359 results about "Oxidizing acid" patented technology

The improved process for preparing high strength porous microsphere active carbon includes the following steps: oxidizing thermosetting resin ball at 60-400 deg.c in oxygen containing atmosphere or pre-treating thermosetting resin ball at 60-300 deg.c in oxidizing acid, SO2 or SO3; carbonizing at 600-1200 deg.c in helium, nitrogen or their mixture atmosphere; and activating at 600-1200 deg.c in activating water vapor atmosphere to obtain high strength porous microsphere active carbon with grain size of 10 micron to 2 mm, BET specific surface area of 500-4000 sq m/g, and grain strength of 50-200 MPa. The process is simple, low in cost and high in yield, and the prepared microsphere active carbon has high strength and high purity and is one excellent medical active adsorption material.

The invention relates to a preparation method of a single-walled carbon nanotube metal-organic framework in the nanotechnology field, which comprises the following steps: a. mixing 1 weight proportion of dried single-walled carbon nanotube with 50-5000 weight proportions of strong oxidizing acid to be processed by ultrasonic treatment, stirring to react, sucking filtration and washing until the solution is neutral, and obtaining acidulated carbon nanotube after drying; b. adding zinc acetate aqueous solution drop by drop, stirring to react, sucking filtration and washing, dispersing the product in an organic solvent again, sucking filtration once again, and obtaining the product SWNT-MOF-1 after drying; c. mixing the SWNT-MOF-1 and the organic solution to be processed by the ultrasonic treatment, adding the organic solvent solution of an organic ligand, stirring to react, cooling, adding the organic solvent to leach, sucking filtration, dispersing the black products in de-ionized water again, sucking filtration once again, dialyzing the black products, and obtaining the final products after drying. The method is simple and the material with both the perfect structure of the single-walled carbon nanotube and the structure of the metal-organic framework can be obtained.

The invention discloses a method for comprehensively recycling silver, selenium, tellurium and copper from telluride copper slag. The method comprises the following steps of (1), oxidizing acid leaching, wherein the telluride copper slag is added into a sulfuric acid solution containing an oxidizing agent to be heated and stirred so as to be leached, after filtering, copper sulfate leaching liquid and acidic leaching residues are obtained, and the leaching liquid is conveyed to a furnace for copper recycling; and (2) alkali leaching separation, wherein the acidic leaching residues are added into sodium hydroxide solutions to be leached, sodium tellurite solutions and basic leached residues are obtained, the basic leached residues are sent to the KALDO furnace for smelting, so that the silver and the selenium are recycled, and after purification, tellurium deposition, forging and electrolysis of the alkali leaching liquid, refined tellurium is obtained. According to the method, the recycling rate of the silver, the selenium, the tellurium and the copper is high, the silver, the selenium, the tellurium and the copper are not lost, the concentration ratio is high, the silver, the selenium, the tellurium and the copper can be separated from other impurities well, the pollution to the environment is small, the technology is simple, and needed equipment cost is low.

This invention discloses a wet method for treating high In-Fe-S Zn concentrate by oxidative acid leaching. Compared with traditional high-pressure leaching technique, the method obviously reduces the operation temperature and pressure. Ore slurry composed of Zn concentrate, surfactant and sulfuric acid aqueous solution is operated at 95-105 deg.C under 0.2-0.4 MPa. The surfactant is sodium or calcium lignosulfonate, which can change the hydrophobicity of sulfide and sulfur, raise the leachin speed, and improve the suspension fluidity of the ore slurry. Since the operation temperature is lower than the normal pressure boiling point of the solution system, normal rubber pipe pump can be used to replace oil diaphragm high-pressure slurry pump, and Ti heat exchanger and vacuum flash evaporator are not needed. The leaching rate of Zn and In is up to 95-99%, and the yield of S is higher than 80%. The leaching solution can be treated according to normal method to recover valuable components, with total recovery rate of In up to 90-95%.

The invention relates to a preparation method of a multicomponent-modified carbon-fiber-reinforced epoxy resin composite material, which comprises the following steps: oxidizing carbon nanotubes (CNTs) with strong acid; carrying out acyl-chlorination and amination on the oxidized CNTs sequentially with thionyl chloride and diamine to introduce amino functional group; oxidizing carbon fiber with strong oxidizing acid, and carrying out acyl-chlorination treatment with thionyl chloride to introduce acyl chloro group; mixing the prepared modifying CNTs and modifying carbon fiber to perform graft reaction, thereby obtaining the CNTs-grafted carbon fiber; mixing the CNTs-grafted carbon fiber with polyhedral oligomeric silsesquioxane (POSS) to perform graft reaction, thereby obtaining the binary POSS-grafted carbon fiber; and sufficiently infiltrating the binary POSS-grafted carbon fiber in the base resin, and carrying out hot pressing to perform curing formation. The CNTs and POSS cografted on the carbon fiber surface can improve the surface topography of the carbon fiber, increase the contact area with the resin base and penetrate into the resin base under the anchoring action, so that the interfacial mechanical mesh action is higher.

The present invention is the production process of aluminum template with nano holes, and is especially the combined anode oxidation and ion bombardment process of producing aluminum template with nano holes in high density and high order. The technological process includes annealing aluminum foil, cleaning, electrochemical polishing, anode oxidation in water solution of oxidizing acid, such as sulfuric acid, oxalic acid, phosphoric acid, to form alumina film, ion bombardment to form holes in the film physically, water rinsing and stoving. The technological process is simple and low in cost, and the holes are densely distributed in certain order and have controllable shape and size of several nano to 100 nano. The said template may be used widely in direct assembling of nano device except its traditional industrial application.

A zinc or zinc/alloy surface of a metal artifact is protected by passivating or activating the surface with a solution comprising an oxidizing acid or activating acid; applying to the surface an aqueous priming solution of an alkali metal permanganate in the presence of halogen ions, with the solution having a pH of about 1 to 8; and then further applying to the surface an aqueous sealing solution such as a lithium silicate and a sodium or potassium silicate solution. Strong corrosion protection can be achieved. Improvements may also be obtained with the addition of a rare earth salt to the priming solution.

A special fertilizer for Chinese goosebeery is prepared by oxidizing and modifying humic acid into humate and adding nitrogenous fertilizer, phosphorus fertilizer and potash fertilizer. The preparation process comprises the following steps: (1) humic acid modification: oxidizing humic acid material with oxidizing acid and adding sulphite for modification to obtain humate; (2) chelation: adding potash fertilizer and compound fertilizer auxiliary material into the humate, and leading steam into a reaction kettle, heating to more than 80 DEG C and preserving the temperature for chelation for more than 8 h; (3) mixing: after the chelation, adding nitrogenous fertilizer and phosphorus fertilizer and mixing; and (4) thickening: adding micro conditioner for thickening, measuring and packing. In the invention, through adding modified HA salt, the original special fertilizer (M fertilizer) for Chinese goosebeery is further processed, and the pure inorganic fertilizer in the M fertilizer is changed into an organic-inorganic compound fertilizer with different characteristic, so that the operating factor of the fertilizer is improved by 14 percent through the fertilizer modification.

The invention belongs to the technical field of sewage treatment, in particular to a method for preparaing dephosphorized and ferrum-carried activated carbon adsorbent, which comprises the following steps of: soaking powdered activated carbon through hydrochloric acid, washing through water, and drying at the temperature of 100-150 DEG C; injecting the obtained activated carbon into strong oxidizing acid solution so as to be soaked, rinsing, and drying a rinsed sample; and finally, mixing the obtained activated carbon and inorganic ferric salt solution, stirring, re-drying, cooling to room temperature, removing surface layer coverings, washing unloaded ferric oxide through water until rinsing to be without obvious color and without red color through test by potassium rhodanide solution, and drying continuously to obtain the high-efficient dephosphorized activated carbon adsorbent rich in iron oxide compound. Compared with the prior art, the method has the advantages of simplicity, moderate preparing condition, easiness in implementation, strong operability, high processing efficacy for waste water containing phosphorus, and purification cost reduction.

The invention provides a gradient arsenic removing method for high-arsenic metallurgical wastes, which is generally suitable for comprehensive arsenic removing treatments of high-arsenic smoke dust generated in the smelting process of lead, zinc, antimony, copper, tin and the like, high-arsenic anode mud generated in the electrolytic process of wet lead, silver, copper and the like and other metallurgical wastes. The method comprises two stages of water leaching arsenic removal and oxidizing acid leaching arsenic removal and specifically comprises the following steps of: first, selectively dissolving out free arsenic trioxide and water soluble arsenate (like sodium arsenate and potassium arsenate) through water leaching; and then further leaching out indissolvable arsenate and arsenic sulfide in the water leaching residue as well as little incomplete arsenic trioxide dissolved out by water by using a mixed leaching liquor of acid and water soluble oxidizing agent. The method provided by the invention has the advantages of low consumption of acid and alkali, high arsenic removing efficiency, safety, environment friendliness and suitability for arsenic removing treatment of various arsenic contained metallurgical wastes, in particular for arsenic removing treatment of the smoke dust with high content of free arsenic trioxide.

There is provided a hydrometallurgical process of recovering indium and gallium values from mixtures thereof with other metal values for example recycled and scrap solar panel cells which comprises subjecting the mixture to strongly oxidizing acid conditions, preferably via the simultaneous addition of sulfuric acid and hydrogen peroxide to the leach vessel, so as to form indium and gallium salt species of at least the major proportion of the indium and gallium values in the mixture, extracting the indium and gallium values with an organic extractant by adjusting the pH so as to extract individually the indium and gallium values with the organic extractant, stripping indium and gallium values from the extractant using an acid and an alkaline solution respectively and recovering the indium and gallium values.

A process for preparing the chitosan-carbon nanotube composition by covalent graft includes such steps as acidifying carbon nanotubes by strong-oxidizing acid to make its surface to carry carboxy radicals, converting them to acylchlorinated carbon nanotubes by sulfoxide chloride, and reaction between said carbon nanotubes and the chitosan in N,N-dimethylformamide and/or N,N-dimethylacetoamino pyridine at 120-140 deg.C.

The invention discloses a method for preparing a metal nano-particle modified polysaccharide wrapped carbon nano tube in the technical field of nano composite materials. The method comprises the following steps: placing a carbon nano tube raw material in oxidizing acid and mixed acid in turn, performing ultrasonic truncation treatment on the solution, mixing the treated solution and polysaccharide solution to obtain polysaccharide wrapped carbon nano tube solution, then reducing a metal precursor to obtain a metal crystal seed modified carbon nano tube by using a strong reducing agent, and finally reducing a metal salt precursor to obtain a series of metal nano-particle modified polysaccharide wrapped carbon nano tubes with different growth degree by using a weak reducing agent. The method can improve the dispersion of the carbon nano tube in the water, effectively fix the metal nano-particles and control the modification density and grain size of the metal nano-particles, further cancontrol the plasma resonance absorption performance of the surface metal nano-particles, and is expected to be applied in the fields of targeted detection of cancer cells, photo-thermal treatment, biosensors and the like.

The invention relates to a method for separating tin and stibium from tin-lead anode slime. The method comprises the following steps: firstly performing oxidizing leaching on the tin-lead anode slime with hydrochloric acid and sodium chloride to cause most the tin, the stibium, bismuth and copper and the like to enter leaching solution and separate from the lead and the silver, then selectively precipitating the tin in the leaching solution in the form of ammonium chlorostannate by ammonium chloride to realize separation of the tin from the stibium, the bismuth and the copper; then depositing copper in filtrate by sodium sulfide, then hydrolyzing the solution after copper deposition to obtain crude antimony oxychloride, and finishing separation of the tin and the stibium. Compared with the prior art, the method helps reduce hydrochloric acid consumption by over 40% and reduce about half of the production cost.

The invention discloses a dephosphorization flocculating agent and a preparation method thereof. The dephosphorization flocculating agent is formed by compounding an inorganic flocculating agent and an organic flocculating agent. The raw materials of the inorganic flocculating agent comprise sodium ferrate, borax, ferrous sulfate, silicate or aluminate; the raw materials of the organic flocculating agent comprise modified chitosan or modified polyacrylamide. The preparation process comprises the following steps: firstly adding a non-oxidizing acid into the silicate or aluminate to obtain a polysilicate colloid or an aluminum hydroxide colloid, then adding a borax solution and a sodium ferrate solution sequentially while stirring, further dropping a ferrous sulfate solution, mixing to form the inorganic flocculating agent, standing, then adding the modified polyacrylamide or modified chitosan into the inorganic flocculating agent, curing and adding the acid till the pH value is less than 7 to obtain the finished dephosphorization flocculating agent. The flocculating agent is suitable for a wide range of water quality, is little affected by co-existing salts, the pH value of sewage and temperature and is particularly effective for dye wastewater, oilfield sewage and the like.

The invention provides a method for modifying carbon fibers by dendritic macromoleculars, relating to a method for modifying the carbon fibers and aiming at solving the problem of poor stability due to that only one functional group of organic silicon compound can react with the fiber modified surface so as to limit a membrane in a bidimensional surface. The method comprises the following steps: adding carbon fibers in a strong oxidizing acid, utilizing ultrasonic for processing, heating and refluxing, drying, adding into dendritic macromolecular solution for ultrasonic processing once again, reacting under the temperature of 20-100 DEG C, washing and drying to obtain the carbon fibers modified by the dendritic macromoleculars. The dendritic macromoleculars used in the invention have the advantages of tri-dimensional structure, evenly-distributed and thick outer functional groups, lower viscosity, unique flowing deformation property, good film forming property and favorable modified effect. The epoxy resin composite material prepared by using the carbon fibers modified by the dendritic macromoleculars obtained in the invention has 53.2-55.8MPa of interface shearing strength.

Disclosed is a modification method for native graphite materials used for lithium ion batteries. The method comprises the following steps that native graphite powders are placed into an autoclave, dense oxidizing acid, oxidizing salt and hydrochloric acid are used for oxidation treatment, wherein the oxidation treatment proceeds at a temperature ranging from 180 to 250 DEC G, the native graphite materials which are washed or not are centrifugalized, then native graphite materials which are centrifugalized are calcined, semi-modified native graphite materials are gained, silanization film forming treatment is completed on the semi-modified native graphite materials, then tetrahydrofuran is used to wash and dry the native graphite materials, thereby obtaining modified native graphite materials. The modified native graphite materials are capable of satisfying the application of the lithium ion batteries, have the advantages of high cost performance, low costs, large specific capacity, perfect circulative property and higher initial charge and discharge efficiency, and simultaneously are adapted to the negative pole application of high-current charge and discharge lithium ion batteries.

The invention provides a phosphorus-doped graphene quantum dot and an electrochemistry preparing method thereof. According to the preparing method, phosphorus-contained macromolecular organic compounds soluble in water are selected to serve as electrolytes, through controlled potential electrolyzing, phosphorus oxygen bonds are broken, phosphorus atoms are separated from the macromolecular organic compounds to enter the interior of the graphene quantum dot, carbon phosphorus bonds and the phosphorus oxygen bonds are formed, doping is completed, and the phosphorus-doped graphene quantum dot with the higher doping concentration content is prepared; the quantum dot has the good cleaning-up effect on hydroxyl radicals, and through ESR energy spectrum test, the clearing-up rate of the hydroxyl radicals can reach 78.49%; the method is easy and convenient in the operation process, the whole preparing process is conveniently planed as a whole, strong oxidizing acid or strong reducing agents are not used, and certain commercial feasibility is achieved; and graphene precursor which is rich in reserving and friendly to environment is adopted to replace expensive materials of graphite oxide, carbon nano-tubes and the like, and the method is hopefully and widely applied in the biomedical field.

The invention discloses a method for recycling uranium from uranium extraction coal residue with a wet method, which comprising the following steps: (1) particle size requirements: crashing the coal residue below 200 meshes; (2) oxidation and acid leaching: in a dilute sulphuric acid-hydrofluoric acid medium, using peroxide as an oxidizer to carry out reverse oxidation leaching twice; (3) desilicification and purification: using ammonia to adjust the pH value of once leaching filtering liquid of the uranium to 9.8-10.2, enabling the silicon in the solution to become silicic acid sediments, after filtering, carrying out ion exchange on the filtering liquid, desilicificating slag and stockpiling; (4) ion exchange: using a 717 type ion exchange resin to carry out exchange absorption by the filtering liquid, and then using 1 mol/L of NaCl-0.1 mol/LH2SO4 of mixed solution to elute the resin, after using tributyl phosphate to carry out extraction and back-extraction on eluent, obtaining uranium concentrates containing about 65% of the uranium. The invention successfully extracts and separates the uranium from the uranium extraction coal residue to produce the uranium concentrates, has t high recycling rate of uranium as high as 80-85% and low cost, and comprehensively utilizes the uranium extraction waste, thereby eliminating the influence of the radiation wastes on the ecological environment.

The invention relates to a process for treating waste water containing alkali and oil. The process comprises the following steps: neutralizedly treating the waste water containing alkali and oil; thensequentially carrying out inclined plate precipitation, tapes filtration and ultra-filtration treatment; finally discharging. The neutralization is achieved in a step that the waste water containingalkali and oil is neutralized by adding oxidized acid, and meanwhile, emulsion breaking, delamination as well as oil-water separation are carried out also by same. The process adopts neutralization and flocculation firstly and then carries out ultra-filtration treatment, after which the water quality is good, and less chemical agents are used.

The invention relates to a method for preparing a multiwall carbon nano-tube (MWCNTs)/cobalt zinc ferrite (Co1-xZnxFe2O4) magnetic nanocomposite material, which comprises the following steps of: (1) mixing a strong oxidizing acid and MWCNTs in a mass ratio of 1:200-1:400 and reflowing the solution in an oil bath after ultrasonic dispersion; and (2) dispersing the acidized MWCNTs into solution of ethylene glycol at room temperature, weighing a ferric salt, a zinc salt and a cobalt salt, dissolving the salts into the solution, adding polyethylene glycol and anhydrous sodium acetate after the added salts are fully dissolved, mechanically stirring the mixture, putting the mixture into a high-pressure reaction kettle for reaction after polyethylene glycol and anhydrous sodium acetate are fully dissolved, cooling the mixture to room temperature, and washing, collecting and drying a product. The magnetic nanocomposite material prepared by the method has the advantages of pure crystalline phase, high dispersibility, difficult agglomeration, high magnetization intensity and high magnetic induction sensitivity; and the method has the advantages of simple preparation process, relatively lower requirements on production equipment and easy industrial production.

The invention discloses a method for modifying natural graphite. The method comprises the steps of: (1) using oxidizing acid or salt to carry out oxidation treatment on the natural graphite to obtain an intermediate product graphite A; (2) centrifuging, washing and drying the graphite A to obtain an immediate product graphite B; (3) dissolving a polymer which is used as a shell material into an organic solvent to obtain a polymer solution; (4) adding the graphite B into the polymer solution, stirring the mixture, thus uniformly soaking the graphite B into the polymer solution, stewing the mixture, and evaporating an organic solvent, sieving the mixture to obtain graphite C; (5) curing the graphite C for 0.2-12 hours at 100 DEG C to 600 DEG C under the protective atmosphere to obtain graphite D; (6) carbonizing the graphite D for 1-24 hours at 700 DEG C to 1500 DEG C to finally obtain the modified graphite to be prepared in the invention. According to the method disclosed by the invention, the process is simple, the control is easy, the price is low, and the industrial application is facilitated.

The invention discloses a preparation method of a retarding and water reducing agent. The preparation method comprises the following steps: 1) oxidization: oxidizing the raw material sweet potato starch; 2) acidification: acidifying the oxidized sweet potato starch with hydrochloric acid; and 3) etherification: adding ethylene oxide to the acidified oxidized sweet potato starch in the nitrogen environment to obtain the retarding and water reducing agent. The preparation method of the retarding and water reducing agent provided by the invention has the beneficial effect that the simple and easy-to-get raw material sweet potato starch is taken as the major raw material, and the operation of the preparation method is simple and convenient.