1233 results about "Hydrometallurgy" patented technology

The invention relates to the technical field of heavy metal wastewater treatment devices, in particular to heavy metal wastewater treatment equipment for molybdenum concentrate hydrometallurgy, which comprises a mixing barrel, a layering plate is fixedly mounted in the mixing barrel, a water inlet pipe is arranged below the mixing barrel in a penetrating manner, a water outlet pipe is arranged above the mixing barrel in a penetrating manner, and the upper end of the layering plate is fixedly connected with a central pipe. A chemical feeding device is arranged in the center pipe, a driving face shell is fixedly installed at the bottom end of the layering plate, a driving device is arranged between the driving face shell and the center pipe, and a blade plate is rotationally installed at the inner end of the driving face shell; through the Karman vortex street effect formed by the front end cambered surface and the tail end sharp corner structure of the water-drop-shaped blade plate in the wastewater flowing process, the tail end of the blade plate swings periodically, and the swinging frequency is automatically adjusted along with the change of the water flow speed, so that the medicine applying speed synchronously changes along with the water flow speed.

The embodiment of the invention provides a pipeline blockage monitoring method and system for wet metallurgy slurry conveying, and belongs to the technical field of pressure measurement and pipeline blockage monitoring. The method comprises the following steps: collecting multi-point pressure signals along a slurry pipeline, and extracting pressure pulsation amplitudes and phase characteristics in a pump fundamental frequency and frequency multiplication range based on the multi-point pressure signals so as to establish an on-way pulsation transmission sequence; determining equivalent on-way impedance based on comparison between the on-way pulse transmission sequence and a reference working condition, and outputting an initial judgment result for representing a blockage risk; flow temperature and viscosity estimation parameters are introduced based on the initial judgment result to carry out rheological correction on an impedance threshold value, and a high-frequency phase difference is extracted at an elbow section to update a candidate blockage position; and based on the updated candidate blockage position and the corrected impedance threshold, fusing a phase stability index, and generating and outputting a current blockage evaluation result. According to the scheme, early-stage accurate positioning and stable judgment of slurry pipeline blockage can be achieved under complex working conditions.

The invention provides an environment-friendly cyanide-free gold leaching agent and a technology for extracting gold in electronic waste through the environment-friendly cyanide-free gold leaching agent, and belongs to the technical field of hydrometallurgy. A series of environment-friendly cyanide-free gold leaching agents are prepared by designing the environment-friendly cyanide-free gold leaching agents, using non-toxic and renewable biomass resources as raw materials, optimizing the molecular structure level of the raw materials through a series of derivatization means and introducing specific functionalized molecular groups. The problem that an existing cyanide-free leaching agent is difficult to treat electronic waste is solved. On the premise that technology feasibility is met, balance of economy and environment is achieved to the maximum extent, the gold leaching technological process is simple, operation is convenient, the gold leaching technological process conforms to original facilities of existing enterprises, and extra equipment upgrading cost does not need to be input.

The invention discloses a deep learning and automatic control chemical reactor and a resource recovery method, and relates to the technical field of hydrometallurgy, and the deep learning and automatic control chemical reactor comprises a chemical reactor, a motor, a heating device, a monitoring device, a data center and a PLC control system. Based on a PLC control system, a Transform-LSTM time sequence prediction model is integrated, so that real-time monitoring of parameters such as mixed liquid temperature, reaction chamber pressure, mixed liquid viscosity, conductivity and the like in a wet leaching reaction process can be realized; and the heating power of the heating device, the rotating speed of the motor, the raw material adding amount of the feeding port, the mixed material discharging time of the discharging port and the air displacement of the air exhaust port can be automatically and accurately controlled. The problems that stirring efficiency is low, parameter regulation and control are lagged, and manual experience is relied on are solved, through a predictive control strategy, the real-time monitoring and dynamic regulation level is remarkably improved, the wet leaching process is optimized, energy consumption is reduced, the high-grade metal leaching efficiency is improved, and the method is suitable for various wet metallurgy processes.

The invention belongs to the field of hydrometallurgy, and particularly relates to an extraction organic phase for selectively extracting niobium in a niobium-containing sulfuric acid solution and an extraction method, the extraction organic phase comprises a component a, a component b and a hydrophobic solvent; wherein the component a is a compound with a structure # imgabs0 # as shown in a formula 1; the component b comprises at least one of TBP (tributyl phosphate), MIBK (methyl isobutyl ketone), sec-octanol or isooctanol; r1 is alkyl of C1-C2, and R2 is alkyl of C1-C2; r < 2 > is alkyl of C < 7 > to C < 11 >; a is HCO3 <-> or CO3 < 2->; n is the absolute value of the valence of A. Based on the combination of the component a and the component b, the extraction rate of niobium in the sulfuric acid solution and the extraction separation selectivity of niobium and other elements can be further improved based on the combination and synergy of the components.

The invention discloses a preparation method of a polymeric cyanamide low-toxicity gold leaching agent, and belongs to the field of hydrometallurgy. The preparation method comprises the following steps: uniformly mixing urea, sodium carbonate and ferrous chloride and finely grinding; then putting the fine grinding material into a high-temperature heating container, gradually raising the temperature, and preserving the heat; gradually cooling the reaction product to room temperature along with the furnace; and finally, a reaction product is crushed and ground into powder, and the polymeric cyanamide low-toxicity gold leaching agent is obtained. The synthetic raw materials of the gold leaching agent are simple, cheap and easy to obtain, the synthetic process is simple and easy to regulate and control, and the synthetic cost is low. The gold leaching agent obtained through the method is low in toxicity, the gold leaching speed is high, the gold leaching rate is high, and leaching tailings are common solid waste and are easier to treat.

The invention provides a method for recycling scandium, iron and aluminum from acid leachate through fractional precipitation, and belongs to the field of hydrometallurgy. The method comprises the following steps: adding a reducing agent into an acid leaching solution to obtain a first modified leaching solution; adding a stable complexing agent into the first modified leaching solution to obtain a second modified leaching solution; adding a pH regulator into the second modified leaching solution, and regulating the pH value of the second modified leaching solution to 3.5-4.5 to obtain a coarse scandium product and a scandium precipitation solution; an oxidizing agent is dropwise added into the scandium precipitation solution, and an iron product and an iron precipitation solution are obtained; and adding a pH regulator into the iron precipitation liquid to regulate the pH value of the iron precipitation liquid to be greater than or equal to 6.0, and carrying out ultrasonic enhanced aluminum ion precipitation to obtain an aluminum product and an aluminum precipitation liquid. Selective modification of metal ions is achieved by adding a reducing agent and a complexing agent, scandium is precipitated through pH regulation and control, iron is precipitated through oxidation regulation and control, and finally complexation and precipitation of aluminum are blocked, so that the separation efficiency of scandium, iron and aluminum in the acid leaching solution is improved at the same time.

The invention relates to the technical field of hydrometallurgy, in particular to a method for selectively leaching and separating cobalt and manganese from crude cobalt hydroxide leaching residues. The separation method provided by the invention comprises the following steps: S1, pre-reduction treatment; and S3, cobalt is leached through selective oxidation, and manganese is precipitated. According to the separation method, the synergistic effect of ORP and pH is regulated and controlled, proper reducing agents and oxidizing agents are selected, cobalt is selectively leached through step-by-step oxidation, dissolution of manganese is inhibited, manganese circularly entering a leaching and extraction system is reduced, the leaching and extraction operation cost is reduced, meanwhile, a selective complexing agent is introduced, impurity co-dissolution is reduced, the subsequent purification process is simplified, and the method is suitable for industrial production. The preparation method is simple to operate and easy for industrial production, and has a good application prospect.

The invention provides a method for recovering lithium in lithium precipitation mother liquor, which belongs to the technical field of hydrometallurgy and comprises the following steps: (1) activating a titanium adsorbent: activating the titanium adsorbent by using an acid solution; (2) adsorption: adsorbing lithium in the lithium precipitation mother liquor by using an extruded titanium adsorbent; (3) material washing: washing the adsorbent after adsorption by using pure water; (4) analysis: carrying out circulating analysis on the washed adsorbent by using hydrochloric acid with corresponding concentration to obtain a lithium-rich analysis solution; and (5) refluxing the lithium-containing desorption solution to the lithium precipitation unit. The extruded adsorbent used in the invention has high adsorption capacity and good ion selectivity, and by using the method, the high lithium recovery rate can be ensured, the interference of carnallite ions on lithium recovery can be avoided, the energy consumption is low, and the reduction of the operation cost is facilitated.

The invention belongs to the field of hydrometallurgy, and particularly discloses a high-purity vanadium oxide electrode and a preparation method thereof. The method comprises the following steps: pre-treating the alkaline vanadium leaching solution by using an activated aluminum oxide adsorption column to obtain a pre-treated solution; adding a composite impurity removal agent taking modified lignosulfonate as a main agent into the pretreatment liquid for primary impurity removal to obtain primary impurity-removed filtrate; adding a calcium hydroxide suspension and a flocculating agent into the primary impurity-removed filtrate for secondary impurity removal to obtain secondary impurity-removed filtrate; purifying the secondary impurity-removed filtrate by using an ion exchange column to obtain a purified solution; ammonium salt is added into the purified liquid for vanadium precipitation, and ammonium metavanadate crystals are obtained; calcining the ammonium metavanadate crystal to obtain high-purity vanadium pentoxide; and preparing the high-purity vanadium oxide electrode by using the high-purity vanadium pentoxide. According to the scheme, the high-purity vanadium pentoxide is prepared by taking the alkaline vanadium leaching solution as a raw material through a multi-stage deep impurity removal process, and the high-purity vanadium oxide electrode is prepared by taking the alkaline vanadium leaching solution as the raw material.

The invention belongs to the field of hydrometallurgy, and particularly relates to a method for extracting niobium and / or scandium in a phosphoric acid solution system, which is characterized in that the phosphoric acid solution system containing niobium and / or scandium and an extraction organic phase are subjected to auxiliary extraction under a composite field of ultrasonic-magnetic field to obtain a loaded organic phase. Innovative research shows that extraction is carried out under an ultrasonic-magnetic field composite field, the final physicochemical characteristics of niobium-scandium in a phosphoric acid solution can be adapted accidentally, excellent extraction capacity can be obtained accidentally, and especially excellent scandium-niobium separation selectivity can be obtained under a composite phosphoric acid system containing niobium and scandium.

The invention relates to a method for extracting tungsten and molybdenum from low-grade tungsten-molybdenum ore, belongs to the technical field of non-ferrous metal hydrometallurgy, and solves the problems of harsh conditions, low extraction efficiency, high cost and environmental pollution when tungsten and molybdenum are extracted from low-grade tungsten-molybdenum ore in the prior art. The method comprises the following steps: leaching the low-grade tungsten-molybdenum ore by adopting sulfuric acid, and carrying out solid-liquid separation to obtain a leaching solution and leaching residues; extracting molybdenum from the leachate by adopting a cationic extraction agent to obtain tungsten-containing molybdenum extraction raffinate and a negative molybdenum organic phase; and extracting tungsten from the tungsten-containing molybdenum extraction raffinate by adopting a neutral extraction agent to obtain tungsten extraction raffinate and a negative tungsten organic phase. The method is carried out at normal temperature and normal pressure, the complexing characteristic of molybdenum to tungsten in the low-grade tungsten-molybdenum mixed ore under the acidic condition is ingeniously utilized, synergistic leaching of tungsten and molybdenum is achieved, the tungsten and molybdenum extraction efficiency is high, operation is easy and convenient, complexing agents such as phosphoric acid do not need to be added, and the leaching cost is greatly reduced; and the method is clean and environment-friendly, and development and utilization of low-grade tungsten-molybdenum ore are promoted.

The invention relates to the technical field of rare earth metal hydrometallurgy, in particular to a rare earth molten salt electrolysis truss type multifunctional metal output system and a control method.The system comprises a main body supporting and moving frame, an integrated function execution module set, a bottom cleaning function module, an electrolytic bath station unit and an intelligent control system; wherein the integrated function execution module group, the bottom cleaning function module, the electrolytic tank station unit and the intelligent control system are respectively arranged in the main body support and motion frame, and the main body support and motion frame is arranged in a gantry truss structure; the four functions of pot lifting, casting, cooling and bottom cleaning in rare earth electrolysis are integrated on the integrated bearing platform of the same gantry truss type rack, and through multi-sensing information fusion and intelligent control, the system can automatically complete the whole process operation of crucible extraction, molten metal casting, cooling forming and electrolytic bath bottom cleaning; and the exposure of workers in high-temperature and high-risk environments is obviously reduced, and the production safety and efficiency are improved.

The invention belongs to the field of hydrometallurgy, and particularly relates to a preparation method of a chromium-doped manganese lithium ion sieve and application of the chromium-doped manganese lithium ion sieve in lithium extraction. The preparation method comprises the following steps: by taking a lithium source, a manganese source and a chromium source as raw materials, synthesizing a chromium-doped spinel type lithium ion sieve precursor through a high-temperature solid-phase method, and further performing acid leaching treatment, thereby obtaining the ion sieve with high adsorption selectivity and low manganese solution loss. The method is simple in process and low in cost, and the prepared chromium-doped manganese lithium ion sieve is stable in crystal structure and low in manganese solution loss rate. The developed chromium-doped manganese lithium ion sieve is suitable for efficient extraction of lithium resources of salt lake brine, and a low-cost solution is provided for efficient extraction of the lithium resources of the salt lake.

The invention discloses a preparation and application method of active magnesium oxide for cobalt precipitation, which comprises the following steps: adding acetate during preparation of an active magnesium oxide precursor magnesium hydroxide to obtain magnesium hydroxide with a double-tooth structure; when magnesium oxide is prepared through calcination, conversion from magnesium hydroxide to magnesium oxide can be achieved at a low temperature, and meanwhile high activity is obtained; and finally, the magnesium oxide slurry is added into the cobalt precipitation pre-solution for cobalt precipitation, the cobalt precipitation effect is good, and the obtained coarse cobalt hydroxide cobalt is high in grade. The magnesium hydroxide regulating agent is used for promoting generation of magnesium oxide rich in active sites, the magnesium hydroxide regulating agent is applied to the wet metallurgy cobalt deposition process, the cobalt deposition effect of active magnesium oxide prepared through a chemical method is effectively improved, other methods except for the method for reducing the particle size and promoting the activity of magnesium oxide are developed, acetate is selected as the magnesium hydroxide regulating agent, the dosage is small, and the cost is low. Magnesium oxide obtained through calcination is high in purity, the cobalt deposition process is not affected, unit consumption of magnesium oxide can be reduced, and cost is saved.

The invention discloses an MHP short-process nickel-cobalt-manganese purification liquid preparation technology, and belongs to the technical field of hydrometallurgy. Comprising the following steps: drying a cobalt nickel hydroxide raw material; carrying out size mixing, reduction leaching and separation to obtain a primarily purified nickel-cobalt-manganese solution and manganese-containing slag; carrying out acidification leaching on the manganese-containing slag, and separating to obtain manganese-silicon slag and a nickel-containing pickling solution; adding a neutralizing agent into the primarily purified nickel-cobalt-manganese solution to adjust the pH value, adding an oxidizing agent, and separating to obtain filtrate and filter residues; concentrated sulfuric acid is added into the filter residues for curing and leaching, and cured leaching residues and desiliconized filtrate are obtained through separation; cured leaching residues are returned for reduction leaching; adding a second neutralizer into the desiliconized filtrate to adjust the pH value, reacting, and separating to obtain iron-aluminum slag and nickel-containing impurity-removed filtrate; adding a third neutralizer into the nickel-containing impurity-removed filtrate to adjust the pH and precipitate nickel, and separating to obtain a nickel-containing alkaline substance; and removing impurities in the filtrate to obtain the nickel-cobalt-manganese purified liquid. According to the method, the nickel-cobalt-manganese purified liquid, the scandium-containing iron-aluminum slag, the by-product manganese-silicon slag and the like can be obtained, solid waste reduction and high value are achieved, and the method is more economical, more efficient and more environmentally friendly.

The invention discloses a device and method for treating molybdenum concentrate hydrometallurgy wastewater, and relates to the technical field of wastewater treatment.The device comprises a top box and a rack fixedly connected to the outer surface of the top box; the airflow generating mechanism is used for generating airflow in the inner cavity of the top box, by arranging the airflow generating mechanism, gas flow can be generated in the inner cavity of the top box and the inner cavity of the bottom box when molybdenum concentrate hydrometallurgy waste water is recycled, and particle precipitates after precipitation can be discharged out of the device in a precipitation mode; meanwhile, in the air flotation mode, bubbles are poured into the inner cavity of the device, so that suspended solids in the sewage float to the top of the inner cavity through the bubbles, and then the suspended solids are discharged; and the switching mechanism is used for switching two treatment modes of sewage precipitation and air floatation, so that the effect of recycling particulate matters and suspended matters in the metallurgical wastewater is achieved.

The invention relates to a method for preparing sponge iron from laterite-nickel ore hydrometallurgy tailings, which comprises the following steps: (1) carrying out acid leaching on laterite-nickel ore hydrometallurgy tailings to obtain leached residues without at least part of CaSO4; (2) oxidizing and roasting the leaching residues obtained in the step (1), so that at least part of sulfate is discharged as sulfur-containing gas; performing hydrogen reduction to obtain a reduced material; and (3) the reduction material in the step (2) is sequentially subjected to ore grinding and magnetic separation, and the sponge iron with the Fe content being 90 wt% or above and the S content being 0.01 wt% or below is obtained. According to the method, iron resources in the laterite-nickel ore hydrometallurgy tailings are recycled, desulfurization and reduction are carried out step by step, the desulfurization efficiency is improved, the reduction temperature is reduced, and the sponge iron with the Fe content being 90 wt% or above and the S content being 0.01 wt% or below is obtained.

A hybrid load-energy storage system applicable to a microgrid of a hydrometallurgical plant, includes: a plurality of first electrical equipment, a plurality of second electrical equipment, first energy storage equipment, and second energy storage equipment. An electric usage priority of the first electrical equipment is lower than that of the second electrical equipment. The first energy storage equipment is on-grid and off-grid energy storage equipment, and the second energy storage equipment is grid-forming energy storage equipment. The first electrical equipment is connected to the first energy storage equipment via branches provided with first circuit breakers, and the second electrical equipment is connected to the second energy storage equipment via branches provided with second circuit breakers. The first second energy storage equipment are respectively connected to an AC bus via branches provided with a third and a fourth circuit breakers, and the AC bus is connected to an external power grid.

This invention relates to a method for the combined leaching of high-silicon zinc roasted ore and high-sulfur zinc oxide powder, belonging to the field of hydrometallurgical technology. The high-sulfur zinc oxide powder is leached neutrally to obtain zinc oxide leaching residue and zinc powder leaching solution. The zinc powder leaching solution is then mixed with high-silicon zinc roasted ore slurry for controlled silica leaching of the high-silicon zinc roasted ore to obtain zinc ore leaching residue and zinc ore leaching solution. The zinc powder leaching residue and zinc ore leaching residue are mixed and then subjected to low-acid leaching to obtain low-leaching residue and low-leaching solution. The low-leaching residue is then subjected to hot acid leaching to obtain hot-leaching residue and hot-leaching solution. The hot-acid residue is then subjected to high-acid leaching to obtain lead-silver slag product and high-leaching solution. The hot-leaching solution is neutralized and reduced by high-sulfur zinc oxide powder to obtain neutralized solution and neutralized residue. The neutralized solution is then subjected to mineralization and iron precipitation to obtain hematite product and iron-removed solution. This invention can effectively control the leaching of silicon in the high-silicon zinc roasted ore leaching process, and simultaneously realize the oxidative leaching of sulfides in zinc oxide powder and the reductive leaching of zinc ferrite in zinc roasted ore, thus simplifying the leaching process of zinc roasted ore and zinc oxide powder.

The invention belongs to the technical field of slag recycling, and discloses a method for extracting iron ore concentrate from laterite-nickel ore hydrometallurgical slag, which comprises the following steps: heating biomass to 350-600 DEG C in a nitrogen atmosphere for treatment, heating to 350-600 DEG C in a carbon dioxide atmosphere for treatment, cooling, crushing and sieving to obtain biomass charcoal; the laterite-nickel ore hydrometallurgical slag, biomass charcoal and an additive are mixed and then subjected to reduction roasting, and a roasted product is obtained; and adding a dispersing agent into the roasted product, carrying out ball milling, and carrying out size mixing and magnetic separation to obtain iron ore concentrate. The process for extracting the iron ore concentrate from the biomass charcoal is developed for the laterite-nickel ore hydrometallurgical slag, has the advantages of being short in process, low in cost, environmentally friendly, good in recovery effect and the like, and has a positive effect on solving the environmental problems caused by long-term stockpiling, landfill and the like of the laterite-nickel ore hydrometallurgical slag.

The invention discloses a method for recycling laterite-nickel ore metallurgical slag resources, and belongs to the technical field of hydrometallurgy. The method comprises the following steps: carrying out alkaline leaching treatment on the laterite-nickel ore hydrometallurgical slag to obtain alkaline leaching liquid and alkaline leaching slag; carrying out acid leaching treatment on the alkaline leaching residues to obtain acid leaching liquid and acid leaching residues; mixing the acid leaching residues, a biomass reducing agent and an additive, performing primary ball milling treatment, and performing reduction roasting treatment on an obtained product to obtain a roasted product; and mixing the roasted product with a dispersing agent, carrying out secondary ball milling treatment, and carrying out magnetic separation on the obtained product to obtain iron ore concentrate. According to the method, the biomass is carbonized and activated to obtain the biomass reducing agent with enhanced reducibility, the biomass reducing agent is low in cost and environmentally friendly, the biomass reducing agent and the acid leaching residues are continuously mixed according to a specific proportion, reduction roasting is carried out under a specific atmosphere, and then magnetic separation is carried out; and iron ore concentrate with relatively high purity and yield is obtained.

The invention discloses a zinc sulfate solution impurity removal method based on a three-section countercurrent purification process, and belongs to the technical field of hydrometallurgy. Heating the zinc sulfate solution containing impurities to 60-70 DEG C in a first-section reaction tank, reacting for 30-60 minutes, adding the second-section pressure filter residue, and performing pressure filtration to obtain a first-section purified solution and a first-section pressure filter residue; the first-section purified liquid is transferred into a second-section reaction tank, zinc powder and third-section filter residues are added, the adding amount of the zinc powder is 0.8-2 times of the theoretical amount of the zinc powder needed for metal cadmium replacement, the temperature is increased to 70-80 DEG C, a reaction is conducted for 60-90 min, and second-section purified liquid and second-section filter residues are obtained after filter pressing; the second-section purified liquid is transferred into a third-section reaction tank, zinc powder is supplemented, the adding amount is 180-300 times of the theoretical amount of the zinc powder needed for metal cobalt replacement, the temperature is increased to 80-90 DEG C, a reaction is conducted for 90-120 min, and third-section purified liquid and third-section filter pressing residues are obtained after filter pressing; and returning the third-section press-filter residue to the second-section reaction tank, returning the second-section press-filter residue to the first-section reaction tank, and reversely recycling. The method has the advantages of sufficient reaction kinetics, high utilization rate of zinc powder, low zinc content in purified slag, simple process, deep impurity removal, low consumption and high efficiency.

The invention discloses a method for cascade recovery of tellurium from a complex tellurium-containing material. The method comprises the steps of acid pickling, reduction neutralization, pyrogenic transformation, leaching and neutralization. According to the method, through cooperative treatment of a wet process and a pyrogenic process, the problem of slag phase wrapping is effectively solved, and tellurium with different valence states in a complex tellurium-containing material is converted into high-quality tellurium neutralization slag in a gradient mode. The selenium removal rate is not lower than 95%, the tellurium recovery rate reaches up to 90% or above, efficient separation of selenium and tellurium is achieved, and the produced tellurium dioxide neutralization slag can be used for further purification and refining.

The invention belongs to the technical field of hydrometallurgy, and particularly relates to a pretreatment method for improving the leaching rate and the carbon adsorption rate of high-sulfur-arsenic gold ore. Comprising the following steps that the high-sulfur-arsenic gold ore is ground and then prepared into ore pulp; a green oxygen activating agent and hydrogen peroxide are sequentially added into the ore pulp, oxidation pretreatment is conducted on the high-sulfur-arsenic gold ore, ore pulp activating liquid is formed, and the green oxygen activating agent is a mixture of calcium oxide, sodium persulfate and soluble bivalent iron salt; and adding a gold leaching agent into the ore pulp activation solution, adjusting the pH value of the ore pulp to 9-12, carrying out stirring gold leaching treatment, filtering to obtain a leaching solution, and then adding activated carbon to adsorb and extract gold. According to the method, a stronger oxidation environment is provided, meanwhile, the residual concentration of arsenate radicals in the solution is effectively reduced, the leaching rate of gold and the adsorption rate of activated carbon are greatly increased, excellent oxidation performance and environment friendliness are shown, and a more sustainable high-sulfur-arsenic gold ore pretreatment process is provided.

The invention relates to the technical field of hydrometallurgy production, and particularly discloses a method for synergistically extracting gallium and scandium by coupling titanium white waste acid with vanadium extraction converter sludge, which comprises the following steps: mixing titanium white waste acid and vanadium extraction converter sludge in proportion, stirring and leaching to obtain a leaching solution; adding an extraction agent and a diluent into the leaching solution for extraction, and washing to obtain a gallium and scandium loaded organic phase; a first stripping agent is added into the loaded organic phase of gallium and scandium for stripping treatment, and a gallium stripping solution and a loaded organic phase of scandium are obtained; sequentially carrying out alkali precipitation, alkali dissolution and electrolytic treatment on the gallium reverse extraction solution to obtain crude gallium; a second stripping agent is added into the scandium-loaded organic phase for stripping treatment, and a scandium precipitation solution and an organic phase solution are obtained; and the scandium precipitation solution is filtered, washed and subjected to acid dissolution, and a scandium-containing solution is obtained. According to the method, the titanium white waste acid is effectively recycled, rare and precious metals in the vanadium extraction converter sludge are efficiently and synergistically extracted, and the method has a relatively good popularization prospect.

The invention provides a low-cyanide gold leaching agent system and a dump leaching process thereof, and belongs to the technical field of hydrometallurgy. According to the method, a synergistic process of'interface activation, cyanide etching and iron precipitation inhibition 'is constructed by designing a low-cyanide gold leaching agent system. The amino acid auxiliary leaching agent adsorbs the gold surface to weaken lattice energy, so that the etching efficiency of trace cyanide ions is improved; mercapto-containing malic acid is used as a chelating agent, specific mercapto in molecules of the mercapto-containing malic acid and iron ions form an ultrahigh-stability water-soluble complex, generation of ferric hydroxide precipitates is thoroughly blocked, ferrous ions stabilized by the chelating agent are subjected to in-situ oxidation through dissolved oxygen and efficiently regenerated into potassium ferricyanide, and accumulation of free cyanogens in a solution system is eliminated; meanwhile, a chelating agent-iron complex forms a self-buffering pair, the pH of the dump leaching solution is accurately controlled, and secondary precipitation caused by local alkalization is prevented. According to the process, under the synergistic effect that the core chelating agent guarantees permeation stability and the leaching aid accelerates gold dissolution, the heap leaching period is compressed to 45 days.

The invention belongs to the technical field of hydrometallurgy, and particularly relates to a pretreatment method for enhancing peroxide to improve the leaching rate of high-sulfur-arsenic gold ore. Comprising the following steps that the high-sulfur-arsenic gold ore is ground and then prepared into ore pulp; an oxidizing agent is added into the ore pulp, oxidation pretreatment is conducted on the high-sulfur-arsenic gold ore under the catalytic action of ultraviolet light, and ore pulp activation liquid is formed; and the pH of the ore pulp activating solution is adjusted to 9-12, a gold leaching agent is added into the ore pulp complexing solution, and stirring gold leaching treatment is conducted. According to the method, efficient oxidation of sulfide and arsenide is achieved under the mild condition through the synergistic effect of photocatalysis and chemical oxidation, the leaching rate of gold is remarkably increased, compared with a conventional peroxide oxidation method for pretreatment, the leaching rate can be increased by 10%-35%, and meanwhile the agent use amount and environmental pollution are reduced.

The invention relates to the technical field of hydrometallurgy production systems, in particular to a solvent regeneration control system for separating zirconium and hafnium through MIBK method centrifugal extraction, which comprises a control module used on a solvent regeneration neutralization reactor, and the control module comprises a heat exchange module; the heat exchange module comprises a heat exchange unit; the heat exchange unit comprises a cooling liquid flow adjusting unit, a cooling liquid temperature detecting unit and a cooling liquid pressure detecting unit. And the heat exchange module is used for controlling the flow of the cooling liquid, the pressure of the cooling liquid and the temperature of the cooling liquid of the heat exchange unit so as to adjust the temperature of the mixed phase in the neutralization reactor. The control system can monitor the flow, temperature and pressure of cooling liquid in real time, accurately control opening, closing and temperature adjustment of the heat exchange unit, quickly respond to temperature change of a mixed phase in the neutralization reactor, remove reaction heat in time, effectively avoid the problem of extraction system emulsification caused by high-temperature decomposition and polymerization of thiocyanic acid in the solvent regeneration process, and improve the extraction efficiency. The solvent regeneration efficiency and quality are ensured.

The utility model relates to the field of hydrometallurgy, in particular to a nickel sulfate solution deoiling device. Comprising a standing tank connected with a production process outlet end, one end of an oil removal device is connected with the standing tank, the other end of the oil removal device is connected with a resin adsorption column, the resin adsorption column is connected with a regeneration tank, and the regeneration tank is connected with a solution storage tank. According to the oil removal device arranged in the device, oil can be treated step by step according to different existing forms and physical properties of oil in nickel sulfate through internal fiber cotton filtration, resin adsorption and filter screen filtration, and compared with the prior art, the oil removal effect is better; the device is provided with the oil-water separator and the bag filter, so that the oil removal effect can be further improved, and impurities in the nickel sulfate solution can be separated.