265results about How to "Improve aging resistance" patented technology

The invention relates to the technical field of power cables, and provides a medium-voltage fireproof cable, which comprises a conductor, and an insulating layer, an armor layer and a sheath layer which are sequentially arranged outside the conductor, the insulating layer comprises the following components in parts by weight: 70-80 parts of polyethylene, 5-10 parts of a flame retardant, 3-5 parts of a cross-linking agent, 1-2 parts of a plasticizer and 1-3 parts of an antioxidant; the sheath layer comprises the following components in parts by weight: 100 parts of polyvinyl chloride, 8-16 parts of a flame retardant, 1-2 parts of a plasticizer, 1-3 parts of an antioxidant and 5-10 parts of filler; the filler comprises silicon dioxide, inorganic fibers and tetrapod-like zinc oxide whiskers. According to the technical scheme, the problem that the strength and the aging resistance of the cable in the prior art are poor is solved.

The invention relates to an anti-yellowing automobile composite film and a preparation method thereof, and belongs to the technical field of high polymer materials. The yellow-resistant automobile composite film is prepared from the following components in parts by weight: 60 to 70 parts of PVC (Polyvinyl Chloride) master batch, 10 to 20 parts of TPU (Thermoplastic Polyurethane) master batch, 1 to 2 parts of plasticizer, 0.5 to 0.8 part of flatting agent, 0.1 to 2 parts of yellowing-resistant modifier and 0.1 to 2 parts of modified flame retardant, sym-triazine cyanuric chloride and a benzotriazole intermediate in the anti-yellowing modifier absorb ultraviolet rays and reduce yellowing of the ultraviolet rays on the composite material, and maleimide groups, maleic anhydride and isocyanurate rings for increasing the crosslinking density cooperate with one another, so that the heat resistance of the material is improved, and the yellowing is reduced; phosphorus and nitrogen main chains of phosphonitrilic chloride trimer in the modified flame retardant have a conjugation effect, so that a protective film is formed, oxygen is isolated, and the phosphonitrilic chloride trimer and nitrogen are synergistically flame-retardant; the anti-yellowing automobile composite film prepared by the invention not only has excellent ultraviolet absorption performance, heat resistance and anti-yellowing effects, but also has a good flame retardant effect.

The invention discloses a preparation method of a bio-based epoxy resin anticorrosive coating, and relates to a preparation method of a bio-based epoxy resin coating. The bio-based epoxy resin anticorrosive paint mainly comprises an anticorrosive filler COFs-AA, bio-based epoxy resin and a curing agent. Wherein the anticorrosive filler COFs-AA is prepared from a two-dimensional covalent organic framework COFs and a bio-based material arachidonic acid (AA) through a covalent condensation reaction; the bio-based epoxy resin is prepared by epoxidizing a bio-based material galangin serving as a raw material through epichlorohydrin, and the curing agent is a common curing agent for epoxy resin. The bio-based epoxy resin anticorrosive paint is compounded by taking biomass as a basic component, and has the characteristics of greenness, environmental protection, no toxicity, good hydrophobicity and good corrosion resistance; the bio-based epoxy resin anticorrosive paint can be applied to the field of corrosion protection of materials such as various metals and woodware.

The invention provides a flame-retardant polyolefin composition as well as a preparation method and application thereof, and the flame-retardant polyolefin composition comprises the following components in parts by weight: 13-22 parts of an ethylene-vinyl acetate copolymer, 1.5-8.5 parts of linear low density polyethylene, 8-17 parts of a polyolefin elastomer, 35-55 parts of a flame retardant and 0.5-2.5 parts of an antioxidant. The antioxidant comprises a main antioxidant and an auxiliary antioxidant; the main antioxidant comprises a hindered phenol antioxidant and an amine antioxidant; and the auxiliary antioxidant comprises a thioester antioxidant and / or a phosphite ester antioxidant. According to the flame-retardant polyolefin composition disclosed by the invention, the ethylene-vinyl acetate copolymer, the linear low-density polyethylene and the polyolefin elastomer are compounded according to a specific content, and meanwhile, the antioxidant with specific composition is matched, so that the flame-retardant polyolefin composition is good in heat resistance, aging resistance and precipitation resistance; meanwhile, the mechanical property is good.

The invention discloses an injection molding method of an anti-aging simulation plant. The injection molding method comprises the following steps: preparing raw materials; uniformly mixing the raw materials according to a set material proportioning model so as to obtain anti-aging proportioning raw materials exceeding a preset threshold value; according to the shape and the size of the simulation plant, through a system integrated with an intelligent design engine, design data are extracted, and a design mold is generated; the proportioned raw materials are heated in a heating cylinder of an injection molding machine to be in a molten state, and molten plastic is obtained; the molds are firmly clamped together; injecting the molten plastic into the cavity of a mold under a predetermined pressure; a preset pressure of a preset time is kept in the cavity; cooling and solidifying the material in the mold to form the shape of the mold; and opening the mold to obtain the formed simulation plant. According to the technical scheme, the service life of the anti-aging simulation plant is prolonged, and the safety of the anti-aging simulation plant is improved by optimizing the raw material ratio, accurately controlling the injection molding process and other key steps.

The present invention belongs to the technical field of alkyd resin coatings, and discloses an alkyd external enamel and a preparation method thereof. The present invention adopts a bio-based high flash point alkyd resin as a base resin, adopts nano titanium dioxide, nano zinc oxide, nano aluminum oxide and micron aluminum oxide with different particle size distributions for compounding, and adds isocyanate silane and glycerol ether silane in the system. After grinding, the pigments and fillers can be modified to improve the filling and modification effect of the pigments and fillers. At the same time, the active groups such as isocyanate groups, epoxy groups, and hydroxyl groups in the coupling agent can interact with the alkyd resin to improve the compatibility of the pigments and fillers with the alkyd resin, and give the coating film excellent adhesion to the inorganic substrate. With a high flash point solvent, a bio-based coating with high flash point, high adhesion, high aging resistance and high wear resistance can be prepared to meet the use requirements of the external enamel. The alkyd external enamel is environmentally friendly and safe, and can be stored and transported according to general chemicals.

The invention relates to the technical field of epoxy splicing adhesives, in particular to a high-performance prefabricated part epoxy splicing adhesive and a preparation method thereof.The epoxy splicing adhesive comprises a component A and a component B. The component A is prepared from 3%-8% of polyether polyol, 2%-4% of hydrophobic fumed silica, 0.1%-1% of a silane coupling agent, 0.01%-0.5% of a defoaming agent, 50%-75% of modified quartz sand, 1%-5% of color paste and the balance epoxy resin; the modified quartz sand is prepared by grafting an amino silane coupling agent on the surface of quartz sand, then reacting with polychlorophosphazene, and then reacting with glycidol; the component B comprises the following components in percentage by weight: 0.2-4% of color paste, 1-5% of hydrophobic fumed silica, 0.1-1% of an amino silane coupling agent, 10-25% of 0.5 mm quartz sand, 40-60% of 0.1 mm quartz sand and the balance of a modified amine curing agent; the preparation method has the advantage that the mechanical strength and the bonding strength of the epoxy splicing adhesive are improved.

The invention discloses a high-temperature-resistant adhesive tape and a preparation method thereof, and belongs to the technical field of adhesive tape preparation. The adhesive tape is composed of a composite adhesive and a composite polyester film, and the composite adhesive is composed of hydroxyl polydimethylsiloxane, boric acid, 2, 2-bis [4-(4-aminophenoxy) phenyl] propane and 4, 4-bis (4-aminophenoxy) phenyl] propane. The composite polyester film is prepared from polyethylene glycol terephthalate, 1-allylimidazole, 2-bromobutane, potassium hexafluorophosphate, methacryloyloxyethyl trimethyl ammonium chloride and nano silicon dioxide, and the composite polyester film is prepared from polyethylene glycol terephthalate, 1-allylimidazole, 2-bromobutane, potassium hexafluorophosphate, methacryloyloxyethyl trimethyl ammonium chloride and nano silicon dioxide. The adhesive tape prepared by the method has excellent viscosity, high temperature resistance, aging resistance and antistatic property.

The invention provides an antistatic polypropylene material as well as a preparation method and application thereof, and belongs to the technical field of polypropylene materials. The preparation method comprises the following steps: modifying graphene, preparing a graphene / titanium dioxide compound, reacting, and performing extrusion molding. The method comprises the following reaction steps: putting a functionalized graphene / titanium dioxide compound into a reaction container, introducing N, N-dimethylformamide, uniformly stirring, adding modified graphene, dicyclohexylcarbodiimide and 4-dimethylaminopyridine, heating to 73-77 DEG C, carrying out ultrasonic treatment, and after ultrasonic treatment is finished, carrying out heat preservation stirring for 1.8-2.2 hours to obtain the graphene / titanium dioxide composite material. Then heating to 116-123 DEG C at the speed of 1.7-2.3 DEG C / min, stirring for 1.8-2.2 hours while keeping the temperature, after stirring is finished, filtering, washing, freeze-drying, and naturally recovering to room temperature, so as to obtain a graphene-graphene / titanium dioxide compound; the antistatic polypropylene material prepared by the invention is good in antistatic property, excellent in mechanical property and good in aging resistance.

The invention discloses a polyester-polyurethane composite coating as well as a preparation method and application thereof, and relates to the technical field of coatings. The polyester-polyurethane composite coating comprises polyester resin, hydroxy acrylic resin, a polyester resin curing agent, an acrylic resin curing agent, a texturing agent and an auxiliary agent, and the mass of the hydroxy acrylic resin is 5-20% of the mass of the polyester resin. The polyester-polyurethane composite coating provided by the invention is used as base powder of a vacuum plating process, a formed coating has an obvious grain effect, can be matched with metal powder to present an excellent silver flashing effect after vacuum plating, also has good flexibility, corrosion resistance, hardness and other properties, is suitable for the vacuum plating process, and has a good application prospect. The coating can be further matched with a vacuum electroplating process provided by the invention to achieve a better effect, and is suitable for vacuum electroplating surface coating of the hub.

The invention relates to the technical field of polyvinyl chloride, and discloses a wear-resistant and aging-resistant PVC (polyvinyl chloride) material.The wear-resistant and aging-resistant PVC material is characterized in that glycidyl acrylate grafted ABS is used as a compatilizer, carboxyl-terminated nitrile rubber is used as a flexibilizer and a wear-resistant modifier, and polyvinyl chloride is subjected to filling modification; the modified polyvinyl chloride can react with terminal carboxyl groups of nitrile rubber, so that nitrile rubber and polyvinyl chloride have better compatibility, and the notch impact strength and wear resistance of the PVC material are improved. The hindered phenol-lanthanum complex stabilizer contains a hindered phenol structure which can capture free radicals generated in the oxidation process, inhibit free radical chain reaction and overcome decomposition of polyvinyl chloride; meanwhile, lanthanum ions in the complex can react with hydrogen chloride generated by thermal decomposition of polyvinyl chloride, so that the phenomenon that the polyvinyl chloride is degraded by the hydrogen chloride is reduced.

The present application relates to a green and low-carbon functional inorganic rock coating artistic effect paint and a preparation method thereof, belonging to the field of coating technology. The present invention modifies the waterborne epoxy resin emulsion and introduces amino calcium carbonate and modified carboxymethyl cellulose at the same time. The multi-components work together to effectively improve the adhesion level and obtain good salt spray resistance and aging resistance.

The invention discloses a preparation method of an environment-friendly degradable rubber material, and relates to the technical field of rubber material preparation. The environment-friendly degradable rubber material disclosed by the invention is prepared by the following steps: plastifying natural rubber at high temperature, then adding reinforcing filler, palm oil paste, an anti-aging agent and an active agent for first-stage plastifying, and then adding part of rubber softening oil, zinc oxide, a foaming agent, a vulcanizing agent and a xanthate accelerant containing benzothiazole for second-stage rubber mixing; and adding the rest rubber softening oil to carry out third-stage rubber mixing to obtain a rubber material, and finally carrying out thin passing, packaging, standing and two-time vulcanization on the slurry to obtain the rubber material. The environment-friendly degradable rubber material provided by the invention is simple in preparation method, stable in processability, excellent in mechanical strength and rebound resilience, excellent in wear resistance, insulativity, acid and alkali resistance, aging resistance, high and low temperature resistance and waterproofness, and can be applied to the fields of diving suits, tires, wires and cables and the like.

The invention relates to the technical field of adhesive tapes, and particularly discloses a double-sided adhesive tape with excellent weather resistance and a preparation method thereof.The double-sided adhesive tape comprises a first release film layer, a first adhesive layer, a base material layer, a second adhesive layer and a second release film layer, the adhesive layer is prepared from an adhesive through simple processes of coating, drying and the like, industrial production is easy, and the adhesive tape has good weather resistance. The adhesive is obtained by mixing an acrylate polymer, modified polyvinyl alcohol, a defoaming agent and a plasticizer, the acrylate polymer and the modified polyvinyl alcohol have excellent adhesive power and can be firmly adhered to various materials, the raw materials of the adhesive form a stable composite system through structural complementation, and through chemical bonding and physical effects, the adhesive can be firmly adhered to various materials. The comprehensive performance of the double-sided adhesive tape is further improved, and the double-sided adhesive tape has excellent toughness and stability, is not easy to age and fall off, and is improved in weather resistance, adhesion and tensile strength, so that the double-sided adhesive tape is more durable in the use process.

The invention discloses a camouflage material, a hyperspectral camouflage coating and a preparation method and application thereof, and belongs to the technical field of camouflage materials, and the molecular formula of the camouflage material is Co2Cr3TiLiNiO10. The camouflage material has the performance of simulating spectral characteristics of natural yellow and green plants and has a good bionic function, crystals of the camouflage material are of a spinel structure, and the camouflage material has the characteristics that the lightness value L is relatively low, the hue is relatively dark, a green camouflage coating is easier to prepare, the camouflage material has the characteristics of good aging resistance, good thermal stability and the like, and the camouflage material can be used as a green camouflage coating. The reflectivity of the infrared plateau area is higher, the camouflage performance is easier to realize, and the spectral characteristics of green vegetation can be better simulated.

The invention relates to a polybutylene terephthalate resin composition as well as a preparation method and application thereof. The polybutylene terephthalate resin composition comprises bio-based polybutylene terephthalate resin, a titanium element, a phosphorus element and a cobalt element, the weight content of a titanium element in the polybutylene terephthalate resin composition is 20 to 150 ppm, the weight content of a phosphorus element is 2 to 50 ppm, and the weight content of a cobalt element is 4 to 100 ppm; the mass ratio of the titanium element to the phosphorus element to the cobalt element in the polybutylene terephthalate resin composition is (2-20): (1-2): (1-10). According to the polybutylene terephthalate resin composition provided by the invention, the weight content and the mass ratio of the titanium element, the phosphorus element and the cobalt element are controlled in a proper range, so that the polybutylene terephthalate resin composition has high whiteness, excellent mechanical property and ageing resistance.

The invention belongs to the field of medical rubber materials, and particularly relates to a vulcanization preparation process of a medical puncture-resistant rubber gasket. A vulcanization preparation process of a medical puncture-resistant rubber gasket comprises the following steps: S1, raw rubber raw material preparation: crushing and mixing raw rubber raw materials to be vulcanized into raw rubber powder, removing impurities, and sieving; the raw rubber raw materials comprise halogenated butyl rubber, polyisoprene rubber and epichlorohydrin rubber; s2, preparing a rubber compound; the preparation method comprises the following steps: preheating an internal mixer to 80-100 DEG C, adding 80-90 parts by weight of raw rubber powder into the internal mixer, and refining at 115-125 DEG C for 5-9 minutes; adding 12-22 parts by weight of a modified composite filler, 2-6 parts by weight of zinc oxide, 1-3 parts by weight of stearic acid, 3-8 parts by weight of a crosslinking auxiliary agent and 0.5-1.2 parts by weight of an anti-aging agent, and mixing for 18-22 min; s3, calendaring and sheet discharging: calendaring and molding the rubber compound obtained in the step (2) to obtain a rubber compound sheet; s4, prevulcanization: putting the rubber compound sheet calendered in the step (3) into a mold cavity of a press vulcanizer, and carrying out under-vulcanization production to obtain a preformed sheet; the preformed rubber sheet in the step (4) and an organic solvent are subjected to cleaning treatment and drying and then put into a vulcanization mold to be subjected to vulcanization forming, the rubber gasket is obtained, the vulcanization temperature ranges from 140 DEG C to 150 DEG C, and the vulcanization time ranges from 3 min to 7 min. In order to solve the problem that the use performance of a medical rubber gasket is affected due to the fact that the medical rubber gasket is needled to fall scraps and is poor in rebound resilience, the invention provides the vulcanization preparation process of the medical needling-resistant rubber gasket.

The invention provides a preparation method of sealing aging resistant PBAT resin, biodegradable plastic and application, and the preparation method comprises the following steps: mixing adipic acid, butanediol and a first catalyst, and carrying out a first esterification reaction to obtain a first intermediate product; mixing terephthalic acid, m-phenylenediacetic acid, butanediol and a second catalyst, and carrying out a second esterification reaction to obtain a second intermediate product; performing a pre-polycondensation reaction on the first intermediate product, the second intermediate product and a pre-polycondensation catalyst in a polymerization reaction kettle to obtain a pre-polycondensation product; and carrying out final polycondensation on the pre-polycondensation product to obtain the sealing aging resistant PBAT resin. The edge sealing bag prepared from the sealing aging-resistant PBAT resin provided by the invention has more excellent sealing performance, and the sealing aging-resistant performance of the edge sealing bag is better.

The invention discloses a sensing optical cable for detecting vibration, and belongs to the technical field of communication cables, the sensing optical cable for detecting vibration comprises an inner layer sensing optical fiber, a TPEE sleeve, an inner layer water-blocking fiber paste, a PBT sleeve, an outer layer water-blocking fiber paste and an outer sheath in sequence from inside to outside; the inner-layer water-blocking fiber paste and the outer-layer water-blocking fiber paste are both optical fiber filling paste; the optical fiber filling paste is prepared from paraffin-based hydrogenated white oil, poly-alpha-olefin synthetic oil, epoxy vinyl silicone oil, an oil separation inhibitor, a polyisobutene material, siloxane modified polyvinyl alcohol, organic ammonium modified bentonite, ferric acetylacetonate and an antioxidant. The sensing optical cable for detecting vibration is simple in structure, has excellent mechanical strength, toughness, gas barrier property, waterproofness, corrosion resistance, high and low temperature resistance, wear resistance, aging resistance, flame retardance and the like, can still ensure high stability and high sensitivity of optical fiber vibration detection in harsh environments such as underwater or underground, and prolongs the service life of the sensing optical cable.

This invention provides a modified glass fiber, glass fiber reinforced butyl hot melt adhesive, and their preparation method. The modification method of the glass fiber includes: mixing a silane coupling agent with ethanol, stirring and hydrolyzing to obtain a silane coupling agent solution; placing the glass fiber in the silane coupling agent solution, stirring and reacting at 40-80℃ for 4-6 hours, then filtering, and curing the obtained solid product at 100-150℃ for 0.5-2 hours to obtain pre-modified glass fiber; immersing the pre-modified glass fiber in a toluene solution containing furanylsilane coupling agent, reacting under inert gas protection at 70-90℃ for 1-3 hours, and performing graft modification treatment to obtain the modified glass fiber. The use of silane coupling agent and furanylsilane coupling agent to introduce dynamic covalent bonds, synergistically modifying the glass fiber with a bilayer coupling agent, and introducing the modified glass fiber into the butyl rubber system, can effectively improve the mechanical properties and aging resistance of the butyl rubber while maintaining its original water tightness and air tightness.

The invention relates to the field of finish paint, in particular to chemical-resistant electroplating finish paint as well as a preparation method and application thereof. The chemical-resistant electroplating finish paint is prepared from the following raw materials in parts by mass: 30 to 50 parts of modified acrylate, 15 to 30 parts of epoxy resin, 5 to 10 parts of modified particles, 3 to 6 parts of photoinitiator, 2 to 3 parts of flatting agent, 0.5 to 1 part of defoaming agent, 3 to 10 parts of pigment and 20 to 40 parts of solvent. The finally prepared electroplating finish paint not only has excellent durability and chemical resistance, but also can be further improved in water resistance, aging resistance and mechanical properties, so that the performance requirements of the existing electroplating finish paint are effectively met, and the electroplating finish paint can be effectively applied to the field of cosmetic packaging and has wide application prospects. And meanwhile, the resistance to chemical substances (such as perfume, emulsion and the like) is also effectively improved, and the product has a very excellent application prospect.

The invention belongs to the technical field of graphene, and particularly relates to graphene leather capable of realizing temperature-sensitive color development and a preparation method of the graphene leather. As the graphene heating functional layer adopts the high-thixotropic silver paste, the printed circuit pattern is clear in edge, uniform in thickness and extremely high in consistency with the designed pattern; and a clear interface is formed between a silver paste circuit and leather fibers, and improper penetration is avoided. And the circuit resistance value consistency is excellent (the deviation is controlled within + / -5%), so that rapid, uniform and stable planar heating can be realized after the graphene heating layer is connected, and the local overheating hidden danger is perfectly eliminated. According to the present invention, the natural texture and the soft touch feeling of the leather are maintained while the efficient and safe heating performance with the visual color developing function is achieved.

The utility model relates to cable connection protection technical field discloses a sheath pipe structure for two cable joints, including upper casing, the outer wall fixed connection of upper casing has the connecting barrel, the inner wall rotationally connected with press column of connecting barrel, the lower surface fixed connection of press column has rotary column, the inside fixed connection of rotary column has the card post, the outer wall sliding connection of card post has the limit block, the outer wall fixed connection of limit block has lower casing, the inner wall fixed connection of connecting barrel has the limit piece, the outer wall sliding connection of rotary column has the spring. In the utility model, through the mutual cooperation between upper casing, connecting barrel, press column, rotary column, card post, limit block, limit piece, spring and lower casing, can greatly promote installation and maintenance efficiency, significantly reduce construction time and manpower cost, can simplify operation procedure simultaneously, reduce the dependence on professional tool and complex skill, reduce installation error risk.

The application belongs to the technical field of heat insulation films, and discloses a polyester-based explosion-proof heat insulation composite film and a preparation method and application thereof. The explosion-proof heat insulation composite film is a composite film with a layered structure. The layered structure comprises a sandwich heat insulation film, an anti-scratch layer and a mounting adhesive layer arranged on both sides of the sandwich heat insulation film. The sandwich heat insulation film is composed of a first polyester film, a second polyester film and a heat insulation layer sandwiched between the first polyester film and the second polyester film. In the heat insulation coating liquid, chlorinated polyolefin is used to increase the bonding adhesion and leveling dispersibility of the coating liquid on the polyester film, so that the coating type sandwich heat insulation film has excellent tear resistance and peeling resistance. The defects of the current coating type heat insulation film, such as easy blistering, heat insulation performance attenuation and reduced explosion-proof performance, are solved. The coating preparation process is simple and does not require a complex magnetron sputtering process, so that the cost of the explosion-proof heat insulation film is scaled and the production is realized.

The present application relates to a kind of low-temperature-resistant oil-resistant damping rubber composite material for outdoor engineering and its preparation method, belong to damping rubber modification technical field.The low-temperature-resistant oil-resistant damping rubber composite material for outdoor engineering described in the present application is prepared by high-vinyl polybutadiene rubber, butyl rubber, flocculation butyl nitrile rubber / oxidized carbon nanotube composite raw rubber and auxiliary mixing co-vulcanization.The vinyl content of high-vinyl polybutadiene rubber is 83-85%, Mn is 430-470, and the relative molecular mass distribution index is 2.0-2.5.The low-temperature-resistant oil-resistant damping rubber composite material for outdoor engineering described in the present application has a wider damping temperature range, excellent low-temperature damping performance, mechanical properties and oil resistance;Meanwhile, a simple and convenient preparation method is provided.

The invention relates to the technical field of high polymer material preparation, and discloses an anti-aging TPEE composite material and a preparation method thereof, the anti-aging TPEE composite material comprises the following raw materials: TPEE resin, maleic anhydride grafted polypropylene, a self-repairing anti-aging compound, a fire-resistant flame-retardant filler, a lubricant and an ultraviolet absorbent, wherein the self-repairing type anti-aging compound is prepared by taking natural rubber as a polymer matrix and sequentially introducing a disulfide bond and a hindered phenol group; the TPEE composite material prepared by the preparation method disclosed by the invention has excellent self-repairing performance, ageing resistance, impact resistance, mechanical strength and flame retardance, can meet the use requirements in various environments, and is high in safety, high in flame retardancy, good in flame retardancy, good in flame retardancy, good in flame retardancy and long in service life, and the service life of the TPEE composite material is prolonged, and the service life of the TPEE composite material is prolonged. And the service life is long.

The utility model relates to the technical field of concrete square piles, and discloses an anti-compression and anti-pulling precast concrete square pile which comprises a concrete square pile body, a pile tip and an anti-pulling mechanism, the pile tip is fixedly arranged at the bottom end of the concrete square pile body, and the anti-pulling mechanism is fixedly arranged at the outer end of the concrete square pile body. An auxiliary mechanism is fixedly arranged at the inner end of the concrete square pile body; the anti-pulling mechanism comprises grooves, barb-shaped steel bars and anti-rust paint, the grooves are evenly formed in the outer end of the concrete square pile body, the barb-shaped steel bars are fixedly arranged on the side, close to the pile tip, of the outer end of the concrete square pile body, and the barb-shaped steel bars extend to the inner end of the concrete square pile body. According to the compression-resistant and pulling-resistant prefabricated concrete square pile, by arranging the pulling-resistant mechanism, the pulling-resistant performance of the concrete square pile is conveniently improved, the buoyancy of underground water is conveniently resisted, the anti-seismic effect is improved, normal use of a building is guaranteed, the use requirements of people are conveniently met, and the practicability is improved.

The present application relates to the field of polyurethane elastomer material, and particularly relates to a polybutadiene silicone diol, a preparation method thereof and a thermoplastic silicone polyurethane elastomer. The polybutadiene silicone diol with the structure of formula (I) has a moderate solubility parameter, the thermoplastic silicone polyurethane elastomer prepared from the polybutadiene silicone diol has a small degree of phase separation in the molecular chain of the elastomer, the product has unexpectedly good transparency, and in addition, the elastomer has the characteristics of PDMS and CTPB, and has excellent mechanical properties, outstanding low-temperature resilience, aging resistance, surface hydrophobicity and smoothness and other properties.

The invention provides a nano-composite anti-seepage coating for goaf sealing and a preparation method and application thereof. The impermeable coating comprises the following components in percentage by mass: 10 to 30 percent of nano silica sol subjected to surface organic modification, 15 to 35 percent of styrene-butadiene latex subjected to pH buffer stabilization, 0.5 to 10 percent of functional nano material subjected to surface activation treatment, 20 to 60 percent of superfine sand and the balance of short fiber, inorganic powder filler and auxiliaries. The method comprises raw material pretreatment; step-by-step gradient blending is performed; and functions are compounded. According to the application, the nano-composite anti-seepage coating is applied to surrounding rock reinforcement, crack plugging or anti-seepage sealing engineering of a coal mine goaf. The slurry has the advantages of being high in deep infiltration capacity, excellent in surface film forming and internal compatibility and stable in performance, an internal infiltration reinforcing layer and a surface sealing layer can be formed at the same time after construction, and an integrated double-layer anti-seepage network is formed.

The utility model relates to hexagonal net weaving forming equipment technical field, concretely to a kind of polyester hexagonal net weaving forming equipment, including bearing assembly and first bearing station, the bearing assembly includes support frame, installation rod is provided on the support frame, wire wheel is rotatably connected on the installation rod, the upper portion of wire wheel is provided with first mounting table, first mounting table rotatably connects with guide wheel, the downstream of guide wheel is provided with first mounting bracket, guide porcelain ring is installed on the first mounting bracket, the downstream of guide porcelain ring is provided with sliding rod, sliding block is installed on the sliding rod, tension porcelain ring is installed on the sliding block, to solve the raw material tension instability, transmission is easy to deviate, production continuity is poor, production efficiency is low and the problem such as operation complex in the existing polyester hexagonal net production equipment, realize the efficient, high quality, automated production of polyester hexagonal net.