The application discloses a kind of high-efficiency low-attenuation
antimony-doped N-type
monocrystalline silicon rod and preparation method thereof, belongs to
monocrystalline silicon rod manufacturing technical field, its preparation method is as follows:
polycrystalline silicon material is layered in
quartz crucible according to bottom layer, middle layer, top layer order layering charge,
antimony source is uniformly mixed in middle layer
silicon material;After vacuumizing to
single crystal furnace, fill in
argon as protective
atmosphere, make
polycrystalline silicon material and
antimony source completely melt by subsection heating, and form stable melt;
Seed crystal is added to melt, then after seeding, shoulder is released and enters constant
diameter growth stage, and the pulling speed is dynamically adjusted and the
crystal rotation speed is matched with the
crucible rotation speed;After constant
diameter growth to target length, start to finish, after in-situ annealing treatment, cool, and obtain.The application is based on
Czochralski method by
doping high-purity antimony source in
system, and dynamically controls constant
diameter growth process parameters, which can eliminate the light-induced attenuation hidden danger of N-type
monocrystalline silicon, significantly improve the resistivity uniformity, and realize the balance of low
dislocation density and high
crystal yield.