46results about "Chlorine oxides" patented technology

The utility model relates to the technical field of chlorine dioxide equipment, in particular to a chlorine dioxide generating device which comprises a reaction tank, a first accommodating part, a second accommodating part, a liquid level sensor and a controller, the first accommodating part and the second accommodating part convey corresponding solutions to the reaction tank; the liquid level sensor measures the liquid levels of solutions in the first containing part and the second containing part in real time and sends the liquid levels to the controller in real time; the controller receives data of the liquid level sensor and judges whether the hydrochloric acid solution and the sodium chlorate solution are conveyed normally or not according to a preset threshold value or a proportional relation, and when the controller detects that the liquid level data are abnormal, the controller can control the alarm unit to send out an alarm signal, so that workers are reminded to debug, maintain or replace equipment; the liquid level of hydrochloric acid and sodium chlorate solutions is monitored in real time through the liquid level sensor, problems are found in time, accurate conveying of hydrochloric acid and sodium chlorate is ensured, the synthesis efficiency of chlorine dioxide is improved, and raw material waste caused by unbalanced conveying proportion is reduced.

The invention relates to an impurity removal method of a chlorine dioxide vertical generator, which comprises the following steps: adding first pure water and a sodium hypochlorite solution into the chlorine dioxide vertical generator, continuously boiling under a vacuum condition, cooling and discharging liquid; washing with second pure water and discharging liquid; the boiling temperature is lower than 80 DEG C. Different from the prior art, the technical scheme provides a mode for efficiently removing impurities in a mode that the sodium hypochlorite solution is boiled at the temperature lower than 80 DEG C, the boiling temperature in the mode is lower than the efficient decomposition temperature 80 DEG C of hypochlorite, the hypochlorite is high in stability, the decomposition amount is small although the hypochlorite is boiled, and therefore the impurity removing efficiency is higher; the chlorine dioxide vertical generator impurity removal device has the advantages of simple and effective impurity removal of the chlorine dioxide vertical generator, no residue, reduction of the decomposition of chlorine dioxide, and improvement of the production efficiency and the production safety.

To provide an apparatus for generating chlorine dioxide capable of reducing components to be used.SOLUTION: In an apparatus for generating chlorine dioxide 1, a sodium chlorite solution 5 and fumed silica 7 are mixed in a container 3 to generate chlorine dioxide.SELECTED DRAWING: Figure 2

The utility model discloses a concentrated sulfuric acid distributor for preparing chlorine dioxide, which comprises an outer tantalum tube, an inner tantalum tube and a spray head, two ends of the outer tantalum tube are respectively provided with an outer tantalum tube flange, one end of the inner tantalum tube is arranged on the outer side of the outer tantalum tube, the other end of the inner tantalum tube is arranged on the inner side of the outer tantalum tube, and an inner tantalum tube flange is arranged at one end of the inner tantalum tube. The nozzle is arranged in the outer tantalum tube and is coaxial with the outer tantalum tube, the nozzle comprises a first cone and a second cone which are coaxially arranged, a sealing plate is arranged on the top surface of the second cone, the second cone is fixedly connected with the inner wall of the outer tantalum tube through a plurality of rib plates, and a plurality of small holes are uniformly distributed in the surface of the second cone between two adjacent rib plates. According to the utility model, the flow velocity of reaction liquid can be effectively utilized, so that a concentrated sulfuric acid solution is uniformly distributed, the condition that chlorine dioxide is decomposed due to overhigh local acidity is avoided, and the chlorine dioxide yield of the device is further improved.

The utility model relates to the technical field of chlorine dioxide generation, and discloses a protective chlorine dioxide generator which comprises a generator body, metering pumps are installed on the two sides of the generator body, and a sodium chlorate storage tank is installed on one side of the metering pump on the left side of the generator body. A hydrochloric acid storage tank is mounted on one side of the metering pump on the right side of the generator main body, and guide grooves are formed in the exteriors of guide rods and are formed in the two sides of the front end and the rear end in the generator main body. According to the utility model, the components such as the rubber protection plate, the spring, the guide rod and the guide groove are arranged, and when the generator main body is used, a protection structure formed by the components is additionally arranged at the front end and the rear end of the generator main body, so that the generator main body has a certain protection property; when external impact force is encountered, the protection structure formed by the components can reduce the external impact force to protect the generator main body.

The utility model discloses an efficient chlorine dioxide generator, which relates to the field of reaction kettle structures, and comprises a reaction kettle body used for accommodating the generation reaction of chlorine dioxide; the appearance of the catalysis part is of a plate-shaped structure, the catalysis part is movably clamped in the reaction kettle body, a gap exists between the catalysis part and the bottom wall of the reaction kettle body, and the catalysis part is arranged to provide a catalyst for the generation reaction of chlorine dioxide; the raw materials for the chlorine dioxide generation reaction can circulate above the catalytic part and in the gap. According to the reaction kettle disclosed by the utility model, the catalytic part is arranged in the reaction kettle body, and the gap is formed between the catalytic part and the bottom wall of the reaction kettle body, so that raw materials for generating reaction of chlorine dioxide can circulate above the catalytic part and in the gap, and the purposes of improving the catalytic efficiency and saving the use amount of reaction sulfuric acid are achieved.

This utility model discloses a chlorine dioxide generator and its quantitative feeding component and device. The quantitative feeding component includes a hopper and a feeding mechanism. The hopper has a storage chamber and a feeding chamber. The top of the feeding chamber is connected to the storage chamber through a first inlet, and the bottom of the feeding chamber has a first outlet, which is staggered from the first inlet. The feeding mechanism is rotatably connected to the hopper. The quantitative feeding device includes a quantitative feeding component, a material tray, a weighing structure, and a feeding drive component. The chlorine dioxide generator includes a shell, a feeding device, a reaction chamber, a gas supply device, and a quantitative feeding device. This utility model can directly add chlorine dioxide effervescent tablets to water to react and obtain ClO₂ gas. It can control the amount of chlorine dioxide effervescent tablets fed, thereby controlling the amount of ClO₂ gas generated. No storage is required; it is ready to use immediately, improving ease of use, enhancing the effect of disinfection and odor removal, improving safety, and reducing costs.

To provide a chlorine dioxide generating composition for simultaneously discharging chlorine dioxide and moisture, and a one pack type and compact chlorine dioxide generating tool using the same which has less chlorine odor at the time of use start and can generate more chlorine dioxide, and ensures a longer period during which chlorine dioxide is generated.SOLUTION: A hydrous tablet generates chlorine dioxide, wherein the hydrous tablet contains a chlorite (A), a water-absorbing resin (B) and a hydrophilic binding agent (C), a content of the moisture in the hydrous tablet is 3 wt.% or more and 20 wt.% or less with respect to the total weight, and the hydrous tablet generates chlorine dioxide while discharging moisture.SELECTED DRAWING: None

A method for producing a moisture-activated powder that provides for the generation and release of chlorine dioxide without detectable amounts of any toxic by-products, such as chlorine gas, chlorite, or chlorate, is provided. The powder does not need to be exposed to light before or during its exposure to moisture or relative humidity to generate gas. The powder can also be prepared under conditions that minimize or prevent the decomposition or oxidation of sodium chlorite or premature moisture activation of the powder during the manufacturing process to maximize its activity.

The invention discloses a method for preparing a high-concentration chlorine dioxide solution without a catalyst, relates to the technical field of disinfection, and compared with a conventional method, the stability and the purity of the generated chlorine dioxide solution are improved. The method comprises the step of reacting a sodium chlorite solution with potassium persulfate to generate chlorine dioxide. According to the present invention, the prepared sodium chlorite solution and the potassium persulfate are subjected to the light-shielding reaction in the reactor, such that the sufficient reaction of the sodium chlorite solution and the potassium persulfate is definitely ensured, the efficient chlorine dioxide preparation is achieved, no additional buffer agent is added so as to prepare the aqueous phase chlorine dioxide solution, and the long-term stable storage can be achieved.

An improved chlorine dioxide gas generating device comprises a bottle body and a cover body, the cover body is provided with a first vent groove used for emitting disinfection gas to the external environment, the bottle body is provided with a fixed structural part at a bottle opening, the fixed structural part is provided with a channel communicated with the interior of the bottle, and the channel is communicated with the interior of the bottle. A ventilation structural part capable of sliding up and down is assembled in the channel, the ventilation structural part comprises a ventilation part, a groove communicated with the first ventilation groove is formed in the ventilation part, and a plurality of second ventilation grooves are annularly formed in the side wall of the groove. A protruding ring is arranged on the inner wall of the channel, the outer wall of the ventilation structural part is matched with the inner diameter of the protruding ring, and the groove length of the second ventilation groove is larger than the width of the protruding ring. When the ventilation structural part moves downwards to the lower limit, the convex ring blocks the upper portion of the second ventilation groove, and disinfection gas in the bottle body sequentially passes through the lower portion of the second ventilation groove, the groove and the first ventilation groove to be emitted to the external environment.

To provide a chlorine dioxide generating apparatus and a fumigation composition that are more reliable and smooth in reaction with a heat generating agent and a chlorine dioxide generating agent than in the prior art, ensure a sufficient amount of chlorine dioxide to be generated stably, have simple operation, and are easy to dispose after use, and are environmentally friendly.SOLUTION: Provided is a chlorine dioxide generating apparatus that includes a metal can having an upper lid and a bottom lid at an easy open end, which metal can contains a water-permeable or water soluble bag accommodating a fumigating composition comprising a solid heat generating agent for generating heat when in contact with water and a solid chlorine dioxide generating agent for generating chlorine dioxide when in contact with water. Preferably, the upper lid is a partially-open end lid and the bottom lid is a full-open end lid. The apparatus may be provided in a form of kit that further includes a container containing a sufficient amount of water to generate water vapor from the heat generating agent.SELECTED DRAWING: Figure 2

To provide a sterilization kit that has high safety and is usable in a simple manner.SOLUTION: A sterilization kit comprises: a container capable of forming a closed space; and a disinfectant gas supply unit that is installable in the closed space and delivers a disinfectant gas at concentration within a defined range depending on the size of the closed space.SELECTED DRAWING: Figure 1

The present disclosure provides a medicinal agent that is useful for disinfection of microorganisms and the like. The present disclosure provides a chlorine peroxide radical. The chlorine peroxide radical is preferably provided as a liquid. Also provided are: a method for producing the chlorine peroxide radical; a method for killing microorganisms using the chlorine peroxide radical; a microorganism-killing agent; a method for measuring bactericidal activity; a device for measuring the chlorine peroxide radical; and a kit for preparing the chlorine peroxide radical. This method for producing the chlorine peroxide radical includes a step for bringing a chlorine oxide into contact with an excess of hydrogen ions.

The invention belongs to the technical field of water treatment and disinfection, and particularly relates to a chlorine dioxide releasing agent with low corrosivity and a flocculation function and a preparation method of the chlorine dioxide releasing agent. The chlorine dioxide releasing agent is prepared from the following raw materials in percentage by mass: 8 to 12 percent of potassium ferrate, 16 to 22 percent of sodium chlorite, 15 to 23 percent of organic acid, 12 to 14 percent of ferric salt, 10 to 20 percent of peroxide donor, 6 to 12 percent of succinic acid and the balance of drying agent. The pH value of a solution activated by the chlorine dioxide releasing agent is close to neutral, and the problems that an existing chlorine dioxide releasing tablet is too low in pH and too strong in corrosion are solved; and moreover, the conversion rate of sodium chlorite and the purity of chlorine dioxide are effectively improved. In addition, the releasing agent also has dual effects of disinfection and flocculation of clear water, not only improves the disinfection efficiency, but also greatly reduces the production cost.

To provide a chlorine dioxide generating agent and a method for producing a chlorine dioxide generating agent, which can efficiently generate chlorine dioxide gas.SOLUTION: A chlorine dioxide generating agent generates chlorine dioxide gas upon contact with air. The chlorine dioxide generating agent is in the form of powder. The powder comprises a porous carrier having a transition metal supported on its surface, and powders of a chlorite and a coating agent are attached to the surface of the carrier with an adhesive. When the chlorine dioxide generating agent comes into contact with air, chlorine dioxide gas can be stably generated.SELECTED DRAWING: Figure 1

This invention belongs to the field of water treatment and disinfection technology, specifically relating to a chlorine dioxide releasing agent with both low corrosivity and flocculation functions, and its preparation method. The chlorine dioxide releasing agent is composed of the following raw materials in the indicated mass percentages: potassium ferrate 8-12%, sodium chlorite 16-22%, organic acid 15-23%, iron salt 12-14%, peroxide donor 10-20%, succinic acid 6-12%, with the balance being a desiccant. The activated solution of the chlorine dioxide releasing agent obtained by this invention has a near-neutral pH value, solving the problem of excessively low pH and strong corrosion in existing chlorine dioxide releasing tablets; it also effectively improves the conversion rate of sodium chlorite and the purity of chlorine dioxide. Furthermore, this releasing agent has dual functions of disinfection and flocculation of clean water, not only improving disinfection efficiency but also significantly reducing production costs.

To provide a chlorine dioxide generator that is effective for sterilization or bacteriostasis and deodorant of microorganisms under the environment of a recessed form such as a drain port of a bathroom, a kitchen or the like which is always exposed to moisture, and a structure of which is simplified to reduce a manufacturing cost.SOLUTION: A chlorine dioxide generator installed to a drain port of a bathroom or a kitchen, in which chlorine dioxide generating agent containing chlorite, pH adjuster and water absorbent is housed in a container body made of a resin container, one or more pores are formed on the container body, an opening area per single pore is 0.02 to 15 mm2 or less, and water enters from the pore into the container body.SELECTED DRAWING: Figure 1

The utility model belongs to the technical field of wastewater treatment, and relates to a chlorine dioxide generation system and a wastewater treatment system. The chlorine dioxide generating system comprises a control box, a pretreatment stirring tank for uniformly mixing raw materials and a reaction kettle for generating chlorine dioxide, according to the utility model, concentrated sulfuric acid, hydrogen peroxide and sodium chlorate are used as raw materials for reaction, the reaction equation is as follows: chlorine dioxide gas with the purity of more than 95% is generated under the catalysis of a catalyst at a specific temperature, the conversion rate is high, byproducts are few, and the safety of personnel and equipment can be effectively ensured by arranging a pressure gauge on the reaction kettle.

The present invention provides a chlorine dioxide generator that can reduce the amount of components used. [Solution] In the chlorine dioxide generator 1, a sodium chlorite solution 5 and fumed silica 7 were mixed in a container 3 to generate chlorine dioxide.

To provide a method for generating chlorine dioxide in solution without using catalysts or hypochlorites, and a method for efficiently generating chlorine dioxide by light application under neutral to basic conditions, which has been difficult with sodium chlorite due to superior corrosion resistance and safety aspects.SOLUTION: A method for generating chlorine dioxide is characterized by applying light including ultraviolet light to an aqueous solution containing chlorite represented by the following formula (1) and adjusted to pH 6 or higher. (In formula (1), R11, R21, R31, and R41 are each an alkyl group, and may contain an ether bond, a ketone (carbonyl group), an ester bond, or an amide bond, or an aromatic ring.)SELECTED DRAWING: None

The utility model discloses a chlorine dioxide disinfectant production facility, specifically related to production facility technical field, including frame, the frame upper end fixedly connected with plastic bucket, the frame upper end fixedly connected with absorption subassembly, plastic bucket inner chamber bottom wall fixedly connected with aeration subassembly, plastic bucket upper end fixedly connected with circulation subassembly, the frame upper end fixedly connected with stirring subassembly, absorption subassembly inner chamber left part rotation is connected with rotating subassembly. The chlorine dioxide disinfectant production facility can be realized to the chlorine dioxide in the bottom of water and is discharged through the aeration subassembly and stirring subassembly of design, then and the waste gas produced by water fusion will be discharged from circulation subassembly and return to the bottom of water, carry out the secondary use of waste gas, and can make the disinfection ability of chlorine dioxide disinfectant improve, and the used waste gas is absorbed from absorption subassembly again, avoids waste gas to reach the outside and thereby influences the environment.

To provide technology that can prevent corrosion of equipment even when a high concentration of chlorine dioxide is generated and keeps the equipment clean.SOLUTION: A chlorine dioxide gas generator comprises a chlorine dioxide gas generating section that generates a high concentration of chlorine dioxide gas and a blower that sends out the chlorine dioxide gas generated in the chlorine dioxide gas generating section. The blower has a blade that rotates, a motor housing, a motor housed in the motor housing, and a shaft that transmits the power of the motor to the blade. A rotating seal that seals between the shaft and the motor housing contains grease for preventing the chlorine dioxide gas from entering the inside of the motor housing.SELECTED DRAWING: Figure 1

The utility model discloses a chlorine dioxide gas generating system which comprises a primary reaction device and a main reaction device, the primary reaction device comprises a primary reactor, and a reaction raw material inlet and a reaction mixed liquid outlet are formed in the primary reactor; the main reaction device comprises a main reactor, a packed bed is arranged in the main reactor, and the main reactor is provided with a hot diluent gas inlet, a residual liquid outlet and a reaction gas outlet; a reaction mixed liquid outlet of the primary reactor is positioned above the packed bed in the main reactor; the system disclosed by the utility model is sufficient in reaction, high in yield and not easy to block equipment.

The present invention addresses the problem of providing a method for rapidly generating chlorine dioxide gas at a desired time while maintaining the temperature during a reaction at a low temperature. Provided is a method for producing chlorine dioxide gas, comprising a step of reacting a chlorite salt, an amino acid, and an aldehyde compound in a solvent in a container under acidic conditions.

The application discloses a kind of pry dress formula chlorine dioxide generation device, comprising: support platform, set in container bottom and specifically box bottom predetermined height;Multiple storage tanks, be set on support platform, multiple storage tanks are used to store acid raw material and reducing agent respectively;Primary reaction chamber and secondary reaction chamber, set on support platform, the primary reaction chamber utilizes multiple metering pumps and is connected with multiple storage tanks pipeline respectively, and / or secondary reaction chamber utilizes multiple metering pumps and is connected with multiple storage tanks pipeline respectively;Diluter, be set on support platform, one end of the diluter is connected with diluent storage tank pipeline, other end is connected with the primary reaction chamber and / or secondary reaction chamber pipeline, and the diluter is used to mix diluent with high concentration chlorine dioxide solution generated in primary reaction chamber and / or secondary reaction chamber proportionally to generate chlorine dioxide solution and discharge.The technical scheme of the application avoids the security risk problem caused by chlorine dioxide gas volatilization, ensures construction safety.

The invention discloses a preparation method of high-purity chlorine dioxide, which relates to the field of preparation of chlorine dioxide, and comprises the following steps: adding a reagent A and a reagent B into a reaction kettle for reaction to prepare chlorine dioxide, wherein the reagent A comprises chlorate, hydrogen peroxide, a stabilizer and water, and the reagent B comprises sulfuric acid, a catalyst and water. Under the action of the stabilizer and the catalyst, chlorate reacts with hydrogen peroxide in the acidic medium to prepare chlorine dioxide, so that the purposes of improving the purity of the prepared chlorine dioxide and the conversion rate of chlorate and reducing the reaction acidity are achieved.