The invention provides anti-aging self-
adhesive high-temperature vulcanized
silicone rubber and a preparation method thereof. The aging-resistant self-
adhesive high-temperature vulcanized
silicone rubber is prepared from the following components in parts by
mass: 90 to 100 parts of raw methyl vinyl
silicone rubber, 40 to 50 parts of
fumed silica, 10 to 20 parts of a borosiloxane structure self-
adhesive agent, 4 to 10 parts of
cerium oxide paste, 1 to 3 parts of a heat-resistant agent, 0.1 to 0.3 part of
zinc stearate, 4 to 6 parts of hydroxyl
silicone oil and 2 to 3 parts of a
peroxide paste catalyst. Gas-phase
silicone rubber and
boric acid are combined to avoid combination of
lone pair electrons of an
oxygen element in a hydroxyl group and a 2p empty
orbit of a B element in a synthesis process and enhance self-adhesion and mechanical properties,
boron and
benzene in a heat-resistant agent are introduced into a main chain,
boron and
silicon form a Si-O-B bond, the energy of the O-B bond can reach 537.6 J / mol, the energy of the Si-O bond can reach 422.5 J / mol, higher energy is needed for
bond energy damage, and the service life of the heat-resistant agent is prolonged. And at high temperature, degradation caused by back
biting of
oxygen elements in hydroxyl can be avoided, side group oxidation is prevented through mutual cooperation of
benzene and
cerium oxide, and the
aging resistance and high-
temperature resistance of the
silicone rubber are remarkably improved.