The invention discloses a method for preparing a
titanium-based
graphene coating for
solid phase microextraction. The method comprises five steps. According to the method, a
silanization agent serves as an intermediate carrier,
graphene is modified on the surface of a
metal titanium wire, a
coating which has a multi-layer sheet
graphene structure is formed on the
titanium-based surface, and the material can be applied to the extraction head in the
solid phase microextraction technology. The method is advanced in thought, clear in concept, simple and convenient in
coating preparation, the thickness is controllable, and the obtained coating is uniform, stable and high-temperature resistant. According to the
solid phase microextraction head, trace
phthalate in different water samples such as running water, underground water and
lake water can be extracted at high efficiency, the corresponding
detection limit can be 0.030mu g / L, the reproducibility is 2.2-12.6 percent, the marked
recovery rate is 73.8-104.5 percent, and the repeated extraction frequency exceeds 200 times. The method has wide application prospects in the technical field of
analytical chemistry and
environmental analysis.