The invention discloses a special photocatalytic self-cleaning
coating for photovoltaic glass and a preparation method of the special photocatalytic self-cleaning
coating, and aims to provide the special photocatalytic self-cleaning
coating for the photovoltaic glass, which is capable of degrading organic pollutants under
natural illumination, keeping high light
transmittance and prolonging the service life of a photovoltaic module. According to the technical scheme, the preparation method comprises the following steps: preparing TiO2 / SnO2
heterojunction nanocrystals, activating the TiO2 / SnO2
heterojunction nanocrystals, adding a
silane coupling agent, stirring for 30-60 minutes, stirring for 1-3 hours at the temperature of 50-70 DEG C, and centrifugally
drying to obtain modified TiO2 / SnO2; then dispersing in a mixed
solvent, dropwise adding tetraethoxysilane, adjusting the pH value, stirring for 1-2 hours at 40-45 DEG C, heating to 75-82 DEG C, and reacting for 1-3 hours to generate hydroxylated
silicon dioxide (at) TiO2 / SnO2 core-shell microspheres; then dispersing the product in isopropanol, adding SnCl4. 5H2O and SbCl3, adding
triethanolamine at the same time, and hydrolyzing at 58-62 DEG C for 2.5-3 hours to form hydroxylated
silicon dioxide (at) TiO2 / SnO2 (at) ATO composite
sol; mixing the
mixed solution with acidic silica
sol in a
mass ratio of 1: (3-5), adding a dispersing agent, adjusting the pH value to 4.0-4.5, and carrying out
ultrasonic dispersion; and coating photovoltaic glass with the obtained product, and carrying out gradient heating curing. The invention belongs to the technical field of coatings.