248 results about "Magnesium fluoride" patented technology

The invention relates to the technical field of glass welding, in particular to a clamping device for metal-glass laser welding and a welding method. The device comprises a bottom plate, a cover frame and supporting columns connecting the bottom plate and the cover frame, and a lifting part is formed between the cover frame and the bottom plate. A mechanical lifting assembly with an adjusting rocker and a graduated scale is installed on the bottom plate in the lifting part, the lower end is connected with the bottom plate, and the upper end is connected with the machining table to drive the machining table to ascend and descend. And the center of the cover frame is provided with a quartz glass pressing plate plated with a magnesium fluoride antireflection film. A cylindrical metal mounting base coaxial with the glass pressing plate is arranged on the machining table and used for mounting metal to be welded. During welding, the adjusting rocker is rocked to lift the machining table so that to-be-welded glass can make contact with the glass pressing plate, and optical contact is achieved by observing the situation that an interface Newton ring disappears from appearing; the whole clamping device is moved to a laser machining platform, and welding is conducted through a glass pressing plate; and after completion, the machining table is lowered to disassemble the weldment.

The invention discloses a far-infrared high-transmittance composite material, a preparation method thereof and an optical device, and the far-infrared high-transmittance composite material comprises the following components in parts by weight: 70-99 parts of a polymer matrix; 1-30 parts of an anti-reflection auxiliary agent; the polymer matrix is a sulfur-containing polymer prepared by polymerization reaction of a polymeric monomer and sulfur, and the proportion of carbon-carbon unsaturated bonds is less than 3%; the polymeric monomer is selected from at least one of a vinyl monomer, a propenyl monomer, an acrylic acid monomer, a methacrylic acid monomer, an epoxide monomer, a thiopropyl ring monomer, an alkynyl monomer, a butadiene monomer, an isoprene monomer and a norbornene monomer; the anti-reflection auxiliary agent comprises at least one of nano zinc sulfide, nano zinc selenide, nano calcium fluoride, nano magnesium fluoride and nano magnesium oxide. The composite material and the optical device thereof have high far infrared transmittance and good mechanical properties and processability, and can meet the requirements of various far infrared optical fields.

The invention belongs to the technical field of photovoltaic coatings, and discloses a photovoltaic coating as well as a preparation method and application thereof. The photovoltaic coating is prepared from the following raw materials: a solvent, an ultraviolet light absorber, a wetting agent, an antistatic agent, modified hydrophilic silicon dioxide, nano magnesium fluoride and nano tin dioxide, the modified hydrophilic silicon dioxide is hydrophilic silicon dioxide modified by ethylenediamine and glacial acetic acid. A coating formed by the photovoltaic coating is high in adhesive force and resistant to aging, and the light transmittance, the self-cleaning property and the antistatic property of photovoltaic glass can be obviously improved.

The invention belongs to the technical field of sodium-ion battery positive electrode material preparation, and particularly discloses a double-modified sodium-ion battery layered oxide positive electrode material and a preparation method thereof, and the preparation method comprises the following steps: S1, synthesizing a P2-type sodium-ion battery nickel-manganese-based layered oxide by using a high-temperature solid-phase method; s2, uniformly mixing two or more of lithium fluoride, sodium fluoride, calcium fluoride or magnesium fluoride in proportion to prepare a multi-element fluoride coating material; and S3, uniformly mixing the P2-type sodium-ion battery nickel-manganese-based layered oxide and the multi-fluoride coating material according to a ratio, and then carrying out high-temperature quenching treatment to obtain the surface fluoride-coated and near-bulk-phase-doped dual-modified sodium-ion battery layered oxide positive electrode material. According to the dual-modified layered oxide positive electrode material for the sodium-ion battery and the preparation method, surface fluoride coating and near bulk phase doping are cooperatively utilized, so that the high-voltage cycle performance of the layered oxide positive electrode material for the sodium-ion battery is improved.

An electrolyte solution for a lithium secondary battery is provided, comprising a lithium salt, a nonaqueous organic solvent with at least 50% FSA by volume, and a silver (Ag) compound additive selected from AgHFB, AgPFP, or silver trifluoroacetate. The additive is present in an amount of about 0.05 wt % to 0.2 wt % to promote stable SEI layer formation and reduce lithium deposition overvoltage. The solution may also include a secondary additive such as calcium hydride (CaH2) or magnesium fluoride (MgF2) to further suppress lithium dendrite growth. The lithium secondary battery incorporating this electrolyte is designed to form a lithium metal layer with a thickness of 40 to 45 μm and a surface pore average diameter of less than 1 μm during the initial charging process, optimizing performance and stability.

A hydrocarbon gas detection system including a longwave infrared camera, a spectral filter, and a computation unit. The spectral filter is disposed in the light path of the camera sensor. The spectral filter is made of a material selected from the group consisting of calcium fluoride, zinc sulfide, magnesium fluoride, and silicon. The computation unit is arranged to process image data of the longwave infrared camera for the hydrocarbon gas detection.

The invention discloses a near-net-shape preparation process of high-light-transmittance large-size magnesium aluminate spinel ceramic, and belongs to the technical field of preparation of high-performance transparent ceramic. The process comprises the following steps: firstly, mixing magnesium aluminate spinel raw material powder with a lithium-free composite sintering aid according to a mass ratio, wherein the composite sintering aid consists of magnesium fluoride, ytterbium fluoride and ytterbium oxide according to a molar ratio; performing cold isostatic pressing on the mixed powder to prepare a preformed blank, crushing, and performing high-low pressure circulation pressurization near-net forming. The obtained green body is firstly subjected to hot pressing and presintering, then placed in a fluorine-containing atmosphere to be treated and finally subjected to hot isostatic pressing sintering, and a finished product is obtained through aftertreatment. According to the technology, the bottleneck of large-size component preparation is successfully overcome, net forming of the magnesium aluminate spinel ceramic with the diagonal size larger than 400 mm is achieved, the light transmittance of a finished product in the wavelength range of 400 nm to 800 nm exceeds 93%, the breaking strength reaches 194 MPa or above, and meanwhile the raw material cost and equipment dependence are remarkably reduced.

The invention provides high-transparency rare earth doped fluoride glass and a preparation method thereof, and belongs to the technical field of glass. The calcium fluoride ensures high transparency and chemical stability, the magnesium fluoride improves the ultraviolet transmittance and the mechanical strength, and the barium fluoride optimizes the melting fluidity and the rare earth doping uniformity; aluminum fluoride is added to inhibit crystallization and enhance uniformity, the rare earth element realizes optical function regulation and control, and ammonium fluoride provides a fluorine source and reduces impurities; in a preparation link, quick lime is dedusted and then reacts with pure water in proportion, impurities in a calcium nitrate solution are removed by hydrogen peroxide, uniform growth of calcium carbonate crystal nucleuses is controlled by ammonia water and carbon dioxide, and calcium fluoride is synthesized by hydrofluoric acid in proportion and dried at low temperature after plate-frame pressure filtration and purification; after the raw materials are refined through ball milling, the melting temperature is controlled in stages, impurities, reaction integrity and a microstructure are accurately controlled in the whole process, and finally the high-transparency functional glass is prepared.

The embodiment of the invention provides a friction material composition, a brake lining, a preparation method of the brake lining, a brake and a vehicle. The friction material composition comprises the following raw materials in parts by weight: 2-10 parts of a fluoride mixture, 8-15 parts of graphite, 8-12 parts of phenolic resin, 4-12 parts of a metal oxide, 15-40 parts of a fiber material and 20-40 parts of other fillers, wherein the fluoride mixture comprises at least two of calcium fluoride, barium fluoride, cerium fluoride, aluminum fluoride, magnesium fluoride, potassium fluoride, sodium fluoride, beryllium fluoride and manganese fluoride. The brake lining prepared from the friction material composition can solve the problems of high wear rate and heat fading at the same time, the service life of the brake lining is prolonged, and the braking effect is improved.

A method for manufacturing a fused metal sight window that melts the metal of the frame around the window, instead of the traditional method of melting the window into the frame. Since most of the superior optical transparent materials (such as fused silica, sapphire, YAG, ALON, diamond, fused quartz and magnesium fluoride) have a melting point higher than most metals, it was not previously possible to create fused metal sight windows with these materials. By melting the frame onto the window, many new combinations of metals and optical materials may be used while retaining the strength of the sight window that results from fusing the metal and the window.

The utility model relates to an anti-reflection film and an optical lens, the anti-reflection film comprises n metal oxide film layers and n'ceramic film layers which are staggered and laminated along the thickness direction, and n and n 'are respectively integers; wherein the metal oxides of the n metal oxide film layers are respectively and independently titanium dioxide or tantalum pentoxide, and the ceramic materials of the n'ceramic film layers are respectively and independently silicon dioxide, silicon nitride, silicon carbide or magnesium fluoride; the optical lens comprises an optical substrate and the antireflection film arranged on the optical substrate. The antireflection film provided by the utility model has the advantage of increasing the light transmittance, and can be matched with the transmittance of a grating structure through stacking at least two types of materials with refractive index differences, thereby achieving the effect that the coupling-in region, the transition region and / or the coupling-out region of the optical lens are approximately transparent.

The invention discloses a high-reflectivity nano-composite ink formula and a gradient curing preparation method thereof, and belongs to the technical field of reflective ink. According to the formula, the high-reflectivity nano-composite ink comprises 28-45 parts of matrix resin, 15-30 parts of a nano-composite reflective material, 4-8 parts of a photoinitiator, 1-5 parts of a dispersing agent, 0.5-3 parts of an antioxidant, 0.5-1 part of a flatting agent and 35-50 parts of a solvent, wherein the matrix resin is fluorosilicone modified acrylic resin, and the nano-composite reflective material is gadolinium lanthanum and magnesium fluoride compounded core-shell barium sulfate. In order to solve the problem that the reflectivity of a traditional reflective ink product in a short-wave illumination application scene is greatly reduced, the matrix resin and the reflective material are improved and optimized, the nano-composite ink with high reflectivity in visible light and ultraviolet light wavebands is prepared, and the nano-composite ink is good in stability and can meet the use requirements of more scenes.

The invention relates to the technical field of electroluminescent devices, in particular to a large-current quantum dot electroluminescent device and a preparation method thereof. The device comprises a substrate, a cathode, an electron transport layer, a quantum dot light-emitting layer, a current focusing layer, a hole transport layer, a hole generation layer and an anode which are tightly stacked in sequence, the current focusing layer is provided with a slit which is used for regulating and controlling the injection path of hole current to the quantum dot light-emitting layer and improving the bearable current density threshold value of the device. The material of the current focusing layer is one or more of lithium fluoride, magnesium fluoride and aluminum oxide; and the hole generation layer is used for efficiently enhancing hole injection. The invention further provides a preparation method for preparing each layered structure through spin coating and vacuum evaporation deposition. The electroluminescent device has the advantages that the hole generation layer and the current aggregation layer are utilized to construct the electroluminescent device capable of realizing large-current driving, the problem that carrier injection in the device under large-current driving is limited is solved, and the current tolerance and the luminous intensity of the device are effectively improved.

The invention provides a preparation method of alpha, omega-diiodo perfluoroalkane, and belongs to the technical field of iodo perfluoroalkane synthesis. The preparation method disclosed by the invention comprises the following steps: under a protective atmosphere, enabling a nano flower type magnesium fluoride catalyst, 1, 2-diiodo tetrafluoroethane and tetrafluoroethylene to react, so as to obtain 1, 4-diiodo perfluorobutane and 1, 6-diiodo perfluorohexane. The nano flower type magnesium fluoride catalyst has high specific surface area and abundant coordination unsaturated sites, can effectively activate reactant molecule bonding sites, and avoids the problems of side reaction and catalyst deactivation caused by free radical paths; by optimizing the pore structure and reaction conditions of the catalyst, efficient synergistic conversion of IPF-2 and TFE can be realized, and the selectivity and yield of IPF-4 and IPF-6 are remarkably improved. The method provided by the invention has the advantages of mild conditions, safe operation, adjustable product distribution and the like, and meets the requirements of industrial production on high-selectivity fluorine-containing bifunctional compounds.

The invention discloses an ultra-wideband high-efficiency absorber in the technical fields of optics, material science and energy, which takes silicon dioxide (SiO2) as a substrate, and a titanium (Ti) nano rectangular body array is arranged above the substrate; a silicon nitride (Si3N4) regular hexagonal prism array is constructed on the top of the titanium layer, six cylindrical holes are etched in the midpoint of each vertex of a regular hexagon on the bottom surface of the titanium layer, and magnesium fluoride (MgF2) is filled in the cylindrical holes to form magnesium fluoride nano cylinders; a chromium (Cr) ring and a silicon nitride ring are sequentially superposed at the top end of the hexagonal prism and are tangentially matched with the hexagon on the top surface of the hexagonal prism. According to the UWB-HEA, the incident wavelength ranges from 400 nm to 4000 nm, the designed efficient absorption range (namely absorption band) of the UWB-HEA covers from near-infrared 855 nm to mid-infrared 3540 nm, about 2685 nm, the average absorption rate of 96.67% is achieved under TM waves, and the highest absorption rate is 99.66%; the average absorption rate of 96.44% is achieved under TE waves, the highest absorption rate is 99.72%, and the absorption rate is almost unrelated to polarization. In order to reduce radiation energy loss of an object, an ideal solar heat absorber needs to realize efficient light absorption in a wide wave band range.

The present invention discloses a high thermal shock resistance ceramic material and a preparation method thereof, which comprise the following raw materials in parts by weight: 100 parts of alumina powder, 3 - 18 parts of pretreated mullite fiber, 2 - 8 parts of binder, 2 - 5 parts of dispersant, and 2 - 8 parts of mineralizer, wherein the mineralizer is composed of 1 - 4 parts of aluminum fluoride and 1 - 4 parts of magnesium fluoride. By pretreating the mullite fiber, a low-expansion composite fiber component is formed at high temperature, and a mineralizer is introduced to stabilize the fiber strength and structure at high temperature. The alumina composite granulated powder is prepared by a spray granulation process. The mullite fiber forms a network structure in the ceramic material and has a smaller thermal expansion coefficient, effectively absorbing thermal stress, so that the ceramic material does not crack when cooled to room temperature after heating and can withstand a higher temperature change, effectively improving the thermal shock resistance of the ceramic material. At the same time, the alumina powder as the main component ensures high hardness and strength, and the addition of the mullite fiber improves the toughness and impact resistance of the material.

Magnetic particles with a highly reflective protective membrane (300), comprising: a magnetic core (100), a shell (200) formed on the outer surface of the magnetic core (100), having a multi-layer structure and comprising a first shell (210) made of a dielectric material, and a second shell (220) made of metallic material, formed on the outer surface of the first shell (210) and being a multi-layer membrane in which two or more layers (221, 222, 223) of mutually different metallic materials are stacked on top of each other, and a highly reflective protective membrane (300) which is in contact with the second shell (220) and is formed on the outer surface of the shell (200), wherein the highly reflective protective membrane (300) comprises a multi-layer structure comprising a low refractive index membrane (310) formed on the outer surface of the shell (200) and having an optical thickness between 0.15 to 0.35 of the wavelength, and a high refractive index membrane (320) formed on the outer surface of the low refractive index membrane (310) and having an optical thickness between 0.15 to 0.35 of the wavelength, the dielectric material is one or more materials selected from a group comprising titanium dioxide, aluminum oxide, calcium carbonate, zirconium oxide, magnesium fluoride, zinc oxide and zinc sulfide, the metallic material is one or more materials selected from a group comprising copper, nickel, gold, platinum, silver, aluminum and chromium, the low refractive index membrane (310) consists of one or more materials selected from a group comprising silicon dioxide, magnesium fluoride, polystyrene, polymethyl methacrylate, polystyrene-co-butadiene, vanadium pentoxide, cadmium oxide, polyisobutylene and polyethylene, and the high refractive index membrane (320) consists of one or more materials selected from a group comprising titanium dioxide, aluminum oxide, zinc oxide, zirconium oxide and chromium oxide.

The invention relates to the technical field of lithium ion batteries, in particular to a nickel cobalt lithium manganate positive electrode material and a preparation method thereof. According to the invention, the technical problems of poor cycle performance and low specific capacity of the existing nickel cobalt lithium manganate positive electrode material are solved. The preparation method comprises the following steps: synthesizing precursor powder by adopting a coprecipitation process; then carrying out high-shear mixing on the precursor, lithium hydroxide, nano niobium oxide and magnesium fluoride; after the mixed material is subjected to pre-oxidation and high-temperature oxygen-enriched gradient sintering, a gradient reduction etching process is adopted in the cooling stage, and strong wind quenching is matched for surface shaping; and finally, carrying out air jet pulverization and demagnetization to obtain the nickel cobalt lithium manganate positive electrode material. According to the method, lattice respiration stress is effectively dissipated by constructing a radial ordered structure, a bulk phase structure is stabilized through multi-element synergistic doping, interfacial ion transport kinetics is optimized through reduction-induced surface oxygen vacancies and a lattice distortion layer, and the synergistic strategy ensures high stability of the material structure and meanwhile, the material structure has a good application prospect. And the de-intercalation efficiency of the active lithium is greatly improved.

The objective of the present invention is to provide a positive electrode active material for ensuring excellent cycle characteristics or electrode resistance characteristics, a positive electrode active material slurry, a positive electrode, a lithium ion secondary battery, and a method for preparing a positive electrode active material. A positive electrode active material according to an embodiment contains a mixture of lithium transition metal oxide particles and magnesium fluoride particles and shows a peak at 685 eV to 687 eV in the spectrum of fluorine 1s electrons, as observed by X-ray photoelectron spectroscopy.

The invention belongs to the field of electronic packaging materials, and particularly relates to a high-thermal-conductivity ceramic material for LED packaging and a manufacturing process of the high-thermal-conductivity ceramic material for LED packaging. The high-thermal-conductivity ceramic material is prepared from silicon nitride, aluminum nitride, magnesium fluoride, yttrium fluoride, lithium carbonate and two newly-designed modified compounds. The phase change regulator is composed of a boron-doped rare earth silicate nanocrystalline phase change regulator and a bimetallic chalcogenide compound interface modifier according to a specific weight part ratio. The preparation process mainly comprises the following steps: ball-milling and mixing the components, drying, granulating, and carrying out segmented hot pressed sintering in a protective atmosphere to finally obtain the compact ceramic material. The high-power LED packaging structure is particularly suitable for packaging of high-power LEDs, and the technical problem that heat dissipation and mechanical performance are difficult to consider at the same time is effectively solved.

A window according to one or more embodiments of the present disclosure includes a base layer, a first layer on the base layer, a second layer below the base layer, a third layer on the first layer, and a fourth layer on the third layer, each of the first and second layers including magnesium oxide (e.g., MgO), magnesium fluoride (e.g., MgF2), and yttrium oxyfluoride (e.g., YOF). In addition, a display device and an electronic device including the window are also provided.

This invention discloses a method for deep removal of calcium and magnesium from battery-grade manganese sulfate solution, belonging to the field of hydrometallurgical technology. The invention employs a three-stage purification process: pretreatment for impurity removal, gradient precipitation with manganese fluoride, selective extraction, and chelating resin refinement. First, the manganese sulfate leachate undergoes pretreatment to remove iron, aluminum, and heavy metals. Then, an in-situ / direct addition of manganese fluoride precipitation system using magnesium fluoride seeding and gradient fluoride supplementation efficiently removes most calcium and magnesium impurities from the solution, achieving a single-precipitation rate of over 93% for magnesium ions. Subsequently, a P507 / Cyanex272 / TBP compound saponification organic system is used with a reverse extraction logic of "extracting calcium and magnesium while retaining manganese in the aqueous phase" to precisely remove residual calcium and magnesium, avoiding the problems of competition between manganese and calcium and low magnesium extraction efficiency in traditional extraction methods. Finally, trace amounts of calcium, magnesium, and residual fluoride ions are completely removed through aluminum salt complexation for fluoride removal combined with deep refinement using aminocarboxylic acid chelating resin. This invention introduces no foreign impurities such as sodium and ammonium throughout the entire process, has a wide process window and strong industrial stability, and the final purified manganese sulfate solution can stably meet the high-end battery-grade index requirements of Ca²⁺≤5mg / l, Mg²⁺≤5mg / l, and F⁻≤1mg / l, making it suitable for the large-scale production of high-purity manganese sulfate, a raw material for lithium battery cathodes.

When an anti-reflective coating, conventionally applied to glass lenses, is applied to a plastic lens, the difference in thermal expansion between the plastic substrate and the anti-reflective coating causes significant expansion of the plastic substrate in high-temperature environments. This leads to a problem where the anti-reflective coating cannot keep up with the expansion of the substrate and is prone to fracture (cracking). Therefore, we aim to realize a new optical thin film that achieves both the desired optical properties and the suppression of crack formation. [Solution] The optical thin film of this disclosure includes one or more MO mixed layers (11) in which organometallic compounds are mixed within a layer formed by the physical deposition of magnesium fluoride.

The invention belongs to the technical field of electrical equipment insulating materials, and particularly relates to a short-wave sensitive type high-light-transmittance composite insulating material and a preparation method thereof. The short-wave sensitive high-transmittance composite insulating material comprises the following components in percentage by mass: 55-65% of epoxy resin, 30-40% of modified aluminum oxide filler, 2-5% of an interface enhancer and 3-5% of a curing agent, wherein the modified aluminum oxide filler is aluminum oxide particles of which the surfaces are coated with nanoscale magnesium fluoride coatings; the interface reinforcing agent is a compound of a silane coupling agent and polyvinyl alcohol.

The present invention provides a method for recovering and preparing high-purity magnesium fluoride from fluorine-containing solid waste, comprising: mixing the fluorine-containing solid waste with magnesium sulfate and then performing a wet ball milling process, putting the obtained wet-milled conversion residue into a sodium hydroxide solution for alkali leaching and then filtering to obtain an alkali-leached conversion residue and an alkali-leached conversion solution; performing acid leaching on the alkali-leached conversion residue to obtain an acid leached solution, performing a magnesium ultrasonic extraction process on the acid leached solution, and performing a magnesium ultrasonic back extraction process on the obtained magnesium-loaded organic phase to obtain a magnesium-free organic phase and a magnesium sulfate solution; acidifying the alkali-leached conversion solution and then filtering to obtain an acidified solution, performing a fluorine extraction process on the acidified solution to obtain a fluorine-loaded organic phase, and using the magnesium sulfate solution as an anti-extraction agent to perform a fluorine back extraction process on the fluorine-loaded organic phase to obtain magnesium fluoride. The method adopted by the present invention can efficiently separate calcium and magnesium in the fluorine-containing solid waste, convert the fluorides in the fluorine-containing solid waste into high-purity magnesium fluoride, and realize the recycling of fluorine and magnesium resources in the fluorine-containing solid waste.

An optical device includes, in sequence, a surface formed of a metal oxide, a samarium oxide-containing layer in contact with the surface formed of a metal oxide, and a magnesium fluoride-containing layer in contact with the samarium oxide-containing layer so as to suppress optical absorption resulting from high-rate sputter deposition of a magnesium fluoride-containing layer on a surface formed of a metal oxide.

An object is to provide a method for manufacturing a positive electrode active material that achieves high powder properties and high load resistance (e.g., rate performance and output resistance) when used in a lithium-ion secondary battery, within a short manufacturing cycle time and at low cost. To perform heat treatment at temperatures lower than the melting point of magnesium fluorine, lithium fluoride is mixed to melt magnesium fluorine and modify the surface of lithium cobalt oxide powder. By mixing lithium fluoride, magnesium fluorine can be melted at a temperature lower than its melting point, and a positive electrode active material is formed utilizing this eutectic phenomenon.

The present application relates to the technical field of nuclear fuel cycle, and particularly relates to a method for recycling uranium fluorination wastewater. The method is as follows: adjusting the concentration ratio of bicarbonate and carbonate in the uranium conversion leaching solution, carrying out decolorization and filtration treatment to obtain a filtrate; the filtrate is subjected to uranium adsorption through a resin, and the resin adsorbed with uranium is subjected to leaching; the adsorption tail liquid is added with magnesium hydroxide slurry to adjust the pH to above 11, and then filtered, and the filtrate is adsorbed by amidoamine-based adsorption fiber; the adsorption tail liquid is added with magnesium carbonate slurry to generate magnesium fluoride and carbonate ions, and then filtered to obtain a sediment and a filtrate respectively; the filtrate is returned as a leaching agent of fluorination tail gas or is discharged after treatment; the sediment is used together with new magnesium carbonate to participate in fluorine removal reaction again, and the unreacted magnesium carbonate is used again. The present application realizes efficient recovery of uranium in the leaching solution and recycling of the leaching solution, fully utilizes the residual alkali in the returned liquid, reduces the treatment cost of fluorination tail gas, controls the radioactivity of the waste residue, and realizes radioactivity exemption of the treated sediment.

This invention relates to the field of co-processing and resource utilization of fluorine- and silicon-containing solid waste, specifically disclosing a high-quality, tiered resource utilization process for fluorosilicone slag. This process uses fluorosilicone slag as raw material, sequentially undergoing alkali dissolution activation, acidification polymerization, primary defluorination crystallization, secondary deep defluorination, and salt resource recovery steps to produce washed silica, magnesium fluoride, cryolite, and sodium sulfate, while simultaneously achieving mother liquor recycling and wastewater reduction. This invention features a short process flow, closed-loop material circulation between units, and a SiO2 recovery rate of over 95% in the fluorosilicone slag. The silica, magnesium fluoride, cryolite, and sodium sulfate products meet relevant national or industry standards, achieving high-quality, tiered resource utilization and overall wastewater reduction for fluorosilicone slag.

The application provides a high-thermal-conductivity radiation refrigeration coating for a 5G communication base station cabinet and a preparation method thereof, and belongs to the technical field of coatings. A SiC@BN / TiB2 three-phase fiber framework obtained through three-stage calcination is bonded with methylphenyl silicone resin through a silane coupling agent to form a longitudinal high-speed thermal conduction framework. Starburst calcium titanate and edge in-situ magnesium fluoride form a refractive index ladder and a rough multi-faceted structure, which not only reflects ultraviolet-near infrared light, but also endows weather resistance. Holmium / ytterbium co-doped calcium fluoride nanosheets are transversely overlapped to scatter near infrared light and convert the near infrared light into medium-far infrared radiation which can penetrate the atmospheric window, thereby further dissipating heat. Through mutual cooperation of a longitudinal continuous heat conduction path, a transverse heat dissipation network, optical multiple scattering and energy downshift radiation, stable chemical bond network support is achieved to realize high-efficiency, long-term reliable heat dissipation performance.