The invention relates to a paper making material, a preparation method and a paper making method of environment-friendly synthetic paper. The material comprises modified mineral fiber, thermoplastic starch, cellulose derivative, compatilizer, auxiliary components and the like, wherein the average particle diameter of the modified mineral fiber is 5-10 micrometers, the ratio of the length of the modified mineral fiber to the diameter of the modified mineral fiber is 8-15:1, and the modified mineral fiber is treated by fibrosis ultrafine grinding and surface recombination modification; the thermoplastic starch is formed by performing micronization and plasticization modification on norm starch; and the auxiliary components comprise lubricant and colorant. The paper making material is prepared by sequentially mixing the raw material components fully and then extruding and granulating the mixture by a screw extruder at 60-180 DEG C. According to the plastic process mode, the material can be treated by blow molding through a calender or a paper film machine for carrying out two-way stretch to prepare corresponding paper products. The paper making material can overcome the defects of the current synthetic paper and can be widely applied to the fields of commercial printing, publications, office paper, packing and the like, and the processing procedure of making paper by using plastic processing equipment has environmental protection and low cost.