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2833results about How to "Abundant raw materials" patented technology

Method for efficiently extracting lithium from salt lake brine

The invention relates to a method for efficiently extracting lithium from salt lake brine. The method comprises the following steps: (1) forming an extraction organic phase by an extraction agent, a co-extraction agent and a diluent, and then mixing the extraction organic phase with salt lake brine according to the volume ratio of (3-4):2 for three-stage extraction with single extraction time being 2-10 minutes to obtain an organic phase; and (2) mixing the organic phase obtained in step (1) with a reverse extraction acid solution (0-1 mol/L) for three-stage reverse extraction with single reverse extraction time being 2-10 minutes, and collecting an aqueous phase which is an aqueous solution containing lithium ions. The co-extraction agent of an extraction system of the method is hydrophobic ionic liquid, compared with conventional synergist ferric trichloride, the interference caused by iron ions is avoided, the reverse extraction acidity is greatly reduced, more importantly the lithium-magnesium separation factor is significantly improved, and the elution step of magnesium ions is reduced; in addition, the method provided by the invention is easy in process, easy to control, high in operation reliability, and good in recyclability of the organic phase, and greatly reduces the production cost for extracting the lithium from the salt lake brine.
Owner:TIANJIN UNIVERSITY OF SCIENCE AND TECHNOLOGY

Composite catalytic electrode for producing oxygen by electrolyzing water, and preparation method and application thereof

The invention discloses a composite catalytic electrode for producing oxygen by electrolyzing water, and a preparation method and application thereof. The electrode expression is Ni(OH)2/Ni3S2/Ni, wherein a Ni(OH)2 lamina is used as an outer layer coating layer, Ni3S2 nanoparticles are used as an active substance, and Ni foam is used as a conducting substrate. The preparation method comprises the following steps: carrying out ultrasonic cleaning on a metal nickel source sequentially with deionized water, alcohol and acetone; impregnating the pretreated metal nickel source in a sulfur source water solution, adding into a high-pressure autoclave, and carrying out hydrothermal reaction at 140-200 DEG C for 1-8 hours; and cooling, taking out the sulfurized metal nickel, rinsing with deionized water, and carrying out vacuum drying. The composite electrode for electrolyzing water has ultralow water electrolysis overpotential and high current density, obviously reduces the electric power consumption, and thus, has important application in the field of water electrolysis. Meanwhile, the composite electrode synthesis method is simple, has the advantage of low cost for raw materials and synthesis, and is suitable for application in water electrolysis industry.
Owner:ZIBO ANZE STANDARD GAS CO LTD

Method for preparing calcium oxide and sulfur by double-atmosphere fluidized roasting of desulfurated gypsum

The invention provides a method for preparing calcium oxide and sulfur by double-atmosphere fluidized roasting of desulfurated gypsum, belonging to the technical fields of solid pollutant treatment and in environmental protection chemical production. The method comprises the following steps: drying and dehydrating aged desulfurated gypsum, and then entering a multi-stage suspension heat exchangerfor pre-heating; entering hot-state gypsum into a circulating fluidized bed decomposition furnace, and introducing primary and secondary air for decomposition; cooling discharged hot-state calcium oxide, wherein cooled hot-state calcium oxide is used as a desulfurizer for later use; entering discharged smoke containing sulfur dioxide into the multi-stage suspension heat exchanger; removing calcium oxide dust in cooled hot smoke through multi-stage dust removing equipment; and feeding the smoke without the dust into a high-temperature-resistant high-efficiency filter for further removing the dust, and feeding clean smoke into a sulfur recovery system; and preparing the sulfur product by the processes of hot reduction, catalytic reduction, Clause reaction and the like, and feeding Clause tail gas into a coal burning boiler in a power plant for combustion. The method has the advantages of good environmental protection benefits and strong economic benefits.
Owner:CHINA PETROCHEMICAL CORP +1

Hybrid solar cell with aluminum-doped zinc oxide nanorod as electron transfer layer

A hybrid solar cell with an aluminum-doped zinc oxide nanorod as the electron transfer layer is composed of a transparent conducting glass substrate, the aluminum-doped zinc oxide nanorod electron transfer layer, a layered perovskite-like hybrid material CH3NH3PbX3(wherein X is Cl, or Br or I),2,2',7,7'-Tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9'-spirobifluorene hole transfer layer and an Au metal back electrode layer, wherein all the parts form a laminated structure in sequence. The hybrid solar cell with the aluminum-doped zinc oxide nanorod as the electron transfer layer has the advantages that due to the fact that the aluminum-doped zinc oxide nanorod is used as the electron transfer layer in the hybrid solar cell, the specific surface area is large, electron-transport capacity is high, electron-hole combination is effectively restrained, and photoelectric conversion efficiency is high; the manufacturing method and technique are simple, reaction temperature is low, efficiency is high, raw materials are rich, cost is low, and environmental friendliness is achieved. The hybrid solar cell with the aluminum-doped zinc oxide nanorod as the electron transfer layer is suitable for industrialized large-scale production.
Owner:TIANJIN UNIVERSITY OF TECHNOLOGY

Hybrid solar cell with Cs mingling with ZnO as electron transfer layer

Provided is a hybrid solar cell with Cs mingling with ZnO as an electron transfer layer. The hybrid solar cell with the Cs mingling with the ZnO as the electron transfer layer is composed of a transparent conductive glass substrate, a Cs mingling with ZnO nanorod electron transfer layer, layered perovskite hybrid materials CH3NH3PbX3(wherein X is C1, Br or I), a 2, 2', 7 and 7'- four [N, N - two (four - methoxy phenyl) amidogen] - 9, 9' - spirobifluorene hole transport layer and an Au metal back electrode layer which sequentially form a layered structure in a combining mode. The hybrid solar cell with the Cs mingling with the ZnO as the electron transfer layer has the advantages that the Cs mingling with the ZnO as the electron transfer layer is used in the hybrid solar cell, compared with zinc oxide, 2-3 orders of magnitude of electronic transmission capacity are improved, the recombination of electron-hole is effectively constrained, and the photoelectric conversion efficiency is high; the preparing method of the hybrid solar cell is simple in process, low in reaction temperature, high in efficiency, rich in raw material, low in cost, environmentally friendly, free of pollution, and suitable for industrial mass production.
Owner:TIANJIN UNIVERSITY OF TECHNOLOGY

Biomass coke compound fertilizer and production method thereof

InactiveCN102093123ACapable of reducing carbon emissionsAbundant raw materialsFertilizer mixturesBiological materialsBiomass
The invention discloses a biomass coke compound fertilizer and a production method thereof, which belong to the technical field of fertilizers. The fertilizer is prepared from conventional chemical fertilizer and biomass coke and is granular, wherein the biomass coke accounts for 20 to 70 percent of the total mass of the fertilizer. The biomass coke is a solid product produced by a process of cracking a biological material (such as straws and the like) at the high temperature of between 300 and 700 DEG C under the anoxic condition, and has prominent characteristics of light texture and many pores. The compound fertilizer is conventional compound fertilizer containing N, P2O5 and K2O, and the content of the total nutrients is 15 to 30 percent. The production method for the biomass coke compound fertilizer comprises the following steps of: weighing the conventional chemical fertilizer according to different nutrient content and proportion, preparing the conventional chemical fertilizer into powder, adding biomass coke granules in a mass ratio, mixing the powder and the biomass coke granules uniformly, and performing granulation, collection and drying to form the granular biomass coke compound fertilizer. The biomass coke compound fertilizer has the advantages of rich raw materials, simple technology, good effect and the like, meanwhile, has certain carbon emission reduction capacity, and is suitable for large-scale production.
Owner:CHINA AGRI UNIV

Ferromanganese modified straw active carbon adsorbent for As (III) adsorption, and applications thereof

The present invention relates to a ferromanganese modified straw active carbon adsorbent for As (III) adsorption, and applications thereof. The technical scheme comprises: preparing straw into straw active carbon, adding to nitric acid, carrying out an acidification treatment to obtain acidified straw active carbon, adding the acidified straw active carbon to a metal iron salt and HCl mixing solution, carrying out a reaction at a room temperature for 22-24 h, heating to a temperature of 95-105 DEG C, carrying out a reaction for 6-7 h to obtain iron modified active carbon, mixing a metal manganese salt and the iron modified active carbon, carrying out a reaction at a temperature of 75-85 DEG C, adding a KMnO4 and KOH mixing aqueous solution, carrying out a reflux reaction at a temperature of 75-85 DEG C, and washing he product so as to obtain the target product. According to the present invention, with the ferromanganese modified straw active carbon adsorbent, the As (III) can be selectively recovered from the solution containing the As (III) ions and the impurity metal ions; and the ferromanganese modified straw active carbon adsorbent has advantages of low cost, high selectivity, high adsorption capacity, and the like.
Owner:LIAONING UNIVERSITY

Method for preparing high-density spherical lithium iron phosphate for lithium ion power battery

The invention relates to a method for preparing high-density spherical lithium iron phosphate for lithium ion power batteries, which is characterized by comprising the preparing processes: acid, a ferric iron resource and phosphor resource are mixed into mixed water solution; alkali is prepared into water solution; the mixed water solution and the alkali water solution are respectively and continuously introduced into a reaction kettle to carry out coprecipitation reaction, and a spherical iron phosphate precursor is synthesized; the precursor is used as a raw material and is evenly mixed with a lithium resource, a carbon resource and a doping metal compound, and then, the mixture is heated in a stove to obtain a spherical lithium iron phosphate powder material under a protective atmosphere. The spherical lithium iron phosphate powder material prepared by the method has freely controllable average grain diameter being from 4 microns to 15 microns, narrow distribution of the grain diameter tap density as higher as 1.4 g / cm<3> to 2.2 g / cm<3>, and has the characteristics of high specific capacity, rate discharge and good safety performance. The method has simple technical processes and is suitable for industrial mass production.
Owner:LANZHOU JINCHUAN NEW MATERIAL SCI & TECH

Graphite-phase carbon nitride nanosheet-based composite photocatalytic material as well as preparation method and application thereof

The invention provides a graphite-phase carbon nitride nanosheet-based compsite photocatalytic material as well as a preparation method and application thereof, which relates to the field of photocatalytic materials. A metal oxide semiconductor can uniformly cover the surface of a graphite-phase carbon nitride nanosheet by virtue of hydrolytic reaction and roasting of metal salts, so that the interaction between the graphite-phase carbon nitride nanosheet and metal oxide semiconductor interface can be adjusted. The interaction between the interfaces influences the transmission of charge carriers, the interface with close interaction can promote the charge transportation, so that the photocatalytic efficiency of the composite material can be improved. In the process that the metal oxide semiconductor is in-situ generated on the surface of carbon nitride, the blocky graphite-phase carbon nitride are converted into the graphite-phase carbon nitride nanosheet due to the heat etching effectin the calcining process, so that the specific surface area of a sample can be improved, the agglomeration of the particle-shaped oxide semiconductor particles can be prevented to certain extent, andthe metal oxide semiconductor can be uniformly dispersed on the surface of the graphite-phase carbon nitride nanosheet.
Owner:JINGDEZHEN CERAMIC INSTITUTE

Expanded vitrified micro-bead fireproof thermal-insulation board and preparation method thereof

The invention relates to an expanded vitrified micro-bead fireproof thermal-insulation board and a preparation method thereof, belonging to the field of construction materials. In the invention, inorganic expanded vitrified micro-beads, which are used as main raw materials, are combined with an organic binder, molded in a die and sintered, so that the expanded vitrified micro-beads are bound to form a compact single-layer board; and meanwhile, in the sintering process, the content of organic matters in the thermal-insulation board is greatly reduced to further enhance the fire resistance of the fireproof thermal-insulation board, thereby obtaining the fireproof thermal-insulation board with favorable comprehensive properties. The preparation technique of the expanded vitrified micro-bead fireproof thermal-insulation board is simple; and the expanded vitrified micro-bead fireproof thermal-insulation board has the advantages of low coefficient of thermal conductivity, high strength, excellent fire resistance, low water absorptivity, favorable thermal insulation effect, long service life and low volume weight, and can not deform or deteriorate when being used for a long time, therebybeing a green, economical and environment-friendly fireproof thermal-insulation material.
Owner:WUHAN TEXTILE UNIV

Preparing method for self-healing polysaccharide hydrogel

The invention relates to a preparing method for self-healing polysaccharide hydrogel. The preparing method comprises the steps that cellulose is added into ionic liquid to be dissolved, the mixture is then cooled to the room temperature, and a cellulose solution is obtained; the cellulose solution is heated and dripped with tert-butyl acetoacetate under the protection condition of introducing nitrogen, a reaction is carried out at the constant temperature, the solution is then cooled to the room temperature, purified and subjected to vacuum drying, and acetoacetic acid cellulose is obtained; under the room temperature, a chitosan solution is added into the acetoacetic acid cellulose solution, oscillated and mixed, and the self-healing polysaccharide hydrogel is obtained. The polysaccharide hydrogel prepared through the method has the self-healing performance, and has the pH responsiveness at the same time. The preparing method is simple in process, rich in raw material and suitable for modification of most polysaccharide derivatives; meanwhile, due to the good biocompatibility of cellulose and chitosan, the prepared polysaccharide hydrogel has good application prospects in the fields such as tissue engineering repair, medicine controlled release and biological bionics.
Owner:DONGHUA UNIV

Polarization multiplexing holographic imaging method based on transmission type all-medium metasurface

The invention belongs to the technical field of micro-nano optics, polarization optics and optical holographic, and discloses a polarization multiplexing holographic imaging method based on a transmission type all-medium metasurface. A response main wavelength <lambda> is determined; geometric parameters of a unit structure are determined; a GS phase recovery algorithm is adopted to obtain phase distribution of the unit structure responding to the main wavelength; the pixel point of each element is expanded into a 2*2 array by adopting a Dammann grating method, and the obtained each pixel unitcomprises information responding to horizontal polarized light and information responding to vertical polarized light; and a synthesized silicon nano-antenna array is irradiated by horizontal polarized light and vertical polarized light with the wavelength of <lambda>, and different holographic images are reconstructed. According to the method, phase modulation of 0-2 <pi> can be realized only bychanging the size of the short axis of the silicon nano-antenna, and an embossment phase modulation structure of any step number can be realized equivalently; and a simple process, high processing error tolerance and quite high stability and reliability are achieved.
Owner:UNIVERSITY OF CHINESE ACADEMY OF SCIENCES
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