5529 results about "Nano silicon dioxide" patented technology

The invention belongs to the technical field of biodegradable materials, and particularly relates to an environment-friendly degradable modified composite material, a preparation method and application. The material comprises PBAT, PBS, PLA, an inorganic mineral filler, natural plant fibers, PBAT-PTMO, nano-silica, an auxiliary agent and a plasticizer. In the preparation process, PLA is prevented from being hydrolyzed in vacuum drying, calcium carbonate and nano silicon dioxide are preheated and activated, natural plant fibers are dispersed through steam explosion and ethanol treatment, and raw material pretreatment comprises high-speed mixing and agglomeration breaking and medium-speed secondary premixing so as to realize uniform distribution. The co-rotating twin-screw extruder accurately controls the temperature, the speed, the rotating speed and the length-diameter ratio, and ensures melting plasticizing, uniform mixing and stable extrusion molding. According to the invention, by adopting accurate proportioning of multiple raw materials and a modification treatment process, the properties of mechanics, degradation, processing and the like of the material are synergistically improved, and the material is widely applied to multiple fields such as packaging bags, disposable tableware and agricultural plastic mulching films.

The invention relates to the field of concrete, and provides high-strength concrete and a preparation method thereof, and the high-strength concrete comprises modified basalt chopped fiber, a self-repairing agent, cement, fly ash, slag powder, coarse aggregate, natural sand, a water reducing agent and an air entraining agent. The modified basalt chopped fiber is oxidized by hydrogen peroxide, etched by hydrochloric acid and modified by a nano silicon dioxide coating, so that the interface bonding force is enhanced. The self-repairing agent is prepared by adopting expanded perlite to load bacillus through thallus culture, purification, dipping adsorption and low-temperature vacuum drying, CaCO3 deposition can be induced at concrete cracks, and self-repairing is achieved. The invention further provides a preparation method of the concrete. The preparation method comprises the steps of aggregate screening, hydrated liquid preparation, wet mixing, fiber and self-repairing agent adding, vibration forming and curing. The crack resistance of the concrete is improved by enhancing the fiber-matrix interface bonding force, meanwhile, the service life of the concrete is prolonged by utilizing a biological self-repairing technology, and the concrete is suitable for high-durability concrete engineering.

The invention belongs to the technical field of electrical epoxy resin materials, and particularly relates to anti-aging electrical epoxy resin and a preparation method thereof. The epoxy resin is prepared from the following raw materials in parts by weight: 70 to 80 parts of epoxy resin, 3 to 5 parts of modified nano silicon dioxide, 1 to 3 parts of aminated graphene, 5 to 8 parts of polyurethane, 0.5 to 1 part of methyltriethoxysilane, 0.1 to 0.5 part of lauryl sodium sulfate, 0.5 to 1 part of antioxidant and 0.5 to 1 part of ultraviolet absorbent. Through silane modified nano silicon dioxide and aminated graphene, the anti-aging and corrosion-resistant performance of epoxy resin is improved, nano silicon dioxide enhances hardness and rigidity, aminated graphene improves toughness and heat conductivity, nano silicon dioxide and aminated graphene have a synergistic effect, multiple physical barriers are formed, permeation of aging factors and corrosive media is reduced, and the anti-aging and corrosion-resistant performance of epoxy resin is improved. And the surface is subjected to hydrophobic treatment by adopting methyl triethoxysilane, so that the weather resistance and the moisture resistance are further improved.

The invention belongs to the technical field of polymer plastic materials, and particularly relates to a high-temperature-resistant anti-corrosion polytetrafluoroethylene material and a preparation method thereof. The polytetrafluoroethylene is prepared from the following raw materials in parts by weight: 50 to 60 parts of polytetrafluoroethylene, 5 to 10 parts of fluorinated modified graphene oxide, 3 to 5 parts of aluminum powder, 5 to 8 parts of modified silicon carbide fiber, 3 to 5 parts of silane modified nano silicon dioxide, 2 to 3 parts of polyphenylene sulfide, 2 to 3 parts of polyimide, 0.5 to 0.8 part of dispersing agent and 0.5 to 1 part of antioxidant. The heat conduction performance and the interface bonding force are improved through the fluorinated modified graphene oxide, the impact resistance and the wear resistance are enhanced through the silicon carbide fibers, and the corrosion resistance and the wear resistance are improved through the aluminum powder; silane modified silicon dioxide enhances the mechanical property of the composite material by improving the dispersity of the filler, and PPS and PI interact with the surface of the filler through polar groups in molecular chains, so that the interface strength is improved, and the toughness and the thermal stability are improved.

The invention relates to a self-cleaning nano coating material and a preparation process thereof, and belongs to the technical field of functional coatings. The coating material is prepared from nano silicon dioxide, nano aluminum oxide, graphene nanosheets, nitrogen-doped titanium dioxide, fluorinated silane, polyurethane, polydimethylsiloxane, a microcapsule repairing system, ethanol and deionized water according to a specific proportion through a multi-layer composite structure. The preparation process comprises the steps of base material surface pretreatment, reinforced particle surface modification, base material dissolution, functional additive introduction and multi-layer coating preparation. Through bottom layer enhancement, middle layer flexible buffering and surface layer functional design, excellent mechanical strength, wide-spectrum photocatalytic performance, self-repairing capacity and environmental adaptability are achieved. The problems that in the prior art, a self-cleaning coating is insufficient in mechanical performance, low in photocatalytic efficiency, lack of a self-repairing function and poor in weather resistance are solved, the service life of the coating is remarkably prolonged, and the functional stability of the coating is remarkably improved.

The invention belongs to the field of photovoltaic glass coatings, and particularly relates to a super-hydrophilic anti-reflection wear-resistant self-cleaning coating for room-temperature curing of photovoltaic glass, which takes nano silicon dioxide sol as a main film-forming agent to cure and form a film and comprises the following raw materials in parts by weight: 55-90 parts of deionized water, 9-20 parts of nano silicon dioxide sol, 1-10 parts of a silane coupling agent and 0.001-1 part of nano titanium dioxide. The coating is prepared from the following components in parts by weight: 0.01-1 part of a surfactant, 0.01-1 part of modified polyvinyl alcohol, 0.01-1 part of water-based acrylic resin, 0.001-1 part of an antistatic agent, 1-5 parts of a curing agent, 1-5 parts of a flatting agent and 0.1-1 part of a wear-resistant agent. The super-hydrophilic anti-reflection wear-resistant self-cleaning coating has super hydrophilicity, the water contact angle is below 10 degrees, the hydrophilicity, the antistatic property, the anti-reflection property, the wear resistance and other properties of glass can be remarkably improved, and when the super-hydrophilic anti-reflection wear-resistant self-cleaning coating is applied to photovoltaic module glass, the photoelectric conversion efficiency in photovoltaic power generation can be improved.

The invention relates to the technical field of folding screen supporting films, and particularly discloses a double-layer buffering supporting film for a flexible folding display screen and a preparation method of the double-layer buffering supporting film. The double-layer buffer supporting film for the flexible folding display screen sequentially comprises a release film layer, a first adhesive layer, a first stainless steel layer, a second adhesive layer, a second stainless steel layer and a protective film layer from top to bottom, the first adhesive layer and the second adhesive layer are prepared by curing the same pressure-sensitive adhesive composition; the pressure-sensitive adhesive composition is prepared from the following raw materials: acrylate copolymer, hydrogenated rosin glyceride, hyperbranched polyesteramide-dopamine conjugate, acylhydrazone bond modified siloxane, a curing agent and a silane coupling agent; the protective film layer comprises the following raw materials: PET particles, nano silicon dioxide, an ethylene-vinyl acetate copolymer and an antioxidant. The double-layer buffer supporting film has the advantages of being high in supporting rigidity and interlayer peel strength, and serious folds caused by long-term repeated folding of the folding screen can be relieved.

The invention relates to the technical field, and particularly discloses a nano-modified epoxy building thermal insulation material and a preparation method thereof. The nano modified epoxy building thermal insulation material is prepared from the following raw materials in parts by mass: 80 to 120 parts of Portland cement, 20 to 40 parts of slag powder, 5 to 10 parts of hollow mesoporous silicon dioxide, 0.1 to 1 part of pyrrole, 0.1 to 0.2 part of ammonium persulfate, 5 to 10 parts of nano silicon dioxide, 10 to 15 parts of bisphenol S epoxy resin, 1 to 5 parts of acrylic acid, 1 to 2 parts of polylysine, 0.01 to 0.1 part of catalyst and 1 to 2 parts of curing agent. The concrete is prepared from the following raw materials in parts by weight: 20-30 parts of epoxy resin, 4-8 parts of loaded aerogel, 0.1-1 part of polycarboxylate superplasticizer, 1-4 parts of composite fiber and 0.2-1.25 parts of hydrogen peroxide. The fireproof building material has excellent toughness, can better resist cracking and absorb energy, effectively avoids cracking and damage under the action of thermal stress, and ensures that the building material has a fireproof effect.

The invention provides anti-cracking and anti-seepage high-performance concrete, which relates to the technical field of concrete and comprises Portland cement, aggregate, a high-activity mineral admixture, a calcium-magnesium composite expanding agent, nano silicon dioxide particles, a microcapsule-packaged sodium silicate and calcium lactate solution, paraffin / expanded graphite composite phase change microspheres, steel fibers, PVA fibers and nano cellulose. The self-repairing concrete has the characteristics that the anti-cracking performance is comprehensively improved, the anti-seepage grade is broken through, the self-repairing capability is long-acting, the construction adaptability is enhanced, and the like.

The invention provides a hot in-place recycling asphalt mixture and a construction method, and relates to the technical field of asphalt mixtures, and the hot in-place recycling asphalt mixture is obtained by recycling old asphalt pavement materials in a high proportion, reducing new material consumption and carbon emission, realizing resource recycling and green construction and introducing a regenerant to recover the performance of aged asphalt. The high-temperature rut resistance, the low-temperature crack resistance, the fatigue resistance and the interface bonding strength of the mixture are synergistically improved by matching with the styrene butadiene rubber modifier, the basalt fiber, the nano silicon dioxide and other functional materials, and the mixture is ensured to be uniform and free of segregation through precise feeding sequence, high-pressure atomization spraying and forced stirring parameter control. The defects of gray materials, oil balls and the like are avoided, the compactness, the flatness and the overall structure stability of the regenerated pavement are improved, and the problems of performance degradation and insufficient durability of a traditional regenerated mixture are solved.

The invention relates to the technical field of oilfield exploitation, and discloses a nanometer oil-displacing agent for oilfield oil extraction and a preparation method thereof.The nanometer oil-displacing agent takes modified nanometer silicon dioxide and a surfactant as main components, polymer macromolecules are modified on the surface of the nanometer silicon dioxide to serve as a main body of the nanometer oil-displacing agent, and the nanometer oil-displacing agent is prepared. Under the action of the surfactant, the nano silicon dioxide can flow into the fine throat and the micro throat, and the polymer macromolecules of the branched structure can generate a relatively strong interaction force with the rock, so that the polymer macromolecules are firmly adhered to the surface of the rock, the adhesion of crude oil on the surface of the rock is reduced, a smooth crude oil channel is constructed, and the flowing pressure of liquid is reduced; and crude oil fluidity is improved. The structure of the cross-linking agent contains quaternary ammonium cations, so that the electrostatic repulsion effect between nano silicon dioxide can be greatly enhanced, aggregation between nano silicon dioxide and nano silicon dioxide can be avoided, the interfacial tension can be efficiently maintained, the oil-water interfacial tension is greatly reduced, and the recovery rate of crude oil is effectively increased.

The invention relates to the technical field of building materials, in particular to a Yellow River superfine sand aggregate interface reinforcing agent and a preparation and use method thereof.The interface reinforcing agent is prepared from 0.05-0.1 part of graphene oxide powder, 50-100 parts of a silane coupling agent, 50-100 parts of nano-silicon dioxide, 10-30 parts of oxalic acid and 5000-7000 parts of water; graphene oxide powder, a silane coupling agent and nano silicon dioxide are jointly used for preparing an interface modifier for performing interface modification treatment on the Yellow River superfine sand, so that the interface bonding force between the Yellow River superfine sand and a cement hydration product is enhanced.

The invention discloses a preparation process of an aluminum oxide ceramic material, which comprises the following steps: S1, pretreatment of aluminum oxide powder: taking alpha-Al2O3 powder as a raw material, adding a dispersion medium, carrying out ball milling, transferring into an ultrasonic dispersion machine, dispersing, and further carrying out vacuum drying to obtain pretreated aluminum oxide powder; s2, chemical activation treatment: weighing pretreated aluminum oxide, magnesium oxide, nano silicon dioxide, calcium oxide, zirconium dioxide, titanium dioxide and modified nano silicon carbide in parts by weight, mixing, sequentially adding a dispersing agent absolute ethyl alcohol and a KH550 silane coupling agent, stirring at a high speed, adding a polyvinyl alcohol binder, and continuously stirring to obtain ceramic slurry; s3, sieving the ceramic slurry, filling the ceramic slurry into a mold, and performing isostatic pressing to obtain a ceramic green body; and S4, putting the ceramic green body into a box-type sintering furnace, sintering step by step, and cooling to room temperature along with the furnace to obtain the aluminum oxide ceramic material. The prepared aluminum oxide ceramic material has high compactness, excellent dielectric strength and mechanical property, low energy consumption and great application potential.

The invention discloses a nano blocking agent for drilling fluid and a preparation method thereof, and belongs to the technical field of blocking agents, the nano blocking agent for drilling fluid is prepared by reaction of a core layer blocking agent and a shell layer blocking agent, the core layer blocking agent is prepared by reacting nano silicon dioxide, gamma-methacryloxypropyltrimethoxysilane and a first part of vinylphosphonic acid, and has secondary blocking capability; and the shell blocking agent is prepared by reacting a second part of vinyl phosphonic acid, styrene and 2-dodecene-1-yl succinic anhydride, and has the characteristic of flexibility. The nano plugging agent has rigid supporting and flexible deformation capabilities, and the high-temperature stability and compressive strength of a plugging layer are remarkably improved. The chemical binding force of the plugging agent and the rock is enhanced; the hydrolysable methoxyl reserved in the core layer provides a secondary plugging function, and the plugging validity period is prolonged. The invention relates to a preparation method of a nano blocking agent for drilling fluid, which is used for preparing the nano blocking agent for drilling fluid.

The invention belongs to the technical field of soil fertilizers, and particularly relates to a soil conditioner and a preparation method thereof. Wherein the soil conditioner is prepared from the following raw materials in parts by weight: 30 to 40 parts of modified charcoal, 20 to 30 parts of microbial complexing agent, 15 to 25 parts of humic acid and 1 to 5 parts of biological enzyme; according to the microbial complexing agent, dopamine grafted and modified nano silicon dioxide and hydroxyapatite form a composite shell, pseudomonas aeruginosa and bacillus subtilis are wrapped, and the microbial complexing agent has the functions of protecting microorganisms, adsorbing heavy metals and slowly releasing phosphorus elements; the modified biochar is compounded with the attapulgite through acid-base treatment to form a porous structure with physical inlaying and chemical functional groups synergistic, so that the adsorption and fixation capability on heavy metals and organic pollutants is remarkably improved; the biological enzyme accelerates organic phosphorus conversion, and enzymatic hydrolysate provides a phosphorus source for microorganisms, promotes microorganism breeding, effectively increases the content of available phosphorus in soil, and enhances the stability of a remediation system.

The invention relates to the technical field of high polymer materials, in particular to ethylene-vinyl acetate copolymer modified polypropylene high-toughness plastic particles and a preparation process thereof. The composite material is prepared from the following raw materials in parts by weight: 60 to 80 parts of polypropylene, 15 to 30 parts of ethylene-vinyl acetate copolymer, 5 to 10 parts of maleic anhydride-2-ethylhexyl acrylate copolymer grafted ethylene-vinyl acetate copolymer, 3 to 8 parts of nano silicon dioxide / graphene quantum dot composite filler, 5 to 12 parts of polyolefin elastomer, 0.5 to 2 parts of antioxidant and 0.5 to 2 parts of lubricant. The content of vinyl acetate in the ethylene-vinyl acetate copolymer is 20-33 wt%, the composite filler is modified through a silane coupling agent KH-560, the grafting rate of the grafted ethylene-vinyl acetate copolymer is 1.5-3.5 wt%, and the composite filler is prepared through a melt grafting method. Through multi-component collaborative design and process optimization, the low-temperature toughness, rigidity, heat resistance and aging resistance of the material are improved, the problems of rigidity and toughness imbalance, low-temperature brittleness, poor stability and the like of a traditional modification system are solved, and the material is excellent in comprehensive performance and wide in application range.

The embodiment of the invention discloses a biological composite liquid material capable of releasing negative oxygen ions as well as a preparation method and application of the biological composite liquid material. The invention discloses a preparation method of a traditional Chinese medicine. The biological composite liquid material is prepared from 12 to 18 parts of plant extract, 1 to 4 parts of silver ion solution, 2 to 5 parts of titanium dioxide, 10 to 15 parts of nano silicon dioxide, 2 to 8 parts of sodium oxide, 1 to 6 parts of magnesium oxide dispersion liquid, 0.5 to 1.5 parts of calcium hydroxide solution, 1 to 3 parts of ferric oxide colloidal solution, 2 to 6 parts of zinc oxide dispersion liquid, 12 to 18 parts of mixed silica sol and 15 to 20 parts of nano borosilicate liquid material. 0.5-1.5 parts of a surfactant, 4-8 parts of glycerol and 10-15 parts of deionized water. The biological composite liquid material has the characteristic of efficiently releasing negative oxygen ions, can effectively improve the air quality, is good in stability, convenient to use, safe and reliable, can be widely applied to the fields of air purification, medical care, building materials and the like, and has a wide market prospect.

The invention relates to a preparation method and application of an inner-rigid outer-soft core-shell structure silicon dioxide blocking agent for marine drilling fluid, and belongs to the field of deepwater oil and gas drilling. N-vinyl-2-pyrrolidone, dimethyl diallyl ammonium chloride, acrylamide and 2-acrylamide-2-methylpropanesulfonic acid are polymerized and grafted on the surface of nano silicon dioxide to form the silicon dioxide blocking agent with a core-shell structure and a rigid inside and a soft outside; by means of rigid plugging of a nano material and deformation filling flexible plugging of a high-molecular polymer, shale micro-nano pores are efficiently plugged with rigid inside and flexible outside, so that the stability of a well wall is maintained, meanwhile, secondary generation of hydrates is effectively inhibited, and the safety and efficiency of deepwater drilling are improved; the plugging agent provided by the invention reduces the demand on a large number of thermodynamic inhibitors, not only saves the cost, but also has the characteristic of environmental protection.

The invention discloses a high-strength polyethylene film and a preparation method thereof, and relates to the technical field of high polymer materials. The invention discloses a high-strength polyethylene film. The high-density polyethylene composite material is prepared from the following raw materials in parts by weight: 35 to 45 parts of high-density polyethylene, 25 to 35 parts of linear low-density polyethylene, 12 to 18 parts of ethylene-vinyl acetate copolymer, 5 to 10 parts of nano silicon dioxide, 3 to 7 parts of organic montmorillonite, 1.5 to 3.5 parts of hindered amine light stabilizer, 1.5 to 2.5 parts of antioxidant 1010, 0.8 to 1.2 parts of calcium stearate, 0.8 to 1.2 parts of zinc stearate, 0.8 to 1.2 parts of silane coupling agent and 4 to 6 parts of maleic anhydride grafted polyethylene. The composite material is prepared from the following components in parts by weight: 1.5-3.5 parts of a quaternized chitosan-nano silver compound, 6-9 parts of a modified toughening agent, 4-7 parts of a modified heat-resistant agent, 1.5-3.5 parts of a processing aid, 0.15-0.35 part of dibenzoyl peroxide and 0.5-1.5 parts of a nucleating agent DBS. The composite material is excellent in comprehensive performance, high in strength, good in flexibility and puncture resistance, excellent in aging resistance, heat resistance, chemical resistance and antibacterial property, good in processability, capable of meeting the requirements of multiple fields such as packaging and agriculture, scientific in preparation method and high in practical value.

The invention relates to the technical field of biological induction of calcium carbonate deposition, in particular to self-repairing concrete for biological induction of calcium carbonate deposition and a preparation method thereof. The cement comprises the following components in parts by weight: 320-380 parts of Portland cement and the like. The biomineralization composite inducer contains a genetically engineered bacterium solution, a urea-calcium chloride solution and a nano strontium carbonate seed crystal; the nano silicon dioxide-graphene composite powder is prepared by chemical vapor deposition; the wall material of the double-response microcapsule contains a temperature-sensitive polymer, and the core material contains a plurality of components; nanocellulose whiskers are also added; self-repairing is achieved through cooperation of multiple components, and all the components are specially treated or prepared. The self-repairing concrete is high in self-repairing efficiency, and wide cracks can be repaired; the mechanical property is excellent, and the compression strength and the breaking strength are remarkably improved; working performance is good, and construction is convenient; durability is good, and erosion and permeability are resisted; environmental protection and economy are considered, and the application prospect is wide.

The invention belongs to the technical field of cement manufacturing, and particularly relates to high-strength weather-resistant environment-friendly cement and a preparation method thereof. The environment-friendly cement is prepared from the following raw materials in parts by mass: 40 to 55 parts of Portland cement, 15 to 25 parts of fly ash, 10 to 15 parts of slag powder, 6 to 12 parts of biomass reinforced composite mineral material, 2 to 4 parts of nano silicon dioxide, 1 to 4 parts of modified polymer emulsion and 1 to 3 parts of additive. The biomass reinforced composite mineral material is prepared from zeolite, bentonite, sepiolite and chitosan; the modified polymer emulsion comprises a modified polyacrylate emulsion and a modified polystyrene-butadiene emulsion in a mass ratio of (1-3): 1; the additive is prepared from basalt fiber, sodium lignin sulfonate, a rosin thermopolymer and sodium gluconate. The environment-friendly cement prepared by the invention not only has high strength and good weather resistance, but also remarkably reduces carbon footprint and saves natural resources.

The invention provides a cement paste system with high strength, elasticity and toughness and application of the cement paste system in deep coal bed gas horizontal well cementation, and the cement paste system is prepared from the following raw materials in parts by mass: 40-70 parts of oil well cement, 13-40 parts of fly ash, 15-45 parts of slag, 5.0-20.0 parts of water-based organic silicon resin, 0.1-0.5 part of ultra-high performance polyethylene fiber, 3.0-8.0 parts of calcium oxide and 2.0-5.0 parts of calcium sulfate whisker. 1.0-8.0 parts of nano silicon dioxide, 1.0-6.0 parts of a fluid loss agent, 0.5-2.0 parts of a drag reducer, 0.2-1 part of a defoaming agent and 50-80 parts of water. The cement paste system disclosed by the invention has the characteristics of remarkable low-temperature quick setting and high early strength, also has the advantages of low water loss, controllable thickening, simple preparation operation and the like, and set cement is high in compressive strength, high in breaking strength and very excellent in elastic and tough mechanical properties.

The invention discloses an antistatic polyisoprene rubber anesthesia air storage bag, and relates to the technical field of anesthesia air storage bags. The antistatic polyisoprene rubber anesthesia air storage bag is prepared from the following raw materials in parts by weight: 100 parts of polyisoprene latex, 0.5 to 2 parts of a stabilizer, 1 to 2 parts of a sodium p-styrenesulfonate aqueous solution, 3 to 6 parts of nano silicon dioxide suspension dispersion liquid, 1 to 2 parts of an anti-aging agent, 0.8 to 2 parts of conductive graphite and 3 to 6 parts of a vulcanization bag, the anti-aging agent is prepared by the following steps: reacting 3-(3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid with glycerol 1-oleyl ether-d5 to generate an esterification product, epoxidizing the esterification product with hydrogen peroxide and formic acid, and reacting the epoxidized product with N-phenyl-1, 3-phenylenediamine, and has excellent migration resistance. By adding the anti-aging agent into the polyisoprene rubber, the anti-aging capability of the anesthesia air storage bag is improved.

The invention relates to the technical field of high-performance polyester, in particular to a high-strength low-shrinkage polyester fiber and a preparation method thereof. The defects that existing polyester fibers are poor in strength and shrinkage resistance are overcome. The preparation method comprises the following steps: mixing the modified resin, the modified nano silicon dioxide, the composite antioxidant, the composite nucleating agent and the composite lubricant, and carrying out melt spinning. Wherein the modified resin is prepared from the following raw materials: dimethyl terephthalate, isophthalic acid, ethylene glycol and isosorbide; the modified nano silicon dioxide comprises nano silicon dioxide, KH570 and silver nitrate; the composite antioxidant comprises an antioxidant 1010, an antioxidant 168 and an antioxidant 1222; the composite nucleating agent comprises sodium benzoate and nano montmorillonite; the composite lubricant is prepared from ethylene bis stearamide and pentaerythritol stearate. The prepared polyester fiber is high in strength, high in shrinkage resistance and suitable for manufacturing of outdoor equipment.

The invention relates to a degradable filter element and a preparation method thereof, and belongs to the technical field of PLA filter elements. The degradable filter element is arranged between an atomizing element shell and a metal heating wire, a plurality of capillary holes are formed in the degradable filter element and used for being filled with tobacco tar, and the degradable filter element is prepared from a degradable composite material through melt spinning. The degradable composite material comprises the following components: polylactic acid and modified silicon dioxide, wherein the modified silicon dioxide is prepared by taking nano silicon dioxide, a silane coupling agent, ferulic acid, amino acid and copper chloride as raw materials, the silicon dioxide is organically modified, so that the dispersity of the silicon dioxide in a polylactic acid system is improved, the interface binding force of the silicon dioxide is improved, and the mechanical property of a polylactic acid material is improved; various antibacterial components are introduced, so that the antibacterial property of the polylactic acid material can be effectively improved.

The invention discloses ardealite-based concrete and a preparation method thereof, and belongs to the technical field of building materials. The ardealite-based concrete is prepared from the following raw materials in parts by weight: 40 to 60 parts of ardealite powder, 10 to 15 parts of cement, 8 to 10.5 parts of slag powder, 5 to 7 parts of fly ash, 4 to 6 parts of desulfurized fly ash, 5 to 10 parts of natural sand, 10 to 15 parts of ardealite-based artificial aggregate, 3 to 5 parts of eggshell powder, 1.5 to 3 parts of nano silicon dioxide, 0.5 to 1.5 parts of a water reducing agent, 0.05 to 0.2 part of a retarder, 0.1 to 0.5 part of an exciting agent and 0.3 to 1 part of an antifreeze agent. According to the invention, through process innovation of multi-component collaborative design and gradient aggregate doping, the technical bottlenecks of low strength, poor durability, high environmental protection risk and the like of traditional ardealite concrete are overcome while large-scale resource utilization of ardealite is realized, and a new thought is provided for high-valued utilization of industrial solid wastes.

The invention belongs to the technical field of material preparation, and aims to solve the problems of interface separation and weak oxidation resistance under complex working conditions caused by insufficient interface bonding force of the existing carbon / carbon composite material. In order to achieve the purpose, the invention provides a carbon / carbon composite material and a preparation method thereof. The carbon / carbon composite material comprises the following components in percentage by mass: 40%-55% of polyacrylonitrile-based carbon fibers, 10%-25% of pitch-based carbon fibers, 8%-20% of nano silicon dioxide grafted carbon fibers, 8%-20% of biological pitch, 8%-15% of nano graphene modified phenolic resin, 3%-6% of silicon carbide whiskers, 2%-4% of zirconium boride nanoparticles, 2%-4% of graphitized carbon fibers and 1%-3% of a natural plant extract antioxidant. The carbon / carbon composite material provided by the invention can provide stable interface bonding force and remarkable oxidation resistance, so that the structural integrity and mechanical property stability of the material when bearing various complex stresses such as stretching, compression, bending, shearing and the like are guaranteed, and the application range of the material in the field of high-temperature oxidation resistance is widened.

The invention provides a concrete admixture with sulfate corrosion resistance and rust resistance functions. The concrete admixture is prepared from the following raw materials in parts by weight: 50-65 parts of fly ash, 8-12 parts of barium carbonate, 8-12 parts of barium hydroxide, 8-12 parts of mineral powder, 5-8 parts of modified hydrotalcite or hydrotalcite, 1-3 parts of nano silicon dioxide and 1-3 parts of calcium nitrite. Nano silicon dioxide is adopted as a compact component, the porosity of the material is reduced, the compactness of concrete is improved, sulfate in the environment is inhibited from being transmitted into the concrete, meanwhile, hydrotalcite is modified by polymaleic acid serving as a scale inhibition component, and the scale inhibition effect is improved through the dual effects of high adsorbability and slow release of the scale inhibition component of hydrotalcite. The preparation method has the advantages that generation of ettringite and gypsum in a sulfate radical environment is inhibited, calcium nitrite is added as a corrosion-inhibiting component, a protective film is formed on the surface of a reinforcing steel bar, the corrosion phenomenon of the reinforcing steel bar in a concrete structure is inhibited, and finally, the concrete admixture with sulfate corrosion resistance and corrosion-inhibiting functions is formed through compounding.

The invention discloses a high-content steel slag-based functionalized nano-composite cementing material and a preparation method thereof, and belongs to the technical field of solid waste resource comprehensive utilization. The nano composite cementing material is prepared from the following raw materials in parts by mass: 50 to 65 parts of steel slag, 10 to 20 parts of fly ash, 10 to 25 parts of carbide slag, 8 to 15 parts of desulfurized gypsum, 0.3 to 1.0 part of nano silicon dioxide and 0.003 to 0.03 part of silane coupling agent. On the basis of a solid waste synergism theory and an internal alkali excitation effect, quaternary solid wastes such as steel slag and fly ash are optimized and compounded by adopting methods of mechanical-thermal activation, addition of modified nano silicon dioxide, synergistic gelling between solid wastes and the like; the paint is prepared through gradient grinding and a medium-temperature wet curing process. The preparation method is simple, high-temperature calcination is not needed, cement clinker and exogenous excitant do not need to be added, the obtained cementing material can replace part of cement to be applied to the fields of road bases, mine filling, low-carbon building material products and the like, resource utilization and high-value utilization of regional bulk industrial solid waste can be achieved, and carbon emission and production cost are effectively reduced.

The invention relates to the technical field of sole processing, in particular to a sole composite processing method, which comprises the following steps: according to the rigidity requirement of an arch support area, preparing high-density slurry in which silicon nitride ceramic powder accounts for 30-40%, forming # imgabs0 # crystal phase through microwave-assisted sintering, and controlling the porosity to be 10-20%; according to the energy rebound requirement of the forefoot buffer area, graphene oxide / carboxymethyl cellulose aerogel powder is added into the slurry until the concentration is 25%, and the porosity is increased to 40-60% by combining the honeycomb porous network design; a nano silicon dioxide reinforcing agent is introduced into a wear-resistant area of the heel to 15%, a diamond-like carbon coating is formed through plasma surface treatment, and the porosity is limited to be 5-15%. According to the invention, silane is encapsulated by adopting polyurea microcapsules, and is released only when the material is damaged, so that dynamic self-repairing is realized, the shoe sole is endowed with dynamic repairing capability, and the service life is prolonged.