The invention relates to a 3D printing composite positive
pole piece, a preparation method thereof and a
solid-state battery, the 3D printing composite positive
pole piece comprises 90-97wt% of a positive active material, 10-15wt% of a conductive agent, 10-15wt% of a binder, 10-15wt% of a
plasticizer and 10-15wt% of a
polymer monomer; the proportion of the conductive agent is 1 to 3.5 weight percent; the
plasticizer accounts for 0 to 1.5 wt%; the binder accounts for 1 to 5 weight percent; the proportion of the
polymer monomer is 1 to 5 weight percent. The method has the advantages that the raw materials are printed on the positive
electrode current collector in a 3D printing mode, the printed
electrode has high integration and high material
utilization rate, compared with a
coating mode, the battery manufacturing time and cost can be effectively reduced, monomers in the
electrode and an
electrolyte precursor solution are polymerized, the combination degree between the
solid electrolyte and the electrode is improved, and the battery performance is improved. And electrode /
solid electrolyte integration is realized, so that the
interface impedance between the electrolyte and the electrode is reduced, the
lithium ion interface transmission is accelerated, and the capacity
exertion and rate capability of the positive
electrode material are improved.