371 results about "Superhydrophobe" patented technology

The invention discloses an anti-icing testing method, device and equipment for a super-hydrophobic surface structure of energy equipment and a storage medium, and relates to the technical field of super-hydrophobic surface testing. Designing a super-hydrophobic surface structure based on the environmental main control factor to obtain a structure parameter set; simulating the super-hydrophobic surface structure by using an environment load condition determined based on the environment working condition matrix and a structure parameter set to obtain an equipment critical vibration frequency, and determining a current surface structure morphology based on the structure parameter set and the equipment critical vibration frequency; and determining a morphology simulation error based on the current surface structure morphology and the actual surface structure morphology of the super-hydrophobic surface structure, and monitoring the super-hydrophobic surface structure based on the morphology simulation error, the structure parameter set, the equipment critical vibration frequency and the preset control mechanical excitation frequency to obtain the ice growth rate and the ice adhesion work. The efficiency of anti-icing testing of the super-hydrophobic surface structure is improved.

The application discloses a preparation method of a flexible super-hydrophobic anti-icing coating and relates to the technical field of super-hydrophobic materials.The preparation method comprises the following steps: preparing nano-silver loaded multi-layer graphene; mixing PVP solution and multi-layer graphene suspension uniformly, adding glucose, stirring uniformly, adding silver-ammonia solution to react when the suspension reaches a set temperature, centrifugally separating after the reaction is completed, obtaining the nano-silver loaded multi-layer graphene product, cleaning by using pure water or ethanol, and drying in an oven for standby; and preparing a flexible super-hydrophobic layer; smearing a mixture of PDMS and a PDMS curing agent on the surface of a glass sheet, uniformly spraying nano-loaded multi-layer graphene powder to the surface of the mixture of uncured PDMS and the PDMS curing agent by using an airbrush, and placing in an oven for curing to obtain the flexible super-hydrophobic anti-icing coating.The preparation method is simple and environment-friendly, can be used on a large scale, and can solve the problems of anti-icing and deicing on various surfaces.

The invention relates to an anti-icing super-hydrophobic coating for an aluminum conductor as well as a preparation method and application of the anti-icing super-hydrophobic coating. Single-ended epoxy fluorosilicone oil is grafted to the surface of an amino-functionalized metal organic framework material through an epoxy-amino ring-opening reaction to obtain a hydrophobically modified metal organic framework material, the hydrophobically modified metal organic framework material has a flexible fluorocarbon chain shell, and according to the design, the mechanical strength of a coating is enhanced through a rigid framework of MOFs; the stress concentration is relieved by utilizing the flexibility of a molecular chain of the fluorosilicone oil. The modified metal organic framework material is further dispersed in a matrix composed of fluorine-containing epoxy resin and an amino fluorosilicone oil curing agent, a multi-layer micro-nano structure is formed through ultrasonic dispersion and spraying curing processes, and the super-hydrophobic coating is obtained. According to the coating, through the synergistic effect of fluorosilane grafting modification and a micro-nano structure, the excellent performance that the static water contact angle is larger than or equal to 155 degrees, the rolling angle is smaller than or equal to 4 degrees, the ice adhesion strength is smaller than or equal to 40 kPa, and the wear resistance is excellent is achieved.

The invention discloses a super-hydrophobic chitosan aerogel PDMS (at) Co-PBA / CS and an application of the super-hydrophobic chitosan aerogel PDMS (at) Co-PBA / CS in oil-water separation. Adding Co-PBA into a chitosan aqueous solution, and then adding PVA; adding acetic acid and glutaraldehyde into the obtained mixed solution, stirring in a water bath, and freeze-drying to obtain Co-PBA / CS aerogel; and dissolving a hydrophobic material and a curing agent in an organic solvent, stirring to obtain a uniform suspension, immersing the Co-PBA / CS aerogel into the suspension, and carrying out vacuum drying to obtain PDMS-coated Co-PBA / CS. The super-hydrophobic chitosan aerogel PDMS (at) Co-PBA / CS prepared by the preparation method disclosed by the invention has relatively high adsorption capacity on both organic solvents and oil, and the removal efficiency is close to 100%. In addition, the composite material also has excellent self-cleaning and photo-thermal conversion performance, and can realize surface cleaning and removal of high-viscosity oil. The multifunctional aerogel provides a new strategy for removing pollutants such as oil in a complex and severe water environment.

The invention provides a directional moisture absorption and sweat releasing functional fabric and a preparation method thereof.The fabric comprises a sweat releasing and drying layer, a capillary moisture guiding layer and a hydrophilic moisture absorption layer from outside to inside, the hydrophilic moisture absorption layer is a cellulose acetate electrostatic spinning super-hydrophilic modified layer, the capillary moisture guiding layer is formed by weaving porous polyester yarn, and the hydrophilic moisture absorption layer is a super-hydrophilic modified cellulose acetate electrostatic spinning super-hydrophilic modified cellulose acetate electrostatic spinning super-hydrophilic modified cellulose acetate electrostatic spinning super-hydrophilic modified cellulose acetate electrostatic spinning super-hydrophilic modified fiber. The perspiration drying layer is a silane super-hydrophobic modified layer. Porous cross-section polyester fibers are prepared by adopting a washable template method, the moisture conductivity is improved, an electrostatic spinning cellulose acetate nanofiber membrane is subjected to super-hydrophilic modification, the sweat absorption rate is increased, the skin-friendly performance is improved, a sweat-releasing and drying layer is subjected to silane hydrolysis spraying and then heat treatment to form a super-hydrophobic siloxane coating, the surface dryness is enhanced, and the moisture absorption rate is increased. Unidirectional migration and rapid evaporation of sweat from inside to outside are achieved.

The invention relates to a melamine sponge with a chitosan-wheat straw biochar coating as well as a preparation method and application of the melamine sponge. The preparation method comprises the following steps: crushing wheat straws, and pyrolyzing under an anaerobic condition to obtain biochar; the biochar is soaked in a Prussian blue dispersion liquid for modification, and Prussian blue modified biochar is obtained; dispersing the material in a chitosan acetic acid solution for reaction to form a chitosan-charcoal composite system; adding PDMS (Polydimethylsiloxane) to carry out siloxane reaction to form stable composite sol; and finally, spraying the composite sol on the surface of the pretreated melamine sponge to form the super-hydrophobic coating. Through the synergistic effect of Prussian blue, chitosan and PDMS, the hydrophobicity and oil adsorption capacity of the material are remarkably improved, the water contact angle of the obtained sponge material can reach 168 degrees, the adsorption capacities to normal hexane and chloroform respectively reach 34 g / g and 80 g / g, and the sponge material has good cycle stability and wide application prospects in the fields of oil-water separation and environmental pollution treatment.

The invention discloses an anti-aging bronze powder pigment and a preparation method and application thereof in the technical field of bronze powder pigments, and the anti-aging bronze powder pigment takes copper-zinc alloy as a base material, and is sequentially connected with a composite chemical passivation layer, a functionalized organic-inorganic hybrid compact barrier layer and a surface super-hydrophobic layer through chemical bonding from inside to outside; wherein the composite chemical passivation layer is formed by treating a passivation solution containing phytic acid, ammonium metavanadate and sodium tungstate; the functionalized organic-inorganic hybrid compact barrier layer is constructed by a silane mixed solution containing 3-mercaptopropyltriethoxysilane, a reaction type ultraviolet light absorber Si-BP, a reaction type hindered amine light stabilizer Si-HALS and tetraethyl orthosilicate through a sol-gel process. Through the design of a multi-layer composite system, the aging resistance of the bronze powder is improved, and meanwhile, the optical decoration performance can be reserved to the maximum extent, so that the dual strict requirements of high-end outdoor applications such as automobile coatings on durability and visual texture can be met.

A superhydrophobic multifunctional coating and a preparation method thereof are provided, which relate to the technical field of coating materials. The superhydrophobic multifunctional coating includes the following components in percentage by volume: 0.1-3.0% of hydrophobic composition, 1.5-12% of texture stabilizer, 17-60% of binder and 25-80% of alcohol-free substrate material. The multifunctional coating not only has the characteristics of high hydrophobicity, high wettability angle greater than or equal to 160+5 degrees, rolling angle less than or equal to 5 degrees, oleophobic property, chemical erosion medium resistance, chemical inertia, low surface tension and the like, but also does not need to pretreat materials, so that the surface physical and chemical characteristics of various materials can be improved.

This invention discloses a method for preparing a fluorine-free superhydrophobic nano-silica cotton fabric, belonging to the field of superhydrophobic textile technology. The invention utilizes trichlorooctadecylsilane (OTS), γ-glycidyl etheroxypropyltrimethoxysilane (KH-560), and hexadecyltrimethoxysilane (HDTMS) to modify silica, obtaining a fluorine-free superhydrophobic coating. This coating, applied to the surface of the cotton fabric, results in a fabric with both low surface energy and a rough surface structure, exhibiting excellent superhydrophobic properties. Furthermore, it also imparts durability, self-cleaning, and stain-resistant capabilities to the hydrophobic coating.

This invention relates to the field of polytetrafluoroethylene (ePTFE) membrane technology. Addressing the problem that existing expanded PTFE films cannot meet the high-performance standards of superhydrophobicity and superoleophobicity, this invention specifically discloses an expanded PTFE composite membrane and its preparation method. The expanded PTFE composite membrane includes an ePTFE base membrane and an fPTFE / SiO2 particle composite layer disposed on the surface of the ePTFE base membrane. The fPTFE / SiO2 particle composite layer includes a PTFE composite and SiO2 particles. The PTFE composite comprises polyethylene oxide and PTFE in a dry weight ratio of 1:10-30, and the SiO2 particles have a particle size of 100-1000 nm. By coating the ePTFE base membrane with PTFE and SiO2 particles to construct the fPTFE / SiO2 particle composite layer, and then modifying the membrane surface with silica-fluorination, the distribution of SiO2 particles can be specifically controlled to impart superhydrophobic and superoleophobic properties to the expanded PTFE composite membrane, with both water and oil contact angles >150°.

The invention belongs to the technical field of nano materials and environment-friendly functional coatings, and discloses a preparation method and application of a lignin-based super-hydrophobic coating. The method comprises the steps that lignin is pretreated with ethylene carbonate to break steric hindrance and improve the grafting rate, then hexadecyl trimethoxy silane is added for grafting to form a hydrophobic chain, and surface energy is reduced; then adding silicon dioxide and N, N-dimethylformamide, carrying out ultrasonic dispersion to synergistically construct a micro-nano coarse structure, spraying the micro-nano coarse structure on a base material by using a spraying method, and putting the base material into a drying oven for curing, so as to obtain the lignin-based super-hydrophobic coating material. According to the method disclosed by the invention, a high-activity epoxy group is grafted on a lignin skeleton through ethylene carbonate pretreatment, so that steric hindrance in a three-dimensional space is broken, and dense anchor points are provided for a subsequent hydrophobic chain; then cocondensing with hexadecyl trimethoxy silane to form an alkyl-siloxane double network, and cooperating with nano silicon dioxide to construct micro-nano double roughness, so that a stable super-hydrophobic core under a fluorine-free condition is realized, and the technical route is simple and efficient.

The invention belongs to the field of new materials, and particularly relates to a super-hydrophobic composite coating with mechanical firmness, self-cleaning property and high wear resistance, a method and application thereof. According to the preparation method, epoxy resin (E51) is adopted as a binder, quartz sand, modified F-TiO nano particles and SiO nano particles are combined, and the quartz sand / F-TiO / SiO coated EP super-hydrophobic composite coating of a double-layer structure is prepared through a simple and convenient blade coating-spraying process. According to the coating, through multi-scale hierarchical structure design and low surface energy modification, a static water contact angle of 151 degrees and 1t are achieved; the rolling angle of 5 degrees shows excellent self-cleaning performance on liquid and solid pollutants. A mechanical stability test shows that in a Taber abrasion test, the coating still keeps good hydrophobicity after being abraded for 3000 cycles under the load of 250 g and abraded for 600 cycles under the load of 750 g; after 500 times of adhesive tape stripping experiments, the static water contact angle is still greater than 120 degrees, the rolling angle is as low as 5 degrees, and excellent wear resistance and substrate adhesion are shown.

This invention provides a process for preparing a superhydrophobic surface of a titanium alloy plate using a laser assisted flow of ethanol. The process involves: rough milling the surface of the titanium alloy plate to remove the oxide layer; introducing flowing ethanol onto the milled surface; using a laser to pass through the flowing ethanol to fabricate a grid structure framework on the titanium alloy plate surface; removing impurities from the surface of the titanium alloy plate; and then modifying it with fluorosilane and performing heat treatment to achieve the superhydrophobic surface. This invention improves the hydrophobicity of the titanium alloy plate, making it easier to achieve superhydrophobicity, reducing water flow resistance, and improving water transport efficiency. Furthermore, this process is cost-effective, easy to control, and allows for stable automated production.

This invention provides a method for constructing boundary conditions for a superhydrophobic cylindrical surface based on OpenFOAM, comprising the following steps: (1) reading the parameter setting file; (2) obtaining the position of the center of the cylindrical surface; (3) finding the position of the center of the first layer of grid near the cylindrical surface and its tangential velocity; (4) finding the position of the center of the second layer of grid near the cylindrical surface and its tangential velocity; (5) calculating the sum of the distances between the center of the cell and the center of the cylindrical surface; (6) calculating and updating the velocity of the cylindrical surface; (7) performing flow numerical simulation, repeating S2~S7 until the calculation is completed. This invention is based on OpenFOAM and has been further developed to construct a superhydrophobic surface boundary condition suitable for flow around a cylinder. This boundary condition supports parallel computation of the entire calculation process, improving computational efficiency and the scale of the problem solution.

This invention relates to the field of refractory materials technology, specifically to an anti-slag-adhesion environmentally friendly refractory spray coating adapted to the contact surface of an tundish cover and its preparation method. The dry powder of this spray coating mainly consists of corundum aggregate, modified spinel powder, composite binder, and modified anti-slag additives. Through precise gradation and spatial decoupling of components, a strong and tough skeleton is constructed. During water addition, rheological changes, and baking, the anti-slag additives spontaneously target and migrate outwards, reconstructing a superhydrophobic slag-repellent armor on the slag-facing surface. Combined with the internal spinel-based slag-locking and deformation buffer defense lines, a gradient synergistic defense is achieved. This invention is completely chromium-free and environmentally friendly, completely eliminating the pain point of high-temperature slag adhesion and spalling, extending its service life to 40 heats, and is suitable for large-scale adaptation to special steel continuous casting conditions.

The application discloses a kind of composite super-hydrophobic paper based on alkyl ketene dimer and metal polyphenol network and preparation method thereof, belong to functional paper-based material field.The method is first immersed in 0.25%~5% alkyl ketene dimer emulsion in cellulose paper, is dried at 90~110 DEG C and is cured 48-96h to prepare modified paper;Then, the pH is 8.0-9.0 of tris-hydroxymethyl aminomethane hydrochloride buffer solution, hydrochloric acid dopamine is dissolved in the buffer solution to form dopamine solution, and the concentration is 0.25~20mg / mL of metal ion solution;Finally, the modified paper is immersed in dopamine solution and metal ion solution in turn, and is dried to obtain composite super-hydrophobic paper.The obtained composite super-hydrophobic paper uses cellulose paper-based material as substrate, and hydrophobic layer and metal polyphenol network layer are formed on the surface in turn, the composite paper has super-hydrophobic performance, water barrier performance and photo-thermal response performance, the preparation process is simple, and is suitable for waterproof packaging, self-cleaning surface, anti-icing and deicing and photo-thermal antibacterial and other fields.

This invention discloses a liquid metal encapsulation structure and its manufacturing method, as well as an electronic device, relating to the field of heat dissipation element technology. It includes: a liquid metal filling area for filling liquid metal between an electronic component and a heat sink; the heat sink covering the electronic component; a superhydrophobic reflux area located around the liquid metal filling area, used to agglomerate liquid metal overflowing from the liquid metal filling area based on its hydrophobicity and guide the agglomerated liquid metal backflow; a leakage detection area located around the superhydrophobic reflux area, used to detect liquid metal leaking from the superhydrophobic reflux area and trigger an alarm; and an absorption area located around the leakage detection area, used to control the oxidation reaction of liquid metal leaking from the leakage detection area, thereby blocking the flow of liquid metal in that area. Through the collaborative design of multiple functional areas, this effectively achieves liquid metal sealing and leakage prevention, avoiding risks such as equipment damage and business downtime caused by liquid metal leakage.

This invention discloses a hydrophobicity rating system for superhydrophobic surfaces of energy equipment, relating to the field of hydrophobicity rating technology. The system includes a data acquisition module, an optimal parameter combination module, a sample preparation module, a hydrophobicity quantification and evaluation module, a test closed-loop calibration module, and a hydrophobicity rating classification and output module. These modules are interconnected, and through their collaborative operation, the system quantifies, performs closed-loop calibration, and classifies the hydrophobicity index of superhydrophobic samples of energy equipment with different microstructures. The closed-loop calibration process fully considers both anti-icing and weather resistance, significantly improving the accuracy and generalization ability of the hydrophobicity rating results. This solves the problems of inaccurate evaluation results and inability to adapt to extreme field conditions caused by traditional evaluation systems relying solely on conventional laboratory environments, single physical tests, and empirical thresholds for rating. This enhances the intelligence level of hydrophobicity rating evaluation for superhydrophobic surfaces of energy equipment.

This invention relates to an insulating oil and an oil-paper insulation system containing superhydrophobic nanoparticles, as well as their preparation method and application, belonging to the field of electrical equipment insulation technology. This invention provides an insulating oil containing superhydrophobic nanoparticles, wherein the superhydrophobic nanoparticles are silane-modified nanoparticles, and the nanoparticles include at least one of SiO2, TiO2, and h-BN; the insulating oil includes at least one of mineral insulating oil, synthetic insulating oil, and natural ester insulating oil. This invention achieves the superhydrophobicity of the nanoparticles and good compatibility with the oil phase through silane modification. Adding silane-modified nanoparticles to the insulating oil effectively reduces the water content of the insulating oil and optimizes the interfacial performance of the oil-paper. Combined with the low-temperature, high-efficiency, and uniform rapid impregnation process of this invention, the overall electrical performance and service life of the oil-paper insulation system are significantly improved.

The application provides a white clover surface with super-low ice adhesion strength and a preparation method thereof, which comprises analyzing the relationship between the white clover surface structure and the super-hydrophobic cold resistance; copying the white clover surface structure, and processing periodic micropores on a base material by means of femtosecond laser direct writing; boiling the surface of the periodic micropores; and fluorinating the surface to modify it into a functional surface with super-hydrophobicity. The white clover surface with super-low ice adhesion strength has a micro-nano hierarchical structure, which comprises closely arranged larger micrometer-level periodic pore structures, smaller micrometer-level granular particles dispersedly distributed on the surface of the micropore structures, and densely distributed sub-micrometer-level sheet structures on the surface. The surface has super-hydrophobic low adhesion, the ice adhesion strength is as low as 1.08 kPa, the static icing prolonging time can reach 4 h, the dynamic frost prevention capacity can last for 5 h in a low-temperature and high-humidity environment, and the surface has good wear resistance and reusability.

This invention relates to a high-efficiency fog collector unaffected by fog flow direction and its manufacturing method. First, a superhydrophobic coating is formed on the surface of a copper sheet. Then, patterns are drawn on the copper sheet using a laser as punctuation marks. After electroplating, multiple superhydrophilic protrusions are formed. Finally, a uniquely shaped umbrella-like structure is formed through plastic stamping. The fog collector provided by this invention not only has high fog collection efficiency and adapts to any fog flow direction, but also uses abundant and readily available raw materials. Furthermore, the manufacturing process is simple, time-saving, and highly efficient, providing new ideas for the design of future high-efficiency fog collectors.

This invention relates to the field of superhydrophobic functional coating materials. The invention discloses a carbon-coated nano-silica photothermal superhydrophobic coating and its preparation method. The preparation method includes: preparing carbon-coated nano-silica particles via a hydrothermal method; mixing the particles with an adhesive and PDMS and spraying the mixture onto a substrate surface, followed by a first curing to form a base coating; then immersing the mixture in a solution containing perfluoroalkyl silanes, followed by a second curing to obtain the final coating. The coating of this invention exhibits a water contact angle exceeding 150° and a roll-off angle less than 10°. Under 1 solar intensity, the surface temperature can rise to over 60°C within 6 minutes. It possesses advantages such as high-efficiency photothermal conversion, superhydrophobicity and oleophobicity, synergistic passive anti-icing and active de-icing, and good mechanical stability. Furthermore, the process is simple and scalable, making it suitable for anti-icing and de-icing protection in fields such as power facilities, wind power generation, and aerospace.

This invention discloses a superhydrophobic unsaturated transition metal chalcogenide compound, its synthesis method, and its applications. The invention involves heating chalcogenide powder to above its melting temperature to form a molten chalcogenide. This molten chalcogenide is then mixed with a reducing agent to undergo a disproportionation reaction. A strongly acidic solution containing transition metal cations is then added for aging, yielding a transition metal chalcogenide compound with a uniform porous structure, numerous surface defect sites, and a superhydrophobic surface. This transition metal chalcogenide compound exhibits good water resistance and high selective adsorption performance for nonpolar atoms and molecules, making it suitable for the removal of heavy metals or oxides from high-humidity flue gas. Furthermore, its unique porous structure and numerous catalytically active sites demonstrate good adsorption, capture, and catalytic conversion activity for oxidizing gases, making it suitable as an electroreduction catalyst.

This invention provides a method for preparing a superhydrophobic silk / ultrafine viscose high-softness fabric, comprising the following steps: S1. Degumming the silk / ultrafine viscose fabric to obtain a degummed silk / ultrafine viscose fabric; S2. Adding hydrophobic micron-sized flake-like aerogel powder to ethyl acetate solvent and stirring to mix evenly to obtain a hydrophobic finishing solution; S3. Applying the hydrophobic finishing solution prepared in S2 to the surface of the fabric after degumming in step S1 in one direction, and then drying the fabric, repeating the application in the same direction as the first application to obtain a silk / ultrafine viscose fabric with a surface covered with flake-like powder; S4. Adding PDMS and hydrophobic nano-TiO2 nanoparticles to a spinnable tetraethyl orthosilicate solution, mixing and stirring evenly, and aging to a spinnable viscosity, using the side of the fabric surface covered with flake-like powder as the receiving surface, and performing electrospinning to obtain a superhydrophobic silk / ultrafine viscose high-softness fabric.

The invention relates to the field of materials, in particular to a profile-followed fabric for coating a complex curved surface, which consists of a bottom layer fabric, a surface layer and a middle layer, a three-layer gradient composite structure is designed, a bottom layer fabric is a flexible cement-based film with water-triggered activity, a middle layer is a bionic laminated layer formed by connecting high-strength cement-based unit sheets through flexible polyurethane hinges, and a surface layer is a super-hydrophobic wear-resistant coating; compared with the prior art, the obtained fabric has the outstanding effects that the fabric is dry and flexible, can be cut at will, can be rapidly hardened and bonded when meeting water, can be perfectly attached to a complex curved surface, and is excellent in durability and simple, convenient and efficient to construct; the coating has wide application prospects in the fields of building special-shaped structure decoration and maintenance, industrial equipment pipeline coating, sculpture cultural relic protection and other complex curved surface coating.

The invention belongs to the field of new materials, and particularly relates to a fluoride-free super-hydrophobic photo-thermal anti-icing coating, a method and application thereof. According to the present invention, the silane coupling agent 3-glycidyl ether oxypropyl trimethoxy silane modified dihydroxyl-terminated polydimethylsiloxane (PDMS) is adopted as the adhesive, the ethyl acetate is adopted as the solvent, and the TiO2 and the SiO2 are mixed to prepare the coating, such that the adhesion performance of the coating is improved to 1.35 MPa from the original 0.62 MPa, the modified PDMS has the adhesion and the ultrahigh contact angle of 155 DEG C, and the adhesion performance of the coating is significantly improved. After 100 times of a friction test of a weight loaded with 50 g and 192 hours of irradiation under a UV lamp, the contact angle is still kept to be larger than 150 degrees, the anti-icing performance under the condition of-10 DEG C is delayed to 200 s from 90 s, and under a simulated illumination experiment, temperature data prove that the deicing performance of the coating is greatly improved due to the photo-thermal effect of TiO2. And the environment-friendly fluorine-free anti-UV aging photo-thermal super-hydrophobic coating with deicing and icing resistance is prepared through a spraying method.

This invention belongs to the field of waterborne coatings and discloses a filler-modified organosilicon waterborne polyurethane, its wear-resistant superhydrophobic coating, and its preparation method. The wear-resistant superhydrophobic coating is made by stirring waterborne polyurethane emulsion as the main raw material, adding hydrophobic modified organosilicon, nanofiller modifiers, and additives. This coating not only has excellent adhesion and wear resistance but also superhydrophobic properties. Specifically, the introduction of hydrophobic modified organosilicon improves the coating's adhesion strength to the substrate and its wear resistance; the introduced low surface energy -Si-O-Si segments improve the coating's hydrophobicity, giving it superhydrophobic properties; and different fillers impart good UV resistance and wear resistance to the coating.

The present invention belongs to the technical field of optical preparation. Disclosed are an apparatus and method for preparing a superhydrophobic coating on a closed metallic curved surface. The apparatus comprises a laser device, a conical concave reflecting mirror, a fixture, a position adjusting platform and a control unit, wherein the fixture is fixed on the position adjusting platform, and the laser device is arranged above the adjusting platform, both the laser device and the position adjusting platform being electrically connected to and controlled by the control unit; the conical concave reflecting mirror is arranged between the fixture and the laser device; the lower base of the conical concave reflecting mirror is sealed, a through hole being provided right in the middle of the lower base; and the laser device is configured to emit laser to the conical concave reflecting mirror, and the conical concave reflecting mirror is configured to reflect and focus the laser. By means of the cooperation of the conical concave reflecting mirror and the laser device, the laser performs rotational scanning around the surface of a closed-curved workpiece, thereby achieving rapid marking; in addition, by dynamically adjusting and controlling a laser scanning path, the preparation of a superhydrophobic coating with high precision, low cost and simple operation is achieved.

This invention discloses a superhydrophobic radiation-cooling polymer coating, its preparation method, and its application. The coating is white and possesses a bicontinuous micro / nano porous structure. It is prepared by a ternary copolymerization reaction of polyurethane acrylate oligomers, acrylate reactive diluents, and vinyl siloxane porogens. The method involves initiating free radical polymerization of monomers in the porogen under ultraviolet light, inducing rapid phase separation, and naturally evaporating the porogen to obtain the coating. This coating exhibits superhydrophobicity without post-treatment, virtually no absorption in the solar spectrum, and near-100% emissivity in the mid-infrared window. Furthermore, the optical properties and superhydrophobicity of the coating are minimally affected by long-term ultraviolet irradiation, thermal aging, acids, and alkalis. This coating can be applied over large areas in high-performance radiation-cooling applications.

The application discloses a preparation method of a self-repairing super-hydrophobic composite bio-based polyurethane coating and relates to a polyurethane coating preparation method, which takes Jatropha curcas oil as raw material, takes alcohol as a ring-opening agent, prepares Jatropha curcas-based polyester polyol, and prepares a self-repairing super-hydrophobic composite bio-based polyurethane by using polytetrahydrofuran as a chain extender. The introduction of the synergistic self-repairing function of the double dynamic network structure enhances the mechanical strength and elasticity of the material. The disulfide bond and hydrogen bond in the polyurethane can be dynamically broken and reconnected, so that the damaged area can be self-repaired without external intervention. The introduction of the super-hydrophobic function can effectively resist the adhesion of water and other liquids on the surface of the material, which not only greatly enhances the resistance of the material to the external environment, but also exhibits excellent protective performance in the initial use stage of the material, which is particularly crucial for maintaining the structural integrity and aesthetic appearance of the material. The self-repairing super-hydrophobic ability greatly prolongs the service life of the material and reduces the maintenance cost.