279 results about "Zinc phosphate" patented technology

The invention relates to the technical field of metal surface protection, and discloses a corrosion-resistant self-repairing metal fastener and a preparation method thereof.The corrosion-resistant self-repairing metal fastener comprises a zinc alloy matrix, a nanometer passivation layer, a slow-release corrosion-resistant layer and a self-repairing functional layer, and the nanometer passivation layer, the slow-release corrosion-resistant layer and the self-repairing functional layer sequentially wrap the zinc alloy matrix; the zinc alloy matrix consists of Al, Cu, Mg, Ce and Zn; the nano passivation layer adopts zinc phosphate / silane composite sol to construct a Si-O-P covalent bond network, and plasma is combined to graft epoxy groups to enhance the interface bonding strength; the slow-release anti-corrosion layer is used for loading a pH response type benzotriazole derivative through gradient aperture mesoporous silica, so that the dynamic controlled release of a corrosion inhibitor is realized; the self-repairing functional layer adopts a synergistic effect of a mechanical triggering type sulfydryl siloxane microcapsule and a pH triggering type EDTA chelating agent microcapsule to form a physical plugging-chemical passivation dual-mode repairing mechanism. Through four-stage cooperation of matrix modification, interface strengthening, slow-release regulation and control and intelligent repair, the corrosion resistance of the corrosion-resistant self-repairing metal fastener in a complex environment is remarkably enhanced.

The invention discloses a water-borne epoxy resin coating which comprises a component A and a component B, the component A is prepared from 60 to 80 parts of 50 percent modified water-borne epoxy resin emulsion, 5 to 15 parts of deionized water, 0.5 to 1 part of wetting dispersant, 0.2 to 0.8 part of defoaming agent, 5 to 10 parts of modified zinc phosphate, 3 to 5 parts of ion exchange antirust pigment, 4 to 6 parts of sericite powder, 3 to 5 parts of glass flake, 5 to 10 parts of precipitated barium sulphate, 1 to 5 parts of nano silicon dioxide and 0.5 to 1 part of rheological additive; 1 to 2 parts of modified organic bentonite slurry; 0.1 to 0.3 part of a pH conditioning agent; and 0.2 to 0.8 part of a flash rust inhibitor. The component B is prepared from 40 to 50 parts of waterborne epoxy-amine adduct, 20 to 30 parts of 50 percent modified polyamide curing agent, 5 to 15 parts of 60 percent Mannich base phenolic aldehyde amine curing agent, 0.5 to 1.5 parts of epoxy silane coupling agent, 1 to 2 parts of nonionic surfactant and 15 to 20 parts of deionized water. The emulsion stability of the waterborne epoxy resin coating is improved through a bisphenol A / F mixed epoxy emulsion and a grafted polyethylene glycol hydrophilic chain segment.

The invention discloses an inorganic modified super-long salt-spray-resistant water-based paint and a preparation method thereof, and relates to the technical field of water-based industrial paints. The inorganic modified super-long salt-spray-resistant water-based paint at least comprises the following raw materials in parts by mass: 60-70 parts of water-based acrylic resin, 0.1-0.5 part of a bactericide, 0.2-0.4 part of a wetting agent, 0.5-1 part of a dispersing agent, 0.1-0.3 part of a defoaming agent, 0.5-1 part of a pH regulator, 8-12 parts of nano silicon dioxide coated polymerized calcium phosphate, 0.5-2 parts of modified zinc phosphate, 8-10 parts of silk mica powder, 2-4 parts of a coalescing agent and 10-20 parts of water. And 0.5 to 1 part of a polyurethane thickening agent. The inorganic modified super-long salt-fog-resistant water-based paint prepared by the invention has super-long salt fog resistance, high base material adhesion and low ion dissolution amount, and the hardness and water resistance of a coating are also improved.

The invention discloses a high-corrosion-resistance powder coating and a preparation method thereof, and belongs to the technical field of powder coatings. Through modification of the resin system, the ultraviolet absorbent modified epoxy resin and the weather-resistant polyester resin are compounded, so that the ultraviolet resistance and the weather resistance of the resin system are remarkably improved, and the corrosion resistance reduction caused by light aging is avoided; the flake graphene forms an excellent physical barrier to block corrosion medium permeation, then chemical passivation of zinc phosphate is combined to inhibit electrochemical corrosion, the synergistic effect is achieved, the corrosion resistance is synergistically enhanced from the physical and chemical angles, the path of the corrosion medium is further prolonged in combination with the laminated structure of the glass flakes, and the corrosion resistance is improved. And meanwhile, the filler A and the filler B can also play a role in enhancing the mechanical strength of the coating, so that the powder coating with high corrosion resistance can be obtained on the whole.

The invention relates to the technical field of ship protection materials, in particular to a ship accessory rust-proof coating and a preparation method thereof.The ship accessory rust-proof coating comprises the following three-layer structure and components from inside to outside: a basic corrosion-resistant layer comprises 10-30 parts of a nano ceramic material; 5-15 parts of a rare earth oxide; 0.5 to 1.5 parts of aminated graphene oxide; 40 to 60 parts of fluorocarbon resin; 20 to 30 parts of epoxy-polyurethane hybrid resin; 3-8 parts of a zinc phosphate corrosion inhibitor; 2-5 parts of a self-repairing microcapsule; 1-3 parts of a photoinitiator; the interface transition layer comprises the following components in parts by weight: 3-5 parts of gamma-aminopropyltriethoxysilane; 2-5 parts of organic silicon resin coated copper powder; the antifouling surface layer comprises the following components in parts by weight: 10-15 parts of Cu coated SiO2 core-shell particles; 10 to 15 parts of a copolymer of polydimethylsiloxane and methyltrimethoxysilane; and 1-3 parts of an antifouling auxiliary agent. According to the multifunctional protective coating for the ship, through the synergistic effect of multiple components, comprehensive improvement of corrosion resistance, pollution resistance, self-repairing and construction efficiency is achieved, and remarkable technical progress and practical value are shown.

The invention discloses a waterborne epoxy coating for heavy corrosion prevention and a preparation method of the waterborne epoxy coating, and relates to the technical field of coatings. The waterborne epoxy resin, the waterborne epoxy curing agent, the titanium dioxide, the barium sulfate, the superfine talcum powder, the mica powder, the zinc phosphate, the aluminum tripolyphosphate, the superfine mica iron oxide, the glass flakes and the like are used as raw materials for preparing the epoxy coating. Meanwhile, the sheet structures of the superfine mica iron oxide and the glass flakes prolong the time for water and a corrosive medium to reach the surface of the base material, and sufficient dissociation time is given to phosphate. The anticorrosive paint disclosed by the invention has good flexibility and corrosion resistance.

The invention discloses high-oxidation-resistance flaky silver-coated copper particles and a preparation method thereof, and relates to the technical field of silver-coated copper powder. The process comprises the steps of flaky copper powder preparation, copper powder pretreatment, silver coating plating and post-treatment. The surface of the copper powder is pretreated, and active sites on the surface of the copper powder are reduced; secondly, a zinc phosphate plated film is formed, full coverage of a silver layer is achieved by adding nano-silver to assist in a silver ammonia solution, meanwhile, micropores of the silver layer are filled, and the compactness of the silver-coated copper powder is improved; besides, the silver content of the silver-coated copper powder is controlled to be 8.7-14.6%, and the normal-temperature oxidation resistance of the silver-coated copper powder is improved, so that the optimal anti-oxidation effect is achieved, and performance deterioration caused by oxidation is reduced.

The invention discloses a durable modified epoxy resin composite coating and a preparation method thereof. The durable modified epoxy resin composite coating comprises a component A and a component B, the component A comprises the following components in parts by mass: 100 parts of epoxy resin, 15 parts of mica, 20 parts of glass flakes, 10 parts of mica iron oxide, 5 parts of zinc phosphate, 3 parts of a penetrant and 10 parts of a solvent; the component B is prepared from the following components in parts by mass: 20 parts of doped polyaniline, 100 parts of N-methyl pyrrolidone and 30 parts of a modified amine curing agent. The prepared durable modified epoxy resin composite coating provides more durable surface protection for concrete structures of expressways and bridges, the salt freezing resistance and chloride ion corrosion resistance of the concrete structures subjected to modified epoxy resin surface treatment can be remarkably improved, and the durability of the concrete structures is enhanced.

The invention discloses a heavy anti-corrosion coating applied to the outer wall of a wind power generation tower drum and a preparation method of the heavy anti-corrosion coating, and belongs to the technical field of heavy anti-corrosion coatings. The paint comprises a primer, an intermediate paint and a finish paint in parts by weight, and the primer comprises the following components in parts by weight: 18-22 parts of bisphenol A epoxy resin, 60-70 parts of zinc powder, 4-8 parts of zinc phosphate, 3-6 parts of a reactive diluent, 3-6 parts of self-made modified montmorillonite, 0.3-0.5 part of fumed silica, 2-5 parts of titanium dioxide, 0.1-0.3 part of carbon black, 0.2-0.5 part of polyamide wax and 0.1-0.3 part of a defoaming agent; 8-12 parts of a modified phenolic aldehyde amine curing agent and 0.1-0.5 part of an accelerant. According to the heavy anti-corrosion coating disclosed by the invention, interlayer combination is promoted through modification of the filler, more efficient and more lasting protection is realized under the synergistic effect of multilayer and multi-mechanism barrier superposition, the damp-heat aging resistance and corrosion resistance of a paint film of the heavy anti-corrosion coating are improved, and longer protection on the outer wall of a power generation tower drum is realized.

The invention discloses an inorganic copolymer anticorrosive paint and a preparation method thereof, and relates to the technical field of paints. The invention discloses inorganic copolymer anticorrosive paint. The coating is prepared from the following raw materials in parts by weight: 20 to 30 parts of silica sol, 8 to 15 parts of sodium hydroxide, 30 to 45 parts of metakaolin, 8 to 20 parts of quartz sand, 15 to 25 parts of water, 0.3 to 2 parts of sodium polyacrylate, 0.2 to 3 parts of polydimethylsiloxane emulsion, 5 to 12 parts of modified nano titanium dioxide, 6 to 10 parts of modified epoxy resin, 10 to 25 parts of hydroxyethyl methylacrylate, 5 to 10 parts of zinc phosphate, 3 to 8 parts of aluminum triphosphate and 2 to 6 parts of iron oxide red. The raw materials of the inorganic copolymer anticorrosive paint are scientifically proportioned, and the anticorrosive performance is enhanced through the modified nano titanium dioxide and the epoxy resin. Material uniformity is ensured through step-by-step feeding and ultrasonic dispersion in preparation, and stability is improved through vacuum defoaming and nitrogen protection. The components such as the silica sol and the zinc phosphate have a synergistic effect to form a compact coating, and the coating is high in corrosion resistance, good in constructability and suitable for various scenes.

The application relates to the technical field of paint, and particularly discloses a water-based insulating paint and a preparation method; the water-based insulating paint comprises components A and B, the mass ratio of the components A and B is (7-9):1, the component A comprises the following raw materials in parts by weight: deionized water 100-150 parts, bentonite 3-8 parts, fumed silica 3-8 parts, titanium white 40-80 parts, barium sulfate 90-110 parts, mica powder 40-60 parts, zinc phosphate 60-80 parts, feldspar powder 40-60 parts, epoxy emulsion 400-500 parts, base material wetting agent 3-5 parts and dispersant 30-80 parts; the component B comprises the following raw materials in parts by weight: curing agent 40-60 parts and solvent 40-60 parts; the dispersant comprises a sulfonate dispersant and a polycarboxylate dispersant; the application promotes the insulating performance of the paint through the synergistic effect of various components, reduces the agglomeration of particles in the paint system, and improves the dispersing performance of the paint.

The invention relates to the technical field of coating compositions, in particular to a rapid self-repairing antibacterial compression garbage truck metal plate coating and a preparation method thereof. The defects that an existing metal plate coating of the compression garbage truck is poor in durability and antibacterial property are overcome. The metal plate coating is obtained by preparing a bottom coating and a top coating and coating the surface of a metal plate with the bottom coating and the top coating, wherein the bottom coating is prepared from the following raw materials: modified novolac epoxy resin, a polyamide curing agent, modified carboxymethyl chitosan, zinc phosphate and nano silicon dioxide; the surface coating comprises the following components: styrene-acrylate emulsion, modified lignin, ethylene glycol butyl ether, improved self-repairing microcapsules and a polyacrylic acid dispersing agent; by adding the improved self-repairing microcapsules, the self-repairing performance of the coating is enhanced, so that the durability of the coating is enhanced; and by adding modified carboxymethyl chitosan, modified lignin and improved self-repairing microcapsules, the antibacterial property of the coating is also guaranteed.

The invention belongs to the field of dental implants, and particularly relates to a preparation method and device of a zirconium oxide implant surface osteogenesis-promoting and antibacterial zinc phosphate coating, and the preparation method of the zinc phosphate coating comprises the following steps: S4, mixing zinc oxide, phosphoric acid, nitric acid and deionized water, and adding an additive to prepare a phosphating solution; s5, putting the phosphating solution and the zirconium oxide implant into a reaction kettle, heating the reaction kettle in a baking oven at 150-230 DEG C for 3-12 hours, and taking out the zirconium oxide implant after natural cooling; and S6, carrying out ultrasonic cleaning for 1-5 minutes by adopting deionized water, and drying in a drying oven at 40-60 DEG C to finally obtain the zirconium oxide implant coated with the zinc phosphate coating. The zinc phosphate coating is prepared on the surface of the zirconium oxide dental implant by applying a hydrothermal method, and the zirconium oxide dental implant has good mechanical properties, cytocompatibility, osteogenesis performance and antibacterial performance by changing the formula of a phosphating solution and adjusting the temperature and time of a hydrothermal reaction, and has important significance for expanding clinical application of a zirconium oxide ceramic implant material in the field of oral cavities.

The invention discloses an antiskid antibacterial ceramic tile and a preparation method thereof, and belongs to the technical field of ceramic materials. Through the unique design of the green body layer, the composite functional layer and the surface treatment layer, the anti-skid and antibacterial ceramic tile achieves good anti-skid and lasting antibacterial performance. The raw material formula of the green body layer, such as kaolin, silicon carbide micro powder and the like, is reasonably proportioned, so that the basic strength and stability of the ceramic tile are ensured. In the composite functional layer, zinc phosphate coated nano-zinc oxide and silver-loaded zeolite are key antibacterial materials, and the ceramic tile has an efficient and lasting antibacterial effect under the combined action of the zinc phosphate coated nano-zinc oxide and the silver-loaded zeolite. The surface treatment layer is formed by carrying out gradient concentration treatment on anti-skid liquid containing an organic metal framework material, the anti-skid antibacterial ceramic tile solves the problems that a traditional ceramic tile is insufficient in anti-skid performance and not lasting in antibacterial effect, can be widely applied to various public places and home decoration, and provides a safe and sanitary living and working environment for people.

The invention belongs to the technical field of coatings, and particularly relates to quick-drying zinc phosphate epoxy paint and a preparation method thereof. The quick-drying zinc phosphate epoxy paint comprises a component A and a component B. The component A is prepared from, by mass, 10-20 parts of epoxy resin, 4-10 parts of petroleum resin, 5-10 parts of a resin modifier, 0.5-1.5 parts of an anti-settling agent, 0.5-1 part of a dispersing agent, 0.5-1 part of a defoaming agent, 0.1-0.7 part of a silane coupling agent, 60-70 parts of pigment filler and 8-15 parts of an organic solvent. And the component B is a modified amine curing agent. According to the invention, the epoxy resin with strong corrosion resistance, wear resistance and impact resistance is matched with the resin modifier to improve the flexibility; petroleum resin is matched, so that the hardness of the paint is improved, and the drying speed of a paint film can be increased; and the anti-settling agent is added to improve the thixotropy of the paint so as to improve the sagging resistance and storage stability of the paint. A certain amount of zinc phosphate is added, so that the paint has good anti-rust performance and waterproof performance. And finally, matching with a self-made modified amine curing agent to finally obtain the quick-drying high-sagging anti-corrosion epoxy coating.

The invention relates to a high-waterproof corrosion-resistant fireproof coating and a preparation method thereof, and belongs to the technical field of fireproof paints.The high-waterproof corrosion-resistant fireproof coating is prepared from, by mass, 20-25 parts of waterborne epoxy resin, 10-15 parts of pure acrylic emulsion, 5-10 parts of polyurethane emulsion, 15-20 parts of organic silicon modified ammonium polyphosphate, 8-10 parts of dipentaerythritol and 6-8 parts of melamine. The coating is prepared from the following components in parts by weight: 3-5 parts of graphene oxide-polyacrylic acid-nano silicon dioxide compound, 8-12 parts of pigment filler, 4-6 parts of zinc phosphate, 4-6 parts of auxiliaries and 8-10 parts of water. Through optimization of the formula, the coating can form an expanded carbon layer at a high temperature, heat and oxygen are effectively isolated, and flame spreading is delayed or stopped, so that the fireproof coating has high fireproof performance, and the effects of high water resistance and corrosion resistance are achieved.

The invention provides a long-acting anticorrosive epoxy powder coating and a preparation method thereof. The coating comprises epoxy resin, polyester resin, thiadiazole corrosion inhibitor loaded cerium-doped hydrotalcite composite particles, silane modified mica iron oxide, zinc phosphate, barium sulfate and the like. The core innovation lies in that 2-amino-5-(4-hydroxyphenyl)-1, 3, 4-thiadiazole corrosion inhibitor molecules are designed and synthesized, the molecules are loaded between cerium-doped magnesium-aluminum hydrotalcite nano container layers through an anion exchange method, corrosion environment pH responsive gradient release is achieved, a coating constructs a passive shielding, active corrosion inhibition and interface anchoring triple protection mechanism in the coating, and the corrosion resistance of the coating is improved. The neutral salt spray test resistance exceeds 2000h, and the coating is suitable for long-acting corrosion protection of iron accessories and cable bridges.

The invention relates to the technical field of high polymer materials and protective coatings, and discloses a single-layer anti-ultraviolet heavy-duty powder coating as well as a preparation method and application thereof. The preparation method of the single-layer anti-ultraviolet heavy anti-corrosion powder coating comprises the following steps: adding carboxyl polyester resin, triglycidyl isocyanurate, modified nano silicon dioxide, modified chitosan, 2-(2H-benzotriazole-2-yl)-4, 6-di-tert-pentylphenol, bis (2, 2, 6, 6-tetramethyl-4-piperidinyl) sebacate, flaky aluminum powder, zinc phosphate, BYK-3920, 2-hydroxy-1, 2, 4-triazole-2-yl)-1, 3, 4-triazole-2-yl)-1, 3, 5-triazole-2-yl)-1, 3, 5-triazole-2-yl)-1, 3, 5-triazole-2-yl)-1, 3, 5-triazole-2-yl)-1, 3, 5- The preparation method comprises the following steps: stirring and mixing 2, 2-diphenylethanone and gamma-aminopropyltriethoxysilane at room temperature at 300-350rpm for 10-15min to obtain a mixture, extruding the mixture through a double-screw extruder at the extrusion temperature of 110-120 DEG C and the screw rotation speed of 450-500rpm, and grinding to obtain the single-layer anti-ultraviolet heavy-duty anticorrosive powder coating. The single-layer anti-ultraviolet heavy anti-corrosion powder coating can be applied to metal base material protection. The coating prepared by the invention has good ultraviolet resistance and corrosion resistance.

The invention discloses an explosion-proof coating as well as a preparation method and application thereof. The raw materials of the coating comprise a component A and a component B, and the mass ratio of the component A to the component B is (100: 100)-(100: 50); wherein the component A is prepared from the following components in parts by weight: 70 to 90 parts of epoxy resin, 3 to 8 parts of reactive diluent, 2 to 6 parts of silane coupling agent and 0.5 to 3 parts of fumed silica; and the component B comprises the following components in parts by weight: 30-60 parts of a nano reinforced curing agent, 5-30 parts of aluminum hydroxide, 8-15 parts of ammonium polyphosphate, 3-10 parts of expanded graphite, 3-8 parts of zinc phosphate, 3-12 parts of hollow glass beads, 3-15 parts of hexagonal boron nitride, 3-10 parts of silicon carbide whiskers, 2-5 parts of graphene dispersion liquid, 5-10 parts of a solvent, 0.2-1.5 parts of a dispersing agent and 0.1-1 part of a defoaming agent. The coating disclosed by the invention has the functions of toughening, flame retardance, heat conduction and non-combustible gas release, and can be applied to flame-retardant and explosion-proof products.

The invention provides a protective coating for a fuel storage and transportation cabin and a preparation method thereof, the protective coating comprises a primer layer, and the primer layer comprises a component A and a component B, the component A is prepared from the following raw materials in parts by weight: 20 to 40 parts of phosphorylated-sulfur heterocyclic modified epoxy resin, 0.1 to 1 part of dispersing agent, 0.1 to 1 part of flatting agent, 0.1 to 1 part of defoaming agent, 0 to 10 parts of n-butyl alcohol, 0 to 10 parts of xylene, 10 to 15 parts of zinc phosphate, 0.5 to 1.0 part of thixotropic agent, 10 to 15 parts of flaky filler, 20 to 35 parts of talcum powder, 5 to 10 parts of barite powder and 3 to 10 parts of titanium dioxide; the component B is prepared from the following raw materials in parts by weight: 99 to 100 parts of amino resin and 0.3 to 0.8 part of a catalyst. Phosphorylation-sulfur heterocycle is utilized to modify epoxy resin, a phosphating group (P-O-C) is generated, the lipophobicity is increased, an intrinsic anti-swelling network is constructed based on a sulfur / phosphorus atom covalent bonding epoxy skeleton, and by utilizing the three-dimensional shielding effect of phosphorus atoms and the high-density cross-linking characteristic of thioether bonds, the anti-swelling performance of the epoxy resin is improved. Fuel oil permeation channels are blocked from the molecular level, pollutant dissolution is inhibited, and it is ensured that the coating has good soaking resistance to fuel oil.

In order to solve the problems that in the prior art, a zinc negative electrode is prone to corrosion and zinc dendrite growth in the charging and discharging process, the zinc negative electrode comprises a negative electrode base material, a negative electrode active layer and a composite coating, the composite coating comprises a first coating and a second coating, the negative electrode active layer is arranged on the surface of the negative electrode base material, and the second coating is arranged on the surface of the negative electrode base material. The second coating is arranged on one surface, deviating from the negative substrate, of the negative active layer; the first coating is arranged on one surface, deviating from the negative active layer, of the second coating; the first coating comprises a first material, the second coating comprises a second material, the first material comprises an amide polymer and / or an amide non-polymer, and the second material comprises one or more of an ionic liquid material, a zinc phosphate material and a cerium oxide material. The surface of the zinc negative electrode is coated with the composite coating, so that multiple protection on the zinc negative electrode is formed, contact between zinc and electrolyte is effectively reduced, corrosion reaction and zinc dendrite growth are inhibited, and the cycle performance and safety of the nickel-zinc battery are improved.

The application provides a zinc phosphide negative electrode material, which comprises a zinc sheet substrate and a zinc phosphate protective layer; the zinc phosphate protective layer is obtained in situ on the surface of the zinc sheet by immersing the zinc sheet in a phosphoric acid solution; the phosphoric acid solution comprises phosphoric acid, zinc oxide, sodium fluoride, zinc nitrate, sodium perchlorate, organic ammonium and ammonia water. The zinc phosphide negative electrode material has good reversible deposition / dissolution performance, excellent energy storage performance, high stability and can be stably cycled for a long time.

The invention provides a preparation method of an osteogenesis, sequential degradation and antibacterial strengthening and toughening zinc-based medical material, and belongs to the technical field of biomedical metal. The preparation method of the strengthened and toughened zinc-based medical material comprises the following steps: (1) performing chemical deposition treatment on pure zinc to obtain pure zinc with a zinc phosphate coating deposited on the surface; (2) the cylindrical device is placed in a mold, an iron wire is placed on the inner layer of the cylindrical device, and Zn-X alloy is filled to be flush with the iron wire; (3) the outer layer of the cylindrical device is filled with the pure zinc with the zinc phosphate coating deposited on the surface obtained in the step (1), the cylindrical device is drawn out, cold press molding is conducted, and a green body is obtained; and (4) pre-sintering the green body obtained in the step (3), and performing hot extrusion to obtain the strengthened and toughened zinc-based medical material. The strengthened and toughened zinc-based medical material has a time sequence degradation mode, and meanwhile has excellent tensile and compression performance and good antibacterial and corrosion-resistant performance.

The present invention relates to the technical field of metal coatings, and specifically relates to a high-temperature resistant metal coating and its preparation process. In the present invention, first, acrylic acid and 1,1,3,3-tetramethyldisiloxane are used as raw materials to prepare intermediate A, and diethanolamine, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, and paraformaldehyde are reacted to obtain intermediate B; intermediate A and intermediate B are reacted at a molar ratio of 1:2 to obtain a silicon-containing flame-retardant diol; then polytetrahydrofuran ether diol 2000 and the silicon-containing flame-retardant diol are mixed and reacted with isophorone diisocyanate and chain-extended to obtain a modified polyurethane emulsion; the modified polyurethane emulsion, deionized water, wetting agent, defoaming agent, dispersant, titanium dioxide, barium sulfate powder, zinc phosphate, leveling agent, and thickening agent are mixed and stirred to obtain a high-temperature resistant metal coating.

The invention belongs to the field of anticorrosive paint production, and particularly relates to an anchor rod anticorrosive paint and a preparation method thereof. The coating is prepared from the following components in parts by weight: 35 to 45 parts of fluorocarbon modified epoxy resin, 15 to 25 parts of PVDF / acrylate copolymer, 5 to 10 parts of acrylic rubber with a core-shell structure, 8 to 12 parts of curing agent, 2 to 5 parts of 2, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate, 4 to 8 parts of zinc oxide, 3 to 6 parts of mica powder, 2 to 5 parts of talcum powder, 5 to 10 parts of zinc phosphate, 4 to 8 parts of aluminum triphosphate, 0.6 to 1.2 parts of dispersing agent, 0.15 to 0.5 part of defoaming agent and 0.3 to 0.8 part of flatting agent. By adding acrylic rubber with a core-shell structure, a good elastic network is formed in a coating, the flexibility and impact resistance of the coating are remarkably improved, fluorocarbon modified epoxy resin combines the weather resistance and chemical resistance of fluorocarbon resin and the high adhesive force and high hardness of epoxy resin, excellent adhesive force is provided, and meanwhile, the coating can be applied to the coating. Due to the high hardness characteristic, the coating has good wear resistance and scratch resistance, and the completeness of the coating can be kept in complex construction and use environments.

The invention discloses a long-acting anti-corrosion coating for a heavy corrosion working condition as well as a preparation method and application thereof, and belongs to the technical field of coating preparation. The invention relates to a long-acting anticorrosive paint for heavy corrosion working conditions. The paint is prepared from the following components in parts by weight: 25-39 parts of epoxy resin, 12-22 parts of fluorocarbon resin, 12-21 parts of zinc powder, 5-9 parts of zinc phosphate, 10-18 parts of talcum powder, 2-7 parts of nano silicon dioxide, 1-5 parts of an organic corrosion inhibitor, 0.8-2.3 parts of an adhesion promoter, 1-4 parts of a dispersing agent, 1-3 parts of a flatting agent, 1-3 parts of a defoaming agent and 12-24 parts of ethylene glycol butyl ether. The anticorrosive paint prepared from the substances has excellent long-acting anticorrosive properties such as high temperature resistance, acid and alkali resistance, oxidation resistance and the like, and is suitable for infrastructures in the fields of petroleum, chemical industry, steel manufacturing, port facilities, wind power generation, heavy mechanical equipment, military industry and aerospace.

The present invention provides a method for preparing an environmentally friendly coating using a modified polyaspartic acid ester resin and an isocyanate and its application, belonging to the field of coating technology. The environmentally friendly coating includes the following raw materials by mass fraction: component A: 22-27 parts of modified polyaspartic acid ester resin, 6-11 parts of polyaspartic acid ester resin, 13-18 parts of long-chain olefin-modified dicyclopentadiene resin, 2-5 parts of zinc phosphate, 1-3 parts of dispersant, 2-5 parts of adhesion promoter, and 12-18 parts of modified mixed filler; component B: 75-80 parts of toluene diisocyanate, 20-30 parts of HDI trimer, 3-5 parts of defoamer, and 2-3 parts of leveling agent. The environmentally friendly coating prepared by the present invention has excellent corrosion resistance, wear resistance, and bending resistance, and has good adhesion on PE T plastic surfaces.

This invention relates to the field of anti-corrosion coating technology, specifically to a water-based corrosion-inhibiting anti-corrosion coating and its preparation method. When zinc phosphate is used alone as a corrosion inhibitor in water-based anti-corrosion coatings, it tends to agglomerate and has poor compatibility with resins. The protective coating formed on the metal surface by these water-based anti-corrosion coatings exhibits poor and unstable corrosion resistance. To address these problems, this invention provides a water-based corrosion-inhibiting anti-corrosion coating composed of two components, A and B. Component A contains a self-made composite corrosion inhibitor, ZnP-PEG-IPTS-GO. This composite corrosion inhibitor, through the bridging of IPTS, chemically bonds GO, PEG, and zinc phosphate, achieving an organic combination of "physical shielding" and "active passivation," significantly improving the overall anti-corrosion performance of the coating.

The invention relates to a composite coating for protecting a liquid cooling plate of a new energy power battery and a preparation method of the composite coating. The invention relates to a modified graphene / Cu-ZIF-8 double-carrier composite photocatalyst, which is prepared from the following raw materials in parts by weight: 70 to 90 parts of modified MXene / graphene double-carrier, 5 to 12 parts of core-shell structure Cu-ZIF-8 double-carrier powder, 15 to 25 parts of alkali-soluble acrylic copolymer resin, 0.5 to 1.5 parts of KH-570, 0.2 to 0.8 part of fluorocarbon surfactant L30, 8 to 12 parts of zinc phosphate, 8 to 12 parts of mica powder, 12 to 18 parts of polyamide wax, 2 to 4 parts of K-7318 and 12 to 18 parts of kieselguhr. Wherein the Cu (at) ZIF-8 (at) double-carrier powder with the core-shell structure is of a core-shell structure formed by in-situ growth of Cu (at) ZIF-8 on an MXene / graphene interface. According to the invention, a comprehensive protective layer with super-hydrophobicity, corrosion resistance, antibacterial property and high adhesive force is provided for the liquid cooling plate, and the performance is excellent.

The invention discloses a production and preparation process of a heavy-duty water-based epoxy primer applicable to a high-salt and high-humidity environment, and relates to the technical field of production of water-based epoxy primers. Comprising the following raw materials in parts by mass: 30-50 parts of bisphenol A type water-borne epoxy resin emulsion, 10-20 parts of a curing agent T-31, 3.5-5 parts of a reinforced anti-settling agent, 8-12 parts of zinc phosphate, 5-8 parts of aluminum triphosphate, 10-15 parts of precipitated barium sulphate, 3-6 parts of silica powder, 0.8-1.2 parts of a sodium polyacrylate dispersing agent, 0.4-0.8 part of an organic silicon defoaming agent and 0.3-0.7 part of an acrylate flatting agent. And 0.6-1 part of a polyurethane thickening agent. The bentonite and the modified zirconium phosphate silicate powder in the reinforced anti-settling agent can improve the microstructure of the primer in a primer system, so that a coating is more compact and can be conveniently applied to a high-salt and high-humidity environment, and the salt spray resistance of the waterborne epoxy primer is enhanced.