The invention discloses a livestock and poultry feces organic fertilizer fermentation compound functional package, which comprises a compound functional package A and/or a compound functional packageB. The compound functional package A comprises a compound microbial agent, a compound enzyme preparation, humic acid, white spirit vinasse powder and zeolite powder; the compound functional package Bcomprises isomaltooligosaccharide, molasses meal, monopotassium phosphate, magnesium sulfate, ferrous bisglycinate, manganese bisglycinate, bamboo vinegar powder and citric acid. The package A and thepackage B are combined, the fermentation speed can be greatly increased, quick heating deodorization and thorough decomposition can also be achieved in the low-temperature season, diseases and insect pests and antibiotic residues can be effectively removed, the quality is stable, the quality guarantee period is long, and practicability is high. The invention further discloses a preparation method and application of the compound functional package, the compound functional package is used for livestock and poultry feces organic fertilizer fermentation, the harmless treatment efficiency is high, resource utilization is high, an obtained organic fertilizer product is high in functionality and comprehensive in nutrition, and has no toxicity, stink, harm and pollution, and the organic fertilizer use standard requirement is met.