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This invention discloses a method for preparing sulfonamide-modified benzo[a]fluorene-5-one derivatives, using 1,7-enyne and N Using sulfonylaminopyridine salts as raw materials, a series of sulfonated benzo[a]fluorene-5-one compounds were successfully synthesized by catalyzing the sulfonation / cyclization tandem reaction of 1,7-enynes under photocatalytic conditions. This method has excellent functional group tolerance and high economic applicability.

The application relates to the field of sodium ion batteries, and discloses a preparation method of hierarchical porous Fe7S8 / nitrogen-doped carbon composite nanowires and application thereof. The application takes NTA as a metal ion chelating agent, chelates zinc ions and iron ions through a solvothermal reaction, and prepares a ZnFe-NTA precursor; the precursor is pyrolyzed at high temperature under an inert atmosphere, metal ion reduction is induced through a carbon thermal reaction, low-boiling-point zinc particles are volatilized, nitrogen-doped carbon formed through in-situ conversion of an organic ligand is combined, and a hierarchical porous structure is generated; finally, a gas-phase sulfuration method is adopted to form Fe7S8, and the hierarchical porous Fe7S8 / nitrogen-doped carbon composite nanowires are obtained. When the composite nanowires are used as a negative electrode of a sodium ion battery, the hierarchical porous structure can effectively promote full infiltration of electrolyte and rapid migration of sodium ions, and can improve cycle stability and rate performance.