1652results about How to "Strong oxidation ability" patented technology

The invention discloses a photochemical advanced oxygenation-based simultaneous desulfuration and denitration system. The system is provided with a burning and exhausting system consisting of a burner, an electrostatic dust collector, a heat exchanger, a spray tower, a liquid adding tower and a chimney, wherein fume generated by the burner enters the electrostatic dust collector, fume particles are removed from the fume by the electrostatic dust collector, the fume enters the heat exchanger and is cooled by the heat exchanger, and then the fume enters the spray tower; an UV light tube is arranged in the spray tower; hydrogen peroxide solution from the liquid adding tower is pumped by a circulating pump, sprayed into the spray tower through an atomizing nozzle and is activated by ultraviolet light to decompose hydrogen peroxide and then generate hydroxyl radicals (.OH) with strong oxidizing property; after being contacted with the fume in the spray tower, the hydroxyl radicals undergoes a gas-liquid absorption reaction with the fume to oxidize and remove NOx and SO2 in the fume; the fume, after being absorbed and washed, enters the chimney from the top of the spray tower and is exhausted; and sulfuric acid solution and salpeter solution generated in the spray tower are pumped into the separating column by the circulating pump and are reacted with added ammonia water to generate agricultural fertilizers including ammonium sulfate and ammonium nitrate.

A slurry for use in chemical mechanical polishing (CMP) of a metal layer. The CMP slurry includes an abrasive, a plurality of oxidizing agents, a stabilizer including an organic acid having a carboxyl group, a corrosion inhibitor which suppresses corrosion of a metal, a fluorine compound which reduces a difference in removal rates of a metal layer and a barrier layer, and deionized water. The plurality of oxidizing agents include a second oxidizing agent which oxidizes the metal and a first oxidizing agent which restores an oxidizing ability of the second oxidizing agent.

The invention relates to denitrition catalyst with a mercury removal effect. The catalyst has a chemical general formula of: MXn-V2O5-Y/TiO2, wherein, M is a metallic element selected from Fe, Cu, Mn or Co, X is halogen Cl or Br, Y is WO3 or MoO3, and n=2-4, and the elements are in a weight ratio of: 1-10 of M, 1-1.5 of V, 7.5-8.5 of W or Mo, and 75-100 of TiO2. The catalyst is prepared by the steps of: dipping V2O5-WO3/TiO2 or V2O5-MoO3/TiO2 with MCln or MBrn, then conducting frying and calcination. With the catalyst of the invention, catalytic reduction of NOx and catalytic oxidation of Hg<0> can be simultaneously completed in an original flue gas denitrition catalytic reactor, and the generated divalent mercury ions are washed and cured in desulfurized gypsum in a subsequent flue gas wet desulphurization process. Thus, cooperative control of the discharge of NOx and Hg<0> can be realized without increasing flue gas purification facilities of coal-fired power plants.

The invention discloses a self-cleaning water permeable brick comprising a surface material and a base material. The base material is weighed according to weight percentage, comprising 68.4 percent to 77.5 percent of rubble or building rubbish granule or slag, 10 percent to 25 percent of cement, and 5.3 percent to 12 percent of water. The surface material is weighed according to weight percentage, comprising 66.7 percent to 71.8 percent of high-intensity sand, 10.8 percent to 26.5 percent of cement, 3.4 percent to 10.4 percent of water, and 0.1 percent to 1.0 percent of nanometer titanium dioxide. The surface material and the base material are compacted together to form an integrated water permeable brick. The invention further discloses a preparation method of the self-cleaning water permeable brick. The method comprises the following steps: 1) the base material and the surface material are weighed, respectively premixed and then stirred as raw materials for standby application; 2) molding is carried out; 3) steam curing is carried out; and 4) liquid titanium dioxide is sprayed. Road surfacing of the self-cleaning water permeable brick in the invention can reduce water permeable hole plugging and surface pollution, thereby having the effects of road surface temperature decrease and high-efficient sterilization, regaining circulatory system of natural soil air and water, preventing soil pollution and improving ecological environment.

The invention relates to a method which uses ionic liquids extraction coupling tungsten, molybdenum and other polyoxometallate to catalyst oxidation so as to reduce the content of sulfur in the oil. The invention dissolves the catalyst into the ionic liquid and the volume ratio of the ionic liquid and the oil is 1:3 to 1:5, and the quantity range of the catalyst and the sulfur compounds is 1:100 to 4:100. The concentration of the aqueous hydrogen peroxide is 5 percent to 40 percent, and the content range with the sulfur compounds in the oil is 1:2 to 1:10. When the temperature is between 30 and 70 DEG C and the reaction time is 0.5 to 3 hours, coupling catalyst oxidation is extracted to reduce the content of sulfur in the oil to be less than 10 ppm. Compared with the traditional method, the method has the advantages that the sulfur has high removal efficient, and the reaction system is very simple, and the reaction condition is very soft and no pressure equipment is needed; the separation is very convenient and the ionic liquid can be recycled.

The invention provides a technique for treating and recycling lead-zinc ore dressing wastewater and aims to solve the problems of influence on the ore dressing index due to the recycling of the ore dressing wastewater for production and environmental pollution caused by drainage. The novel technique for treating and recycling the lead-zinc sulfide ore dressing wastewater comprises the steps of: adjusting the pH value of the total wastewater of an ore dressing plant; adding ferrous sulfate and flocculant into the wastewater to perform oxidation-coagulation treatment; and oxidizing the treated water by using chlorine dioxide, and performing catalytic oxidation and adsorption by using an active carbon bed, so that the treated water reaches the relevant discharge standard of China; and totally recycling the treated water by adopting the combined application of potential-controlled flotation and an environmental-protection collector. Compared with the field process technique, the method saves the cyanide flotation process and improves the recovery rates of lead, zinc and gold. The method provides whole technical integration of the combined application technique of the potential-controlled flotation and the environmental-protection collector and the wastewater treatment technique for the treatment and recycling of the lead-zinc ore dressing wastewater, and realizes recycling of the ore dressing wastewater.

The invention relates to an ecological restoration and purification method for water of lake and pool wet land. The method is characterized by comprising the following treatment steps sequentially: a first stage, a second stage and a third stage, wherein the first stage comprises the steps of pumping the water of the lake and pool wet land to dryness sectionally, performing activity, disinfection and dehydration treatment on sludge of the lake and pool wet land, prefabricating and mounting a submerged aeration facility, planting a submerged vegetation community, and filling in the water of the original lake and pool wet land; the second stage comprises the step of putting water purification bugs into the water for treating suspended matters in the water and purifying the water, such as algae and detritus; and the third stage comprises the steps of planting floating-leaved plants in the water, and configuring aquatic animals capable of eating partial aquatic plants for restoring a food chain of a water ecosystem. The method can ensure that the restored or purified water can reach a Category III or above primary indicator of Environmental Quality Standards for Surface Water (GB 3838-2002); the water purification effect is enduring; and both a symptom and a root cause are treated.

The invention discloses efficient heterogeneous catalytic oxidation ferric-carbon micro-electrolysis packing and a preparation method thereof. The packing is prepared from the following raw materials in parts by weight: 45-65 parts of pure iron powder, 10-25 parts of cast iron powder, 2-8 parts of graphite powder, 5-15 parts of active carbon powder, 2-10 parts of copper powder, 2-10 parts of manganese powder, 2-10 parts of aluminum powder, 2-10 parts of fine wood bits, 1-6 parts of sodium silicate, 1-6 parts of sodium borate, 2-6 parts of pyrite dust and 5-15 parts of an adhesive. The efficient heterogeneous catalytic oxidation ferric-carbon micro-electrolysis packing disclosed by the invention is prepared by taking heterogeneous metal alloy with high potential difference as a catalyst and using a high-temperature micropore roasting technology and has the characteristics of heterogeneous metal and ferric-carbon integration, micropore framework type alloy structure, large specific surface area, low density, strong activity, high current density and the like; organic wastewater is treated so that COD, ammonia nitrogen and total phosphorus can be efficiently removed, the chroma can be reduced, the biodegradability can be improved, the treatment effect is extremely stable, and the phenomena of packing passivating, hardening and the like caused in the operation process can be avoided.

The invention specifically relates to a regenerable heterogeneous Fenton catalyst, and a preparation method and application thereof, which belongs to the technical field of industrial catalysts. The catalyst provided by the invention uses commercial zeolite as a carrier and is prepared through the following steps: surface modification of the carrier with a high polymer; loading of an active component Fe or Co; and roasting so as to form an iron or cobalt compound-valence oxide on the surface of zeolite. The catalyst shows high-efficiency degradability to industrial intractable organic waste water containing phenols, dyes or the like, and the degradation rate of organic matters in waste water is up to more than 90% at room temperature (less than 30 DEG C) under an almost neutral condition (wherein a pH value is in a range of 6 to 8); and the catalyst has good regeneration performance. According to the method, the heterogeneous Fenton catalyst is used for oxidation removal of organic matters like phenols and dyes in waste water, so cost is low and no secondary pollution is produced; and a process for treating waste water with the Fenton catalyst is a promising organic waste water treatment process.

The invention discloses a heterogeneous-Photo-Fenton-based integrated smoke gas purification system. The smoke gas purification system generates a hydroxyl radical (.OH) with strong oxidizability by using heterogeneous Photo-Fenton to oxidize SO2, NO and Hg0 in the smoke gas into H2SO4, HNO3 and Hg2<+> respectively, wherein the H2SO4, the HNO3 and the Hg2<+> are fixed in solution; after reaction,a solid catalyst in mixed solution can be recycled through simple primary precipitation separation; a small amount of Hg2<+> in the solution can be generated into insoluble HgS by adding the same mole ratio of S2<->, and then the HgS is recycled through secondary precipitation separation; and the remaining sulfuric acid and nitric acid solution can be used as an industrial raw material to be further recycled. The whole integrated desulfuration, denitration and demercuration processes generate no secondary pollution, so the heterogeneous-Photo-Fenton-based integrated smoke gas purification system has a very good application prospect.

Provided are: novel rutile titanium dioxide nanoparticles each having a high photocatalytic activity; a photocatalyst including the rutile titanium dioxide nanoparticles; and a method for oxidizing an organic compound using the photocatalyst. The rutile titanium dioxide nanoparticles each have an exposed crystal face (001). The rutile titanium oxide nanoparticles may be produced by subjecting a titanium compound to a hydrothermal treatment in an aqueous medium in the presence of a hydrophilic polymer. A polyvinylpyrrolidone, for example, is used as the hydrophilic polymer. An organic compound having an oxidizable moiety can be oxidized with molecular oxygen or a peroxide under photoirradiation in the presence of the photocatalyst including the rutile titanium oxide nanoparticles.

The invention discloses a Fenton and air-float integral water disposal method, which comprises the following steps: adding Fenton agent into armed waste water; setting mass ratio of hydrogen dioxide solution of Fenton agent against COD of armed water at 0.3-3:1; reacting at 0.5-5 h; using alkality material to adjust Fenton agent armed water pH value at 6-10; proceeding floating treatment; setting air-float air-solid ratio at 0.03-0.06, surface loading at 7-15m3/m2.h and stopping time at 10-40 min; removing floating contaminant and most of dissolving organic contaminant.

The invention relates to a new method for non-aqueous phase wet oxidation of hydrogen sulfide by taking iron-based ironic liquid as an oxidant. The iron-based ironic liquid is highly hydrophobic liquid which is insoluble in water, and can effectively absorb hydrogen sulfide gas and quickly and efficiently oxidize the hydrogen sulfide gas into elemental sulfur. After centrifugation separation or filtering separation is performed on the sulfur, the iron-based ironic liquid is recycled after being oxidized by air or pure oxygen. Water produced in the recycling process can be automatically separated from the hydrophobic iron-based ironic liquid to prevent dilution of the iron-based ironic liquid by the water. The pH of a reaction system is not required to be adjusted in the process of oxidizing the hydrogen sulfide by using the iron-based ironic liquid, and the acidic characteristic of the iron-based ironic liquid prevents the generation of a sulfur-containing byproduct in the reaction process. Over 90 percent hydrogen sulfide removal efficiency can be achieved and secondary pollution is not caused during the non-aqueous phase wet oxidation of the hydrogen sulfide by adjusting the circulating flow of the ironic liquid and the flow of the hydrogen sulfide gas by an absorption-oxidation-separation-regeneration combined process.

The invention discloses a rechargeable magnesium battery taking oxygen-containing organic matter as a cathode material, and a preparation method of the rechargeable magnesium battery, wherein the oxygen-containing organic matter comprises the components of quinones, phenols, anhydrides derivatives and a compound containing nitro and oxygen radical. The battery and the method have the advantages of being simple in preparation technology, easy to process, environment-friendly and high in regeneration. The rechargeable magnesium battery prepared by the invention has the advantages of being relatively good in structural stability and circulation stability, rich in raw materials, safe in system and the like.

The invention belongs to the technical field of agricultural product deep processing and particularly relates to a safe sprout culture method. The method is characterized by including: purifying and sterilizing sprout seeds, subjecting the same to microwave treatment, soaking and budding treatment, treating with ethylene during budding, lighting the seeds requiring light, treating with ozone after budding, cleaning with ozone water and clean water after sprout harvesting, and packaging. Microwave treatment can evidently increase budding rate of the sprout seeds and increase sprout yield. Ultrasonic atomization treatment provides even and sufficient moisture for the sprouts to prevent sprout withering during growing. The ethylene and air generated from ethephon solution allows the sprouts to be short in roots and robust and bright in sprout body. The ozone treatment can effectively kill bacteria and remove odor, residue is avoided, the sprout bodies are white in appearance, and the quality of the sprouts is improved.

The invention relates to a method for transplanting cotton seedlings. The method comprises three steps of preparation of a matrix, sowing and transplanting sequentially. Step 1, cotton stalks, rape stalks, corn stalks, soybean stalks or wheat straws are crushed, added with a nitrogenous fertilizer, and mixed with human excrement or livestock and poultry manure bio-fertilizer or other fertilizers to obtain a mixture which is treated to obtain a prepared material, then the prepared material is sun-dried or baked, added with a fungicide and bagged for spare use; step 2, the prepared cotton stalk matrix or the matrixes prepared from other stalks are filled in a seedling raising aperture disk or flatly spread on a plastic film laid on the ground as a seedbed, seeds are sown, watered and covered with an agricultural film, and seedlings are raised under heat insulation condition; step 3, an antitranspirant and a rooting agent are applied before transplanting; the taken seedlings are bound, put in the watered rooting agent solution for root soaking, and then taken out and put in a watered gel containing a water retention agent to dip the roots; when in transplantation, the water retention agent is applied to planting furrows; after transplantation, the seedlings are covered with soil, and irrigated with adequate water for fixing the roots. The method is characterized by high seedling survival rate, stable effect, short rejuvenation period, low cost and environmental protection.

The invention relates to energy ceramic with antimicrobial, easy cleaning and water activation functions and a preparation method for the energy ceramic, and belongs to the field of special ceramic materials. An enamel layer is arranged on the surface of a ceramic blank; the ceramic blank is prepared by the following raw materials in mole percentage: 2 to 10 percent of rare earth material, 2 to 10 percent of high-performance sepiolite material, 6 to 15 percent of high-performance tourmaline material and 65 to 85 percent of functional ceramic mud; and the functional ceramic mud consists of 98 to 99 mass percent of ceramic mud and 1 to 2 mass percent of functional material. The preparation method comprises the following steps of: preparing the functional ceramic mud; mixing the 98 to 99 mass percent of ceramic mud and 1 to 2 mass percent of functional material by a ball grinding machine for 10 to 12 hours to obtain the functional ceramic mud; then preparing the blank, forming and biscuiting; and enameling and performing glaze firing to obtain the energy ceramic. The product is antimicrobial, fresh, easy to clean and sanitary, and can activate water and keep people in good health.