614 results about "Nanoceramic" patented technology

The invention relates to the technical field of nano ceramic materials, and discloses a high-strength nano aluminum oxide ceramic product and a preparation process thereof.The preparation process comprises the following preparation steps that aluminum oxide powder, a composite binder, composite gel, a plasticizer and a solvent are mixed and subjected to ball milling, and composite slurry is obtained; placing the composite slurry in a mold, and performing mold pressing and drying to obtain a green body; and putting the green body into a high-temperature sintering furnace, carrying out high-temperature sintering, and cooling to room temperature to obtain the nano aluminum oxide ceramic product. Nano zirconium oxide and nano magnesium oxide are formed on the surfaces of the pretreated silicon carbide whiskers, and can form a solid solution with nano aluminum oxide in the sintering process to serve as a bridge of the silicon carbide whiskers and nano aluminum oxide particles, so that the binding force of the silicon carbide whiskers in a nano aluminum oxide ceramic matrix is remarkably enhanced; phosphoric acid and aluminum ammonium sulfate are firmly combined on the surfaces of nanometer aluminum oxide particles through carboxymethyl cellulose, and the situation that phosphoric acid and aluminum ammonium sulfate are not firmly combined with the nanometer aluminum oxide particles is avoided.

The invention relates to the technical field of composite film preparation, in particular to a multi-layer co-extrusion nano ceramic coating high-barrier medicine packaging composite film and a preparation method thereof.The multi-layer co-extrusion nano ceramic coating high-barrier medicine packaging composite film comprises a base material layer, a gas barrier layer, a bonding transition layer and a nano ceramic functional coating; the base material layer comprises the following components in parts by mass: 80-100 parts of biaxially oriented polypropylene; 20 to 30 parts of metallocene linear low density polyethylene; 5 to 8 parts of nano titanium dioxide; 0.5 to 1 part of beta-(3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid; and 0.3 to 0.6 part of calcium stearate. Through the multi-layer co-extrusion and gradient curing technology and the five-layer co-extrusion technology, it is ensured that the thickness of a base film is uniform and interlayer bonding is firm, the adhesive force of the coating is enhanced through plasma surface treatment, and activity retention and uniform distribution of functional components are guaranteed through the segmented curing strategy of the nano ceramic coating; compared with a traditional hot-pressing compounding or solvent coating process of the composite film, the energy consumption and the solvent residue risk are greatly reduced, meanwhile, the production efficiency and the product consistency are improved, and large-scale application is provided for medicine packaging.

The invention relates to the field of composite materials, and particularly discloses high-entropy nano ceramic fiber reinforced silicon dioxide aerogel and a preparation method thereof. The high-entropy nano ceramic fiber is successfully prepared through the steps of preparation of a precursor spinning solution, electrostatic spinning, high-temperature cracking, a sol-gel method and the like, and the high-entropy nano ceramic fiber is compounded into silicon dioxide aerogel. According to the invention, high-entropy nano ceramic fibers are compounded in silicon dioxide aerogel. The high-entropy nano ceramic fiber not only can greatly improve the heat insulation property of the silicon dioxide aerogel at high temperature, but also can remarkably improve the mechanical properties such as toughness of the silicon dioxide aerogel, so that the application scene of the material can be widened.

The invention discloses nanoscale high-entropy A2B2O7 type oxide ceramic powder and a preparation method of a nano ceramic block of the nanoscale high-entropy A2B2O7 type oxide ceramic powder, and the preparation method comprises the following steps: S1, uniformly dispersing a rare earth element source and a transition metal source in deionized water, stirring at room temperature, and then adding a polymerizing agent and an inducer to obtain a mixed solution; s2, continuously stirring at room temperature to form a transparent clear solution; s3, heating the transparent clarified solution until milk white gel is gradually formed; and S4, drying the milk white gel into dry gel. According to the nanoscale high-entropy A2B2O7 type oxide ceramic powder and the preparation method of the nano ceramic block of the nanoscale high-entropy A2B2O7 type oxide ceramic powder, discharge plasma sintering is combined with a two-step preparation process, the efficiency is high, sintering is compact, the grain size of a ceramic block material can be controlled, and the nano ceramic block can be used for preparing the nano-scale high-entropy A2B2O7 type oxide ceramic powder. And the synthesized oxide has the characteristics of fine powder particle size, uniform distribution, few impurities and the like, and the method is low in synthesis temperature and relatively low in cost.

The invention belongs to the field of metal material processing, and particularly relates to a nuclear power nickel base alloy welding wire and a preparation method thereof.The nuclear power nickel base alloy welding wire comprises, by weight, 0.01%-0.05% of C, 0.10%-0.30% of Si, 28.5%-30.5% of Cr, 7.0%-11.0% of Fe, smaller than or equal to 0.10% of Co, 0.50%-1.00% of W, 3.0%-4.0% of Mo, 0.005%-0.010% of B, 0.1%-0.3% of Al, 0.1%-0.2% of Ti, 0.005%-0.020% of Zr, 2.0%-2.5% of Nb, 0.1%-0.5% of Ta, 0.20%-0.30% of RE, smaller than 0.005% of S, smaller than 0.005% of P, 2.0%-4.0% of nano ceramic materials and the balance Ni, the nickel-based alloy welding material is prepared through the steps of smelting, high-low temperature refining, annealing, forging, rolling, multi-pass drawing, annealing, solid solution-aging treatment, acid pickling, coating and plating, and the problems that in the prior art, when used for welding, a nickel-based alloy welding material is prone to cracks, and the strength is low due to hot corrosion can be effectively solved.

The invention relates to the technical field of capacitor films. The invention discloses a preparation process of a multilayer polypropylene capacitance film, which comprises the following steps: S1, raw material preparation: preparing basic resin, a nano ceramic filler, a nucleating agent and an antioxidant into multilayer raw materials respectively; s2, fusing multiple layers of raw materials by an independent screw extruder, and compounding by a co-extrusion die head to form a film blank; and S3, carrying out air ring gradient cooling on the film blank. And S4, longitudinally and transversely stretching the film blank. And S5, performing heat setting in a segmented heating furnace, and performing corona treatment to improve surface energy. And S6, segmentally curing the moisture-proof coating by using an infrared oven. The multilayer heterostructure is adopted, the comprehensive performance of the capacitor film is improved through material matching, the dielectric constant, the breakdown strength and the moisture resistance are enhanced, and the problem of considering the dielectric property and the mechanical property is solved. The innovative process guarantees stable performance, is compatible with an existing production line, can realize large-scale production, meets the requirements of fields such as new energy and the like, and provides a feasible scheme for localization of high-performance capacitor films.

The invention relates to the technical field of nano ceramic materials, and particularly discloses a self-cleaning antibacterial functional ceramic which is prepared by the following steps: S1, mixing titanium dioxide powder, a composite binder, functional gel, a plasticizer and a solvent, and performing ball milling for 18-20 hours to obtain composite slurry; s2, putting the composite slurry into a mold, and carrying out mold pressing and drying to obtain a green body; and S3, placing the green body in a high-temperature sintering furnace, carrying out high-temperature sintering, and cooling to room temperature to obtain the self-cleaning antibacterial functional ceramic, according to the invention, functional gel and a composite binder are added, and the functional gel is obtained by mixing and reacting composite modified nano zinc oxide, a cross-linking agent and an alumina precursor; the composite binder is prepared by mixing a polyvinyl alcohol aqueous solution, an aluminum dihydrogen phosphate aqueous solution, silica sol and a tackifying component, and through the synergistic effect of the substances, the mechanical property and the antibacterial property of the functional ceramic are improved.

The invention relates to the technical field of ship protection materials, in particular to a ship accessory rust-proof coating and a preparation method thereof.The ship accessory rust-proof coating comprises the following three-layer structure and components from inside to outside: a basic corrosion-resistant layer comprises 10-30 parts of a nano ceramic material; 5-15 parts of a rare earth oxide; 0.5 to 1.5 parts of aminated graphene oxide; 40 to 60 parts of fluorocarbon resin; 20 to 30 parts of epoxy-polyurethane hybrid resin; 3-8 parts of a zinc phosphate corrosion inhibitor; 2-5 parts of a self-repairing microcapsule; 1-3 parts of a photoinitiator; the interface transition layer comprises the following components in parts by weight: 3-5 parts of gamma-aminopropyltriethoxysilane; 2-5 parts of organic silicon resin coated copper powder; the antifouling surface layer comprises the following components in parts by weight: 10-15 parts of Cu coated SiO2 core-shell particles; 10 to 15 parts of a copolymer of polydimethylsiloxane and methyltrimethoxysilane; and 1-3 parts of an antifouling auxiliary agent. According to the multifunctional protective coating for the ship, through the synergistic effect of multiple components, comprehensive improvement of corrosion resistance, pollution resistance, self-repairing and construction efficiency is achieved, and remarkable technical progress and practical value are shown.

The invention relates to the field of lithium battery diaphragms, and particularly discloses an aramid diaphragm for a lithium battery and a preparation method of the aramid diaphragm. The aramid diaphragm for the lithium battery comprises aramid slurry and a base membrane, the aramid slurry is coated on two sides of the base membrane to form an aramid coating, and the aramid slurry is prepared from the following raw materials in parts by weight: 20-40 parts of aramid polymer liquid, 5-10 parts of tencel fibrillation slurry, 1-3 parts of titanium aluminum lithium phosphate nanoparticles, 3-5 parts of nano ceramic particles and 8-15 parts of solvent; the aramid polymer liquid is prepared from the following raw materials in parts by weight: 1 to 3 parts of p-phenylenediamine, 60 to 80 parts of polar solvent, 5 to 10 parts of paraphthaloyl chloride, 1 to 3 parts of 3, 4 '-diaminodiphenyl ether, 1 to 3 parts of o-chloro-p-phenylenediamine and 0.5 to 1 part of polyether surfactant; the aramid polymer liquid is combined with the nano ceramic particles and the tencel fibrillation slurry component to form an intercommunicated porous three-dimensional network structure, so that the air permeability, the thermal stability and the porosity of the aramid diaphragm are improved.

The invention belongs to the field of hydrogen production by alkaline electrolyzed water, and particularly relates to a double-functional-group alkaline electrolyzed water composite diaphragm as well as a preparation method and application thereof. The preparation method of the double-functional-group alkaline electrolyzed water composite diaphragm comprises the following steps: S1, mixing nano ceramic particles with a modification liquid, and performing a modification reaction to obtain amino and sulfydryl double-functional-group modified nano ceramic particles, wherein the modification liquid contains an amino silane coupling agent and a sulfydryl silane coupling agent; the polymer supporting layer is placed in sulfonation liquid to be subjected to sulfonation modification reaction, and then a sulfonated polymer supporting layer is obtained; and S3, mixing the bifunctional group modified nano ceramic particles, a polymer, a pore forming agent and a first organic solvent to obtain a membrane casting solution, degassing the membrane casting solution, coating a sulfonated polymer supporting layer with the membrane casting solution to form a membrane, and performing phase inversion in a coagulating bath to obtain the bifunctional group alkaline electrolyzed water composite membrane. The double-functional-group alkaline electrolyzed water composite diaphragm provided by the invention is good in mechanical property, stable in performance, low in surface resistance and good in air tightness.

The invention discloses a double-component reinforced 5Y-PSZ dental ceramic material and a preparation method thereof, and relates to the technical field of ceramic material preparation. The method comprises the following steps: mixing ZrCl4 and deionized water, and dropwise adding an ammonia water solution to prepare m-ZrO2 nano ceramic powder; zrOCl2. 8H2O, Y (NO3) 3.6 H2O and deionized water are mixed, the m-ZrO2 nano ceramic powder and polyethylene glycol 2000 are added, and the material is prepared through calcination, spray granulation, hot-pressing presintering and high-temperature sintering. According to the 5Y-PSZ dental ceramic material disclosed by the invention, the nano-scale m-phase ZrO2 is adopted as a reinforcing material and is dispersed and distributed inside the 5Y-PSZ, and through volume expansion generated by t-m phase change of the m-phase ZrO2, the anti-aging performance is guaranteed, and meanwhile, the reinforcement of the 5Y-PSZ dental ceramic material is realized. The invention solves the problem of insufficient strength of the 5Y-PSZ dental ceramic material in the prior art.

A preparation method of an explosion-proof thickened wear-resistant rubber and plastic pipe belongs to the field of rubber and plastic pipes, the explosion-proof thickened wear-resistant rubber and plastic pipe comprises an inner layer, a middle layer and an outer layer, the inner layer is an ultrahigh wear-resistant composite layer, is compounded by polytetrafluoroethylene and polyimide, and is reinforced by nanoscale silicon carbide particles and graphene; the middle layer is an anti-explosion energy absorption layer, a shape memory polymer is combined with crosslinked polyethylene to form an intelligent material capable of responding to pressure change, and a high-strength aramid fiber and carbon fiber composite material is embedded into the middle layer; the outer layer is an anti-explosion impact barrier layer, nano ceramic reinforced silicone rubber is adopted, and ultra-high molecular weight polyethylene is combined with ceramic particles, so that the high pressure resistance and the explosion resistance are improved. The inner layer adopts the high-performance material and the nano reinforced filler, so that the wear resistance is remarkably improved; a self-repairing coating technology is introduced into the outer layer, automatic healing of local damage is achieved through a microcapsule structure, the service life of the product is prolonged, and the maintenance cost is reduced.

The invention discloses a production process of high-strength anti-distortion cold-rolled strip steel. The production process comprises the links of raw material preparation, cold rolling, heat treatment, surface treatment and quality detection. Selecting medium-carbon steel with specific components as raw materials, and controlling the tolerance of hot-rolled strip steel; a six-roller unit is adopted for multi-pass rolling in cold rolling, and a plate shape control technology is matched; continuous annealing and gradient quenching-isothermal tempering are applied to heat treatment, so that a specific structure gradient is formed, and the distortion rate is reduced; the surface is subjected to acid pickling, hot galvanizing and a nano ceramic composite coating, so that the corrosion resistance and the wear resistance are improved; and the quality is guaranteed through online detection and sampling inspection. The strip steel produced through the technology is high in strength, good in toughness, high in corrosion resistance and suitable for the high-requirement field.

The invention belongs to the technical field of thermal power heating surface treatment, and provides a multi-layer composite self-repairing anti-oxidation coating for a boiler heating surface and a preparation method of the multi-layer composite self-repairing anti-oxidation coating aiming at the technical problems that a thermal power boiler heating surface protective coating is insufficient in bonding strength, insufficient in long-term anti-oxidation capacity and concentrated in interface stress among multi-layer structures. Comprising a bonding layer, a gradient transition layer, a self-repairing functional layer and a ceramic surface layer which are sequentially arranged from inside to outside. The self-repairing functional layer is made of NiCoCrAlY alloy, the bonding layer is made of NiCrAlY alloy, the gradient transition layer comprises four layers of gradient transition layer units, each layer of gradient transition layer unit comprises a gradient composite structure of NiCrAlY and nano Al2O3, the self-repairing functional layer comprises NiCoCrAlY serving as a base body, thermal response type microcapsules are embedded in the NiCoCrAlY base body, and the ceramic surface layer comprises a nano ceramic material composed of Cr, Co, Ni, Fe, Al, Ti and B elements.

The invention relates to the technical field of batteries, in particular to a lithium ion battery diaphragm and a preparation method thereof.The lithium ion battery diaphragm comprises a porous base membrane and a high-temperature-resistant bonding coating covering the surface of one side or two sides of the porous base membrane; the high-temperature-resistant bonding coating is prepared from the following raw materials in parts by weight: 15-20 parts of modified polymer emulsion, 60-80 parts of inorganic nano ceramic particles, 3-5 parts of fiber polymer, 3-5 parts of a binder, 0.1-0.5 part of an auxiliary agent and 20-30 parts of deionized water. According to the lithium ion battery diaphragm provided by the invention, through the modified polymer emulsion, the air permeability value after cold pressing and the cold pressing cohesive force are improved; meanwhile, the inorganic nano ceramic particles and the fiber polymer are added, so that the high-temperature resistance of the diaphragm is improved, and the safety performance and the cycle performance of the battery are effectively improved.

The invention relates to the technical field of magnet materials, and discloses a high-temperature-resistant neodymium-iron-boron magnet and a preparation method of the high-temperature-resistant neodymium-iron-boron magnet. The high-temperature-resistant neodymium-iron-boron magnet comprises the following components in parts by weight: 25-30 parts of neodymium, 60-65 parts of iron, 1.0-2.0 parts of boron, 3.0-5.0 parts of lanthanum, 0.5-2.0 parts of zirconium, 0.5-1.0 part of molybdenum and 0.1-0.5 part of nano ceramic particles, and the invention further provides a preparation method of the high-temperature-resistant neodymium-iron-boron magnet. S1, preparing and mixing alloy raw materials; s2, nano ceramic coating treatment is carried out; s3, magnetic field assisted pressing forming; and S4, rapid induction sintering. Through the magnetic field assisted directional pressing process, effective control over grain orientation in the pressing forming stage is achieved, magnetic domain arrangement is more ordered, and the residual magnetism and the energy product are improved. Different from a forming mode with disordered grain directions and poor magnetic anisotropy in an existing common cold pressing process, the technical defect that the utilization rate of magnetic performance is low due to poor orientation is overcome.

The invention relates to the technical field of wind power and power grid equipment anti-icing, and discloses a fluorosilicone oil microcapsule anti-icing coating for wind power and power grid equipment. Comprising the following components which are independently subpackaged: a component A, namely a nano ceramic pre-dispersion: 20-30 parts of methyltrimethoxysilane, 5-8 parts of tetraethoxysilane, 40-60 parts of isopropanol and 10-15 parts of silicon dioxide nanoparticles with perfluoroalkyl grafted on the surfaces; the component B is microcapsule dry powder: 25-40 parts of mesoporous alumina microcapsules filled with fluorosilicone oil, 1-4 parts of amino modified carbon nanotubes and 2-5 parts of an oxygen vacancy defect type titanium dioxide photocatalyst, the microcapsules are triggered to release the fluorosilicone oil through the volume expansion rate of a thermal expansion layer and stress sensitive layer composite wall material at low temperature, and meanwhile, when ice pressure exists, the stress sensitive layer can release the fluorosilicone oil, so that the stress sensitive layer can release the fluorosilicone oil. And the polydopamine-coated aluminum oxide layer is elastically deformed to synergistically release the fluorosilicone oil to form a dual-mode anti-icing mechanism.

The invention belongs to the technical field of metal powder material preparation, and relates to a preparation method of high-performance copper powder with high laser absorptivity and a 3D printing method.The preparation method comprises the following steps that firstly, spherical copper powder, nano ceramic particles and an auxiliary reagent are mixed to obtain mixed powder; 2, putting the mixed powder obtained in the step 1 into a grinding tank, and uniformly grinding and mixing through an acoustic resonance mixer; and 3, the mixed powder obtained after uniform grinding and mixing is placed in a vacuum drying box to be subjected to heat treatment, and the high-performance copper powder with the high laser absorptivity can be obtained after treatment is completed. According to the characteristics of the laser 3D printing technology, the nano ceramic particles are added into the spherical copper powder, the laser absorptivity is effectively improved, and the added auxiliary reagent has the effects of removing an oxidation film on the surface of the copper powder and improving the wettability of the copper powder and the nano particles in the printing process; meanwhile, the nano ceramic particles are used as a reinforcing phase, so that the mechanical property of the pure copper can be effectively improved.

The invention relates to the technical field of heat insulation films, in particular to an architectural glass ceramic gel heat insulation film, which is prepared by combining aluminum oxide nano powder, yttrium oxalate, zirconium carbonate and modified nano titanium dioxide and preparing nano ceramic material dispersion slurry through a supergravity rotating packed bed. The nano ceramic material has high heat resistance and low heat conductivity coefficient, and can form a heat barrier in the material, so that the heat conduction efficiency can be remarkably reduced by introducing nano ceramic material dispersion slurry into a heat insulation film, and the heat insulation performance of the material is effectively improved; according to the invention, different types of antibacterial agents and nano titanium dioxide are dispersed, so that part of the antibacterial agents can be adsorbed and dispersed in an aperture structure on the surface of the nano titanium dioxide, and then the modified nano titanium dioxide loaded with the antibacterial agents on the surface can be more uniformly dispersed in the PET material through modification of the silane coupling agent; therefore, the weather resistance and the heat insulation property of the heat insulation film are enhanced under the action of the modified nano titanium dioxide.

The invention discloses a manufacturing method of a second type low-smoke halogen-free standard wall cable of a motor train unit, which relates to the technical field of cables and comprises the steps of conductor preparation, insulation extrusion, buffer isolation layer forming, shielding layer manufacturing, reinforced core preparation and installation, sheath extrusion and post-processing. The conductor is prepared by layering and twisting cerium-titanium alloying copper monofilaments and treating the cerium-titanium alloying copper monofilaments through a nano ceramic coating; post-processing detection shows that the cable is small in bending radius, low in electrical and mechanical performance attenuation rate after repeated bending, excellent in electrical performance, mechanical performance, fireproof performance, environmental protection performance and the like, capable of effectively meeting the cable use requirements under complex working conditions of the motor train unit, capable of guaranteeing the operation reliability and safety, capable of improving the comprehensive performance of the cable and wide in application range. The cable is suitable for power and signal transmission in rail transit fields such as motor train units.

The present invention relates to the technical field of lithium battery materials. Provided are slurry that in-situ compounds an aromatic polyamide, and a preparation method therefor and the use thereof. The slurry that in-situ compounds an aromatic polyamide achieves the compounding of two materials of nano ceramic particles and an aromatic polyamide, thereby effectively avoiding the problem in the prior art of nano ceramic particles being prone to falling off due to the fact that a binder needs to be added to bond the nano ceramic particles on a separator. A lithium battery separator prepared from the slurry that in-situ compounds an aromatic polyamide further improves the performance, such as peel strength, membrane rupture temperature and electrolyte contact angle, of the lithium battery separator in the prior art. Compared with batteries in the prior art, a battery prepared from the lithium battery separator has an improved capacity retention ratio, and improved normal-temperature capacity, high-temperature capacity (55ºC) and low-temperature capacity (-20ºC).

The present invention relates to the field of ceramic technology, and more specifically, to an alumina ceramic fiber board with a fireproof and heat-insulating function and a nano-ceramic coating, which sequentially includes a nano-ceramic coating and an alumina ceramic fiber board from top to bottom; for the nano-ceramic coating, calculated by mass, the raw materials include: 50-70 parts of an adhesive, 10-20 parts of hydroxylated layered Ti3C2 / silica hollow spheres / ceramic particles, 0.1-0.5 parts of 2-acrylamido-2-methylpropanesulfonic acid sodium salt, 0.01-0.1 parts of an initiator, and 10-20 parts of water; the present invention solves the problem that the ceramic fiber board in the prior art cannot meet the fireproof and heat-insulating properties required for ceramic fiber boards in the construction field, and at the same time has excellent adhesion, corrosion resistance, strength, antibacterial property, and hydrophobic and oleophobic properties.

The invention discloses a high-strength wear-resistant aluminum alloy manufacturing method which comprises the following steps: S1, nano particles are added into a precursor solution material of a ceramic coating; s2, dispersing nanoparticles in the precursor solution of the ceramic coating to form a uniformly mixed coating material; s3, a coating method is adopted, and the surface of the aluminum alloy is evenly coated with the evenly-mixed coating material; and S4, curing treatment is carried out, so that the coating material forms a stable and compact nano ceramic coating on the surface of the aluminum alloy. According to the manufacturing method of the high-strength wear-resistant aluminum alloy, the produced product has the characteristics of being excellent in performance and high in adaptability.

The invention discloses a method for refining nano ceramic synergistic modified Al-Si alloy primary silicon based on laser additive manufacturing, which comprises the following steps of: uniformly mixing Al-Si alloy powder with TiB2 and Al2O3 nano ceramic under the protection of inert gas through a ball mill by adopting a ball milling process to obtain ceramic nano strength enhanced Al-Si alloy composite powder; and the nano ceramic modified Al-Si alloy powder is fused layer by layer through laser powder bed fusion forming equipment, and a to-be-established target part is formed. According to the method, when the nano-ceramic reinforced Al-Si alloy melt is solidified, Al2O3 nano-particles are similar to a Si crystal structure and have a good interface coherence relation to serve as heterogeneous nucleation points of primary silicon, the nucleation rate of the primary silicon is increased, and the size of the primary silicon is refined; the TiB2 nanoparticles are distributed on a solid-liquid interface, Si atoms can be prevented from diffusing and gathering towards Si-Si clusters to a certain extent, growth of a primary silicon phase is inhibited, morphology regularization and size refinement of primary silicon are promoted, meanwhile, matrix grains can be effectively improved, and the mechanical property of the Al-Si alloy is remarkably improved.

The invention belongs to the technical field of preparation of high polymer materials, and provides a preparation method of a wear-resistant high polymer material which comprises a nano ceramic layer and a dual-network polymer matrix which are distributed in a gradient manner, the gradient distribution nano ceramic layer is formed by surface-functionalized Al2O3-Si C hybrid nanoparticles in concentration gradient distribution in the longitudinal direction of the material, the dual-network polymer matrix is formed by cross-linking polyurethane and epoxy resin through an interpenetrating network structure, a polyurethane phase provides elasticity, and an epoxy resin phase provides rigidity; according to the preparation method, gradient mechanical property optimization can be achieved, and excellent interfacial compatibility and an efficient preparation process are achieved.

The invention belongs to the technical field of thermal power heating surface treatment, and provides a boiler heating surface high-temperature corrosion protective coating and a preparation method thereof in order to solve the technical problems that in the prior art, a nano ceramic coating and a metal alloy coating for treating thermal power boiler heating surface high-temperature corrosion are insufficient in adhesive force, prone to falling off and short in protection service life. Through multi-layer structure design and technological parameter optimization, a coating system has continuous thermal expansion coefficient gradient distribution in the interval of 500-900 DEG C, the metal bonding layer at the bottom layer has a pore structure which can effectively absorb thermal stress, the nano ceramic layer at the surface layer can maintain high-temperature stability, and it is verified that the overall bonding strength is larger than or equal to 35 MPa, and the thermal expansion coefficient is larger than or equal to 10%. Compared with a traditional single-layer coating, the adhesive force is improved by 200% or above, and therefore the technical problems that in the prior art, adhesive force is insufficient, thermal stress is not matched, and high-temperature softening fails can be effectively solved.

The invention relates to the technical field of radiation protection equipment, and provides a multi-scale self-adaptive fixing system for a lead plate, in the aspect of lead plate fixing, through a three-degree-of-freedom structure and a precise force control system of a shape memory alloy driving clamp, the clamping angle and force can be adjusted in a self-adaptive manner, the plastic deformation of the lead plate is effectively avoided, and the service life of the lead plate is prolonged. The problem that a traditional clamp is poor in fixing precision is solved. And due to the innovative structure of the modular quick connection assembly, the assembly and the disassembly are convenient, the seam leakage rate is greatly reduced, and the radiation protection performance is improved. In terms of environmental adaptation, the temperature and humidity cooperative control system can accurately adjust the temperature of the lead plate, and the self-repairing nano ceramic anti-corrosion coating can effectively isolate corrosion ions and automatically repair the coating. The intelligent monitoring and early warning system utilizes a multi-dimensional sensor, edge calculation and digital twinning technology to monitor the state of equipment in real time, quickly diagnose faults and perform graded early warning, so that the safe and stable operation of the system is guaranteed, and the reliability and the intelligent level of the equipment are greatly improved.

The invention relates to the technical field of battery materials, in particular to a para-aramid lithium battery diaphragm and a preparation method thereof. The para-aramid lithium battery diaphragm comprises para-aramid slurry and a base membrane, the para-aramid slurry is coated on the two sides of the base membrane to form para-aramid coatings, and the para-aramid slurry comprises the following raw materials in parts by weight: 20-40 parts of modified para-aramid polymer liquid, 10-20 parts of nano ceramic composite material powder and 10-18 parts of a solvent; the nano ceramic composite material powder is prepared from the following raw materials in parts by weight: 50 to 100 parts of nano aluminum oxide, 8 to 12 parts of nano zirconium dioxide, 0.3 to 0.8 part of yttrium oxide, 1 to 5 parts of magnesium nitrate hexahydrate, 0.1 to 1 part of polyacrylic acid, 1 to 2 parts of ammonia water, 1 to 3 parts of coupling agent and 20 to 30 parts of silicon dioxide; the nano ceramic composite material powder is added into the para-aramid slurry, so that the para-aramid diaphragm has better thermal stability, and the phenomenon of thermal shrinkage of the diaphragm at high temperature is reduced.

The invention belongs to the technical field of composite material manufacturing, and discloses a structural battery integrated composite board and a forming method and application thereof. According to the composite board, carbon fiber reinforced materials are adopted as positive and negative electrodes, glass fiber materials are adopted as a diaphragm and an insulating layer, epoxy resin-based solid-state structure electrolyte is adopted as a bonding packaging medium, and a curing agent, ionic liquid, electrolyte lithium salt, nano ceramic particles and other auxiliaries of specific types and proportions are introduced into epoxy resin; the multifunctional modification of the resin matrix is realized. And meanwhile, doping and surface grafting modification are performed on the electrode material, so that the energy density and the mechanical strength of the battery are improved. And further constructing a low-temperature formed metal or carbon-based circuit layer on the outer surface of the structural battery to form an integrated complex comprising the circuit board, the structural battery and the bearing structure. The composite board satisfies dielectric insulation and reliability, realizes integrated energy supply and signal processing, and is widely applied to weight and volume sensitive fields such as aerospace and new energy automobiles.

The invention discloses an insulating nano ceramic resin composite coating. The preparation method comprises the following steps: 1, mixing methyl methacrylate and butyl acrylate, and dropwise adding the mixture into an aqueous solution containing an emulsifier, an initiator and a buffer agent under a protective atmosphere for reaction to obtain a seed emulsion; and 2, emulsifying the modified filler, methyl methacrylate, butyl acrylate, an emulsifier and water, adjusting the pH value, and dropwise adding into the seed emulsion and the initiator under a protective atmosphere to react. And then cooling and adding a redox initiation system for continuous reaction to finally obtain the composite coating. The preparation method has the beneficial effects that the hexagonal boron nitride nanosheets are subjected to surface functionalization treatment by synthesizing a multifunctional modifier, so that the dispersity and interface bonding performance of filler in a resin matrix are remarkably improved, and the coating has excellent insulativity, strong adhesive force, good flame retardance and outstanding corrosion resistance at the same time.