lowered effectively; and when the back surface electrode is manufactured, because the passivation overlapping layers for the corrosion depth in the corrosion region is just removed, the problem that the back surface electrode and the silicon wafer have less possibility of forming favorable ohmic contact due to the back surface passivation of the silicon wafer can be solved effectively, at the same time, a dense network structure is formed by connecting all the adjacent electric conducting materials by utilizing a silver wire, and the network structure is especially favorable for the collection and conduction of back surface current carriers of the silicon wafer.
Owner:苏元周

Method for preparing permeable reactive barrier for relieving passivation of zero-valent iron

The invention discloses a method for preparing a permeable reactive barrier for relieving passivation of zero-valent iron. The permeable reactive barrier is prepared from an oxygen-releasing nutrientlayer and a hydrolyzed microorganism-zero-valent iron layer at a volume ratio of 1 to 1. The oxygen-releasing nutrient layer is prepared from oxygen-releasing agent CaO2 particles and cheap soil slow-release fertilizer Woshibao particles at a volume ratio of 3 to 2. The hydrolyzed microorganisms in the hydrolyzed microorganism-zero-valent iron layer are prepared from biochar-immobilized microorganisms. The microorganism is Lactobacillus acidophilus. Biochar is prepared from corn straw by anoxic burning at 300 DEG C for 2 hours. The invention also discloses a method of immobilizing microorganisms by biochar. The method adopts microorganisms for hydrolyzing a passivation film on the surface of the zero-valent iron for the first time. The reaction condition is mild, the cost is low, and no secondary pollution is caused. The permeable reactive barrier provided by the invention has better removal effects on heavy metals and chlorine-containing organic pollutants. The method is simple in operation, low in cost and environmentally-friendly, and has a broad application prospect.
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