The invention discloses a multilayer stone-like ZnS / Zn-MOFs (at) SC super-hydrophobic
coating and a preparation method and application thereof.The preparation method comprises the steps that absolute ethyl
alcohol and deionized water are mixed,
polyvinylpyrrolidone and 2-aminoterephthalic acid are added for ultrasonic treatment,
zinc acetate is added for continuous ultrasonic treatment,
thiourea is added, magnetic stirring is conducted, and a precursor solution is obtained; pouring the pretreated
magnesium alloy into the precursor solution, sealing, performing
hydrothermal reaction, alternately cleaning with deionized water and
ethanol after the reaction is finished, and
drying to obtain a ZnS / Zn-MOFs
composite coating;
stearic acid and
chloramphenicol are co-dissolved in absolute ethyl
alcohol for ultrasonic clarification, the ZnS / Zn-MOFs
composite coating is vertically immersed in the
mixed solution, and
nitrogen is used for blow-
drying; and repeatedly dipping and
drying to obtain the multilayer stone-like ZnS / Zn-MOFs (at) SC super-hydrophobic
coating. The ZnS inorganic framework endows the
coating with high
mechanical strength, the micro-nano double coarse structure of the Zn-MOFs and the
stearic acid low
surface energy layer have a synergistic effect, so that the surface has self-cleaning ability, liquid drops can take away dust when rolling down, and the coating is free of maintenance after long-term operation.