297 results about "Diethanolamine" patented technology

The invention belongs to the technical field of flame-retardant macromolecules, and particularly relates to intrinsic heat-conducting flame-retardant recycled epoxy resin and a preparation method thereof. The preparation method comprises the following steps: (1) carrying out a reaction on diethanol amine and 9, 10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO) to obtain an intermediate A; and (2) carrying out condensation polymerization on the intermediate A and phenylphosphonic acid to prepare the phosphate-terminated polyester flame retardant (PEF). And (3) carrying out epoxidation on 4, 4 '-biphenol to prepare the liquid crystal epoxy precursor LEP. And (4) mixing PEF, LEP and 3, 3 '-dithiodipropionic acid, and heating and curing to prepare the epoxy resin. The prepared epoxy resin has intrinsic heat conduction, flame retardance and efficient recoverability, and is a high polymer material with great potential.

The invention discloses an alkali-free accelerator and a preparation method and application thereof in the technical field of concrete additives, and the alkali-free accelerator provided by the invention comprises the following components in percentage by mass: 40%-50% of aluminum sulfate, 10%-15% of magnesium sulfate, 0.2%-0.6% of diethanol amine, 0.5%-1% of catechol-4-ammonium sulfonate, 5%-10% of a stabilizer and the balance of water. The stabilizer comprises silicate dispersion liquid and silica sol. The alkali-free accelerator provided by the invention can be used for spraying concrete, the mixing amount of the alkali-free accelerator is generally 4-6% of the mass of cement, the alkali-free accelerator is good in rapid setting effect and has excellent early and later compressive strength, and meanwhile, the alkali-free accelerator has relatively excellent stability.

The invention discloses a method for recovering high-purity fluorine and silicon from fluorine-silicon slag and co-producing a low-alkali fluorine-free accelerator, which comprises the following steps: S1, dissolving the fluorine-silicon slag in a sodium hydroxide solution to obtain a solution A; s2, adding dilute sulphuric acid into the solution A, reacting until gel is obtained, and filtering to obtain filtrate A and high-purity silicon dioxide gel; s3, adding calcium sulfate and EDTA (Ethylene Diamine Tetraacetic Acid) into the filtrate A, stirring and reacting, and filtering after the reaction is finished to obtain calcium fluoride and filtrate B; and S4, taking clear water, heating, carrying out heat preservation, then adding aluminum sulfate, lithium sulfate, diethanol amine and the filtrate B obtained in S3, continuously stirring until the aluminum sulfate is completely dissolved, then adding hydrated magnesium silicate, continuously carrying out heat preservation stirring, and obtaining the low-alkali fluorine-free accelerator after stirring is finished. The method is simple in process and easy to implement industrially, and fluoride and silicon oxide obtained through separation are high in purity and beneficial to follow-up extension application; more importantly, high-value recycling of the fluorosilicon slag is achieved, and the problems of stockpiling waste and environmental pollution of the fluorosilicon slag are solved.

The invention discloses dynamic reversible hydrogen bond regulation type nano calcium carbonate as well as a preparation method and application thereof. The preparation method comprises the following steps: preparation of nano calcium carbonate slurry: treating limestone to obtain the nano calcium carbonate slurry; synthesizing a dynamic hydrogen bond modifier: mixing hexamethylene diisocyanate and diethanol amine, adding a catalyst, and reacting to obtain a ureido-containing prepolymer; adding glycerol and monobutyl phosphate into the prepolymer for further reaction to obtain an intermediate; mixing the intermediate with polyethylene glycol, and reacting to obtain a dynamic hydrogen bond modifier; and preparing a nano calcium carbonate product: adding a dynamic hydrogen bond modifier into the nano calcium carbonate slurry, stirring for reaction, and then carrying out filter pressing dehydration, drying and crushing to obtain the nano calcium carbonate product. After the prepared nano calcium carbonate product is applied to the automobile primer, synergistic balance of high yield value and low Bingham viscosity of the automobile primer is realized, and performance improvement and constructability are well coordinated.

The invention provides a nano liquid soil stabilizer as well as preparation and application thereof. The nano liquid soil stabilizer comprises 6-20 parts of a modifier; 4-20 parts of a stabilizer; 0.5 to 2 parts of nano particles; 10 to 20 parts of an active agent; 1-2 parts of an ion stabilizer; 2-11 parts of a dispersant; 2-15 parts of an accelerant; the stabilizer comprises one or more of isopropanol, ethanol, propylene glycol and ethylene glycol; the nano particles comprise silicon dioxide or aluminum oxide with the particle size of 10-100 nm; the ion stabilizer is one or more of sodium chloride, potassium chloride and sodium sulfate; the accelerant is one or more of triethanolamine oleate, triethanolamine, isopropanolamine and diethanol amine. The soil stabilizer is composed of the specific stabilizer, the nano particles, the ion stabilizer and the accelerant, the organic modifier containing polar groups is introduced, the specific organic modifier is adsorbed and acts on the surfaces of the nano particles by means of intermolecular force, the dispersion effect of the organic modifier is improved, the compactness of soil is remarkably promoted, and the mechanical strength and water stability of the soil are improved.

The invention discloses a degradable epoxy resin insulating material for electrical equipment as well as a preparation method and application of the degradable epoxy resin insulating material, and relates to the technical field of functional polymer materials. The degradable epoxy insulating material is prepared from an epoxy monomer, a transesterification catalyst N-methyldiethanolamine and an anhydride curing agent. Compared with a material prepared by a traditional method, the material has more excellent insulating property and mechanical property, the breakdown strength can reach up to 48.2 kV / mm, the dielectric loss is as low as 0.00116, the tensile strength reaches up to 93.5 Mpa, and the thermal stability is equivalent to that of traditional epoxy resin. Meanwhile, the epoxy resin disclosed by the invention can realize hot-pressing remolding recovery and chemical degradation recovery under mild conditions by virtue of a dynamic ester exchange reaction, and the performance retention rate gt of the physically regenerated resin is gt; the performance retention rate of the chemically regenerated resin is gt; 87%. According to the invention, a high-performance and sustainable new scheme can be provided for an electrical equipment insulating material.

The invention discloses sorbitan oleate modified castor oil-based waterborne polyurethane and a preparation method, and belongs to the technical field of paints.Castor oil is used as a soft segment, isophorone diisocyanate is used as a hard segment, and the isocyanate index of polyurethane is fixed to be about 1.1; the preparation method comprises the following steps: introducing sorbitan oleate with rigid furan and an aliphatic hydrophobic side chain into a polyurethane molecular network by adopting a prepolymerization method, and preparing a series of sorbitan oleate modified castor oil based cationic waterborne polyurethane emulsions by adopting N-methyldiethanolamine as a cationic hydrophilic chain extender and 1-4 butanediol as a micromolecular chain extender. According to the sorbitan oleate modified castor oil-based waterborne polyurethane and the preparation method, sorbitan oleate is introduced into a polyurethane molecular network, so that the mechanical property of a castor oil-based waterborne polyurethane material is effectively improved, and the water resistance and corrosion resistance of the castor oil-based waterborne polyurethane material are improved.

The invention relates to the technical field of corrosion protection of petrochemical equipment, and particularly discloses an efficient neutralizing corrosion inhibitor and a preparation method thereof. The efficient neutralizing corrosion inhibitor is prepared from the following raw materials in parts by mass: 40-60 parts of a macromolecular corrosion inhibitor, 10-20 parts of a neutralizing agent, 10-15 parts of a surfactant, 5-10 parts of an auxiliary agent and water, the high-molecular corrosion inhibitor is formed by copolymerization of an alkenyl imidazoline quaternary ammonium salt monomer, an alkenyl sulfonate monomer and an alkenyl dicarboxylic acid monomer. The neutralizing agent comprises monoethanolamine and diethanolamine; wherein the use amount of the water meets the condition that the efficient neutralizing corrosion inhibitor is prepared into a solution with the solid content of 10%-12%, and at the moment, the pH value of the solution is 11.0-11.5. The high-efficiency neutralizing corrosion inhibitor prepared by the invention effectively realizes the synergy of low dosage and high corrosion inhibition rate.

This invention relates to the field of coating production technology, specifically to a method and apparatus for preparing a polyetheramine-modified waterborne epoxy heavy-duty anti-corrosion coating. The polyetheramine-modified waterborne epoxy heavy-duty anti-corrosion coating comprises, by weight, 30-35 parts of modified bisphenol A epoxy resin, 3-8 parts of polyetheramine-modified waterborne epoxy resin, 0.7-1 parts of dispersant, 0.05-0.1 parts of defoamer, 15-20 parts of pigment, 5-10 parts of rust inhibitor, 7-20 parts of filler, 0.5-1 part of flash rust inhibitor, 0.5-1 part of polyurethane thickener, 0.1-0.3 parts of substrate wetting agent, 3-5 parts of dipropylene glycol butyl ether, and 10-15 parts of deionized water. This invention first chemically modifies epoxy resin by using diethanolamine for chain extension to increase its flexibility, thereby obtaining modified bisphenol A epoxy resin. Simultaneously, polyetheramine is used for its reaction to prepare polyetheramine-modified epoxy resin with an amphiphilic structure. After adding additives and mixing thoroughly, a high-performance waterborne epoxy heavy-duty anti-corrosion coating is obtained.

A briquette and binder for use in making the same are disclosed. The briquette including: a ferrous or ferro-alloy steel by-product; a binder mixture making up about 0.025% to about 10% of a batch weight, the binder mixture including: a polyvinyl alcohol resin comprising about 0.025% to about 30% of the binder mixture; a sodium hydroxide and diethanolamine phenolic resin comprising about 1% to about 20% of the binder mixture; and water making up the remainder of the binder mixture; a resin powder comprising about 0.01% to about 10% of the batch weight; and where the briquette, when cured, includes about 0.05% to about 10% of the binder mixture.

The invention discloses a low-temperature early-strength low-viscosity liquid accelerator and a compound production process thereof, and relates to the technical field of concrete admixtures. The accelerator is formed by compounding a basic framework component, a rheological stabilizing component and a low-temperature early strength component. The basic framework component comprises an inorganic aluminum salt coagulant, anhydrous magnesium sulfate, diethanol amine and water; the rheological stabilizing component comprises liquid polyaluminum sulfate, an amphoteric inner salt viscosity reducer and cationic nano silicon dioxide sol; the low-temperature early-strength component comprises water-soluble organic aluminum salt, zirconyl sulfate, lithium acetate and water. The amphoteric inner salt viscosity reducer is matched with the cationic nano silicon dioxide sol, so that the rheological stability of the accelerator under a low-temperature condition is improved; through cooperation of the water-soluble organic aluminum salt, the zirconyl sulfate and the lithium acetate, the early strength development capability of the accelerator under a low-temperature condition is improved.

The present invention relates to an absorbent for capturing carbon dioxide, and more particularly, to an absorbent for capturing carbon dioxide, which is characterized by comprising a liquid amine compound, a solid amine compound, and water, the liquid amine compound comprising monoethanolamine and methyldiethanolamine, the solid amine compound being piperazine, and the water being water. According to the present invention, the concentration composition ratio of piperazine and methyldiethanolamine falls within a given range so as to provide excellent absorption rate and circulation capacity while preventing crystallization of a fresh absorbent in normal temperature and low temperature environments, and ensuring smooth gas-liquid exchange in an absorption part and a regeneration part by reducing the viscosity.

The invention belongs to the technical field of ammonium perchlorate modification, and particularly relates to a low-sensitivity ammonium perchlorate composite material and a preparation method thereof. The preparation method of the composite material comprises the following steps: (1) mixing diethanol amine and an insensitive material to obtain a coating material; (2) adding a part of ammonium perchlorate into a stirrer according to a sandwich type feeding method, spreading the bottom of the stirrer, adding a coating material, finally adding the rest ammonium perchlorate, lifting a stirrer material cylinder, and starting a stirring reaction when the bottom of a stirring paddle is about to touch the material; and (3) after the reaction is finished, stirring and cooling the reaction system to obtain the ammonium perchlorate composite material with low friction sensitivity and impact sensitivity. The process provided by the invention is suitable for preparing low-sensitivity ammonium perchlorate with various particle sizes, has the advantages of simple process flow, good reproducibility, easiness in amplification and almost no pollution to the environment, and does not influence the performance of ammonium perchlorate while reducing the sensitivity of ammonium perchlorate.

A composition for carbon dioxide (CO2) capture includes 2-aminocyclohexanol, cis-1,2-diaminocyclohexane, meglumine, or combinations thereof. A process of CO2 capture includes mixing a CO2-containing gas with the composition. A system includes a component for receiving a gas and the composition, which absorbs CO2 from the gas. A further composition includes a first amine solvent selected from 2-aminocyclohexanol, cis-1,2-diaminocyclohexane, and meglumine and a second amine solvent independently selected from 2-aminocyclohexanol, cis-1,2-diaminocyclohexane, meglumine, ethyl diethanolamine, dimethylethanolamine, piperidine, 2-amino-2-methyl-1-propanol, and monoethanolamine. A further process includes reacting CO2 with an amine selected from 2-aminocyclohexanol, cis-1,2-diaminocyclohexane, and meglumine.

The present application belongs to the processing technology of semiconductor devices, and relates to the materials used therein, in particular to a water-based stripping solution suitable for various structures, and a preparation method and application thereof. The stripping solution comprises the following components in parts by weight: 9-10 parts of an organic amine compound, 60-70 parts of an organic solvent, 0.5-1 part of a corrosion inhibitor, and 0.5-1 part of a modified EDTA compound; the organic amine compound is hydroxyethyl ethylenediamine, methyldiethanolamine, triethanolamine or diglycolamine. The stripping solution can be suitable for various structures, and the corrosion rate is reduced by more than 20% due to the combination of the EDTA compound and the corrosion inhibitor, and the stripping speed is improved.

The invention belongs to the technical field of metal processing lubrication, and provides high-extreme-pressure anti-wear emulsion type expanding oil and a preparation method of the high-extreme-pressure anti-wear emulsion type expanding oil. Comprising the following steps: compounding naphthenic base oil, polyalkyl benzyl sulfide, vulcanized vegetable oil, sodium dodecyl benzene sulfonate, octylphenol polyoxyethylene ether, benzotriazole and methyldiethanolamine according to specific parts by mass to construct a carrier-extreme pressure-emulsification-corrosion prevention integrated system; wherein the naphthenic base oil (the kinematic viscosity at 40 DEG C is 350-400 mm / s) provides a stable carrier, the polyalkyl benzyl sulfide (the sulfur content is 20-30%) is a chloride-free extreme pressure core, the composite emulsifier ensures the stability of the system, and efficient protection is realized through double-component corrosion prevention; according to the invention, the 3% emulsion can be stably placed for more than or equal to 2 weeks, the maximum non-seizure load is more than 1800N, the emulsion is suitable for expanding large-diameter steel pipes made of Q235A, X70 / X80 and the like and cold forming processing of metal, the problems of insufficient extreme pressure, unstable emulsification, poor environmental protection property and the like of the existing product are solved, and the processing quality and efficiency are improved.

The application discloses a synthesis method of aza-cyclic modified hydroxyalkyl diethanolamine borate linking agent, which comprises the following steps: (1) adding hydroxyalkyl diethanolamine and boric acid into a three-neck flask provided with a stirrer, a thermometer and a vacuum distillation device, and stirring and heating to react until no water is generated; (2) adding an aza-cyclic compound into the reaction system obtained in the step (1), increasing the reaction temperature, and removing water generated in the reaction by vacuum distillation when no water vapor is generated, so as to obtain a target product. The borate linking agent obtained by the synthesis method has good hydrolysis resistance, and when the borate linking agent is used in a hydroxyl-terminated solid propellant, the mechanical properties of the hydroxyl-terminated solid propellant can be effectively improved.

The invention provides a method for removing heavy metals by acidizing bleaching earth. The heavy metals in the bleaching earth are removed by using a heavy metal adsorbent. Firstly, acrylate reacts with diethanol amine to generate an esterification product, then the esterification product reacts with trimethylolpropane to form a hydroxyl-terminated hyperbranched polymer, and then the hydroxyl-terminated hyperbranched polymer reacts with isocyanate acrylate to introduce double bonds to obtain hyperbranched acrylate. Meanwhile, sodium alginate reacts with 4-chlorophenylboronic acid to obtain boric acid modified sodium alginate, then the boric acid modified sodium alginate reacts with tannic acid to introduce a large amount of hydroxyl groups, and finally the boric acid modified sodium alginate reacts with 3-aminopropanol vinyl ether to introduce double bonds, so that the sodium alginate compound containing double bonds is prepared. And copolymerizing the two monomers with acrylic acid, N-(2-aminoethyl) acrylamide and 2-acrylamido-2-methylpropanesulfonic acid to obtain the adsorbent with a three-dimensional network structure and multiple functional groups. Through the treatment, the heavy metal content of the bleaching earth is obviously reduced, no foreign impurities exist, and the functions of high decolorization rate and strong adsorbability are reserved.

The present invention provides a heat damage inhibitor composition for hair that suppresses heat-induced damage to the hair and maintains smooth texture and manageability even after heat treatment. [Solution] A heat damage inhibitor composition for hair, comprising (A) an arginine derivative represented by general formula (1) and (B) an anionic water-soluble polymer, wherein the weight blending ratio ((A) component / (B) component) is 0.5 to 10.0. TIFF2026049878000009.tif3864 (In general formula (1), M is a hydrogen atom, an alkali metal, an alkaline earth metal, or an alkanolamine such as monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, or triisopropanolamine.)

The invention discloses an MDEA compound system for decarburization and a synergistic interaction method, and relates to the technical field of natural gas treatment and gas purification, in the MDEA compound system, N-methyldiethanolamine as a main agent accounts for 20-30% of the total mass of the compound system, Ce-MCM-41 accounts for 5-10% of the total mass of the compound system, an ionic liquid accounts for 5-10% of the total mass of the compound system, and the balance is water. The activating agent accounts for 1-3% of the total mass of the compound system, and the balance is water. When the MDEA compound system is applied to a process for removing carbon dioxide in natural gas, solid impurities, part of degradation products and generated anionic salt in an amine-rich solution and a barren solution are effectively removed through a three-stage filtering system and an ion exchange resin tower which are arranged in a process system. Therefore, through the cooperative scheme of the MDEA compound system and the decarburization process, the removal rate of carbon dioxide in the feed gas can be increased, the loss of N-methyldiethanolamine in the MDEA compound system in cyclic utilization can be reduced, and meanwhile, the blockage of equipment and pipelines can be prevented and controlled, so that the purposes of reducing the cost and improving the efficiency are achieved.

This invention discloses a low-temperature early-strength, low-viscosity liquid accelerator and its compounding and production process, relating to the field of concrete admixture technology. The accelerator is compounded from a basic skeleton component, a rheological stabilizing component, and a low-temperature early-strength component. The basic skeleton component includes an inorganic aluminum salt accelerator, anhydrous magnesium sulfate, diethanolamine, and water; the rheological stabilizing component includes liquid polyaluminum sulfate, an amphoteric internal salt viscosity reducer, and cationic nano-silica sol; the low-temperature early-strength component includes water-soluble organic aluminum salt, zirconium oxysulfate, lithium acetate, and water. This invention improves the rheological stability of the accelerator under low-temperature conditions through the combination of the amphoteric internal salt viscosity reducer and the cationic nano-silica sol; and improves the early strength development ability of the accelerator under low-temperature conditions through the combination of the water-soluble organic aluminum salt, zirconium oxysulfate, and lithium acetate.

The invention belongs to the technical field of biological medicines, and particularly relates to a dissociation liquid applied to an aluminum adjuvant adsorption influenza vaccine and a method for measuring the antigen content. The dissociation liquid disclosed by the invention is prepared from a potassium phosphate salt solution, diethanol amine, TritonX-100, tween-20, dodecyl dimethyl betaine and water. The dissociation liquid is excellent in dissociation efficiency, the dissociation recovery rate of the dissociation liquid to H1N1, H3N2 and BV type influenza vaccine hemagglutinin reaches 106%-110%, the antigen activity can be effectively protected, operation is easy and convenient, adaptability is wide, a dissociated sample can be directly used for mainstream detection methods such as a one-way immunodiffusion test, an enzyme-linked immunosorbent assay and a high performance liquid chromatography method, and the dissociation liquid has good application prospects. The precise quantification of the antigen content in the aluminum adjuvant adsorption influenza vaccine is realized, and a reliable technical support is provided for vaccine quality control.

The present application relates to the field of natural gas decarburization, and discloses a decarburization solvent, a decarburization method and system of carbon-containing natural gas, the decarburization solvent comprising a main agent, an activator and an auxiliary agent; wherein the main agent is N-methyldiethanolamine, the activator comprises a primary amine and a secondary amine, and the auxiliary agent is selected from at least one of potassium sorbate, sodium sorbate and sodium sulfite.The decarburization solvent and the decarburization method provided by the present application can not only make the absorption and regeneration equipment flexible to follow the change of the CO2 content of the raw gas in the natural gas development process and expand, but also avoid the corrosion and foaming of the tower equipment in the conventional process; meanwhile, the absorption and regeneration performance of the decarburization solution can be improved under the condition of meeting the purification index, and the regeneration heat consumption and the power consumption for pressurization of the amine liquid circulation can be greatly reduced.

The application discloses a preparation method of a nano TiO2 composite fluorescent whitening agent and relates to the technical field of fluorescent whitening agents. The method comprises the following steps: firstly, one-time condensation is carried out on cyanuric chloride and 4,4'-diamino-stilbene-2,2'-disulfonic acid; secondly, secondary condensation is carried out on diethanolamine, and quaternary ammonium is formed by using epichlorohydrin in the secondary condensation process; finally, tertiary condensation is carried out on amino nanoparticles, so that the nano TiO2 composite fluorescent whitening agent is obtained. The nano TiO2 composite fluorescent whitening agent prepared by the application has the characteristics of good ultraviolet aging resistance and water solubility.

The application provides a compound, a preparation method, and application in desulfurization and a desulfurizer, a structural formula of the compound is as follows: the preparation method is as follows: diisopropanolamine, ethylene glycol diglycidyl ether, and a solvent are uniformly mixed and then are added into a high-temperature and high-pressure reaction kettle, reaction is carried out at 80-120 DEG C for 4-8 h, the solution is poured out after cooling, and the solution is distilled under reduced pressure to obtain a solid product steric amine; then the prepared steric amine and N-methyldiethanolamine are uniformly mixed at a mass ratio of 1-2:2-3, and are compounded into a 40-50 wt% aqueous solution, and the desulfurizer is preferably applied to natural gas desulfurization.

The presently claimed invention relates to an alkaline composition for cleaning a substrate comprising i) copper or copper alloy and ii) cobalt or cobalt alloy, the composition comprising: a) at least one pH adjustor selected from diglycolamine, 4,4-diethoxy-N,N-dimethyl-1-butanamine, 3-dimethylaminopropan-1-ol, dimethylaminoethoxyethanol, N,N-dimethylisopropanolamine, ethylethanolamine, N-methyldiethanolamine, 2-(2-(methylamino)ethoxy)ethanol, 3-(methylamino)propane-1,2-diol, 2-[2-[2-(2-methoxy- ethoxy)ethoxy]ethoxy]ethylamine, 2-[2-(2-aminoethoxy)-ethoxy]-ethanol, N-butyldiethanolamine, diisopropanolamine, N-methyldiisopropanolamine, monoethanolamine, 3-dimethylamino-1,2-propandiol, 2- amino-1-butanol, 2-(2-(2-(2-aminoethoxy)ethoxy)ethoxy)ethanol, prolinol, 1-methyl-2-pyrrolidinemethanol, 1-methyl-2-pyrrolidinemethanol, 1-methyl-3-pyrrolidinol, 2-amino-2-methyl-1-propanol, N,N-dimethylethanolamine, butylethanolamine, diethylethanolamine, 3-methoxypropylamine, 4-(2-hydroxyethyl)morpholine, 4-(dimethylamino)cyclohexanol, 2-amino-2-methyl-1, 3-propanediol, or diisopropylamine; b) at least one complexing agent selected from C2 to C12 hydrocarbon having at least two sulfonic acid or carboxylic acid groups; c) at least one polymeric dispersing agent having a weight average molecular weight ≥ 1000 g / mol; and d) a solvent comprising water.

The application discloses a preparation method of a temperature-ultraviolet light double response type functional polymer, specifically comprising the following steps: preparing a macromolecular initiator PEG2-ABCPA; preparing a p-styrylmethyl diethanolamine borate monomer VMAB; and performing a free radical polymerization reaction on the macromolecular initiator PEG2-ABCPA, the p-styrylmethyl diethanolamine borate monomer VMAB and 7-(4-vinylbenzyloxy)-4-methyl coumarin VBC to obtain a block copolymer, i.e. the temperature-ultraviolet light double response type functional polymer. The polymer not only has unique amphiphilic properties, but also exhibits double response to temperature and ultraviolet light, thereby showing wide application prospects in the fields of drug controlled release, intelligent materials, photoelectric devices and the like.

A tung oil-based polyurethane epoxy toughening agent, its preparation method, and its application are disclosed. The chemical structure is shown below: R1 is a methyl tungate molecular chain, and R2 is a backbone molecule in diisocyanate. The preparation method involves reacting methyl tungate with diethanolamine to obtain diethanol tungamide; the diethanol tungamide is then reacted with diisocyanate and glycidyl ether to obtain an epoxy-terminated tung oil-based polyurethane epoxy toughening agent. This toughening agent can react with a curing agent, covalently integrating into the epoxy resin curing network, improving the compatibility between the toughening agent and the epoxy resin, and avoiding problems such as decreased material transparency due to phase separation. Furthermore, the structure contains amide, urethane, and conjugated triene structures, which can form sacrificial bonds such as hydrogen bonds and π-π interactions with the epoxy resin matrix. This can improve the toughness of the epoxy resin while mitigating the adverse effects of flexible long carbon chains on the strength and other properties of the epoxy resin.

The invention discloses a wound repair medical dressing and a preparation method thereof, and relates to the technical field of medical dressings. The medical dressing for wound repair is prepared from the following raw materials in parts by weight: 30 to 40 parts of bioactive glass, 25 to 35 parts of sodium alginate, 10 to 20 parts of antibacterial agent, 10 to 15 parts of anti-inflammatory agent and 400 to 600 parts of deionized water. The preparation method comprises the following steps: reacting N-hexadecyl diethanolamine with 1-chlorododecane to generate a quaternary ammonium salt compound, and reacting the quaternary ammonium salt compound with 3-[[4-(pyridine-2-yl sulfamoyl) phenyl] diazenyl] benzoic acid to generate the antibacterial agent. The medical dressing for wound repair prepared by the invention has excellent antibacterial performance and anti-inflammatory performance.

The application belongs to the technical field of flame-retardant polymers, and particularly relates to an intrinsic heat-conducting flame-retardant recycled epoxy resin and a preparation method thereof. The preparation method comprises the following steps: (1) diethanolamine is reacted with 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO) to obtain an intermediate A; (2) the intermediate A is subjected to polycondensation reaction with phenylphosphonic acid to obtain a terminal phosphonic acid group polyester flame retardant (PEF); (3) 4,4'-diphenol is epoxidized to obtain a liquid crystal epoxy precursor LEP; and (4) the PEF, the LEP and 3,3'-dithiodipropionic acid are mixed and heated and cured to prepare the epoxy resin. The prepared epoxy resin has intrinsic heat conduction, flame retardation and high efficiency recycling, and is a highly potential polymer material.