9314 results about "Toxic industrial waste" patented technology

The present invention is an industrial waste water microwave electrodeless ultraviolet photocatalysis-dual membrane separation coupling treatment device, the device mainly consists of a reactor (1), a membrane separation system (2), a microwave electrodeless ultraviolet light source system (4), an aeration system, and an ozone tail gas decomposition device (7) connected to the reactor, and an inlet and outlet water system, wherein: the upper and lower parts of the reactor are respectively the reaction zone and the aeration zone, which are separated by a water distribution plate (5); the membrane separation system The microwave electrodeless ultraviolet light source system is located in the reaction zone and is separated by a corrugated partition (3); the aeration system is composed of a microporous aeration head (6) and a blower (8), and the microporous aeration head is located in the aeration At the bottom of the zone, the blower sends air to the aeration zone through the air duct. The invention has the characteristics of high reaction rate, complete degradation of organic matter, long-term operation and the like, and has strong operability and high safety. It is suitable for the treatment of refractory organic industrial wastewater, and it is also suitable for sterilization and disinfection in the field of water supply.

The invention provides methods of manufacturing biodiesel and other oil-based compounds using glycerol and combinations of glycerol and other feedstocks as an energy source in fermentation of oil-bearing microorganisms. Methods disclosed herein include processes for manufacturing high nutrition edible oils from non-food feedstock materials such as waste products from industrial waste transesterification processes. Also included are methods of increasing oil yields by temporally separating glycerol and other feedstocks during cultivation processes. Also provided herein are oil-bearing microbes containing exogenous oil production genes and methods of cultivating such microbes on glycerol and other feedstocks.

There is provided a process for the capture and sequestration of carbon dioxide that would otherwise enter the atmosphere and contribute to global warming and other problems. CO₂ capture is accomplished by reacting carbon dioxide in flue gas with an alkali metal carbonate, or a metal oxide, particularly containing an alkaline earth metal or iron, to form a carbonate salt. A preferred carbonate for CO₂ capture is a dilute aqueous solution of additive-free (Na₂CO₃). Other carbonates include (K₂CO₃) or other metal ion that can produce both a carbonate and a bicarbonate salt. Examples of suitable metal oxides include several alkaline earths including CaO and MgO. The captured CO₂ is preferably sequestered using any available mineral or industrial waste that contains calcium magnesium or iron in non-carbonate forms, or iron in the Fe⁺² oxidation state.

The invention provides a cement-based composite material used for a 3D printing technology as well as a preparation method and application thereof. The cement-based composite material is prepared from the following raw materials based on the total weight of the composite material: 33%-40% of cement, 0%-8% of inorganic powder, 32%-38% of tailing machine-made sand, 2.5%-3% of a high-molecular polymer, 0.1%-0.5% of a water reducing agent and 16.7%-20% of mixing water; a composite thickening time control agent, a thixotropic agent, a volume stabilizer and the like are added into a mixture to prepare an inorganic composite material; and then the inorganic composite material can be directly pumped into a 3D printer for building to be applied to construction. The cement-based composite material is an inorganic material and the materials are easily available; a lot of industrial waste materials can be used; therefore, the cement-based composite material is low in cost, energy-saving and environment-friendly; the condensation time can be flexibly controlled, and the material has super early strength, good caking property and strong stability; the requirements of 3D printing construction continuity of the building and the building strength are met so that the house building has good global stability and use safety; and the application and popularization of 3D printing technology can be greatly promoted.

The process and system of the invention converts carbonaceous feedstock such as coal, hydrocarbon oil, natural gas, petroleum coke, oil shale, carbonaceous-containing waste oil, carbonaceous-containing medical waste, carbonaceous-containing military waste, carbonaceous-containing industrial waste, carbonaceous-containing medical waste, carbonaceous-containing sewage sludge and municipal solid waste, carbonaceous-containing agricultural waste, carbonaceous-containing biomass, biological and biochemical waste, and mixtures thereof into electrical energy without the production of unwanted greenhouse emissions. The process and system uses a combination of a gasifier, e.g., a kiln, operating in the exit range of at least 700° to about 1600° C. (1300-2900° F.) to convert the carbonaceous feedstock and a greenhouse gas stream into a synthesis gas comprising mostly carbon monoxide and hydrogen without the need for expensive catalysts and or high pressure operations. One portion of the synthesis gas from the gasifier becomes electrochemically oxidized in an electricity-producing fuel cell into an exit gas comprising carbon dioxide and water. The latter is recycled back to the gasifier after a portion of water is condensed out. The second portion of the synthesis gas from the gasifier is converted into useful hydrocarbon products.

PCT No. PCT/JP97/00572 Sec. 371 Date Jan. 8, 1998 Sec. 102(e) Date Jan. 8, 1998 PCT Filed Feb. 27, 1997 PCT Pub. No. WO97/31990 PCT Pub. Date Sep. 4, 1997This invention provides a method for reclaiming oil from waste plastic in such a way that thermosetting resins and solid foreign matter in the plastic will not pose a problem. This method greatly reduces the burden of presorting the garbage or industrial waste. To achieve this objective when oil is to be reclaimed from a waste plastic containing chlorine compounds, such as vinyl chloride, the plastic must first be stripped of chlorine. Prior to pyrolysis, while being conveyed forward in a continuous stream, the plastic is mixed with heated sand and/or an additive agent to raise its temperature to 250-350 DEG C. This creates a product which is comprised of a mixture of sand and substantially dechlorinated plastic. The product is mixed with heated sand to heat it directly to a temperature of 350-500 DEG C. It is maintained at this temperature until pyrolysis occurs. In order to obtain high-quality oil with a low boiling point, a first gas/liquid separation process separates the product obtained from the aforesaid pyrolysis into liquid high-boiling point oil, gaseous low-boiling point oil and low molecular-weight gases, and recirculates the liquid high-boiling point oil to the pyrolysis process, and a second gas/liquid separation process separates the gaseous low-boiling point oil and low molecular-weight gases into liquid low-boiling point oil and low molecular-weight gases. The first and second gas/liquid separation process are connected in sequence.

Disclosed is a sorbent for the removal of mercury from combustion flue gas and a preparation method thereof. The sorbent includes an activated heavy oil heavy ash impregnated with 0.1-30% by weight of any chemical substance selected from sulfur, iodine, bromine and chlorine. The sorbent is prepared in an economical manner using heavy oil fly ash, industrial waste generated from heavy oil-fired boilers, and has excellent sorption performance for mercury, so that a low concentration of mercury contained in combustion flue gas discharged from large-scale boilers can be removed by injection of a small amount of the sorbent. Thus, the invention can prevent a reduction in the recycling rate of coal fly ash in coal-fired power plants and minimize operation cost.

Compositions comprising synthetic rock, e.g., aggregate, and methods of producing and using them are provided. The rock, e.g., aggregate, contains CO₂ and/or other components of an industrial waste stream. The CO₂ may be in the form of divalent cation carbonates, e.g., magnesium and calcium carbonates. Aspects of the invention include contacting a CO₂ containing gaseous stream with a water to dissolve CO₂, and placing the water under precipitation conditions sufficient to produce a carbonate containing precipitate product, e.g., a divalent cation carbonate.

The invention relates to a burning-free block brick prepared from bulky industrial waste residues. The burning-free block brick is characterized in that the block brick comprises the following raw materials in parts by weight or volume: 10-80 parts of at least one of tailing, magnesium slag, basic slag, mountain flour, cinder, fly ash, coal gangue, oil shale waste and sulfuric acid slag, 0-80 parts of at least one of gravel, waste sand, construction waste, garbage to be burnt, steel slag, mineral slag, copper slag, iron slag with gold, ardealite, phosphorous slag and carbide slag, 0-50 parts of active cementing material, 0-30 parts of cement clinker, 2-15 parts of cement and a defined amount of water. The preparation method of all types of burning-free and steaming-free standard bricks, perforated bricks, hollow blocks, paving tiles, road edge bricks and fence railings which have low cost and high strength, is as follows: proportioning, stirring for 1-6 minutes, adding a defined amount of water to stir, placing in moulds to form in a machine and performing natural curing for 7-28 days. The burning-free block brick has high raw material selectability, simple technology and wide development and application prospects, and is environmental-friendly.

An air conditioning system for conditioning the space within an enclosure having at least one inlet and one outlet, the system comprising first and second liquid/air heat exchangers; the first heat exchanger having an opening for receiving fresh air from the environment and for propelling the fresh air through the first heat exchanger to exchange heat with the liquid before it is entered into the enclosure, and the second heat exchanger having an opening for receiving air from the enclosure and for propelling it through the second heat exchanger to exchange heat with the liquid before it is expelled into the atmosphere. There are also provided methods for air-conditioning an enclosed space and for evaporation of industrial wastes.

The invention discloses a fertilizing and conditioning agent for improving the saline alkali soil, and the fertilizing and conditioning agent includes an organic material, an inorganic material and a regulator for the plant growth, wherein, the weight proportion between the organic material and the inorganic material is 3:2 to 1:1. The organic material is fermented and maturated by one or a plurality of such organic matters as town living sludge, excrements of livestock and poultry, and furfural slag; and the inorganic material is formed by one or a plurality of such industrial waste and materials as desulfurized gypsum, phosphogypsum, and ammonium sulphate. Moreover, appropriate growth regulator for plant which is added according to the growing requirements can not only improve the saline alkali soil and fertilize the soil, but also can improve the plant growth and promote the plant to grow well as well as providing an effective path for promoting the recycling of the waste resources and reducing the secondary pollution to the town and the country.

A Waste to Liquid Hydrocarbon Refinery System that transforms any municipal solid wastes and hazardous industrial wastes, Biomass or any carbon containing feedstock into synthetic hydrocarbon, particularly, but not exclusively, diesel and gasoline and/or electricity and co-generated heat, comprising three major subsystems: i) the Pyro-Electric Thermal Converter (PETC) (10) and Plasma Arc (PA) waste and biomass gasification subsystem (1); ii) the hydrocarbon synthesis subsystem (2); and iii) the electricity generation and heat co-generation subsystem (3).

The invention discloses permeable recycled aggregate and ceramsite concrete doped with industrial and agricultural solid waste and preparation. The permeable recycled aggregate and ceramsite concrete doped with industrial and agricultural solid waste is characterized in that recycled coarse aggregates and ceramsites are taken as coarse aggregates of concrete, an appropriate amount of pretreated industrial and agricultural solid waste such as industrial waste, agricultural waste, household garbage and the like is taken as an admixture, a cementing agent is prepared from cement, water, a superplasticizer and a reinforcement material, and the materials are mixed with a preset stirring process and preparation method, so that ecological concrete with good mechanical property, permeable property and durability is produced. According to the concrete, the waste utilization rate is up to about 80%, the concrete is environment-friendly, locally available materials can be used, the economic benefit is remarkable, ceramist pore is smaller, and sewage can be continuously and stably treated, so that the concrete is commonly used in water environment comprehensive improvement engineering; and besides, the concrete has light weight, high strength and good water permeability and can be also used in permeable pavement engineering such as a sidewalk, a parking lot and the like as well as plant engineering such as ecological riverway slope protection, roof landscape planting and the like.

The invention discloses active powder concrete which is prepared by Portland cement, steel slag powder, fly ash, silicon ash, effective water reducing agent, river sand, mixing water and steel fiber with the mass ratios of 0.52 to 0.58 : 0.16 to 0.18 : 0.10 to 0.16 : 0.13 to 0.16 : 0.012 to 0.018 : 0.9 to 1.1 : 0.14 to 0.18 : 0.156 to 0.234. The preparation method thereof is as follows: each component is sequentially added into a stirring machine for being uniformly stirred and shaped; then after the components are maintained, the temperature is raised to 80 to 90 DEG C at the temperature rising speed of 15 to 20 DEG C/h and then constant temperature maintaining is carried out for 72 to 96h; then, the components are cooled to room temperature at the cooling speed of not more than 20 DEG C/h to obtain the active powder concrete product. The invention employs the industrial wastes like steel slag powder and fly ash to replace quartz powder, partial cement and silicon ash, and employs thin river sand to replace quartz sand to prepare the active powder concrete of 200 grade under the maintaining conditions of normal pressure below 100 DEG C, thus not only being capable of remarkably reducing the material cost and the shaping maintaining cost, but also playing important roles on saving resources and energies, protecting the environment and promoting sustainable development as a large amount of industrial waste slag is used.

The invention provides an environment-friendly silt curing agent, which is manufactured through the following steps: one or two among fly ash, calcium sulfate, sodium sulfate, sodium carbonate and potassium carbonate, one or two among slag, slag combination, potassium hydroxide, calcium oxide, sodium silicate or silicon dioxide, one or two among carbide slag, lime or gypsum, as well as one or two among triethanol amine surfactant, calcium lignosulfonate or sodium lignosulfonate form a plurality of optimal compound formulations according to respective attributes, are optimized, compounded, ground till the Brinell specific surface areas are between 300 and 900 m2/kg respectively and then mixed, wherein particle sizes are between 0.00040 and 0.5 mm. As a large amount of waste is utilized, the curing agent saves raw materials, solves the problems about waste discharge and environmental pollution, controls waste through waste, and has important significance to environmental protection. The invention aims to provide the environment-friendly silt curing agent which has strong adaptability to a plurality of types of silt and soil, is good in curing effect, good in durability after curing and capable of utilizing industrial waste, and can be widely applied to fill engineering, embanking or embankment reinforcement engineering, road engineering and other fields.

The invention discloses a lightweight aggregate foam concrete which is composed of the following materials in parts by weight: 100-300 parts of cement, 1-150 parts of admixture, 60-250 parts of water, 1-10 parts of additive and 1-11 parts of foaming agent, as well as a lightweight material by a dosage accounting for 5%-60% of the total volume. The admixture comprising PC32.5 cement, coal ash and the like is produced from industrial waste materials such as coal ash, slag powder and clinker, so that discharge and bulk deposition of the industrial waste materials are effectively reduced and the environmental pollution is greatly reduced; therefore, good environmental protection benefit and social benefit are achieved. More importantly, expensive sulfoaluminate cement is replaced by low-cost materials, so that the cost of producing the lightweight aggregate foam concrete is greatly reduced; the performance effect of the product is extremely obvious and the physical properties of the cement is greatly improved; as a result, the outside erosion resisting capability of the concrete is effectively improved.

The present invention discloses a regenerated concrete compound material, which is made of the following components according to weight ratio: 37-53 percent of regenerated aggregate prepared by the building waste residue, 14-30 percent of regenerated fine aggregate prepared by the building waste residue, 6-14 percent of industrial waste sand, 14-18 percent of common cement, 6-8 percent of water, additive and glue powder of waste tyre. The preparation method for the regenerated concrete is that: (1) the waste tyre is crushed and then is dipped in the coupling agent solution, and is to be dried; (2) the building waste residue is crushed, screened to obtain the regenerated coarse or fine aggregate; (3) the additive is added into the aggregate and the waste sand for mixing and blending evenly; (4) the regenerated aggregate, waste sand, cement, water and glue powder are milled evenly and then the regenerated concrete compound material can be obtained. The present invention can solve the problems that the building waste residue is difficult to be treated and the entironment is polluted and deteriorated greatly and so on. The building waste residue is to be used for replacing the natural aggregate that can decrease the consumptions to the natural aggregate in the building industry, solve the problems that the natural aggregates are increasingly lacked and the entironment is damaged by the exploitation of the sand stone. The present invention can protect the living environment for the human, guarantee the sustainable development for the society and accord to the requirement of the sustainable development.

The invention discloses a light-weight ceramic brick, which is a light-weight ceramic brick fired at high temperature and has a honeycomb-like internal structure of closed pores. The invention also discloses a preparation method of the above-mentioned lightweight ceramic tiles, which is formed by dry pressing after wet ball milling, sieving, iron removal, spraying drying tower and powder spraying on the vitrified brick polishing waste produced in large quantities in the ceramic industry at present. Method forming, or kneading using wet extrusion molding, and then firing products in continuous or batch kilns. Manufacture a kind of lighter quality ceramic tiles, aiming at the insufficient use of waste materials in the past, more effectively utilize industrial waste residues in large quantities, and because of its light structure, it can be used in the decoration of high-rise building walls, It has good properties such as light weight, high strength, heat preservation, and sound absorption, and it can significantly reduce the weight of the wall structure. At the same time, it also has the characteristics of easy transportation, easy construction, and fast speed. It has great advantages in saving energy and reducing the weight of buildings. The outstanding advantage is that it is an environment-friendly building ceramic decoration material.

The invention relates to compound thermal insulation plastering material for external wall, which consists of a compound cementing material and a lightweight aggregate. The compound cementing material consists of cement, active admixture, lime powder, promoter, surfactant, anti-crack and waterproof agent, water retaining agent, flame retardant, re-dispersible emulsion powder, alkali-resistance fiber and coal flying ash cenosphere; the lightweight aggregate consists of EPS grain and expanded perlite. The invention has the advantages of low density, thermal performance, high strength, good impact resistance, bond strength and low shrinkage. The compound cementing material adopts a plurality of polymeric cementing materials, allows the insulation material to have good bond performance and simultaneously ensures falling and slipping resistance performance. The invention has good water resistance and high softening coefficient. By using cement-based cementing material as main material and organic reinforced material and waterproof component as auxiliary materials, the invention has a hydrophobic rate more than 98 percent and a softening coefficient more than 0.7. The invention can save energy and protect environment. A great deal of industrial waste residue is used in the materials, which can save a great number of energy, realize resource utilization of the waste residue and is in favor of environmental protection.

The invention provides a composite plate material of foam microcrystalline glass and pure microcrystalline glass. The composite plate material comprises a base body and a decoration surface, wherein the base body is made of a foam microcrystalline glass mixed material; the thickness of the base body is 50mm to 500mm; the decoration surface covers the surface of the base body and is made of pure microcrystalline glass granules; the thickness of the decoration surface is 3mm to 30mm. The invention also provides a manufacturing method of the composite plate material. The composite plate material of the foam microcrystalline glass and the pure microcrystalline glass, provided by the invention, can simultaneously replace a building material and a decoration material, and is small in specific gravity, high in strength, fireproof and corrosion-resistant; environment products which are difficultly handled in a natural environment and industrial wastes which are difficultly treated currently can be consumed; the environment stress is reduced.