63 results about "Vaterite" patented technology

To provide a medical tissue reconstruction material, which is involved in tissue reconstruction and exhibits superior tissue affinity, tissue conductivity, and mechanical properties, and a method for producing the same.SOLUTION: The present invention provides a composite comprising a biodegradable polymer and calcium phosphate exhibiting one of scaly, acicular, grooved, or linear recessed structures, and / or calcium carbonate containing vaterite, the composite meeting specific conditions.SELECTED DRAWING: Figure 3

The invention relates to a method for decalcification and carbon sequestration of fly ash water washing liquid. According to the method, the extraction effect of insoluble organic amine on acid is utilized to improve the pH value of a water washing liquid system, CO2 is continuously absorbed, and calcium in the fly ash water washing liquid is completely removed; the amine in the organic phase is regenerated through alkali, and meanwhile, a small amount of organic diluent mixed in the water washing liquid is separated from low-boiling-point azeotrope containing the organic diluent at the tower top through azeotropic distillation, so that recycling is realized. The prepared calcium carbonate product is small in particle and high in purity, is a high-quality vaterite type calcium carbonate particle, can be used as a very good adsorbent and additive material, and has wide application in multiple fields.

The invention discloses a method for preparing nano vaterite calcium carbonate from carbonized carbide slag. The method comprises the following steps: 1) pretreatment of raw materials: drying the carbide slag, and grinding the carbide slag into powder for later use; 2) leaching: mixing the carbide slag, ammonium chloride and deionized water, stirring at normal temperature, reacting, and filtering to obtain filter residue and calcium-containing filtrate; and 3) carbonization reaction: introducing the calcium-containing filtrate obtained in the step 2) into an external circulation supergravity reactor, introducing CO2 gas at the same time, carbonizing at normal temperature, and filtering, washing and drying to obtain the nano vaterite type calcium carbonate. The method aims at the problems that in an existing process for preparing vaterite calcium carbonate from carbide slag, product particle size distribution is large, production efficiency is low, and additives are needed, and nano vaterite type calcium carbonate with the small particle size (50-80 nm) and uniform distribution can be efficiently prepared.

The invention belongs to the technical field of solid waste resource utilization, and relates to a method and system for preparing vaterite type calcium carbonate from waste incineration fly ash. The method comprises the following steps: by taking ammonium chloride as a leaching agent, leaching the waste incineration fly ash in a leaching agent solution, and then carrying out solid-liquid separation to obtain a calcium solution; and carrying out carbonation reaction on the calcium solution, an alkaline compound, sodium dodecyl benzene sulfonate and carbon dioxide under the conditions that the pressure intensity is 0.5-0.7 MPa and the temperature is 25-180 DEG C for 60-90 minutes to obtain the calcium carbonate. According to the method, high-quality vaterite type calcium carbonate can be prepared at a high conversion rate, the risk of fly ash is reduced, and mineralization of carbon dioxide is realized, so that waste is treated by waste, and green production is realized.

The invention relates to the technical field of water treatment, and discloses a method for circularly inducing crystallization, hardness removal and desalination of calcium carbonate. Adding the seed crystal into high salt water; adding sodium hydroxide into the heavy salt water; adding sodium carbonate to generate a supersaturated solution; introducing the solution containing the calcium carbonate crystal nucleus into crystallization equipment; treating the reacted solution through solid-liquid separation equipment; further desalting the water body subjected to hardness removal by adopting a membrane separation mode; collecting and treating the formed calcium carbonate precipitate, and recovering the precipitate by adopting a separation technology; by adopting the synthesized vaterite type seed crystal, the hardness removal and desalination efficiency is remarkably improved in the cyclic induced crystallization process of calcium carbonate. Compared with the traditional non-synthetic seed crystal, the synthetic seed crystal has higher surface area and uniformity, so that the combination of calcium ions and carbonate ions can be more quickly induced to form a stable crystal nucleus, and the overall effect of the reaction is finally improved.

The invention discloses a calcium carbonate phase change cementing material hardened body as well as a preparation method and application thereof. The preparation method of the calcium carbonate phase change cementing material hardened body comprises the following steps: firstly, uniformly mixing vaterite and a crystal form regulating agent, then adding water, stirring to obtain slurry, after the slurry is formed, carrying out radio frequency heating maintenance with the radio frequency heating frequency of 300KHz-300GHz and the power of 500-900W, and after the radio frequency heating maintenance, carrying out vacuum drying to obtain the calcium carbonate phase change cementing material hardened body. The calcium carbonate phase change cementing material hardened body is prepared. Compared with steam curing, the mode of curing the calcium carbonate phase-change cementing material through radio frequency heating can better promote accumulation of the calcium carbonate phase-change cementing material precursor and conversion of part of the calcium carbonate phase-change cementing material precursor to target mineral aragonite, enables an interface to be fused and bonded, remarkably improves the compressive strength, and is worthy of popularization and application.

The invention provides a method for preparing vaterite type nanoscale calcium carbonate with ardealite as a raw material and application of the method, and relates to the technical field of inorganic nano-material preparation.The method comprises the following steps that firstly, efficient dissociation of calcium ions in the ardealite is achieved through a phase transfer method, then digestion treatment is conducted on a leaching solution, and the leaching solution is obtained; a crystal morphology regulating agent is further introduced to construct a mineralized microenvironment, and then through a carbon dioxide carbonization reaction, vaterite type nano-scale calcium carbonate with a specific average particle size (200-400 nm) is prepared. According to the preparation method, natural high polymer materials such as collagen are introduced in the preparation process to serve as green crystal form guiding agents, so that the coordination effect of the natural high polymer materials and calcium ions can be utilized, the crystal morphology can be effectively regulated and controlled, and the biocompatibility of the nano material is improved; and the application possibility of calcium carbonate in the biomedical fields of drug carriers, bone repair materials and the like is expanded.

The invention discloses a coated defluorination composite material based on a microbial mineralization technology and a preparation method thereof. According to the coated defluorination composite material, urease vaterite calcium carbonate particles are used as a material core part, and the outer surface of the core part is coated with a calcium cross-linked porous composite film to serve as a coating layer of the material; the calcium cross-linked porous composite membrane is a porous membrane material formed by cross-linking calcium ions and a porous matrix, and the porous matrix is selected from any one of chitosan, cellulose, sodium alginate and porous silicon; the urease vaterite calcium carbonate particles are generated in situ after urea hydrolysis is catalyzed by urease and a calcium source is added. The composite material has the advantages of efficient defluorination effect and good stability when used in fluorine-containing wastewater, and the preparation method of the coated defluorination composite material is simple and easy to implement.

The invention provides high-strength modified calcium carbonate and a preparation method thereof, and belongs to the technical field of modified calcium carbonate preparation. The preparation process comprises the following steps: preparing porous vaterite-phase nano calcium carbonate; preparing high-strength filling porous vaterite phase nano calcium carbonate; and preparing high-strength modified calcium carbonate. According to the preparation method, 3-(methacryloyloxy) propyl trimethylsiloxane and poly (ethylene glycol) diacrylate are subjected to a polymerization reaction under the action of azodiisobutyronitrile, and then modified calcium carbonate is grafted, so that the compatibility and dispersity of the modified calcium carbonate and a polymer can be improved, and porous vaterite-phase nano calcium carbonate is prepared; the porous vaterite-phase nano calcium carbonate is subjected to filling modification, so that the strength of the porous vaterite-phase nano calcium carbonate can be improved.

The purpose of the present invention is to provide a concrete that has sufficient strength while reducing the amount of CO2 emission. The present invention pertains to an agent for accelerating production of calcium carbonate having a vaterite-type crystal structure. The accelerating agent contains a compound having a plurality of amino groups, and is used when reacting carbon dioxide with a composition containing 5 mass% or more of calcium silicate hydrate.

The invention belongs to the technical field of calcium carbonate synthesis, and particularly relates to a preparation method and application of vaterite type calcium carbonate. The preparation method of vaterite type calcium carbonate comprises the following steps: (1) mixing a calcium-containing raw material, an ammonia source and a surfactant, and reacting to obtain a calcium ion leachate; (2) introducing gas containing carbon dioxide into the calcium ion leachate, reacting and separating to obtain vaterite type calcium carbonate and filtrate; in the step (1), the pH value of the mixed system is 8-12; in the step (2), the pH value of the reaction is 8-12. The pH value of the reaction system is controlled to be 8-12, so that the reaction system can form an NH3 / NH4 < + > system, the vaterite crystal surface energy is adsorbed and reduced, conversion to calcite is inhibited, and the purity and low-temperature stability of vaterite type calcium carbonate are improved. In addition, the filtrate obtained by the method can be used as an ammonia source to return to the step (1) for recycling.

The invention belongs to the technical field of sandy soil modifying agents, and particularly relates to a sandy soil modifying agent and a sandy soil modifying method. The sandy soil improver comprises a functional bacterium suspension and a cementing liquid, the functional bacteria in the functional bacteria turbid liquid can perform biomimetic mineralization on calcium salt in the cementing liquid to generate inorganic cement calcium carbonate (the crystal form is calcite and / or vaterite), and the inorganic cement is a cementing component widely distributed in natural soil and can maintain high cementing strength and a stable structure of the sandy soil, so that the sand stabilization effect is realized. Secondly, the formed inorganic cement is consolidated on the surface layer of the sandy soil in the form of a crust layer, the main component of the crust layer is calcium carbonate, and the calcium carbonate is white or yellowish white and light in color and can significantly reduce the solar radiation effect, so that the earth surface soil temperature rise speed of the sandy soil is slowed down, the water evaporation is slowed down, the water retention is enhanced, and the drying and hardening of the surface crust layer are slowed down; and germination and growth of plant seeds are facilitated.

The invention discloses a microwave-assisted energy-saving method for preparing vaterite by micro-bubble mineralization regeneration of waste stone powder, and belongs to the field of high-added-value resource utilization of solid wastes. The method comprises the following steps: mixing waste stone powder and iron-rich sludge, preheating, carrying out microwave-assisted heating, activating the waste stone powder, and pyrolyzing the iron-rich sludge into an iron-carbon material to obtain a mixed material; mixing the mixed material with a leaching agent for digestion, separating out the iron-carbon material in the digestion process, and adjusting the pH value to remove impurities; and injecting flue gas generated by heating into the digested solution in a micro-nano bubble form, stirring, adding a crystal form regulator, and reacting to obtain vaterite. According to the method, the waste stone powder and the iron-rich sludge are co-treated in a microwave-assisted pyrolysis manner, the treatment scale is large, the iron-rich sludge is carbonized, the surface iron minerals are modified, a high-energy wave-absorbing point is formed, the energy consumption is low, the obtained micro-nano vaterite and the iron-carbon material have great additional values, the product performance is good, and zero carbon emission is realized in the whole process.

The invention relates to the technical field of calcium carbonate manufacturing, in particular to a preparation method of high-whiteness light calcium carbonate. Comprising the following steps: efficiently leaching the calcium element in the carbide slag; preparing a microbial crystal form control agent; and carrying out electric dispersion treatment and precipitation on calcium ions. The microbial crystal form control agent is prepared by regulating and controlling the mixing ratio of the bacillus pumilus fermentation liquor to the pseudomonas fluorescens fermentation liquor, and it is avoided that in the full mixing process of the microbial crystal form control agent and the calcium-containing filtrate, Ca < 2 + > is mineralized to form large calcium carbonate particles; stearic acid and sodium polyacrylate in the microbial crystal form control agent can enable particles to be more stable, provide ion adsorption capacity, optimize the crystal form of calcium carbonate and form vaterite type crystals with smaller crystal form, and bacillus pumilus can assist generation of small-particle-size calcium carbonate along with time, so that high-whiteness small-particle-size light calcium carbonate is obtained.

The present application belongs to the technical field of paper deacidification, and particularly relates to a method for deacidifying and reinforcing paper by using nanocellulose and vaterite calcium carbonate. The method uses vaterite calcium carbonate as a deacidifying agent and γ-aminopropyl triethoxysilane modified nanocellulose as a reinforcing agent to achieve deacidification and reinforcement of paper. The concentration of the vaterite calcium carbonate dispersion is 5-20 g / L, the concentration of the modified nanocellulose dispersion is 0.5-5 g / L, and the dispersing agents for both are ethanol. The method has good deacidification, reinforcement and anti-aging effects on paper.

Various aspects present advantageous composition with substituting SCMs in blended cements with vaterite at levels between 5% and 15%. In the cement-fly ash blends, the replacement of 10% of fly ash with vaterite resulted in a 40% increase in strength after 1 day, and the increased compressive strength persisted over a 56-day period when compared to the control cement-fly ash blend. Aspect systems may comprise a first reactor, operating at a first temperature, and configured to calcine limestone and produce Portland cement and a gaseous composition comprising carbon dioxide, a second reactor, operating at a second temperature which is lower than the first temperature, and configured to produce vaterite using a portion of the carbon dioxide, and a blending reactor configured to produce a cementitious blend comprising the Portland cement, the vaterite, and SCM.

Various aspects present advantageous composition with substituting SCMs in blended cements with vaterite at levels between 5% and 15%. In the cement-fly ash blends, the replacement of 10% of fly ash with vaterite resulted in a 40% increase in strength after 1 day, and the increased compressive strength persisted over a 56-day period when compared to the control cement-fly ash blend. Aspect systems may comprise a first reactor, operating at a first temperature, and configured to calcine limestone and produce Portland cement and a gaseous composition comprising carbon dioxide, a second reactor, operating at a second temperature which is lower than the first temperature, and configured to produce vaterite using a portion of the carbon dioxide, and a blending reactor configured to produce a cementitious blend comprising the Portland cement, the vaterite, and SCM.

The invention discloses a preparation method of a calcium carbonate-polyvinyl alcohol composite aerogel material, and belongs to the technical field of thermal insulation materials. The invention aims to solve the problems that the crystallization behavior of calcium carbonate is difficult to effectively regulate and control and the porous structure and the heat insulation function of aerogel are easily damaged in the prior art. The method comprises the following steps: reacting a mixed solution of calcium chloride and magnesium chloride with carbon dioxide to prepare micro-nano amorphous calcium carbonate and a small amount of nano calcite; co-doping the chitosan and aspartic acid into polyvinyl alcohol hydrogel, uniformly mixing, and carrying out directional freezing and freeze-drying treatment; finally, high-concentration carbon dioxide atmosphere treatment is adopted in a humid and hot environment, amorphous calcium carbonate is induced to be dissolved on the polyvinyl alcohol framework and recrystallized into calcite and vaterite shell layers, and therefore the composite aerogel material is obtained. While good heat insulation performance and flexibility are maintained, the mechanical strength and damp and heat resistance stability of the material are remarkably improved, efficient curing and utilization of carbon dioxide are achieved, and the material is suitable for the field of green energy-saving buildings.

The present invention provides compositions, methods, and systems for forming vaterite and magnesium oxide. [Solution] This specification provides compositions, methods, and systems comprising vaterite and magnesium oxide. In some embodiments of the above-described aspects, the method further comprises the step of generating a solid comprising magnesium oxide in step (ii), and treating an aqueous solution comprising a calcium salt and magnesium oxide, as well as the solid comprising magnesium oxide, with a gas stream comprising carbon dioxide to form a composition comprising vaterite, magnesium oxide, and a solid comprising magnesium oxide.

Methods are provided herein comprising: a) calcining limestone in a cement plant to form carbon dioxide and a calcium compound selected from calcium oxide, calcium hydroxide, or combinations thereof; b) treating the calcium compound with N-containing salt in water to produce an aqueous solution comprising calcium salt and N-containing salt; and c) contacting the aqueous solution with carbon dioxide under one or more precipitation conditions to produce a precipitate comprising calcium carbonate and a supernatant aqueous solution wherein the calcium carbonate comprises vaterite.

Various aspects relate to production of synthetic aragonite material. In some aspects direct precipitation of aragonite, via controlling certain environmental conditions, is disclosed. In some aspects aragonite crystals may grow on seeds of other particles, such as aragonite crystals, to produce long aragonite structures. In some aspect, metastable calcium carbonate such as vaterite or amorphous calcium carbonate is transformed into aragonite. In various aspects different compositions of calcium carbonate polymorphs, including aragonite, with different aspect ratios are used to produce cementitious or non-cementitious compositions with superior properties.

A carbon dioxide mineralization process is disclosed, which includes introducing ammonium hydroxide solution and a calcium chloride solution into a reaction vessel to form a mixed solution, introducing carbon dioxide gas into the reaction vessel, and forming a calcium carbonate precipitate. Implementations of the carbon dioxide mineralization process can include where the mixed solution further may include tannic acid. A concentration of tannic acid can be from about 0 mg / mL to about 2 mg / mL. A flow rate of the introduction of carbon dioxide gas can be from about 0 L / min to about 1.0 L / min. The carbon dioxide mineralization process may include providing ultrasonic energy at a frequency of from about 20 khz to about 130 khz to the mixed solution. The carbon dioxide mineralization process may include filtering the calcium carbonate precipitate through a polyvinylidene fluoride membrane. The calcium carbonate precipitate may include a metastable vaterite phase.

The invention relates to a method for regulating and controlling the crystal form of calcium carbonate by using electromagnetic pulses, which comprises the following steps: emitting electromagnetic pulses with corresponding frequencies to a mixed solution of a calcium ion source solution and a carbonate ion source solution to regulate and control the forming process of calcium carbonate crystals, thereby regulating the crystal form of the generated calcium carbonate crystals. Compared with a traditional method for directionally synthesizing the calcium carbonate crystal form, the method does not need to regulate and control synthesis conditions and raw material ratio, use a control agent and a guiding agent and other operations, effectively avoids the problems of harsh synthesis conditions, complex steps, poor stability and the like in traditional synthesis, can reduce the reaction time and intermediate loss, improves the production efficiency, and is suitable for industrial production. Finally, calcite type, aragonite type or vaterite type calcium carbonate crystals which have different physicochemical properties and are suitable for different application scenes can be stably and efficiently obtained.

The present application relates to the technical field of calcium carbonate manufacturing, and particularly relates to a preparation method of high-whiteness light calcium carbonate. The method comprises the following steps: efficient leaching of calcium element in carbide slag; preparation of microbial crystal form control agent; and electric dispersion treatment and precipitation of calcium ions. The microbial crystal form control agent is prepared by adjusting the mixing ratio of Bacillus pumilus fermentation liquor and Pseudomonas fluorescens fermentation liquor, so that Ca 2+ The stearic acid and sodium polyacrylate in the microbial crystal form control agent can make the particles more stable and provide ion adsorption capacity after the larger calcium carbonate particles are mineralized, CO2 is introduced after temperature rising, and the crystal form of the calcium carbonate is optimized, so that the vaterite type crystallization with smaller crystal form is formed. The Bacillus pumilus can also assist in generating small-particle-size calcium carbonate over time, so that the high-whiteness small-particle-size light calcium carbonate is obtained.

The invention provides a method for preparing vaterite based on a continuous instantaneous nano precipitation technology. According to the invention, carboxymethylated xylan (CMX) is used as an organic matrix for calcium carbonate nucleation and a crystal growth inhibitor, the carboxymethylated xylan (CMX) and carbonate are co-precipitated in a multi-channel vortex mixer (MIVM), and stable vaterite (CaCO3 (at) CMX) is generated through an instantaneous nano-precipitation technology; the vaterite has the advantages of narrow particle size distribution range and high specific surface area, the particle size range is 1-1.5 mu m, and the specific surface area reaches 97.28 m < 2 > / g; the vaterite has potential application value in the aspect of active ingredient delivery, can be used as an agricultural chemical loading platform, and has good practicability.

Various aspects relate to production of synthetic aragonite material. In some aspects direct precipitation of aragonite, via controlling certain environmental conditions, is disclosed. In some aspects aragonite crystals may grow on seeds of other particles, such as aragonite itself, to produce long aragonite structures. In some aspect, metastable calcium carbonate such as vaterite or amorphous calcium carbonate is transformed into aragonite. In various aspects different compositions of calcium carbonate polymorphs, including aragonite, with different aspect ratios are used to produce cementitious or non-cementitious compositions with superior properties.

The invention belongs to the technical field of auxiliary cementing material preparation, and particularly relates to a method for preparing a high-activity auxiliary cementing material from recycled concrete fine powder. The preparation method comprises the following steps: infiltrating RCF by using ammonia water, then carrying out wind power suspension carbonation treatment to obtain a high-activity auxiliary cementing material, carrying out wind power suspension carbonation (WSC) treatment, reassembling a particle structure of the RCF to form RCF wrapped by calcium carbonate capsules, and inducing vaterite type calcium carbonate to be formed on the surface of the RCF by using an NH3.H2O solution as a crystal form control agent, so that the RCF is subjected to high-activity and high-activity auxiliary cementing material. The vaterite'capsule 'formed by the method not only reduces the water absorption of the RCF, but also improves the reaction activity.

The invention discloses a stable preparation method of an unsteady vaterite calcium carbonate crystal, and belongs to the technical field of inorganic material preparation. According to the method, gamma-dicalcium silicate (gamma-C2S) is taken as a slow-release calcium source, amino acid is taken as a crystal form regulating agent, CO2 is introduced into a system at normal temperature and normal pressure for a carbonization reaction, and an unstable state reaction environment of instantaneous supersaturation-dynamic passivation-heterogeneous adsorption is constructed, so that controllable nucleation of vaterite is realized, and transformation of vaterite to calcite is remarkably inhibited. Optionally, gypsum powder can be added as a crystal form stabilizer, and the stability of vaterite is further enhanced through heterogeneous adsorption. The process is simple, green and energy-saving, and the obtained vaterite calcium carbonate crystal is high in purity, regular in morphology and excellent in long-term stability in water, and is suitable for the fields of carbon mineralization carbon sequestration, functional fillers, low-carbon building materials and the like.

The application discloses an Escherichia coli coated calcium carbonate composite material powder, a block and a preparation method thereof. The preparation method comprises the following steps: mixing and stirring natural Escherichia coli expressing GFP and a buffer solution containing calcium ions to obtain a suspension; adding an aqueous solution containing carbonate ions into the suspension, and after the adding is completed, centrifuging, washing and drying to obtain the Escherichia coli coated calcium carbonate composite material powder. The application effectively combines the natural Escherichia coli expressing GFP and calcium ions to inhibit the crystal type conversion, and after the titration is completed, the centrifugation and washing are rapidly performed, so that the single vaterite powder with stable crystal type is successfully prepared, and then the composite material block is prepared through a cold sintering process. The operation method is simple, the cost is low, and the application is suitable for large-scale production, so that a new research idea is provided for preparing a large-size heterogeneous composite material which can realize the synergistic improvement of strength and toughness and has a macroscopic geometric shape.

The invention belongs to the technical field of nano calcium carbonate processing, and discloses aging equipment for processing nano calcium carbonate, which comprises an aging tank body, and further comprises an initial aging assembly which is arranged on the aging tank body and is used for playing an initial mild circulation effect in the initial aging of nano calcium carbonate and maintaining the integrity of crystals. By means of multi-stage composite stirring, the defect that existing aging equipment is poor in adaptability is overcome in a targeted mode, precise adaptation of all aging stages of nano calcium carbonate slurry with different viscosities is achieved, metastable-state crystal vaterite / aragonite can be prevented from being broken through mild circulation of a hollow pipe and a spiral blade at the early stage of aging, and the integrity of crystals is maintained; in the middle stage, the rotation of the inclined cutter and the slurry dispersing height can be adjusted by means of the electric cylinder, the shearing dispersion of the high-viscosity slurry is enhanced, a foundation is laid for hard agglomeration breaking, and in the later stage, the large-range low-shearing paddles are used for protecting the shaped calcite crystals, ensuring the ageing sufficiency and providing a stable material environment for subsequent quality optimization.