2219 results about "Aluminium sulfate" patented technology

A water-absorbing agent according to the present invention includes water-absorbent resin particles having an internal cross-linked structure,.wherein a vicinity of a surface of the water-absorbent resin particle is cross-linked with a surface cross-linking agent, and the water-absorbent resin particle has therein a sea-island structure having (i) part containing a first water-soluble multivalent metal salt such as aluminum sulfate and (ii) part not containing the first water-soluble multivalent metal salt. With this arrangement, it is possible to provide a water-absorbing agent having less water-soluble component content, more excellent liquid permeability, and more excellent water retention under pressure than the conventional water-absorbing agent.

A process for extracting aluminum oxide from powdered coal ash includes such steps as grinding, calcining, mixing with H2SO4 solution, heating while reaction for extracting aluminum oxide, boiling in water, concentrating, cooling while educing out aluminum sulfate crystals, heating for dewatering, heating for decomposing to obtain gamma-Al2O3, and further preparing metallurgy-class aluminum oxide.

An aluminum phosphate or polyphosphate-based pigment product is made by a process comprising contacting phosphoric acid with aluminum sulfate and an alkaline solution to produce an aluminum phosphate based product; and optionally calcining the aluminum phosphate based product at an elevated temperature, wherein the process is substantially free of an organic acid. The aluminum phosphate or polyphosphate-based pigment is amorphous. The amorphous aluminum phosphate or polyphosphate characterized by a bulk density of less than 2.30 grams per cubic centimeter and a phosphorus to aluminum mole ratio of greater than 0.8. The composition is useful in paints and as a substitute for titanium dioxide.

The invention discloses an alkali and chlorine-free liquid setting accelerator based on industrial polyaluminium sulfate. The liquid setting accelerator comprises the following raw materials by weight: 35-55% of polyaluminium sulfate, 5-25% of magnesium sulfate, alcohol amine accounting for 15-30% of the polyaluminum sulfate, 0-5% of an inorganic acid, 0-5% of a stabilizer, and the balance water. The liquid setting accelerator provided by the invention can be used in the wet jetting industry of sprayed concrete, belongs to alkali and chlorine-free liquid setting accelerators, has a stable period of more than 6 months, a 28d compressive strength ratio of greater than 100%, and good adaptability to different cement. When the dosage is 4.5%, the technical requirements of the JC477-2005 ''setting accelerators for sprayed concrete'' can be satisfied. The liquid alkali-free setting accelerator has superior performance, and can be widely used in tunnels, bridges, first-aid repair and other projects.

The invention discloses a preparing method of alumina through fly ash, which comprises the following steps: grinding fly ash; sintering; activating; stirring with H2SO4 evenly to sinter into dried slag; immersing through hot water; stripping aluminum sulfate; condensing; cooling to evolve aluminum sulfate; crystallizing; heating; dehydrating to obtain anhydrous aluminum sulfate; heating; decomposing to obtain gamma-Al2O3.

The invention relates to an improvement to abrasion-resistant fireproof plastic, which is characterized in that the invention comprises 60-80wt percent of corundum and / or porzite and / or Al2O3 larger than or equal to 80 percent of bauxite clinker, 5-10wt percent less than or equal to4 micron of alumina micro-powder, 6-15wt percent less than or equal to 0.025mm of chromium corundum fine powder, 2-6wt percent less than or equal to1micron of silicon fine powder, 5-10wt percent of kyanite or andalusite or silimanite, 12-15wt percent of aluminium dihydrogen phosphate or aluminium sulfate wedding agent, and 0.5-3wt percent of calcium aluminate or bauxite cement coagulant. Compared with the prior art, the abrasion-resistant fireproof plastic has the advantages of high compressive strength, good wear-resisting property, high temperature used and strong slag resistance and anti-etching power, thereby greatly prolonging the service life and meeting the use with higher requirements.

The invention discloses a method for producing alumina by disposing and utilizing industrial solid wastes, in particular to a method for preparing alumina by fly ash, comprising the steps as follows: the fly ash is mechanically activated; the activated fly ash, water and concentrated sulfuric acid react in a reaction kettle under the conditions of heating and pressurizing; the solid is separated from the liquid after the temperature of the reaction is reduced so as to gain aluminium sulfate liquid; the aluminium sulfate liquid is evaporated, concentrated and cooled so as to precipitate aluminium sulphate crystals; the aluminium sulphate crystals are dehydrated and decomposed to gain gama-Al2O3 and SO3; coarse gama-Al2O3 is dissolved in alkaline solution; after the solid is separated from the liquid, the pure sodium aluminate solution is gained; aluminum hydroxide crystal seed is added to the sodium aluminate solution so as to precipitate the aluminum hydroxide; the coarse gama-Al2O3 can be prepared by circularly dissolving the seed-precipitated alkaline solution after vaporization-concentration; the metallurgical alumina can be gained by baking the prepared aluminum hydroxide. The method adds no additive, can lead the alumina in the fly ash to be effectively leached out with the leaching rate more than 90% and saves the energy resource.

The invention relates to a liquid accelerator for shotcrete and a method for preparing the same. The liquid accelerator is prepared from the following components in percentage by weight: 25 to 70 percent of aluminum sulfate, 0 to 8 percent of metal fluoride, 1 to 10 percent of amine substance, 0.5 to 7 percent of pH regulator, 0.01 to 1 percent of thickening agent, and the balance being water. The method for preparing the liquid accelerator comprises the following steps: firstly, dissolving the fluoride into the water; secondly, adding the amine substance to the mixture and heating the solution to a temperature of between 40 and 80 DEG C; thirdly, adding the aluminum sulfate to the solution to perform heat preservation reaction until the solution becomes a uniform liquid; and fourthly, adding the pH regulator and the thickening agent to the uniform liquid and stirring the mixture evenly to finally obtain a uniform liquid substance which is the liquid accelerator for the shotcrete. The liquid accelerator is free from corrosion, has no penetrating odor, has good storage stability so that the phenomena of deposition, crystallization and the like do not appear after the storage of more than 6 months at a temperature of between 0 and 35 DEG C, and does not influence the effect in practice. Using the liquid accelerator with lower mixing proportion (5 to 8 percent), cement can be initially set within 4 minutes and finally set within 10 minutes, and the strength of cement mortar within one day is more than 10 MPa and the storage rate of the strength within 28 days is more than 100 percent.

The invention discloses a liquid alkali-free chloride-free accelerating agent and methods for preparing and using the same. Raw materials for preparing the accelerating agent include one or a plurality of the following components of aluminum sulfate, magnesium sulfate, hydramine, an early strength agent, a synergist and water. The aluminum sulfate is the purchasable industrial-grade aluminum sulfate hydrate Al2(SO4)3.18H2O and has the solid content of 51%-52%. The magnesium sulfate is MgSO4.7H2O with the solid content of 48%-49%. The hydramine is one or a plurality of mono ethanol amine, diethanolamine, triethanolamine or isopropoxide. The early strength agent is one or a plurality of calcium sulfate, calcium formate or calcium nitrite. The synergist is magnesium fluosilicate and / or magnesium fluoride. The liquid alkali-free chloride-free accelerating agent provided by the invention has the characteristics of good adaptability, low price, low mixing amount, good performance, good stability and the like; and moreover, the liquid alkali-free chloride-free accelerating agent is added into the concrete to be used as sprayed concrete, has the characteristics of low resilience, small dust pollution and the like and can satisfy the requirements of the 'JC477-2005 sprayed concrete accelerating agent' standard.

The electric Fenton oxidation process for processing scale inhibitor in reverse osmosis concentrated liquid adopts anode of iron plate and cathode of porous graphite and ventilated with air pump and processes reverse osmosis concentrated liquid through electrolyzing in stirring, stirring coagulation via adding aluminum sulfate and filtering the coagulated solution. Bivalent iron ion produced intelligent the electric Fenton process is made to react with hydrogen peroxide to produce strong oxidizing free hydroxy radical oxidizing and destructing the scale inhibitor; and the subsequent coagulation separates out scaling salt to lower the scaling trend, so that the concentrated liquid may be utilized as influent water to raise the water recovering rate of reverse osmosis system.

The invention discloses a technological method for producing high-purity low-iron aluminum sulfate by using coal ash and comprehensively utilizing the coal ash, comprising the following steps of: carrying out mechanical activation, flotation decarburization, magnetic separation for deferrization, aluminum extraction with sulfuric acid, solid-liquid separation, concentration of aluminum sulfate crude liquor, organic alcohol alcoholization for acid rinse, organic alcohol alcoholization for deferrization and aluminum sulfate dewatering and drying on the coal ash to obtain the high-purity low-iron aluminum sulfate with low Fe content. The invention solves the problems on impurity removal and purification of the aluminum sulfate in the recycling process of the coal ash, simplifies the process flow, reduces the energy consumption, solves the technical problem of overlarge accumulation of secondary residue quantity, achieves high extraction ratio of aluminum contained in the coal ash, and realizes the recycling of organic alcohol and sulfuric acid and the comprehensive utilization of side products including unburnt black, magnetic iron powder, iron-containing aluminum sulfate crystals, high-silicon-dust active mineral blending materials or novel silicon-magnesium cement, and the like. The technological method has the advantages of simple process, short flow, easiness for control of a production process, high aluminum extraction ratio, low impurity content of products and stable quality.

The invention discloses a polymeric aluminum sulfate synthesis method and discloses a preparation method of a novel alkali-free liquid accelerator based on synthesis of polymeric aluminum sulfate. According to the alkali-free accelerator, an aluminum sulfate solution is neutralized by ammonia water, active aluminum hydroxide gel is prepared, active aluminum hydroxide is filtered, dried and ground into powder, then the aluminum sulfate solution is added, and the polymeric aluminum sulfate is prepared. The alkali-free accelerator comprises, in percentage, 45%-55% of the polymeric aluminum sulfate, 0%-5% of inorganic acid, 0%-2% of a stabilizer, 0%-2% of an organic early strength agent, 0%-2% of an organic tackifier and the balance of water. The cement setting time and the colloidal mortar strength of the accelerator can meet the requirement of first-class accelerators for JC477-2005 sprayed concrete under the condition of the lower mixing amount, and meanwhile, the accelerator is an alkali-free liquid accelerator and can effectively avoid adverse effects caused by excessively high alkali content. The cement types of the accelerator have good adaptability.

The invention relates to fibrous insulation products that exhibit improved flame resistance, relative to previously known products. The insulation product has a fibrous mineral matrix, into which is incorporated a phosphate-containing compound (e.g., an inorganic phosphate salt) and a refractory mineral filler (e.g., alumina or aluminum sulfate). The product exhibits flame resistance superior to the fibrous mineral matrix alone.

The invention relates the method of extracting aluminium from high-silicon siliceous mineral. The method comprises the following steps: mixing the aluminous ore and sulfuric acid, baking, leaching with water, filtering leachate, getting aluminium sulphate solvent, thickening filter liquor, separating out aluminium sulphate, drying, dewatering, getting anhydrous aluminium sulphate; calcining aluminium sulphate, and getting Al2O3. The invention can extracte aluminium from high-silicon siliceous mineral, coal gangue, coal ash, China clay, andalusite, feldspath, ganister, nepheline and vermiculite without baking. The method has the advantages of simple technology, little corrosion, easy operation and high recovery ratio.

The invention discloses a heating-free non-alkali liquid accelerator for jetting concrete and a preparation method of the heating-free non-alkali liquid accelerator. The liquid accelerator is prepared from the following components in percentage by mass: 30%-55% of aluminum sulfate, 3%-10% of aluminium hydroxide, 10%-18% of hydrofluoric acid, 8%-25% of magnesium salt, 1%-8% of alkylol amine, 0.5%-4% of a stabilizer, and 10%-33% of water. The preparation method is characterized by comprising the following processing steps: putting aluminium hydroxide into a reaction kettle; adding water to the reaction kettle, and stirring aluminium hydroxide into paste; slowly adding hydrofluoric acid, and when the temperature reaches 50-55 DEG C, adding aluminum sulfate to stir in batches; after hydrofluoric acid is completely added, adding residual aluminum sulfate and supplementing residual water, so as to obtain reaction liquid; adding the magnesium salt to the reaction liquid, and then adding the alkylol amine and the stabilizer, so that the solution becomes evenly mixed liquid. The accelerator disclosed by the invention has strong adaptability with cement, low energy consumption and good performance, and does not need to be heated in the use procedure.

The invention relates to a gypsum and calcium oxide melt inclusion expansion clinker, a concrete expansion agent, and a preparation method and application thereof, belonging to the field of construction materials. The expansion clinker provided by the invention is prepared by mixed grinding and high-temperature burning of limestone, gypsum and aluminum oxide and / or aluminum sulfate. The concrete expansion agent is prepared by grinding the expansion clinker together with a calcium sulphoaluminate cement clinker, calcium stearate or / and triethanolamine until the specific surface area is 140-400 m<2> / kg. According to the invention, the expansion clinker has high restrained expansion rate and high clinker weathering resistance; the concrete expansion agent has the functions of cracking resistance, seepage resistance, shrinkage compensation and the like, and has the advantage of long product shelf life (up to 6 months). The concrete expansion agent can be used for cracking resistance and seepage resistance of a common concrete structure, and can greatly enhance the durability of the concrete.

The invention discloses a special saline-alkali-soil improvement fertilizer prepared by modification with flue gas desulfurization gypsum and a preparation method thereof. The special improvement fertilizer comprises the following components in parts by weight: 40-80 parts of flue gas desulfurization gypsum, 1-3 parts of citric acid, 0.5-1.5 parts of magnesium sulfate, 1-5 parts of aluminum sulfate, 1-5 parts of ferrous sulfate, 10-30 parts of weathered coal, 10-20 parts of cattle manure or chicken manure, 1-5 parts of urea, 0.5-2.5 parts of ammonium sulfate, 1-3 parts of potassium sulfate, 1-3 parts of monoammonium phosphate, 0.1-0.5 part of zinc sulfate, 0.1-0.5 part of manganese sulfate and 3-10 parts of bentonite. The fertilizer is reasonable in design, provides an effective solution for inland saline-alkali soil of China, and has higher practical value and wide market prospects.

The invention discloses a cementitious capillary crystalline waterproofing agent, which contains the following raw materials in parts by weight: 50 parts of Portland cement; 25 parts of quartz sand; 9 parts of siliceous dust; 3 parts of calcium hydroxide; 2 parts of sodium bentonite; 1 part of kieselguhr; 3.9 parts of instant sodium silicate; 2.5 parts of aluminum potassium sulfate; 0.3 parts of zinc fluosilicate; 0.20 parts of sodium polyacrylate; 0.2 parts of hydroxypropyl methyl cellulose; 2 parts of zinc stearate; 0.5 parts of naphthalene water reducer; 0.2 parts of sugar lime; 0.1 parts of citric acid; and 0.1 parts of antifoaming agent. After the raw materials are weighed according to the proportions, the raw materials are ground into particles with grain size more than or equal to 200-mesh sieve in a ball mill to obtain the finished product. The invention has the advantages that the cost is low, the anti-permeability is good, the self-healing performance is good, the bonding power is strong, the steel bar corrosion is prevented, no toxicity and no harmfulness are caused and the construction is easy.

The invention relates to a preparation process for large pore volume and light bulk density activated alumina, and belongs to the technical field of activated alumina preparation. According to the process, an aluminum sulfate solution and a sodium aluminate solution form a glue in a stainless steel neutralization kettle through a continuous co-current flow method; then an aging treatment is performed for a certain time in a stainless steel aging washing tank; the resulting material is pressed to a plate and frame filter press with a material pressing pump to carry out continuous washing to prepare primary pseudo-boehmite particles with large grains; the removed filter cake is acidified, and proper amounts of a pore expanding agent and a surfactant are added during the acidification process to carry out forming; the formed wet balls are placed in a drying box to carry out drying; and the dried small balls are loaded into a calcination activation furnace to carry out high temperature calcination and pore expanding. The process of the present invention has characteristics of low cost and low equipment corrosion, can performs continuous washing cycle, and has advantages of low wastewater discharging, less pollution, and the like. With the process of the present invention, the production cycle can be reduced, the labor intensity can be reduced, and various performance indicators of the prepared gamma-Al2O3 can meet the international advanced level after pore expanding by water vapor.

The invention belongs to the technical field of tunnel construction, and relates to a low-alkaline liquid accelerating agent and a preparation method thereof. For the low-alkaline liquid accelerating agent, aluminium sulfate solution is neutralized with sodium aluminate solution to produce aluminium hydroxide collosol, and then aluminium sulfate and aluminium hydroxide collosol conduct polymerization reaction in an original solution system to produce polymerized aluminium sulfate, so that the accelerating agent solution has higher aluminium ion content and liquid stability; the low-alkaline liquid accelerating agent is prepared by aluminium sulfate, sodium aluminate and stabilizing agent; and the mass percentage of the components are as follows: 40 to 60 percent of aluminium sulfate, 6 to12 percent of sodium aluminate, 0 to 0.2 percent of stabilizing agent, and the balance of water. The invention has the following positive effects to sprayed concrete: initial set of common cement can be realized in five minutes and final set of the common cement can be realized in eight minutes under lower doping amount; the 1d strength of cement mortar can reach more than 12MPa, and the 28d compression strength ratio of the cement mortar is more than 100 percent; and the invention has good adaptability to cement of different varieties.

The invention provides a composite air purificant containing nanometer mineral matters, which contains 47wt% to 78wt% of attapulgite as a natural mineral, 20wt% to 50wt% of synthetic zeolite molecular sieve as a molecular sieve, 0.5wt% to 5wt% of sodium carbonate or sodium chloride or sodium fluoride or sodium hydrogensulfite as a modifier, 0.5wt% to 5wt% of ammonium bicarbonate or sodium bicarbonate or aluminum sulfate as a foaming agent, 0.5wt% to 2wt% of dodecyldimethylbenzylammonium chloride as a surface active agent, 0.2wt% to 2wt% of nanometer photocatalyst titanium dioxide colloidal solution as a photocatalyst and 0.1wt% to 1wt% of nanometer aircatalyst titanium dioxide colloidal solution as photochemical catalysts. The composite air purificant is prepared by first drying, first pelleting, second drying, second pelleting, third drying, baking and finish product detection and package. The invention has high alternative adsorbability and high decomposition efficiency for organic pollutants in the air.

The invention relates to a method of preparing aluminum sulphate by utilizing industrial solid waste, in particular to a method of preparing aluminum sulphate by utilizing fly ash. The method comprises the following steps: mechanically activating the fly ash; mixing the mechanically activated fly ash with water according to a weight ratio of 1: 0.5-2.5; adding concentrated sulfuric acid at a weight ratio of 0.3-2.2 : 1 to the fly ash to a reaction kettle to generate basic aluminum sulphate at a temperature of 120 to 230 DEG C kept for 1-8h and a pressure of 0.11 to 0.50 MPa; cooling the basic aluminum sulphate after a reaction, separating solid and liquid, adding sulfuric acid to the basic aluminum sulphate liquid, adjusting the system to have the basicity of 0.1 to 0.4 and the pH value of 3 to 4 and converting the basic aluminum sulphate liquid into an aluminum sulphate solution; and evaporating and concentrating the aluminum sulphate solution to 110 to 120 DEG C and cooling and crystallizing the aluminum sulphate solution to separate aluminum sulphate crystals.

The invention relates to a preparation method of low-alkaline liquid accelerating agent, comprising the following steps: 1) preparing sodium aluminate liquid; 2) modifying sodium aluminate liquid; 3)carrying out a reaction between the modified sodium aluminate and the aluminum sulfate; and 4) adding hydramine and hydroxycarboxylic acid and stirring evenly to prepare the finished product. The low-alkaline liquid accelerating agent prepared by the invention has low alkali content, namely, the sum of Na2O and K2O is less than 5%, low preparation cost, is suitable for cement such as ordinary Portland cement, moderate-heat cement, low-heat cement and other brands and types, is applicable to the sprayed concrete construction, can significantly improve initial strength and ensure later strength.

A natural blue colorant solution comprising red cabbage liquid, aluminum sulfate and sodium bicarbonate is disclosed. The pH of the colorant solution is in the range of 3.8 to 4.2 and can be used to provide a blue hue when incorporated into products having a pH greater than 5.5. A highly stable blue colorant solution is created when the weight ratio of the aluminum sulfate and sodium bicarbonate is approximately 2:1. The blue colorant solution can be modified to create a natural green colorant solution by the addition of a natural yellow colorant and additional sodium bicarbonate.

An aluminum phosphate composition comprising aluminum phosphate, aluminum polyphosphate, aluminum metaphosphate, or a mixture thereof. The composisition may be characterized by, when in powder form, having particles wherein some of the particles have at least one or more voids per particle. In addition, the composition is characterized by exhibiting two endothermic peaks in Differential Scanning Calorimetry between about 90 degrees to about 250 degrees Celsius. The composition is also characterized by, when in powder form, having a dispersibility of at least 0.025 grams per 1.0 gram of water. The composition is made by a process comprising contacting phosphoric acid with aluminum sulfate and an alkaline solution to produce an aluminum phosphate based product; and optionally calcining the aluminum phosphate, polyphosphate or metaphosphate based product at an elevated temperature. The composition is useful in paints and as a substitute for titanium dioxide.

A glaze comprises the following components: 30-40 parts of an inorganic binder, 5-20 parts of regulators, 10-30 parts of wear-resistant material, 3-5 parts of reinforced fiber, 0.1-1 part of a water-reducing agent, 3-8 parts of filling material, 0.5-2 parts of a dispersing agent, 1-2 parts of a coupling agent and 1-5 parts of a mineral pigment, wherein the regulator is at least one selected from Al2O3 sol, SiO2 sol, ZrO2 sol, water glass and aluminum sulfate; the wear-resistant material is at least one selected from emery, silicon carbide sand, quartz sand and steel grit; the filling material is at least one selected from silicon powder, talcum powder and calcium carbonate powder. The glaze layer formed by the glaze containing the above components has a similar color and luster with that of a natural stone and can replace decorative effect of the natural stone; further, the glaze layer formed by the glaze mostly adopts commonly used inorganic materials whose cost are lower compared with that of the natural stone. In addition, it is necessary to provide a method for forming the glaze layer.

The invention discloses a lost foam casting cast iron coating for preventing carbon defects, which comprises the following components by weight percent: 60.5%-64.5% of bauxite, 13.5-17.5% of kaolin, 3.5%-6.0% of talc powder, 1.7%-3.5% of attapulgite, 0.4%-0.8% of sodium lignosulphonate, 2.5%-6.0% of aluminum sulfate, 1.7%-3.5% of polyvinyl alcohol, 3.5%-5.0% of silica sol, 0.1%-0.2% of iron oxide powder and 0.01%-0.02% of n-octanol, and the sum of the components is 100%. The lost foam casting cast iron coating is prepared by respectively preparing water solution of the attapulgite, the polyvinyl alcohol and the aluminum sulfate, evenly mixing the bauxite, the kaolin, the talc powder and the iron oxide powder for preparing mixed powder material, mixing the water solution of the attapulgite, the polyvinyl alcohol and the aluminum sulfate, the silica sol and the refractory mixed powder material with the n-octanol, stirring and grinding. The coating has the advantages of good thixotropy, good coating property, high coating strength and good gas permeability; and the surface of a cast is smooth and has no wrinkles and other carbon defects.

The invention provides a preparation method of a composite catalytic material for nanometer molecular sieve or silicon and aluminum oxides, which is characterized in that the method comprises the steps that: firstly, the nanometer molecular sieve is synthesized with directing agent, of which the depositing and dissolving process is treated with microwave and / or ultrasonic, then the serum containing the nanometer molecular sieve is added with a mixed aqueous solution of water glass and aluminum sources and then PH is adjusted to 7 to 9.5 by adding acid to form a gel. The composite catalyst material is obtained after dying and baking the gel. The aluminum source is selected from sodium metaaluminate or aluminium sulphate. The method keeps granule of the molecular sieve product smaller than 100nm and the nanometer molecular sieve thereof is resistant to aggregation. The method is free from acid sol process so that the molecular sieve is not destroyed by acid. The composite material is suitable for catalytic cracking and hydrocracking reactions of large molecules of heavy oils.

A process material with compound artery is prepared from the Si source chosen from amorphous SiO2, si sol, silicon oxide solid, silicon gel, diatomite and water glass, the Al source chosen from sodium aluminate, sodium metaaluminate, aluminium sulfate, aluminium nitrate, etc, at least one of lithium hydroxide, sodium hydroxide, potassium hydroxide, rubidium hydroxide and cesium hydroxide, and template agent through proportional mixing, reaction, ageing and crystallizing.