438 results about "Doped graphene" patented technology

The invention discloses an anti-corrosion fireproof coating applied to a new energy battery box and a preparation method, and relates to the technical field of industrial coatings, the anti-corrosion fireproof coating comprises the following specific components: a base resin system, a curing agent, a functional filler system, a flame retardant system, a solvent system and an auxiliary agent system; the anticorrosive and fireproof coating further comprises additives, wherein the additives specifically comprise a functionalized MXene loaded lithium ion adsorbent, a metal organic framework encapsulated quaternary phosphonium salt, polyaryletherketone coated antimony trioxide nano-particles and boron-nitrogen co-doped graphene aerogel powder; the material is prepared based on the materials. According to the invention, multiple additives are synergistically introduced into a traditional basic coating system, and on the basis of a basic flame-retardant and anti-corrosion structure, lithium ion directional adsorption, gas-phase free radical active intervention, high-temperature carbonization barrier construction and three-dimensional thermal barrier network configuration are further realized; therefore, the multi-dimensional safety performance of the coating in battery thermal runaway, salt spray corrosion and high-temperature impact environments is remarkably improved.

The invention relates to a dual-rare earth metal catalytic nano material, a diaphragm and a preparation method and application thereof. The preparation method comprises the following steps: carrying out hydrothermal reaction on an aqueous solution containing a carbon source, a hard template, a graphene oxide dispersion liquid, a nitrogen source, a phosphorus source, cerium salt and neodymium salt; then carrying out centrifugal separation to obtain a precipitate, and generating a precursor containing Ce and Nd rare earth bimetallic modified nitrogen and phosphorus doped graphene coated microspheres; and carrying out chemical etching on the precipitate after heat treatment to obtain the dual-rare earth metal catalytic nano material (HCS-coated NPrGO / CeNd). The HCS-coated NPrGO / CeNd can be used as a modification material of a lithium-sulfur battery diaphragm, not only can catalyze the conversion of polysulfide, but also can inhibit the shuttle effect of the polysulfide, so that the lithium-sulfur battery has relatively high capacity under high-rate charge and discharge, and has relatively low capacity fading rate in a high-rate long-cycle test.

The invention relates to the technical field of electrode paste, in particular to electrode paste for a submerged arc furnace and a preparation method of the electrode paste. Comprising three-level grain size distribution anthracite aggregate which is electrically calcined at high temperature and modified by a KH-550 silane coupling agent, a modified silicon carbide whisker and boron-doped graphene-like carbon nitride composite filler, a maleic anhydride-mediated compatible medium-temperature pitch-polyborosiloxane binder and a graphite powder-borax functional additive. A step-by-step mixing and two-stage sintering process is adopted in the preparation process, a covalent bond interface bridging structure is constructed through the coupling agent, the composite dispersing agent regulates and controls the multi-dimensional network distribution of the filler, and the process synergistically improves the compactness and the interface bonding force of the green body. The electrode paste is firm in interface bonding, can form a ceramic protective phase at a high temperature, has excellent conductivity and mechanical strength, and prolongs the service life of the electrode paste for the submerged arc furnace.

The invention relates to the field of catalysts, in particular to a preparation method and application of an alumina-loaded copper-doped graphene-like catalyst, and the preparation method comprises the following steps: step 1, dispersing biomass in deionized water to form a suspension A; step 2, adding an aluminum salt and an iron salt into the turbid liquid A to form a turbid liquid B; step 3, adding a nitrogen source into the turbid liquid B to form impregnation liquid C; step 4, pouring the steeping liquor C into a beaker filled with alumina pellets, and drying to obtain dried pellets; and 5, roasting the dried pellets in a tubular furnace, cooling to room temperature, repeatedly washing with water, and drying to obtain the catalyst. The catalyst disclosed by the invention can be used for rapidly degrading refractory organic pollutants in water within 30 minutes under the synergism of microorganisms. The catalyst provided by the invention has good stability in the process of removing organic pollutants, and almost no metal ions are released.

The present invention combines a fluorescence sensor with an array to provide a fluorescence sensing array detection platform and a detection method for multiple plasticizers. The fluorescence sensing array detection platform includes a B-doped graphene quantum dot solution using N,N-dimethylformamide as a solvent and a B-GQDs solution using cyclohexane as a solvent; the fluorescence intensity of the B-GQDs solution with DMF as the solvent at the fluorescence characteristic peak obtained under ultraviolet light excitation at a wavelength of 350 nm, and the fluorescence data at 391 nm, 413 nm, and 434 nm are used as array points 1, 2, and 3; the fluorescence intensity of the B-GQDs solution with CH as the solvent at the fluorescence characteristic peak obtained under ultraviolet light excitation at a wavelength of 350 nm, and the fluorescence data at 386 nm, 408 nm, and 430 nm are used as array points 4, 5, and 6; thus, a 3×2 fluorescence sensor array is constructed. The detection method using the fluorescence sensor array of the present invention has simple steps, and has satisfactory specificity, reproducibility, stability and practicability, and has application potential.

According to the cobalt-doped molybdenum disulfide lithium-sulfur battery composite positive electrode material, the preparation method and the application, a cobalt-doped stable molybdenum disulfide defect structure composite nitrogen-doped graphene material is prepared by combining a solvothermal method and an annealing technology, and the process is mature; the method is simple, and the composite positive electrode material with high sulfur content is easy to obtain. According to the lithium-sulfur battery composite sulfur positive electrode material disclosed by the invention, the strong chemical adsorption effect and catalytic conversion effect of the cobalt-doped stable molybdenum disulfide defect structure composite nitrogen-doped graphene carrier on polar lithium polysulfide are utilized, so that the diffusion of the lithium polysulfide in an ether electrolyte is inhibited, and the electrochemical reaction kinetics is improved; therefore, the shuttling effect is slowed down, and the lithium-sulfur battery has the characteristics of high capacity and long service life.

The invention belongs to the technical field of graphene film preparation, and particularly relates to a graphene thick film preparation method, which comprises: mixing a boric acid aqueous solution and a graphene oxide dispersion liquid to obtain a boric acid / graphene oxide mixed dispersion liquid; after the mixed dispersion liquid of boric acid / graphene oxide is coated, a solvent is evaporated, and a boric acid doped graphene oxide film is prepared; and stacking a plurality of layers of boric acid doped graphene oxide films, performing pressurization treatment, and performing annealing treatment in an inert atmosphere to obtain the graphene thick film. The preparation method provided by the invention not only solves the problem of film interface effect of the graphene thick film in the prior art and remarkably improves the conductivity of the graphene thick film, but also realizes effective regulation and control of the thickness of the graphene thick film through a simple stacking mode, and the preparation method is suitable for large-scale production. Powerful support is provided for application of the graphene thick film in the fields of electrochemical energy storage, electromagnetic shielding, heat dissipation and electric conduction.

The invention relates to the technical field of capacitors, and discloses a high-energy-density capacitor which is characterized in that a positive electrode is composed of a composite active material, a conductive agent and a binder, the composite active material comprises a mixture of nitrogen-sulfur co-doped carbon foam magnetic microspheres and iron sesquioxide nanodot at nitrogen-doped graphene, and the conductive agent is a mixture of nitrogen-sulfur co-doped carbon foam magnetic microspheres and iron sesquioxide nanodot at nitrogen-doped graphene. The preparation method of the nitrogen-sulfur co-doped carbon foam magnetic microspheres comprises the following steps: by taking polyacrylonitrile as a carbon source, thiourea as a sulfur source and ferric nitrate as an iron source, carrying out hydrothermal reaction and then carrying out carbonization treatment at 800-1000 DEG C for 2-4 hours; the energy density of the high-energy-density capacitor can reach 700-800 Wh / kg, the power density is larger than or equal to 10 kW / kg, compared with a traditional super capacitor, the high-energy-density capacitor has the advantages that the energy density is remarkably improved, and the application requirements of the fields with high requirements for energy and power such as electric automobiles and intelligent power grids can be met.

A boron-doped graphene composite solid-state electrolyte and its preparation and application. A mixed solution of polyacrylonitrile (PAN) and N,N-dimethylformamide is prepared into a PAN porous film using electrospinning technology. A PEO casting solution is prepared by mixing boron-doped graphene, polyethylene oxide, lithium bis(trifluoromethanesulfonylimide), and acetonitrile. This solution is then cast onto the PAN porous film and, after vacuum drying, forms a composite solid-state electrolyte with polyacrylonitrile fibers as a support, polyethylene oxide as a matrix, and boron-doped graphene as a filler. The composite solid-state electrolyte prepared by the present invention has high ionic conductivity and lithium ion transference number, providing lithium batteries with good rate performance and cycle stability.

The present invention relates to the technical field of high thermal insulation carbon materials and provides a carbon fiber-doped graphene oxide foam material, a preparation method therefor, and a use thereof. In the present invention, graphene oxide and carbon fibers are composited in a hydrothermal synthesis manner, the resulting composite is processed into a composite aerogel in a freeze drying manner, and the composite aerogel is carbonized and graphitized to prepare the carbon fiber-doped graphene oxide foam material. The carbon fiber-doped graphene oxide foam material of the present invention can resist a high temperature of 2000-3000℃. The carbon fiber-doped graphene oxide foam material has a heat conductivity coefficient of 0.16-0.27 W / m·K and a porosity of 85-95%. The carbon fiber-doped graphene oxide foam material has excellent high-temperature resistance and stability, and maintains good mechanical properties and structural strength while improving the heat insulation performance.

The invention belongs to the technical field of new energy batteries, and particularly relates to a fluorine-doped graphdiyne material and a preparation method and application thereof. The preparation method of the fluorine-doped graphdiyne material comprises the following steps: in a solvent system, mixing graphdiyne and a solid fluorine source, and drying to obtain a composite precursor; under the protective atmosphere, the composite precursor is annealed, so that the fluorine source is decomposed to release hydrogen fluoride and fluorine free radicals, the hydrogen fluoride or the fluorine free radicals are combined with carbon sites on graphdiyne through nucleophilic substitution, C-F bonds are formed, and the fluorine-doped graphdiyne material is obtained; the mass ratio of graphdiyne to the solid fluorine source is 30: (1-4). The fluorine-doped graphdiyne has the advantages that the defects are increased, the disorder is reduced, and the lithium storage capacity of the graphdiyne is improved, so that the long-term cycle performance and the high-rate performance are improved.

The invention discloses a method for screening a high-catalytic-activity nitrogen-doped graphene-loaded single-metal-atom ammonia synthesis catalyst, and belongs to the technical field of ammonia synthesis. The method comprises the following steps: constructing an original graphene configuration; constructing a nitrogen-doped graphene configuration; a nitrogen-doped graphene loaded monometal configuration is constructed; the Eform is formed to judge the stability; constructing an adsorption configuration of reactant molecules; analyzing the relaxation configuration to judge the activation degree; the adsorption stability is judged according to the adsorption energy Eads; determining a path of N2 thermal reduction reaction; adopting NEB and Dimer methods to construct a transition state spatial configuration; reaction heat and activation energy are calculated, and activity differences of different catalyst surfaces are analyzed. Based on density functional theory calculation, catalyst screening standards with formation energy, adsorption energy and activation energy barriers as indexes are established, the high-activity catalyst is screened out theoretically, the experiment trial and error cost is reduced, and the catalyst development efficiency is improved.

A method of forming a graphene device includes: providing a glass substrate with a blocking layer disposed thereon to form a stack; providing a first electrode and a second electrode; increasing the temperature of the stack to at least 100° C.; applying an external electric field (VP) to the first electrode such that at least one metal ion of the glass substrate migrates toward the first electrode to create a depletion region in the glass substrate adjacent the second electrode; decreasing the temperature of the stack to room temperature while applying the external electric field to the first electrode; and after reaching room temperature, setting the external electric field to zero to create a frozen voltage region adjacent the second electrode.

The present invention discloses a sulfur-nitrogen co-doped graphene hollow nanosphere and its preparation and application, belonging to the technical field of graphene nanomaterials. During the preparation, a mixture of thiourea and zinc powder is first calcined under the protection of an inert gas, and then H2O and HCl are added to the calcined product and heated for reaction, followed by post-processing to obtain the target product. The resulting product is a sulfur-nitrogen co-doped graphene material, which presents a hollow spherical morphology. This material has a large specific surface area and pore volume, and both the nitrogen and sulfur doping amounts have reached a high level. It has been verified that the obtained high-sulfur-nitrogen co-doped graphene hollow nanospheres have unique graphite nitrogen-pyridine nitrogen-thiophene sulfur synergistic active sites, which have high atomic utilization and high stability, and exhibit the best performance of activating persulfate to degrade organic matter. It can continuously and rapidly separate organic pollutants in actual water bodies and exhibit excellent stability.

The invention provides application of a metal ion doped aminated graphene oxide membrane material in catalyzing CO2 to synthesize cyclic carbonate. The metal ion doped aminated graphene oxide membrane material has an acidic catalytic site and an alkaline catalytic site at the same time, and a two-dimensional interlayer channel of the metal ion doped aminated graphene oxide membrane material also has a confinement effect. In the process of catalyzing a CO2 / epoxy compound cycloaddition reaction, epoxy compound molecules entering a two-dimensional interlayer confinement channel of the metal ion doped aminated graphene oxide membrane material are subjected to efficient ring opening under the combined action of organic amine molecules and metal ions and react with CO2; and finally, realizing CO2 high-efficiency (the reaction time is less than or equal to 5 minutes, and the conversion rate of the epoxy compound is 75-100%) synthesis of the cyclic carbonate under the conditions of room temperature and low pressure (greater than 0.1 MPa and less than or equal to 1 MPa).

The invention provides a monocrystalline silicon wafer cleaning system and method. The cleaning system comprises a first cleaning tank; a second washing tank; a third cleaning tank; a fourth cleaning tank; a high-pressure conveying device; the fourth cleaning tank comprises a first tank body used for containing a first cleaning solution containing a hydrogen peroxide aqueous solution, a second tank body used for containing a second cleaning solution containing the hydrogen peroxide aqueous solution and a third tank body used for containing a third cleaning solution containing the hydrogen peroxide aqueous solution. The at least one first light source is used for providing light for the first tank body, the at least one second light source is used for providing light for the third tank body, the first tank body is communicated with the second tank body through a first free radical oxidation resistant reverse osmosis membrane, and the second tank body is communicated with the third tank body through a second free radical oxidation resistant reverse osmosis membrane; at least one composite plate is arranged in each of the first groove body and the second groove body; and each composite plate comprises doped graphene, so that the problems of high cleaning cost of the monocrystalline silicon wafer and complex wastewater treatment are solved.

The present application relates to thermal insulation coating technical field, specifically to a kind of low VOCs ultraviolet resistant thermal insulation coating composition and its performance testing device, consisting of the following mass parts components: water-based acrylic resin 30-45 parts, nitrogen-doped graphene 1-3 parts, nano composite powder 2-5 parts, low water absorption and expansion glass microsphere 8-12 parts, silane coupling agent modified sepiolite 5-10 parts, silane coupling agent KH560 0.5-1.5 parts, ultraviolet absorber UV-9 0.3-0.8 parts, hydroxyethyl cellulose thickening agent 0.2-0.5 parts;Composition meets the following conditions: (1) VOCs content≤50g / L;(2) ultraviolet absorption rate≥95%;The present application realizes the purpose that VOCs content is far lower than traditional solvent type coating through the synergistic effect of water-based acrylic resin system and low water absorption and expansion glass microsphere, while nitrogen-doped graphene and nano ITO-SiO2 Composite powder form ultraviolet-infrared dual-effect shielding layer, ultraviolet absorption rate, infrared reflectivity greatly improve, solve the problem that traditional anti-UV coating function is single, VOCs is overproof.

The invention discloses a hydrogen-fluorine atom doped graphdiyne material and a preparation method thereof, and relates to the technical field of carbon materials. According to the method, halogenated aromatic hydrocarbon and an alkynyl compound are taken as raw materials, a palladium catalyst and a copper catalyst are taken as a catalytic system, and an acetylenic bond of the alkynyl compound and the halogenated aromatic hydrocarbon are subjected to a Sonogashira coupling reaction to obtain the hydrogen-fluorine-doped graphite alkynyl material. The graphdiyne material provided by the invention has a large pore diameter, multiple active sites and high thermal stability and chemical stability, so that the hydrofluorine-doped graphdiyne material has excellent electrochemical energy storage property, shows reversible capacity of 1155mAh g <-1 > under 0.05 Ag <-1 > when being used as a negative electrode of a lithium ion battery, and can be used as a negative electrode of the lithium ion battery. And the density is almost 3 times that of a commercial graphite negative electrode material (300-350mAh g <-1 >). The application of the graphdiyne material in the field of electrochemical energy storage is obviously promoted.

The invention discloses an MOF / nitrogen-doped graphene-based electrocatalyst and a preparation method thereof, nitrogen-doped graphene has a single nitrogen configuration, and the nitrogen-doped graphene is pyridine nitrogen or pyrrole nitrogen; the MOF is ZIF-67, and the MOF is connected with a nitrogen atom of the nitrogen-doped graphene through a coordinate bond. Carrying out covalent functionalization on the surface of the graphene by using a specific pyridine nitrogen configuration polymer; then growing MOF in situ by taking the nitrogen-doped graphene as a precursor, and then calcining to realize the compounding of the nitrogen-doped graphene with the single nitrogen configuration and the MOF. According to the prepared MOF / nitrogen-doped graphene composite electrocatalyst, the stability and the electrocatalytic activity (such as OER, HER and ORR) of MOF can be remarkably improved. Meanwhile, the preparation method is simple in process, low in cost and remarkable in industrial application potential.

The invention discloses conductive silver paste doped with graphene powder and a preparation method of the conductive silver paste, and relates to the technical field of conductive silver paste. The method comprises the following steps: performing nitrogen doping on graphene by using plasma, introducing nitrogen atoms into graphene crystal lattices to form nitrogen-doped graphene, and introducing oxygen-containing functional groups on the surface of the graphene through a plasma surface modification technology to further improve the conductivity. The preparation method comprises the following steps: mixing an aniline monomer and an aminobenzoic acid monomer, carrying out in-situ polymerization on the surface of nitrogen-doped graphene to generate a polyaniline-aminobenzoic acid copolymer, and compounding a graphene-polyaniline material obtained by in-situ polymerization with carbon nanotubes to construct a three-dimensional conductive network. Secondly, the prepared three-dimensional filler is added into conductive silver paste, carboxyl in aminobenzoic acid is adsorbed and combined with silver particles through Van der Waals force, a stable interface structure is formed, the interface resistance is reduced, and the connectivity of a conductive network is enhanced. The prepared conductive silver paste has the effect of high conductivity.

The invention discloses an iron-carbon composite material for heavy metal contaminated soil remediation and a preparation method of the iron-carbon composite material, and belongs to the field of heavy metal contaminated soil remediation. The iron-carbon composite material comprises rape straw, hydroxyapatite, zero-valent iron, sulfydryl functionalized magnetic cerium oxide and nitrogen-doped graphene quantum dot-sodium alginate. The sulfydryl-functionalized magnetic cerium oxide is prepared from cerium nitrate and ferric nitrate through precipitation, calcination and sulfhydrylation, and the nitrogen-doped graphene quantum dot-sodium alginate is prepared from citric acid and urea through microwave reaction, dialysis, mixing and freeze drying; the preparation method comprises the following steps: treating straws and hydroxyapatite to obtain ball-milled phosphorus-containing biochar, mixing the ball-milled phosphorus-containing biochar with zero-valent iron and two modifiers, and carrying out molding and high-temperature calcination to obtain the phosphorus-containing biochar-based composite material. The material has a remarkable remediation effect on the heavy metal contaminated soil, can effectively reduce the activity of heavy metals in the soil, has the characteristics of environmental friendliness and high stability, and is suitable for treating the soil compositely contaminated by the heavy metals such as cadmium and lead.

The invention relates to an IrO2-Ta2O5 titanium anode coating based on graphene doping and temperature programming sintering synergistic enhancement and a preparation method of the IrO2-Ta2O5 titanium anode coating, and belongs to the technical field of electrode material preparation. According to the method, graphene is doped in an IrO2-Ta2O5 coating, the content of the graphene is controlled to be 0.2-0.8 mg / mL, preferably 0.6 mg / mL, the content of iridium is 26 g / m, and a 200-500 DEG C temperature programming sintering process is adopted. By optimizing the graphene dispersing and sintering process, the conductivity, the electrocatalytic activity and the structural stability of the coating are remarkably improved. Experimental results show that the coating has lower charge transfer resistance and higher electric double layer capacitance and oxygen evolution reaction activity, and the strengthening life of the coating exceeds 1100 hours and is far longer than that of a traditional titanium anode coating. The method is suitable for high-requirement electrochemical scenes such as electrolytic copper foil and chlor-alkali industry, and has a good industrial popularization prospect.

The invention relates to the technical field of superhard materials, and particularly discloses a polycrystalline diamond compact and a preparation method and application thereof.The preparation method of the polycrystalline diamond compact comprises the following steps that WC-Co alloy powder is sintered to obtain a hard alloy matrix; uniformly mixing nano diamond powder, micron diamond powder and cubic boron nitride, adding a reinforcing agent and a binding agent, and uniformly mixing to obtain a polycrystalline diamond layer mixture; the reinforcing agent is a nitrogen-boron doped graphene bonded amino carbon nanotube; a gradient transition layer raw material and a polycrystalline diamond mixture are uniformly spread on the surface of the hard alloy matrix in sequence, and then a composite blank is obtained through mold pressing; and sintering the composite blank to obtain the polycrystalline diamond compact. Graphene and carbon nanotubes are compounded to form a reinforcing agent with a three-dimensional network structure, so that the strength and wear resistance of the material are improved, and the service life of the material under harsh working conditions is prolonged.

The invention provides an Mxene quantum dot modified nitrogen-doped graphene material, a preparation method and an isolating membrane. The Mxene quantum dot modified nitrogen-doped graphene material comprises Mxene quantum dots and nitrogen-doped graphene, and based on the mass of the Mxene quantum dot modified nitrogen-doped graphene material, the mass percentage content of the Mxene quantum dots is 30%-60%. According to the Mxene quantum dot modified nitrogen-doped graphene material provided by the invention, a conductive-adsorption-catalysis interface can be constructed, the shuttle effect of polysulfide is effectively inhibited, rapid conversion of the polysulfide is promoted, and the cycle performance and rate capability of a lithium-sulfur battery are improved.

The invention belongs to the technical field of catalytic conversion materials, and particularly relates to nitrogen-doped graphene aerogel for H2S removal and a preparation method of the nitrogen-doped graphene aerogel. The preparation method of the nitrogen-doped graphene aerogel for H2S removal comprises the following steps: (1) uniformly mixing a graphene oxide aqueous solution with a nitrogen source to obtain a mixed solution; (2) carrying out a hydrothermal reaction on the mixed solution, and after the hydrothermal reaction is finished, freeze-drying the obtained hydrogel to obtain aerogel; and (3) carrying out carbonization treatment on the aerogel, so as to obtain the nitrogen-doped graphene aerogel for removing H2S. According to the nitrogen-doped graphene aerogel for H2S removal disclosed by the invention, large-size graphene sheet layers are mutually connected to form a macroporous and mesoporous mass transfer passage inside the nitrogen-doped graphene aerogel, and the surface of the material has a rich microporous structure and a high-content nitrogen doping characteristic, so that efficient adsorption and removal of H2S molecules can be realized.

The invention discloses a nickel-cobalt-loaded nitrogen-sulfur-doped graphene aerogel microsphere and a preparation method and application thereof.The preparation method comprises the following steps that S1, a graphene oxide water-phase dispersion liquid is prepared, L-cysteine is added into the graphene oxide water-phase dispersion liquid, the mixture is stirred to be uniform, and a first mixed dispersion liquid is obtained; s2, performing electrostatic spraying, obtaining ice microspheres by combining an ice template method, and performing freeze drying to obtain nitrogen and sulfur doped graphene oxide aerogel microspheres; s3, reduction is carried out, and nitrogen and sulfur doped reduced graphene oxide aerogel microspheres are obtained; s4, preparing a nickel-cobalt compound mixed dispersion liquid, adding nitrogen and sulfur doped reduced graphene oxide aerogel microspheres into the nickel-cobalt compound mixed dispersion liquid, and uniformly stirring to obtain a mixed dispersion liquid II; and S5, carrying out hydrothermal reduction, washing and freeze drying to obtain the nickel-cobalt-loaded nitrogen-sulfur-doped graphene aerogel microspheres. The nickel-cobalt-loaded nitrogen-sulfur-doped graphene aerogel microspheres with high catalytic activity can be provided, and technical support is provided for catalyzing propylene cracking to grow carbon nanotubes.

The invention relates to the technical field of palladium recovery, in particular to a method for recovering palladium. According to the technical scheme, the method comprises a precipitant pre-synthesis stage, a targeted palladium precipitation stage and a multi-stage reduction purification stage, and the precipitant pre-synthesis stage comprises the step of adding 10-15 parts by mass of butanedione, 18-30 parts by mass of hydroxylamine hydrochloride and 0.1-0.3 part by mass of iron phthalocyanine into a reaction kettle. Through a composite precipitator system and a multi-stage reduction process, the method has safety and high efficiency: flammable and explosive solvents such as ethanol and highly toxic reducing agents such as hydrazine hydrate are not needed, so that the potential safety hazard of production and the environment-friendly treatment cost are remarkably reduced; high-selectivity capture and efficient reduction of palladium are achieved through magnetic separation of magnetic nano-microspheres, induced precipitation of nitrogen-doped graphene quantum dots and a staged temperature-control and pressure-control reduction technology, the palladium recovery rate and purity are high, the process period is short, operation is controllable, and the method is suitable for industrial continuous production.

The application discloses a phosphine ligand modified nitrogen-doped graphene oxide / porous carbon supported metal catalyst and a preparation method and application thereof. The catalyst comprises phosphine ligand modified nitrogen-doped graphene oxide / porous carbon and rhodium supported on the nitrogen-doped graphene oxide / porous carbon; and the molar ratio of rhodium to phosphine is 1:1-100 in terms of elements. The phosphine ligand modified nitrogen-doped graphene oxide / porous carbon supported metal catalyst has better catalytic activity and product selectivity.

The application relates to the technical field of graphene, in particular to platinum-loaded nitrogen-doped graphene as well as a preparation method and application thereof. The preparation method of the platinum-loaded nitrogen-doped graphene comprises the following steps: mixing graphene oxide, a platinum salt and a solvent to form a mixed solution, and then performing a hydrothermal reaction to prepare graphene oxide-platinum salt composite powder; mixing the graphene oxide-platinum salt composite powder with an amino compound, and performing ball milling to prepare amino-modified graphene oxide-platinum salt composite powder; and performing microwave irradiation on the amino-modified graphene oxide-platinum salt composite powder to prepare platinum-loaded nitrogen-doped graphene. The preparation process is simple, and the prepared platinum-loaded nitrogen-doped graphene has good oxygen reduction catalytic activity.

The invention relates to a preparation method of an alumina-loaded iron-aluminum co-doped graphene-like catalyst and application of the alumina-loaded iron-aluminum co-doped graphene-like catalyst in the field of water treatment. The method comprises the following steps: dispersing biomass (such as silkworm excrement, corncob and the like) in water to form a suspension, sequentially adding ferric salt, aluminum salt and a nitrogen source (such as urea, melamine and the like), adjusting the pH value, impregnating alumina pellets, drying, and roasting at high temperature in an inert atmosphere to prepare the immobilized catalyst. According to the catalyst, iron-aluminum co-complexed nitrogen-doped graphene is loaded on alumina pellets, and the catalyst has high specific surface area and active sites. The catalyst disclosed by the invention is suitable for degrading refractory organic pollutants (such as tetracycline, bisphenol A and ciprofloxacin) in water, can realize rapid degradation within 30 minutes through a synergistic effect with microorganisms, and is excellent in long-term operation stability (for example, the tetracycline removal rate is kept 100% for 106 days). The immobilized design of the catalyst facilitates separation and recovery, avoids secondary pollution, and is suitable for industrial water treatment. The matched curing bed reactor controls contact reaction of pollutants and a catalyst through a peristaltic pump, and continuous and efficient treatment is achieved. The method has the advantages of low raw material cost, simple process, high catalytic activity and cyclic utilization, and provides an efficient and environment-friendly solution for the treatment of organic polluted water.