Ozone oxidation catalyst based on active gamma-alumina ball carrier and preparation method thereof
A technique for oxidation of alumina balls and ozone, applied in the direction of metal/metal oxide/metal hydroxide catalysts, physical/chemical process catalysts, chemical instruments and methods, etc., can solve problems such as difficult catalytic oxidation, and reduce operating costs , low price, simple and easy-to-control effect
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[0022] And, the embodiment of the present invention also provides a preparation method of an ozone oxidation catalyst based on active gamma-alumina spherical support, comprising the following steps:
[0023] S01. Provide active gamma-alumina balls, dry them after cleaning, and test the water absorption of the dried active gamma-alumina balls;
[0024] S02. The activated γ-alumina balls are placed in a container, and the metal oxide precursor solution is added by an equal-volume impregnation method, and the metal oxide precursor is adsorbed and then dried;
[0025] S03. Put the active gamma-alumina balls adsorbed with the metal oxide precursor into a heating device, heat and calcinate them at 250-600°C for 2-8 hours, and obtain the activated gamma-alumina ball carrier based on the active gamma-alumina balls after aging treatment Ozone oxidation catalyst.
[0026] Specifically, in the above step S01, preferably, the activated γ-alumina balls have a diameter of 4-6mm and a speci...
Embodiment 1
[0039] 1000 grams of activated alumina balls were washed 3 times with tap water and dried in a drying oven at 120°C. Put the weighed active alumina balls into 900 ml of 0.128 mol / L manganese nitrate solution for medium-volume immersion treatment, and stir for 3 hours. The activated alumina balls adsorbing manganese nitrate were placed in a drying oven at 40°C for 10 h. The dried samples were put into a resistance furnace for calcination at a rate of 2°C / min to 250°C and kept for 2h. Finally, the calcined sample was washed with tap water to remove surface fine powder, and put into a drying oven at 120° C. for 10 h to obtain an ozone oxidation catalyst with a loading capacity of 1%.
Embodiment 2
[0041] 1000 grams of activated alumina balls were washed 3 times with tap water, and dried in a drying oven at 150°C. Put the weighed activated alumina balls into 900 ml of 0.703 mol / L manganese nitrate solution for medium-volume impregnation, and stir for 7.5 hours. The activated alumina balls adsorbing manganese nitrate were put into a drying oven and dried at 70°C for 29h. The dried samples were placed in a resistance furnace for calcination at a rate of 6 °C / min to 425 °C and kept for 5 h. Finally, the calcined samples were washed with tap water to remove surface fine powder, and put into a drying oven at 150° C. for 29 hours to dry the ozone oxidation catalyst with a loading capacity of 5.5%.
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