This invention relates to a
microwave radiation method for preparing room-temperature phosphorescent
polymer films based on
polyacrylamide, belonging to the field of organic light-emitting materials. The method involves dissolving
acrylamide monomer,
ammonium persulfate initiator, and β-
diketone ligand in a mixed
solvent of water and
acetonitrile, placing the solution in a
microwave reactor, and polymerizing it under
microwave radiation to obtain the
polymer. The resulting
colloidal solution, dissolved in deionized water, is uniformly coated onto a
polytetrafluoroethylene (PTFE) or
silicone plate, and dried to obtain the room-temperature phosphorescent
polymer film based on
polyacrylamide. The prepared polymer film exhibits blue or blue-green
fluorescence and a green
afterglow. The polymer film containing 4,4,4-trifluoro-1-(2-naphthyl)-1,3-butanedione has an
afterglow time of up to 7.5 seconds. The raw materials of this invention are readily available, the preparation method is simple, convenient, and rapid, requiring no
inert gas protection, the
solvent does not require treatment,
polymerization can be completed in minutes, and the obtained material is non-toxic, non-polluting, free of
heavy metals and halogens, has good water
solubility, and has broad application prospects.