Disclosed is a surface treating agent for 
metallic materials that has various properties such as 
corrosion resistance and overcoating properties and, when used in 
coating-type surface treatment, particularly can form a film , which has excellent adhesion to the surface of 
metallic materials, and can fix, within the film, a component capable of functioning as a 
corrosion inhibitor for 
metallic materials. The surface treating agent for metallic materials comprises a 
silicic acid compound (A), an organoalkoxysilane (B), a metallic compound (C) containing at least one 
metal element selected from the group consisting of Zr, Ti, Co, Fe, V, Ce, Mo, Mn, Mg, Al, Ni, Ca, W, Nb, Cr, and Zn, at least one compound (D) selected from the group consisting of 
phosphoric acid compounds and fluoro compounds, water (E), and an 
alcohol (F) produced upon 
hydrolysis of the organoalkoxysilan (B). The 
molar concentration (mol / L) of the 
alcohol (F) in the treating agent has been regulated in a predetermined range.