The invention belongs to the technical field of environmental functional materials, and discloses a preparation method and application of an
oxygen-vacancy-enriched
ferrocobalt spinel and carbon core-shell
microreactor. According to the method, a
cobalt-iron
spinel and carbon core-shell catalyst with rich
oxygen vacancies is constructed through a defect
engineering and morphology
engineering synergistic strategy, and peroxymonosulfate (PMS) is efficiently activated to degrade
antibiotics in water. The method specifically comprises the following steps: synthesizing a
ferrocobalt spinel-carbon core-shell structure by adopting hydrothermal,
metal ion adsorption and
pyrolysis processes, and introducing
oxygen vacancies through KBH4 reduction to optimize
electron transfer and catalytic activity of the
ferrocobalt spinel-carbon core-shell structure. The carbon
nucleus in the obtained catalyst effectively enriches pollutants and PMS, and the confinement effect shortens the migration path of
active oxygen species; and the PMS activation efficiency is obviously improved by the introduced oxygen vacancies. The catalyst is efficient when used for degrading
antibiotics such as
ciprofloxacin, has the advantages of high
reaction rate constant, high removal rate, wide pH adaptability, strong anti-interference capability, low
metal leaching and the like, and has a wide application prospect in the field of environmental governance.