30 results about "Graphene nanoparticles" patented technology

The invention relates to the technical field of nanofluid enhanced heat transfer simulation, in particular to a molecular dynamics-based mixed nanofluid heat transfer characteristic analysis method, which comprises the following steps of: constructing a molecular model comprising copper, graphene nanoparticles and an ionic liquid / water mixed base solution, and calculating the heat transfer characteristic of the mixed nanofluid through a distribution potential function and a periodic boundary condition; and performing energy minimization and molecular dynamic relaxation to achieve thermodynamic equilibrium. A steady-state temperature gradient is established based on the unbalanced molecular dynamics principle, and the thermal conductivity is calculated according to the Fourier law. Microcosmic parameters such as a radial distribution function, mean square displacement and the number of hydrogen bonds are synchronously analyzed, and a coupling mechanism of interaction and heat transfer performance of the nano-particle-base fluid interface is disclosed. According to the method, the heat transfer characteristic of the mixed nanofluid can be clarified on the molecular scale, and an efficient and reliable analysis means is provided for nanofluid screening and design in application of a solar heat collector, a heat management system and the like.

Disclosed herein is a lubricant composition comprising a base oil or a fully formulated lubricant; and graphene nanoparticles derived from a carbon-containing gas dispersed in the base oil or the fully formulated lubricant.

The invention relates to the technical field of hovercar windows, and particularly discloses a V2O3-coated PC composite heat insulation window and a preparation method thereof.The V2O3-coated PC composite heat insulation window comprises a plurality of layers of PC plates and V2O3-coated PC functional layer sheets which are arranged alternately, and the surface of the V2O3-coated PC composite heat insulation window is coated with a protective layer; the V2O3-coated PC functional layer sheet comprises modified V2O3 nanoparticles and polycarbonate, the modified V2O3 nanoparticles comprise V2O3 composite nanoparticles and a polyethylene glycol-polypropylene glycol block copolymer coated on the surfaces of the V2O3 composite nanoparticles, and the V2O3 composite nanoparticles comprise V2O3 nanoparticles and nitrogen-doped graphene nanoparticles. The V2O3-coated PC composite heat insulation window provided by the invention adopts a multi-stage material composite structure, and the V2O3-coated PC material for realizing the functions of heat insulation and the like is improved, so that the heat insulation window has the excellent performances of light weight, heat insulation, hydrophobicity, antifouling property and long service life.

A method for forming a graphene-reinforced polymer matrix composite is disclosed. The method includes distributing graphite microparticles into a molten thermoplastic polymer phase; and applying a succession of shear strain events to the molten polymer phase so that the molten polymer phase exfoliates the graphite successively with each event until at least 50% of the graphite is exfoliated to form a distribution in the molten polymer phase of single- and multi-layer graphene nanoparticles less than 50 nanometers thick along the c-axis direction.

Nanoparticles made of a metal oxide are heated to a temperature of from 70°C to less than 350°C. Graphene quantum dots are deposited on the surface of the nanoparticles made of a metal oxide by bringing a carbon-containing compound into contact with the nanoparticles made of a metal oxide while maintaining this heated state, thereby forming graphene-nanoparticle composites having the nanoparticles made of a metal oxide and graphene quantum dots deposited thereon.

The invention belongs to the field of graphene nanoparticle preparation, and particularly discloses a neutral medium graphene nanoparticle preparation device and method, and the device comprises an electrolytic bath, a cathode and anode space separated by a high-density membrane, and an anode with a clamp box. According to the innovation, an anode porous filtering partition plate intercepts coarse particles, a cathode porous filtering partition plate slows down mixing, and a lithium hydroxide electrolyte is injected into a cathode space through a floating ball valve. The graphite foil is moved at the speed of 0.5-3.0 cm / h under the electric field intensity of 4-30 V / cm and the current density of 2-60 mA / cm < 2 >, and a neutral medium extraction area (pH 6.8-7.2) is formed between the partition plate and the membrane after electrolysis is carried out for 60-90 minutes. And a regulating valve is opened through a pH meter and photodiode linkage control device to collect the suspension. The problem of alkaline residual loss in the prior art (CN114132921A) is solved in a breakthrough mode, and the method has the advantages that 1) washing-free production is achieved, and graphene loss is reduced by 30-60%; 2) the number of particle size intervals is increased to 8 (30-800 nm); and 3) the consumption of lithium hydroxide is reduced by 40%.

The application discloses a preparation method of a carbonized wood-based electromagnetic shielding material with electrically-conductive and magnetically-conductive properties, which comprises the following steps: immersing Fe3O4@Graphene nanoparticles into the surface of wood after carbonization, and then performing chemical nickel plating to prepare the carbonized wood-based electromagnetic shielding material. The carbonized wood has good corrosion and insect prevention performance, is not easy to absorb water, and is a good moisture-proof wood with a contact angle of 126.2 degrees. Therefore, after the Fe3O4@Graphene nanoparticles are compounded on the surface of the carbonized wood, the chemical nickel plating can endow the carbonized wood with electromagnetic functional properties. By controlling the time for immersing the nanoparticles, the electromagnetic shielding performance of the carbonized wood composite material can be regulated. The conductivity of the carbonized wood composite material prepared after immersing the nanoparticles for 5 hours can reach 631.3 S / cm, and the average electromagnetic shielding efficiency of the carbonized wood composite material in a frequency range of 8.2 to 12.4 GHz can reach 70 dB, and some frequency bands can reach 80 dB.

The invention relates to a composite hydrogen storage material and a preparation method thereof, belongs to the technical field of composite hydrogen storage materials, and discloses a composite hydrogen storage material which comprises the following raw materials in parts by weight: 2-10 parts of graphene, 3-8 parts of nanoparticles and 5-10 parts of MOFs particles. According to the composite hydrogen storage material and the preparation method thereof, by accurately controlling the weight part ratio of the graphene, the nano-particles and the MOFs particles, the dosage of the additive can be remarkably reduced, meanwhile, the hydrogen storage performance is maintained and even improved, and due to the optimized ratio, the composite material has excellent performance in the aspects of hydrogen storage capacity, hydrogen absorption and desorption rate and the like, and does not need to excessively depend on the additive; the graphene provides excellent electrical conductivity and mechanical strength, the nano-particles increase hydrogen storage sites, the MOFs particles have high specific surface area and rich pore structures, adsorption and storage of hydrogen are facilitated, and through reasonable proportioning, the components can achieve a synergistic effect, and efficient hydrogen storage is achieved.

The application discloses an inorganic hydrated salt / graphene aerogel foam composite phase change energy storage material and a preparation method thereof, and comprises the following steps: 1, mixing ten-water sodium sulfate / lithium nitrate composite salt, sixteen-water lithium iron manganate / calcium sulfate octahydrate composite salt, eighteen-water manganese cadmium titanate / sodium borate hexahydrate and two parts of isosorbide alpha nucleating agent to obtain a mixture A; 2, using polyethylene glycol to modify high-thermal-conductivity graphene nanoparticles; 3, preparing pitch-based carbon fiber reinforced graphene aerogel foam; 4, mixing the mixture A, the polyethylene glycol modified graphene nanoparticles and the pitch-based carbon fiber reinforced graphene foam, adding a mixture of polyethylene glycol diacrylate monomer, dipentaerythritol hexaacrylate and a photoinitiator to obtain a mixture C; and 4, irradiating the mixture C with ultraviolet light to obtain the inorganic hydrated salt / graphene aerogel foam composite phase change energy storage material, so that the supercooling degree of the hydrated salt phase change material is reduced and the phase separation of the hydrated salt phase change material is slowed down.

The invention discloses a high elastic modulus alumina ceramic, and relates to the technical field of ceramics, the high elastic modulus alumina ceramic comprises a body material: 75 parts by mass of kaolin, 22.5 parts by mass of bentonite, 13 parts by mass of heavy magnesium carbonate, 2.5 parts by mass of calcium carbonate, and 120 parts by mass of alumina; glaze: 100 parts by mass of silicon dioxide, 22.5 parts by mass of potassium fluoroaluminate, 5 parts by mass of cerium dioxide, 6 parts by mass of yttrium oxide, 5 parts by mass of aluminum borate whiskers, 8 parts by mass of nano-zinc oxide, 3 parts by mass of cerium-graphene nanoparticles and 0.5 part by mass of large-ball mud superfine powder. According to the high-elasticity-modulus aluminum oxide ceramic, rare earth elements including cerium dioxide and yttrium oxide are beneficial to improving the toughness and high-temperature performance of the ceramic, and the strength and wear resistance of the ceramic can be enhanced by adding aluminum borate whiskers and nano-zinc oxide; due to the existence of the cerium-graphene nanoparticles, the electrical conductivity and thermal conductivity of the ceramic can be improved; the large-ball mud superfine powder is beneficial for improving the microstructure of the ceramic, so that the performance of the whole aluminum oxide ceramic is optimized.

The invention relates to the technical field of composite materials, in particular to a method for improving interface performance and impact strength of a fiber-reinforced metal laminated plate. According to the method, chemical copper plating is carried out on the surface of a titanium alloy plate, graphene nano-particles are added into a polyether-ether-ketone matrix, the titanium alloy plate, the graphene nano-particles, the polyether-ether-ketone matrix, the titanium alloy plate, the graphene nano-particles, the polyether-ether-ketone matrix and the graphene nano-particles are combined, and the graphene-reinforced fiber-reinforced metal laminated plate is obtained through curing of titanium alloy and fibers. And the method has great significance for improving the mechanical property. The method for improving the interface performance and the impact strength of the fiber-reinforced metal laminated plate is simple, has no complex operation process, is low in cost and can be applied in a large range.

Disclosed is a breathing apparatus comprising a pressure vessel. The pressure vessel may comprise a composite shell formed from a plurality of fibres and a matrix comprising a resin material and graphene particles. The pressure vessel may comprise at least one permeation barrier layer comprising graphene microparticles or graphene nanoparticles provided on an outer surface of the structural shell or on an outer surface of the liner. Methods of manufacture for pressure vessels are also disclosed.

A microwave plasma torch equipment includes a reaction chamber, a ventilation tube and a microwave source. The reaction chamber has a reaction area, a microwave inlet, a first divert channel, a second divert channel and a microwave diverter. Each of the first and second divert channels has first and second end parts. The first end parts are coupled to the microwave inlet. The second end parts are coupled to each other at the reaction area. The cross-sectional areas of the first end parts are greater than those of the second end parts. The microwave diverter is located at the junction of the microwave inlet and the first and second divert channels. The ventilation tube penetrates through the reaction area along a direction substantially perpendicular to the extending direction of the first and second divert channels. The microwave source is located at the microwave inlet and facing the microwave diverter.

The invention relates to the technical field of water treatment, in particular to a high-adaptability scale inhibition and dispersion agent and a preparation and use method thereof. The scale inhibition and dispersion agent is prepared from the following components in parts by weight: 31 to 47 parts of common seepweed herb, 26 to 38 parts of polyepoxysuccinic acid, 18 to 29 parts of hydrolytic polymaleic anhydride, 15 to 21 parts of sodium gluconate, 7 to 13 parts of graphene nanoparticles, 8 to 15 parts of nanoscale titanium dioxide and 20 to 30 parts of water. The scale inhibitor is specially used for a water treatment system with the concentration multiple being 2.5-3.5 and the chloride ion content being 600-1000 mg / L, can be used in cooperation with a conventional slow release agent, and provides excellent scale inhibition, dispersion and synergistic corrosion inhibition effects.

A method for obtaining a stable suspension of graphene oxide nanoparticles and carbon nanotubes. The method comprises: preparing graphene nanoparticles of size 70-150 nm, graphene oxide nanoparticles, in the process 0.7 g of potassium dichromate is added to 2 g of 96-98% sulfuric acid, 1 g of graphene nanoparticles is introduced, washed with water to a pH of 5.5; the graphene oxide nanoparticle suspension is dispersed in an ultrasonic disperser for 1 minute, 0.5 ml of ethanol is added to the carbon nanotubes, the resulting mixture is introduced into the graphene oxide nanoparticle suspension and dispersed for 5 minutes. In the method, the suspension contains graphene oxide nanoparticles at a concentration of 0.02 g / L or 0.03 g / L; the mixture containing 0.75 g of carbon nanotubes is introduced into the graphene oxide nanoparticle suspension at a concentration of 0.02 g / L, and the mixture containing 0.5-1 g of carbon nanotubes is introduced into the graphene oxide nanoparticle suspension at a concentration of 0.03 g / L.

A multi-layer coating with antibacterial and anti-COVID properties which is usable in various environments, including hospitals, and which can be easily deposited by spraying on different surfaces and capable of providing an effective removable barrier against pathogens and bacteria, which waterproof coating is characterized in that it uses graphene nanoparticles as an antibacterial and anti-COVID agent deposited by spraying a polymer material as a host layer on the surface to promote the dispersion and uniform surface distribution thereof, the polymer material being directly adhered by spraying to the surface to be coated or sprayed on a second polymer, in turn sprayed on the surface to be coated, which is used as an element to promote the adhesion of the first polymer forming the antibacterial and anti-COVID coating to the surface to be coated.

The invention relates to the technical field of nano functional fluid materials, in particular to an ionic liquid-water mixed base graphene nano fluid and a preparation method thereof. The nanofluid comprises a mixed base solution formed by ionic liquid [EMIM] [BF4] and deionized water according to the mass ratio of 1: 9 to 4: 6, 1-3 layers of graphene nanoparticles with the mass fraction of 0.01-0.5% and PVP and / or an Arabic gum dispersing agent. The preparation method comprises the following steps: mixing and stirring the base solution; graphene and a dispersing agent are added for first stirring; and carrying out second stirring and probe type pulse ultrasonic treatment. Through the synergistic effect of the ionic liquid and the graphene, the obtained nanofluid shows remarkably improved heat conductivity coefficient and excellent antifriction and antiwear properties in a wide temperature range, is good in dispersion stability, and can effectively solve the problems of heat management and interface wear in ultra-precision cutting.

The invention provides a graphene nanoparticle composite aerogel microsphere and a preparation method thereof, graphene oxide and a small molecular compound containing sulfur and nitrogen groups are dispersed in deionized water, low-temperature ultrasonic stirring is performed to obtain a stable dispersion liquid, and a low-temperature oil-soluble organic solvent or liquid nitrogen is used as a receiving bath; filling the stable dispersion liquid into a spraying system, and placing a receiving bath right below the spraying system; the preparation method comprises the following steps: filtering through a screen, freeze-drying to obtain graphene oxide aerogel composite microspheres, and carrying out thermal annealing to obtain the graphene nanoparticle composite aerogel microspheres (NS-GAMs). The NS-GAMs are high in specific surface area, rich in three-dimensional communicated porous structure and doped with uniformly distributed N and S atoms, and the product is relatively uniform in size. The Pt / NS-GAMs catalyst can be obtained by loading platinum nanoparticles (PtNPs) onto NS-GAMs through a hydrothermal reduction reaction, and the catalyst shows excellent electrocatalytic oxidation performance on methanol.

The invention discloses a protective coating for galvanization cathode protection iron materials. The protective coating comprises (45-65)% of polyfunctional group acrylic resin, (0.8-1.6)% of strontium chrome yellow nano mixed liquid, (0.02-0.05)% of graphene nano mixed liquid and (5-8.4)% of isocyanate curing agent, 7%-12% of cellulose resin, 6%-12% of silver powder, 5%-8% of solvent, 1%-3% of auxiliaries and the balance of diluent, wherein the content ratio of the polyfunctional group acrylic resin to the strontium chrome yellow nano mixed liquid to the graphene nano mixed liquid to the isocyanate curing agent is (45-65)%: (0.8-1.6)%: (0.02-0.05)%: (5-8.4)%. Strontium chrome yellow nanoparticles form anchoring points on the surface of an iron material, and meanwhile, the strontium chrome yellow nanoparticles are complexed with the polyfunctional group acrylic resin and the cellulose resin, so that the adhesive force of the coating to a zinc coating is enhanced to 10-12N / mm. The graphene nanosheets form a barrier for corrosive substances between the polyfunctional group acrylic resin and the cellulose resin, so that the corrosion resistance of the coating is enhanced. The protective coating disclosed by the invention is simple and convenient to construct, and provides excellent anti-corrosion and anti-aging capabilities for galvanized cathode protection iron materials.

The invention relates to the technical field of silicone rubber, and discloses heat-conducting silica gel and a preparation method and application thereof.The heat-conducting silica gel is prepared from methyl vinyl silicone rubber, hydroxyl silicone oil, a vulcanizing agent and aluminum oxide-graphene composite filler according to the mass ratio of 100: (0.8-1.3): (0.7-1): (30-60); the graphene nano particles and the alumina micro powder are tightly combined and are uniformly and tightly filled in gaps of the alumina large particles, so that the gaps and interface defects between the graphene nano particles and the alumina micro powder are reduced, a continuous heat conduction path is formed, and the heat conductivity and the heat conduction and heat dissipation performance of the silica gel are remarkably improved. The non-covalent modified graphene and the surface modified alumina have better dispersibility, and the compatibility with the silicone rubber is improved to a certain extent, so that the silica gel material keeps good mechanical properties.

The application discloses a paraffin / graphene composite phase change energy storage material and a preparation method thereof. The method comprises the following steps: 1, mixing even carbon normal alkanes and substituted arylamide type beta nucleating agents according to weight parts, stirring and ultrasonic dispersion to obtain a paraffin phase change energy storage material; 2, mixing graphene nanoparticles and a paraffin modifier according to a mass ratio, sequentially stirring, centrifuging and drying to obtain high-thermal-conductivity graphene nanoparticles modified by the paraffin modifier; 3, mixing the paraffin phase change energy storage material, a phase-changeable energy storage polyethylene glycol diacrylate monomer and double pentaerythritol hexa-acrylate mixture, the high-thermal-conductivity graphene nanoparticles modified by the paraffin modifier and multi-layer assembled graphene foam according to weight parts, uniformly stirring and then obtaining a precursor; and 4, irradiating the precursor with ultraviolet light with a wavelength of 365 nm and a light intensity of 1-800 mW / cm 2 to obtain the paraffin / graphene composite phase change energy storage material, and the thermal conductivity and energy storage efficiency of the phase change energy storage material are improved.

The invention provides a high-dielectric composite material and a preparation method thereof. The high-dielectric composite material comprises the following components: polystyrene, an ethylene-octene block polymer and graphene nanoparticles. The mass ratio of the polystyrene to the ethylene octylene block polymer to the graphene nanoparticles is (75 to 85) to (15 to 25) to (0.5 to 1.5), preferably 80 to 20 to (0.5 to 1.5). The dielectric constant of the high-dielectric composite material at 10MHz is 3-56, and the dielectric loss is less than 0.02. According to the high-dielectric composite material, polystyrene, an ethylene-octene block polymer and graphene nanoparticles are mixed, filtered, cleaned, dried and subjected to hot press molding in a polymer blending mode, and the composite material is obtained. According to the high-dielectric composite material obtained by the preparation method disclosed by the invention, complementary advantages of all the components can be realized, the physical and mechanical properties and processability of a polymer are improved, the cost is reduced, and the application range is expanded.

The invention provides a graphene / copper foil reinforced automobile galvanized sheet welding processing method which comprises the following steps: carrying out surface treatment on a galvanized steel sheet to remove oil stains and impurities on the surface; the preparation method comprises the following steps: adding graphene nanoparticles into an acetone solution, uniformly stirring and then vibrating and dispersing to obtain reinforced phase paste; the reinforcing phase paste is evenly coated on the surface of a welding piece, drying treatment is carried out, and the welding piece is a copper foil; the dried welding piece is placed between two galvanized steel sheets subjected to surface treatment, U-MIG welding is conducted, natural cooling is conducted after welding is completed, U-MIG welding is a welding method that transverse ultrasonic vibration is applied through an ultrasonic generator in a traditional MIG welding process, and specifically, under the welding process, the welding piece is subjected to U-MIG welding; the graphene and the copper foil are used as reinforcing phases to improve welding defects of the galvanized steel sheet and microcosmic grains of a welding joint in the welding process, and the performance of the composite welding joint is further improved.

A breathing apparatus including a pressure vessel is disclosed. The pressure vessel may include a composite shell formed from a plurality of fibers and a matrix comprising a resin material and graphene particles. The pressure vessel may include at least one permeation barrier layer including graphene particles or graphene nanoparticles disposed on an outer surface of the structural shell or an outer surface of the liner. A manufacturing method for the pressure vessel is also disclosed.

The present application relates to a kind of wool blended outdoor fabric and its preparation method, it relates to clothing fabric technical field, the fabric structure includes face cloth, bottom cloth and the graphene functional film being compounded between bottom cloth and face cloth;Wherein, the face cloth is polyester-wool blended knitted fabric, bottom cloth is polypropylene warp-knitted fabric;The graphene functional film is with polyurethane spinning solution as raw material, while being compounded core-spun yarn in centrifugal spinning and is made;The structure of the core-spun yarn includes with water-soluble fiber as core yarn layer and on the surface of core yarn layer intermittent polyurethane fiber is coated to form core layer, the surface of the polyurethane fiber is loaded with graphene nanoparticles, because wool fiber has hollow heat insulation function cooperates the windproof and warm-keeping of graphene functional film, far infrared heating makes fabric have excellent warm-keeping property, in addition, fabric also has stronger waterproof, breathable and moisture permeable and bacteriostatic property, so that it has good application prospect in outdoor clothing field.

A method for forming a graphene-reinforced polymer matrix composite is disclosed. The method includes distributing graphite microparticles into a molten thermoplastic polymer phase; and applying a succession of shear strain events to the molten polymer phase so that the molten polymer phase exfoliates the graphite successively with each event until at least 50% of the graphite is exfoliated to form a distribution in the molten polymer phase of single- and multi-layer graphene nanoparticles less than 50 nanometers thick along the c-axis direction.

The invention relates to the technical field of chemical catalysis, and discloses a heterojunction catalyst as well as a preparation method and application thereof, and the catalyst comprises the following raw materials in parts by weight: 5-10 parts of palladium nanoparticles; 45 to 55 parts of graphene nano particles; 10 to 14 parts of tungsten phosphide nano particles; 25 to 35 parts of manganese-cobalt spinel oxide; 20 to 25 parts of a nitrogen-doped carbon nano tube; 10 to 14 parts of disodium ethylene diamine tetraacetate; 5-8 parts of sodium dodecyl benzene sulfonate; 5-9 parts of hydrazine hydrate; in the preparation process, by constructing a heterojunction structure of palladium and graphene, the catalyst achieves the beneficial effect of enhancing the hydrogen adsorption and activation capacity of the fuel cell anode, and due to the heterojunction formed by the palladium nanoparticles and the graphene, the palladium nanoparticles are well dispersed, the hydrogen adsorption and activation capacity of the fuel cell anode is improved, and the hydrogen adsorption and activation capacity of the fuel cell anode is improved. The electron coupling effect of the heterojunction can improve the catalytic oxidation capacity of palladium to hydrogen, so that the fuel cell can efficiently operate at a lower temperature, stable electric energy is output, and finally, the fuel cell can effectively operate at the lower temperature.

Disclosed is a breathing apparatus comprising a pressure vessel. The pressure vessel may comprise a composite shell formed from a plurality of fibres and a matrix comprising a resin material and graphene particles. The pressure vessel may comprise at least one permeation barrier layer comprising graphene microparticles or graphene nanoparticles provided on an outer surface of the structural shell or on an outer surface of the liner. Methods of manufacture for pressure vessels are also disclosed.

Disclosed herein is a lubricant composition comprising a base oil or a fully formulated lubricant; and graphene nanoparticles derived from a carbon containing gas dispersed in the base oil or the fully formed lubricant.

The invention relates to the technical field of rubber materials and discloses a steel cord core conveyor belt and a processing technology thereof. Graphene modified by grafting of siloxane-containing polyimide is blended with silicone rubber. The polysiloxane structure grafted on the surface of the graphene has good compatibility with methyl vinyl silicone rubber, thereby improving the compatibility of the graphene in the silicone rubber and promoting the dispersion of graphene nanoparticles. The evenly dispersed graphene and the rigid polyimide grafted on the surface of the graphene have a synergistic modification effect on the silicone rubber, thereby improving the comprehensive properties of the silicone rubber, such as wear resistance and mechanical strength. The wear-resistant modified silicone rubber is used as the load surface and transmission surface, the steel wire rope is used as the skeleton layer, and the stainless steel mesh is used as the reinforcement layer to obtain a steel cord core conveyor belt with excellent mechanical strength and high wear resistance.