1243 results about "Ceramic particle" patented technology

The invention discloses a lithium battery diaphragm with a self-repairing function and a preparation method thereof, and belongs to the field of lithium battery diaphragms. The lithium battery diaphragm comprises a polymer base membrane and a ceramic coating, the ceramic coating is coated on one side surface, facing the negative electrode, of the polymer base membrane or two side surfaces of the polymer base membrane; the ceramic coating comprises the following raw materials in parts by mass: 40-50 parts of modified ceramic particles, 4-8 parts of self-repairing microcapsules, 0.5-3 parts of a dispersing agent and 50-60 parts of water; the surfaces of the modified ceramic particles are grafted with amino-phenylboronic acid difunctional silane; chitosan / polyurethane is used as a wall material of the self-repairing microcapsule, and polyisocyanate is used as a core material of the self-repairing microcapsule. When the lithium ion diaphragm is stressed or punctured by dendritic crystals, the polyisocyanate can be released to react and crosslink, the generated cracks are closed, and an ion channel is reconstructed. Through the physical barrier of the ceramic coating and the self-repairing effect of the self-repairing microcapsule, the mechanical strength and the ion transmission performance of the lithium battery diaphragm can be effectively maintained.

A method of forming a ceramic matrix composite component includes forming a fiber preform, the fiber preform including a plurality of ceramic fiber plies, a non-reduced fiber region having an areal weight, and a reduced fiber region characterized by a reduced areal weight less than the areal weight of the non-reduced fiber region by at least 5 percent. The method further includes selectively applying ceramic particles to the reduced fiber region in such manner as to avoid applying the ceramic particles to the non-reduced fiber region, and subsequently densifying the preform.

The invention belongs to the technical field of brake discs, and relates to a cast iron brake disc ceramic reinforced iron-based wear-resistant coating and a preparation method thereof.The cast iron brake disc ceramic reinforced iron-based wear-resistant coating comprises a brake disc base body, an iron-based transition coating and a composite wear-resistant coating, the composite wear-resistant coating is formed by mixing iron-based alloy powder, B4C ceramic particles and CeO2 rare earth powder; the preparation method comprises the following steps: 1, carrying out laser cladding on iron-based alloy powder on a brake disc substrate to prepare an iron-based transition coating; 2, carrying out ball milling and mixing according to a weight ratio to prepare composite wear-resistant mixed powder; 3, performing laser cladding on the iron-based transition coating with composite wear-resistant mixed powder; the B4C + CeO2 ceramic particles are mixed into the iron-based alloy powder, so that microcracks of the brake disc coating are reduced, the wear resistance and hardness are improved, dust pollution is reduced, the service life is prolonged, and the friction performance better meets the brake disc strengthening requirement.

The invention provides a lithium ion battery diaphragm, which comprises a base membrane and a functional coating coated on at least one surface of the base membrane, the functional coating comprises a first material and a second material uniformly distributed between the first material, the first material comprises ceramic particles and a binder coated on the surfaces of the ceramic particles, and the second material comprises a second material uniformly distributed between the first material and the second material. The second material is high-temperature-resistant fiber, and the first material and the second material are bonded to form a three-dimensional network structure. Compared with the prior art, the functional coating has good mechanical strength and thermal stability, the functional coating is of a three-dimensional network structure, reaction sites are provided for battery charging and discharging, the network structure has good thermal conductivity, the thermal stability of the battery diaphragm is effectively improved through cooperation of the ceramic material and the high-temperature-resistant fibers in the coating, and the service life of the battery diaphragm is prolonged. And the functional coating coated on the base membrane has good adhesion, so that materials on the coating are firmly adhered on the base membrane without powder falling, and the heat resistance of the diaphragm is further improved.

The invention discloses a porous ceramic filter for liquid magnesium alloy purification and a preparation method thereof, and the porous ceramic filter comprises the following raw materials in percentage by mass: 70-85wt% of ceramic particles, 8-15wt% of multi-element oxide system microcrystalline glass brazing filler metal and the balance of a binder, al2O3-B2O3-SiO2-MgO-CaO multi-element oxide system microcrystalline glass brazing filler metal is adopted, under the condition of air atmosphere high-temperature calcination, a compact reaction layer containing a low-melting-point glass phase, an aluminum oxide phase, a magnesium aluminate spinel phase, a calcium aluminosilicate phase, a borate phase and a silicate phase is generated on the surfaces of ceramic particles of a porous ceramic filter through a chemical reaction; the magnesium alloy filter has high strength and good high-temperature stability, and the problems that the filter loses efficacy and magnesium alloy melt is polluted due to the fact that the filter is eroded by magnesium alloy liquid are effectively solved.

An electrode structure for a solid-state or semi-solid-state battery is provided in which NCM electrode particles coated with an interphase layer and a nitrogen-containing carbon layer are disposed. [Solution] The NCM electrode particles comprise NCM (nickel-cobalt-manganese oxide) particles (15), primary particles (30) that coat the outer surfaces of the NCM particles, an interphase layer (16) that includes a glass phase layer (241) and a plurality of ceramic particles (242), and a nitrogen-containing carbon layer (35) that coats the exterior of the primary particles. Nitrogen-doped carbon molecules in the nitrogen-containing carbon layer aid in the conduction of electrons and lithium ions, modifying the electrical potential of the NCM particles. The nitrogen-containing carbon layer is formed by coating the surfaces of the primary particles with a nitrogen-containing polymer material and calcining the material in an inert atmosphere. Conjugated bonds are formed between the carbon and nitrogen, modifying the energy band structure, reducing the energy required for electrons to transition to the conduction band, and improving overall electronic conductivity.

A method of manufacturing a composite panel is provided. The method includes applying a composite face sheet to a first side of a core structure, the core structure comprising a plurality of first ceramic particles each having a first particle size that is within a first particle size range and the composite face sheet comprising a plurality of second ceramic particles each having a second particle size that is within a second particle size range, wherein the second particle size range is smaller than the first particle size range and densifying the composite panel through infiltration, wherein the infiltration comprises transport of an infiltrant through the core structure and into the composite face sheet.

The invention discloses a regulation and control method and a preparation method of in-situ ceramic particles of a copper-based composite material. The method comprises the following steps: weighing according to a reaction equation and a reaction molar ratio; the molar ratio coefficient is changed, trace alloy is added, and the size and morphology of in-situ particles are regulated and controlled; the copper-based pre-dispersed in-situ ceramic intermediate alloy reinforcer is prepared through powder mixing, cold pressing and sintering; crushing the reinforcer, remelting, stirring and casting; and after the cast alloy is subjected to heat treatment, the high-performance in-situ particle reinforced copper-based composite material is prepared. According to the obtained in-situ ceramic intermediate alloy reinforcer, pre-dispersion of ceramic particles in a copper matrix can be achieved, and good combination of the particles and the matrix is achieved by adding the copper-based pre-dispersion in-situ ceramic intermediate alloy reinforcer into a molten matrix alloy; interface pores caused by sharp corners, surface pollution and the like of the heterogeneous particles in an external addition method are avoided, and the strengthening effect of the heterogeneous particles is weakened.

The invention discloses a high-content fly ash unfired water permeable brick and a preparation method thereof, and relates to the technical field of building materials, the unfired water permeable brick comprises the following raw materials by weight: 55-75 parts of fly ash, 20-35 parts of aggregate, 8-15 parts of a composite cementing material, 0.5-2 parts of toughening fiber, 1-3 parts of a pore regulator, 0.1-0.5 part of a surfactant, and 10-18 parts of water. Wherein the aggregate is 1-3mm waste ceramic particles and 2-5mm building recycled aggregate (1: 1-1: 2); and the rest components have specific proportions, specifications and modification requirements. According to the invention, 55-75 parts of F-type II-grade or higher high-content fly ash is matched with the waste ceramic particles and the pretreated building recycled aggregate to serve as the composite aggregate, solid waste is digested, natural resource dependence is reduced, and the method conforms to the direction of green building materials; by means of a modified composite fiber and composite gel system, the pressure resistance is larger than or equal to 25 MPa, the fracture resistance is larger than or equal to 3.5 MPa, the water permeability is larger than or equal to 1.5 * 10 cm / s, the freeze-thaw loss is smaller than or equal to 3.5%, and the grinding pit is smaller than or equal to 30 mm; through graded mixing, bidirectional pressurization and segmented maintenance, the porosity is kept to be 15%-25%, the percent of pass is increased, and the cost is reduced.

The invention discloses a high-thermal-conductivity PI / ceramic composite insulation packaging sheet and a preparation method thereof, and relates to the technical field of electronic packaging. The high-thermal-conductivity PI / ceramic composite insulation packaging sheet is obtained by mixing a modified polyimide solution and modified ceramic particles according to the mass ratio of (9-13): 1 and then performing high-temperature curing. The modified polyimide solution is obtained by mixing a dianhydride monomer and a diamine monomer in a molar ratio of 1: 1, and 2-methyl-2-acrylic acid-2, 3-dihydroxy propyl ester accounting for 5-10% of the total molar weight, and adding a catalyst for catalysis; the modified ceramic particles are obtained by adding hydroxymethyl acrylamide into a ceramic suspension, mixing, filtering, washing and drying. The packaging sheet prepared by the invention has high thermal conductivity, keeps stable at a relatively high temperature, is not easy to thermally deform, and has relatively high stability.

The invention provides a diaphragm and a preparation method thereof, and a lithium ion battery, the diaphragm comprises a base membrane, a composite ceramic coating and an interface layer, the composite ceramic coating contains inorganic ceramic particles and organic microcapsule particles, the organic microcapsule particles comprise a core material with a melting point range of 55-65 DEG C and a polymer shell coating the surface of the core material, and the polymer shell is coated on the surface of the core material. The polymer shell is selected from at least one of polyurethane, polyurea, polyamide and polycarbonate, the interface layer is formed by depositing an interface modification polymer on the surface of the composite ceramic coating, and the interface modification polymer is selected from at least one of polycatechol derivatives, polyaniline, polyvinyl pyridine, polyacrylic acid and polyacrylamide. The core material in the organic microcapsule particles is melted when heated to trigger hole closing at the initial stage of thermal runaway at 60-80 DEG C, the hole closing rate can reach 92%, the hole closing response time is shortened by 30%, and the porous structure of the interface layer can enhance the liquid absorption rate.

The invention belongs to the technical field of metal ceramic, and particularly relates to a high-toughness metal ceramic particle and a preparation method thereof.The particle is characterized in that ceramic micro powder, surface modified ceramic powder and rare earth element carbonitride form a composite hard phase, and the composite hard phase is dispersed in a metal matrix composed of multiple metal elements; and synergistic regulation and control components are introduced to optimize interface bonding and tissue uniformity. Particles are subjected to a step-by-step heat treatment and isostatic pressing forming process, and a stable structure is formed by controlling the oxygen content and the sintering atmosphere. The obtained material has high bending strength, high fracture toughness and good thermal shock resistance, is suitable for the application field of wear resistance and crack resistance under extreme working conditions, and has tissue compactness and mechanical stability.

The invention discloses lithium battery diaphragm coating slurry with a self-repairing function and a preparation method of the lithium battery diaphragm coating slurry, and belongs to the technical field of lithium battery diaphragm materials. In order to solve the problem of potential safety hazards caused by the fact that an existing lithium battery wet diaphragm is prone to generating small cracks, self-repairing waterborne polyurethane containing dynamic covalent bonds (such as disulfide bonds) is synthesized through molecular structure design, and the self-repairing waterborne polyurethane, ceramic particles, a binder and other components are dispersed to prepare coating slurry; and a self-repairing coating with the thickness of 5-10 microns is formed on the surface of the diaphragm through a roller coating or coating process. The coating is high in repairing efficiency, meanwhile, the tensile strength and ionic conductivity of the diaphragm are improved, the problem of mechanical damage caused by stress fatigue of the diaphragm is effectively solved, the safety of the lithium battery is remarkably improved, and the cycle life of the lithium battery is remarkably prolonged. The preparation method is simple in process and good in environmental protection property, and a brand new technical scheme is provided for preparation of the high-reliability lithium battery diaphragm.

A method for manufacturing a lithium disilicate glass ceramic with gradient properties by using photocuring additive manufacturing, the method comprising: performing wet mixing on a basic glass powder with a solvent, ball milling same until uniformity, drying same, then performing thermal treatment to reach a molten state, then quenching same to form original particles, and then granulating same to obtain lithium disilicate ceramic particles; respectively preparing n groups of pastes with gradually-changing colors and translucencies from n groups of the lithium disilicate ceramic particles, said paste preparation comprising: adding 3Y-TZP powder, a coloring agent and lithium disilicate ceramic particles to a resin mixture, mixing same, rolling same and performing vacuum defoaming to obtain a paste; adding the n groups of pastes in sequence into an additive manufacturing device to undergo photocuring forming, so as to obtain a green body; after the green body is cleaned and dried, degreasing the green body, and sintering same; and finally under a vacuum high-temperature condition, subjecting the sintered sample to an ion exchange reaction with a molten nitrate in a flowing state, so as to obtain a product.

The invention relates to the technical field of batteries, in particular to a lithium ion battery diaphragm and a preparation method thereof.The lithium ion battery diaphragm comprises a porous base membrane and a high-temperature-resistant bonding coating covering the surface of one side or two sides of the porous base membrane; the high-temperature-resistant bonding coating is prepared from the following raw materials in parts by weight: 15-20 parts of modified polymer emulsion, 60-80 parts of inorganic nano ceramic particles, 3-5 parts of fiber polymer, 3-5 parts of a binder, 0.1-0.5 part of an auxiliary agent and 20-30 parts of deionized water. According to the lithium ion battery diaphragm provided by the invention, through the modified polymer emulsion, the air permeability value after cold pressing and the cold pressing cohesive force are improved; meanwhile, the inorganic nano ceramic particles and the fiber polymer are added, so that the high-temperature resistance of the diaphragm is improved, and the safety performance and the cycle performance of the battery are effectively improved.

The invention provides a diaphragm as well as a preparation method and application thereof, and relates to the technical field of lithium ion battery diaphragm materials. The preparation method of the diaphragm comprises the following steps: S1, uniformly mixing a polyamide solution, lithium chloride and a solvent to obtain a spinning solution, and spinning and chopping the spinning solution to obtain polyamide short fibers; s2, dispersing polyamide short fibers, inorganic ceramic particles and auxiliaries in water to obtain water-based coating slurry; and S3, coating a base membrane with the water-based coating slurry, and drying to obtain the water-based composite membrane. The diaphragm provided by the invention has excellent heat resistance, and is helpful for improving the cycle performance and safety performance of the secondary battery.

The invention discloses an underground mine goaf filling body strengthening and subsequent mining joining method, and relates to the technical field of mine mining. Comprising the following steps of intelligent filling body construction and reinforcement, multi-source fusion intelligent monitoring and digital twinning construction, data-driven subsequent mining dynamic intelligent decision making and energy regulation and control, targeted restoration and collaborative ecological reconstruction. The intelligent filling body is made of the shape memory polymer fibers and the nanometer piezoelectric ceramic particles, the layering process is combined to improve the strength and real-time state feedback, the safety and durability of the filling body are remarkably improved, the high-fidelity digital twinborn model is constructed in a fused mode, intelligent decision making and active wave absorbing regulation are linked, and the stability of the filling body is improved. The subsequent mining efficiency can be effectively improved, the damage risk of the filling body can be effectively reduced, in addition, the damage area is accurately positioned through the unmanned aerial vehicle, directional grouting repair is conducted, heavy metal is solidified through microorganisms, solid waste is recycled, the resource utilization rate in the mining process is increased, and the environmental burden is reduced.

The invention relates to the technical field of magnet materials, and discloses a high-temperature-resistant neodymium-iron-boron magnet and a preparation method of the high-temperature-resistant neodymium-iron-boron magnet. The high-temperature-resistant neodymium-iron-boron magnet comprises the following components in parts by weight: 25-30 parts of neodymium, 60-65 parts of iron, 1.0-2.0 parts of boron, 3.0-5.0 parts of lanthanum, 0.5-2.0 parts of zirconium, 0.5-1.0 part of molybdenum and 0.1-0.5 part of nano ceramic particles, and the invention further provides a preparation method of the high-temperature-resistant neodymium-iron-boron magnet. S1, preparing and mixing alloy raw materials; s2, nano ceramic coating treatment is carried out; s3, magnetic field assisted pressing forming; and S4, rapid induction sintering. Through the magnetic field assisted directional pressing process, effective control over grain orientation in the pressing forming stage is achieved, magnetic domain arrangement is more ordered, and the residual magnetism and the energy product are improved. Different from a forming mode with disordered grain directions and poor magnetic anisotropy in an existing common cold pressing process, the technical defect that the utilization rate of magnetic performance is low due to poor orientation is overcome.

The invention relates to the technical field of nuclear fusion surface plasma W materials, in particular to nano rare earth oxide ceramic-Ti microalloy composite reinforced W powder, a composite material and a preparation method of the nano rare earth oxide ceramic-Ti microalloy composite reinforced W powder. The composite powder is of a nearly spherical core-shell hierarchical structure, and the particle size is 30-50 nm; according to the composite powder, refractory metal W serves as a matrix, nano rare earth oxide ceramic particles are evenly dispersed in matrix W crystal grains, Ti mainly forms an enrichment area on the surface of the matrix or a matrix / rare earth oxide interface in a simple substance or oxide mode, the phase interface structure is effectively improved, W crystal boundary migration and dislocation motion are hindered, W crystal grains are remarkably refined, and the composite powder is prepared. Part and W form semi-coherence, fine grain and interface strengthening and toughening are achieved, and a brand new thought and a technical method are provided for synergistically improving the strength and toughness of the W composite material. The composite powder is subjected to organic reduction synthesis and low-temperature reinforced sintering to prepare the composite material, the tensile strength at the room temperature reaches 500-610 MPa, and the ductility is 5%-8%.

The invention relates to a composite diaphragm, a preparation method thereof and a battery. The composite diaphragm comprises a base membrane, a first functional layer arranged on at least one side surface of the base membrane in the thickness direction, and a second functional layer arranged on one side surface, far away from the base membrane, of the first functional layer, the first functional layer comprises ceramic particles and a high-temperature-resistant polymer; the thermal decomposition temperature of the high-temperature-resistant polymer is higher than that of the base membrane and lower than the melting point of the ceramic particles; the second functional layer comprises a functional additive, and the functional additive comprises a polyether polymer; the contact angle between the second functional layer and the electrolyte is smaller than or equal to 50 degrees. Therefore, through the synergistic effect of the first functional layer and the second functional layer, the thermal stability of the composite diaphragm and the wettability of the composite diaphragm to electrolyte are improved at the same time.

The invention discloses a preparation method of surface metallized ceramic particles and a ceramic wear-resistant accessory, and mainly solves the technical problems of high cost, poor product performance, low yield and the like in the existing ceramic composite material preparation method. The preparation method of the surface metallized ceramic particles comprises the steps that wrapping alloy and ceramic particles with the volume ratio being (0.5-1.5): (8.5-9.5) are prepared, and the wrapping alloy comprises active metal, auxiliary welding metal and melting metal with the mass ratio being (15-40): (60-80): (0-10); the method comprises the following steps: mixing ceramic particles and a coating alloy, filling the mixture into a coating reaction tube, vacuumizing, heating, injecting reducing gas and / or protective gas, vacuumizing again, heating, completely reducing surface oxides of auxiliary welding metal and melting metal, vacuumizing again, heating to 900-1250 DEG C, melting the coating alloy, preserving heat, keeping the temperature at normal temperature, and cooling to room temperature. And surface metallization ceramic particles are obtained. The method is short in time, low in energy consumption and higher in production efficiency.

The invention belongs to the technical field of battery manufacturing, and particularly discloses a diaphragm with a gradient structure and a preparation method of the diaphragm. The diaphragm with the gradient structure comprises a diaphragm base membrane and a coating layer, the coating layer comprises ceramic coatings with different particle size ranges, and the two faces of the diaphragm base membrane are coated with ceramic particles A with the particle size D50 smaller than or equal to 100 nm and ceramic particles B with the particle size of 200-400 nm respectively. According to the diaphragm with the gradient structure, the porosity on the side close to the positive electrode is small, the porosity on the side close to the negative electrode is large, and therefore a smoother lithium ion transmission channel can be formed on the negative electrode side of the diaphragm, and the requirement for high lithium ion flux is met.

The invention relates to the technical field of lithium battery diaphragms, and provides ceramic affinity type lithium battery diaphragm organic coating slurry and a preparation method and application thereof.The ceramic affinity type lithium battery diaphragm organic coating slurry is prepared from, by weight, 10-12 parts of deionized water, 1-3 parts of ceramic microcapsule particles, 0.1-0.3 part of hydroxymethyl cellulose lithium and 0.5-1 part of solid electrolyte; core materials of the ceramic microcapsule particles are ceramic particles, and wall materials of the ceramic microcapsule particles are organic polymers; the preparation method of the ceramic microcapsule particles comprises the following steps: S1, dispersing deionized water, ceramic particles and a dispersing agent, uniformly stirring, introducing nitrogen, sequentially adding a lithium salt, a coating agent and a pore forming agent, then adding PVDF powder and PMMA powder, and mixing to obtain a pre-agglomerated solution; and S2, carrying out spray drying granulation on the pre-agglomerated liquid to obtain the ceramic microcapsule particles. According to the technical scheme, the problems of insufficient heat resistance and safety of the lithium battery diaphragm in related technologies are solved.

The invention relates to the technical field of wood, in particular to a multilayer structure insulation laminated wood manufacturing process which comprises the following steps: pretreatment: selecting birch fiber sheets with the thickness of 0.2-0.4 mm, and degreasing, cleaning and drying the birch fiber sheets; flame retardant treatment, wherein the surfaces of the pretreated birch fiber sheets are coated with a flame retardant solvent for 1-3 times through spraying equipment; and preparing impregnation liquid. According to the invention, epoxy resin is further crosslinked with residual hydroxyl of isocyanate resin through ring-opening reaction of epoxy groups to form a three-dimensional interpenetrating network structure, pores of wood fibers are effectively sealed, and an internal ion migration path is blocked, so that the insulativity is improved; meanwhile, the surface activity of the ceramic particles in the functional additive is enhanced after plasma treatment, stronger interface bonding is formed between the ceramic particles and the resin matrix, microcracks and holes at the interface are reduced, the breakdown risk caused by local electric field concentration is avoided, and the insulation effect is enhanced.

The invention discloses a method for obtaining a high-mechanical-property high-entropy alloy laser powder bed melting forming component, which comprises the following steps of: printing a three-dimensional solid component by using mixed powder of a high-entropy alloy and ceramic particles as a raw material and adopting a powder-based laser powder bed melting process; and the high-entropy alloy component which is high in compactness, free of cracks, fine in grain and excellent in mechanical property can be obtained. According to the obtained high-entropy alloy laser powder bed melting forming component, multiple kinds of strengthening such as grain refinement and tissue structure transformation occur in the laser powder bed melting process, and compared with a high-entropy alloy original material, the high-entropy alloy laser powder bed melting forming component has better mechanical performance. The obtained high-entropy alloy laser powder bed melt forming component can be applied to the fields of aerospace engine part manufacturing, anti-corrosion coatings and the like, and the requirement for the high-strength high-entropy alloy component is met.

The invention provides an online monitoring and early warning method for the wear state of a steel-based ceramic lining plate, and the method aims at the steel-based ceramic lining plate formed by compounding a metal matrix and inlaid ceramic particles, and comprises the steps: collecting multi-source monitoring signals which at least comprise a distance signal, an acoustic emission signal and equipment operation condition parameters; based on the multi-source monitoring signals, processing is carried out through a wear analysis model embedded with physical constraints, so that a decoupling evaluation result is output; the physical constraint is used for representing the coupling relationship between the wear state of the metal matrix and the protection effect of the ceramic particles; based on the evaluation result, predicting the evolution trend of the biphase wear coupling of the lining plate, and identifying the chain failure risk that the wear acceleration of the metal matrix is triggered by the failure of the ceramic particles; and integrating the grade and the evolution trend of the linkage failure risk to obtain a graded early warning signal, and generating a maintenance decision suggestion. According to the method provided by the invention, biphase wear is evaluated through real-time online decoupling, linkage risks are predicted, and graded early warning is realized.

The invention discloses a modified ultra-high molecular weight polyethylene fiber as well as a preparation method and application thereof. The modified ultra-high molecular weight polyethylene fiber is prepared from 100 parts by mass of ultra-high molecular weight polyethylene resin, 3-10 parts by mass of modified nano composite ceramic particles, 2-8 parts by mass of modified aramid fiber, 1-5 parts by mass of modified carbon nanotubes and 1-3 parts by mass of an auxiliary agent through the processes of a two-stage blending method, dry-wet spinning, gradient hot stretching, pulse heat setting and the like. The tensile strength of the prepared modified ultra-high molecular weight polyethylene fiber is greater than 4.5 GPa, the elongation at break is kept at 5.0-5.5%, the cutting resistance is as high as 310N, the puncture resistance is as high as 465N, and the modified ultra-high molecular weight polyethylene fiber can be applied to protective products.

The invention provides a gradient nano composite high-entropy alloy coating system with a self-monitoring function and a preparation method, and relates to the technical field of material surface engineering.The system comprises a functional gradient coating module used for achieving gradient dispersion distribution of nano ceramic particles on the curved surface of a shield hob so as to form a gradient nano composite high-entropy alloy coating; the fiber bragg grating sensing module is used for collecting strain data of the shield hob through a fiber bragg grating sensor integrated on the shield hob; the surface thermal image monitoring module is used for collecting temperature data and image data of the surface of the shield hob through an infrared thermal imager; and the self-adaptive repairing module is used for determining repairing parameters of the shield hob and generating a repairing instruction, so that self-adaptive repairing is carried out on the shield hob through preset repairing equipment according to the repairing instruction. According to the invention, the sensor network is successfully integrated in the gradient coating, and integrated fusion of structural health monitoring and protection functions is realized.

The invention discloses a preparation method of a foamed thermal-insulation ceramic decorative plate in the technical field of building decorative materials. The method comprises the following steps: carrying out ball milling, spray drying, granulating and ageing on raw materials such as ceramic waste and kaolin; mixing and dispersing the aerogel-hydrogel gradient core-shell structure composite modified material and ceramic particles, and sieving to obtain composite powder; compounding sodium bicarbonate and azodicarbonamide with a foaming agent, mixing the foaming agent with the composite powder, and adding a surfactant and a dispersing agent to adjust the viscosity so as to prepare expandable ceramic slurry; the slurry is injected into a mold and coated with low-temperature glaze, and stepped heating sintering is conducted through a tunnel kiln and comprises the steps of preheating glue discharging, primary foaming, secondary sintering, gradient cooling and the like. The thermal insulation performance, the mechanical strength, the weather resistance and the decoration performance are synergistically improved, and the product is low in heat conductivity coefficient, high in compressive strength, excellent in ultraviolet aging resistance, firm in decoration layer combination and suitable for building outer walls and other scenes.

The invention belongs to the technical field of composite material manufacturing, and discloses a structural battery integrated composite board and a forming method and application thereof. According to the composite board, carbon fiber reinforced materials are adopted as positive and negative electrodes, glass fiber materials are adopted as a diaphragm and an insulating layer, epoxy resin-based solid-state structure electrolyte is adopted as a bonding packaging medium, and a curing agent, ionic liquid, electrolyte lithium salt, nano ceramic particles and other auxiliaries of specific types and proportions are introduced into epoxy resin; the multifunctional modification of the resin matrix is realized. And meanwhile, doping and surface grafting modification are performed on the electrode material, so that the energy density and the mechanical strength of the battery are improved. And further constructing a low-temperature formed metal or carbon-based circuit layer on the outer surface of the structural battery to form an integrated complex comprising the circuit board, the structural battery and the bearing structure. The composite board satisfies dielectric insulation and reliability, realizes integrated energy supply and signal processing, and is widely applied to weight and volume sensitive fields such as aerospace and new energy automobiles.