The invention discloses a plastic-free low-shrinkage waterproof oil-proof barrier type modified
acrylate emulsion and a preparation method thereof, the plastic-free low-shrinkage waterproof oil-proof barrier type modified
acrylate emulsion comprises the following raw materials by
mass: 3-12 parts of a
nano dispersion, 13-42 parts of a hard
monomer, 30-55 parts of a soft
monomer, 3-10 parts of a
silicon-containing
monomer, 4-12 parts of a polyfunctional monomer, 0.1-3 parts of an initiator, and 2-13 parts of a reactive emulsifier; the modified
acrylate emulsion is prepared from a
nano dispersion, a hard monomer, a soft monomer, a
silicon-containing monomer, a polyfunctional monomer, an initiator and a reactive emulsifier through
soap-free
emulsion polymerization. The plastic-free low-shrinkage waterproof oil-proof barrier emulsion is prepared through
soap-free
emulsion polymerization, the prepared emulsion is small in particle size, can form a dense film after being coated on the surface of paper, and has good barrier performance on
water vapor, oil and the like; according to the plastic-free low-shrinkage waterproof oil-proof barrier emulsion, a polyfunctional structure, especially structures containing-COOH,-OH,-NH2,-NH-C (= O)-NH-and the like, is introduced into a molecular structure, so that the emulsion has good adhesion to paper-based fibers.