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837 results about "Sodium chlorite" patented technology

Sodium Chlorite (NaClO₂) is a chemical compound used in the manufacturing of paper and as a disinfectant.

Integrated process for separation of lignocellulosic components to fermentable sugars for production of ethanol and chemicals

A continuous and modular process converts lignocellulosic materials for the production of ethanol principally and / or chemicals such as methanol, butanediol, propanediol, hydrocarbon fuel, etc. Renewable lignocellulosic biomass such as but not all inclusive hardwoods (gum, beech, oak, sweet gum, poplar, eucalyptus, etc.), soft woods (pines, firs, spruce, etc.), corn stovers, straws, grasses, recycled papers, waste products from pulp and paper mills, etc can be used as feedstock. The process is designed to be modular and the feed entry point can be selected to adapt to different biomass feedstock. Lignocellulosic biomass such as hardwood and softwood are subjected to chemical / pressure treatment stages using potent and selective chemicals such as sodium chlorite / acetic acid (anhydrous) and chlorine / chlorine dioxide to separate the main components—lignin, cellulose (glucose) and hemicelluloses (xylose, arabinose, galactose)—into three process streams. The separated carbohydrates are further subjected to washing, cleaning, neutralization, and / or mild hydrolysis and subsequently fermented to produce ethanol. Residual lignin and extractives remained with the cellulose are removed by chemical treatment steps to enhance the fermentations of cellulose. Pre-hydrolysate after neutralization to neutralize and remove toxic components such as acetic acid, furfural, phenolics, etc. containing (xylose, arabinose, galactose) and hexoses (glucose) can be either separately or together with the purified cellulosic fraction fermented to produce ethanol. Approximately 100 gallons of ethanol, suitable to be used as a fuel, can be produced from one dried ton of wood. Significant amount of lignin are separated as a by-product and can be converted to hydrocarbon fuel, surfactant, drilling aid, or can be incinerated for generation of power and steam.
Owner:NGUYEN XUAN NGHINH

Preparation method of homogenized fine nano-cellulose fiber

The invention relates to a preparation method of a homogenized fine nano-cellulose fiber. The preparation method can solve the problems of uniform diameter distributor of biomass nano-cellulose prepared by the existing strong acid hydrolysis method and the high-strength mechanical shearing method, easy gathering among the nano-fiber and a narrow range of applications of the TEMPO catalytic oxidation method. The preparation method comprises the following steps: 1) extracting biomass fiber with benzyl alcohol solution; 2) carrying out treatment by using acidified sodium chlorite; 3) carrying out gradient treatment with alkaline liquor; 4) using TEMPO, sodium bromide and sodium hypochlorite for catalytic oxidation treatment; 5) using sodium chlorite for treatment; and 6) carrying out nano-scale processing by using the long-term stirring method, the ultrasonic method or the high-pressure homogenization method, drying, and then obtaining the homogenized fine nano-cellulose fiber. The fiber has the uniform diameter distribution, the diameter is 3-5nm, the length-diameter ratio is not less than 500, the fiber is mutually interwoven into a mesh snarling structure, and the method is applicable to preparing the nano-cellulose fiber by using wood pulp, paper-making pulp, wood, bamboo and crop straw.
Owner:NORTHEAST FORESTRY UNIVERSITY

Method for preparing nanometer cellulose fiber through combining ultrasound and high-pressure homogenization treatment

The invention provides a method for preparing nanometer cellulose fiber through combining ultrasound and high-pressure homogenization treatment, which relates to a preparation method of nanometer cellulose fiber. The invention solves the problems of short length, nonuniform fiber diameter distribution and easy interweaving between fiber into cluster nanometer fiber of the nanometer cellulose fiber prepared by the existing method only using mechanical high-pressure homogenization treatment. The method of the invention comprises the following steps that: 1. biomass fiber is extracted by an alcohol benzene solution; 2. the treatment by acidified sodium chlorite is carried out; 3. alkali liquor gradient treatment is carried out; 4. an ultrasonic cell crushing machine is used for treatment; and 5. high-pressure homogenization treatment is carried out, and nanometer cellulose fiber is obtained after being dried. The fiber diameter distribution is uniform, the length is longer than or equal to 150 mum, the slenderness ratio is larger than or equal to 600, and the fiber is mutually interwoven into a reticular winding structure. The method of the invention is applicable to the preparation of nanometer cellulose fiber from wood pulp, papermaking pulp materials, wood materials, bamboo materials and crop straws.
Owner:NORTHEAST FORESTRY UNIVERSITY

Preparation method of biomass cellulose nanofibers with high length-diameter ratio

The invention relates to a preparation method of biomass cellulose nanofibers with a high length-diameter ratio, in particular to a preparation method of nano cellulose fibers, solving the problems that nano cellulose fibers prepared by using a traditional method for hydrolyzing biomass cellulose with strong acid have short length and small length-diameter ratio, nano cellulose fibers prepared by using a mechanical shearing method are easy to mutually aggregate, and a microbial fermentation method has high cost. The method comprises the following steps of: (1) purifying biomass cellulose with a benzyl alcohol solution; (2); treating with acidified sodium chlorite; (3) treating lye; (4) treating with the acidified sodium chlorite again; (5) treating with KOH; (6) treating with hydrochloric acid; and (7) ultrasonically treating and drying to obtain biomass cellulose nanofibers with high length-diameter ratio not less than 1500, fiber diameter from 50 nm to 300 nm, length not less than 150 um and length-diameter ratio not less than 1500. The biomass cellulose nanofibers are mutually interwoven into a tightly wound mesh structure. The invention has low cost and is suitable for preparing nano cellulose fibers from wood, bamboo, cotton, linen and crop straw.
Owner:NORTHEAST FORESTRY UNIVERSITY

Solid chlorine dioxide sustained-release material and preparation method thereof

The invention discloses a solid chlorine dioxide sustained-release material and a preparation method thereof, raw materials comprise sodium chlorite, a solid acid, a carrier material, a coating agentand auxiliary agents; the carrier material is silicon dioxide aerogel micro powder; and the auxiliary agents include an accelerator, a stabilizer, and a binder. The solid chlorine dioxide sustained-release material can realize a controllable release rate of chlorine dioxide by silicon dioxide aerogel micro powder loading, polymer coating and accelerator adjustment, and has more excellent air purification effect; the safety, long-term stability and stability of the chlorine dioxide released by the solid chlorine dioxide sustained-release material can be realized by controlling of the mass transfer of a chemical reaction process for producing the chlorine dioxide; the solid chlorine dioxide sustained-release material product prepared by the method is convenient to use, can effectively removeair pollutants (such as formaldehyde), deodorizes (H2S), and sterilizes, air is purified, and the solid chlorine dioxide sustained-release material product is safe and environmentally-friendly, is stable and reliable in production process, high in efficiency and low in cost, and has a good market prospect.
Owner:SUZHOU SASENS CO LTD

Sustained-release chlorine dioxide disinfectant and method for preparing same

InactiveCN108651453AThe finished product is safe and reliableNo harmBiocideDispersed particle separationDisinfectantHazardous substance
The invention discloses a sustained-release chlorine dioxide disinfectant and a method for preparing the same. The method includes steps of S1, mixing sodium chlorite powder, silica gel powder and diatomaceous earth with one another according to certain proportions to obtain coating agents; S2, mixing the coating agents and carrier granules with one another, feeding the coating agents and the carrier granules into granulators, spraying adhesive into the granulators and carrying out coating, granulating and drying to obtain the sustained-release chlorine dioxide disinfectant; S3, packing the sustained-release chlorine dioxide disinfectant in air permeable bags. The sustained-release chlorine dioxide disinfectant and the method have the advantages that finished products of the sustained-release chlorine dioxide disinfectant prepared by the aid of the method are safe and reliable and are free of harm on human bodies; bacteria and viruses in air can be effectively killed by the sustained-release chlorine dioxide disinfectant, and harmful substances such as formaldehyde can be degraded by the sustained-release chlorine dioxide disinfectant; the finished products are long in shelf life,and the shelf lives of the finished products can be greatly prolonged under wet-insulation storage conditions.
Owner:张志 +1

Method for preparing cellulose nano-fibril film by utilizing wood powder

The invention relates to a method for preparing a cellulose nano-fibril film by utilizing wood powder, which comprises the following steps: 1) chemically pre-processing; 2) mechanically separating; and 3) preparing a film. The method has the advantages: the acid-base pre-processing is combined with wood powder grinding and is adopted for preparing; the lignin in the wood powder is removed by mainly utilizing sodium chlorite under an acidic condition; the half-fibril is removed by using the diluted potassium hydroxide and the remained substrate is cellulose; and the diluted hydrochloric acid is used for splitting the cellulose. The acting force of hydrogen bonds in the fibril is reduced by adopting the splitting treatment, so that the biomass cellulose nano-fibril at high length-diameter ratio is obtained; the mineral substance in the fiber is removed by utilizing HCl treatment, the alkali insoluble half-cellulose in the purified cellulose is influenced and the effect of purifying the cellulose fiber is achieved; the chemical constituents are detected through Fourier transform infrared; the grinding treatment is simple and easy to operate and the mass production is performed; the modulus of elasticity is 3105.27MPa; and the tensile strength is 64.24MPa.
Owner:襄垣县鑫瑞达连氏塑木制造有限公司 +1

Nano-crystalline cellulose fiber high in carboxyl group content and preparation and application thereof

The invention belongs to the technical field of biomass nanometer materials and discloses a nano-crystalline cellulose fiber high in carboxyl group content and preparation and application thereof. A preparation method comprises the steps of preheating fiber slurry for 0.5-1.5h with sodium periodate at the temperature of 50-60 DEG C; adding a sodium chlorite solution and acetum into the slurry to be reacted for 1-3h at the temperature of 30-50 DEG C, adding TEMPO, NaClO2 and NaClO, and performing microwave heating to the temperature of 55-65 DEG C to enable the mixture to be reacted for 1-3h; performing ultrasonic dispersion and freeze drying to obtain the nano-crystalline cellulose fiber high in carboxyl group content. According to the nano-crystalline cellulose fiber, hydroxyl at the positions of C2 and C3 of cellulose is oxidized into a formyl group which is oxidized into carboxyl by sodium chlorite, hydroxyl at the position of C6 is selectively oxidized into carboxyl through a TEMPO neutral oxidation system, and accordingly the total carboxyl group content of the fiber is greatly increased, and obtained products can be used for advanced treatment of waste water at the middle section of paper making.
Owner:SOUTH CHINA UNIV OF TECH

Hypochlorite free method for preparation of stable carboxylated carbohydrate products

A method of making a carboxylated carbohydrate is disclosed, cellulose being a preferred carbohydrate material. Carboxylated cellulose fibers can be produced whose fiber strength and degree of polymerization is not significantly sacrificed. The method involves the use of a catalytic amount of a hindered cyclic oxammonium compounds as a primary oxidant and chlorine dioxide as a secondary oxidant in an aqueous environment. The oxammonium compounds may be formed in situ from their corresponding amine, hydroxylamine, or nitroxyl compounds. The oxidized cellulose may be stabilized against D.P. loss and color reversion by further treatment with an oxidant such as sodium chlorite or a chlorine dioxide / hydrogen peroxide mixture. Alternatively it may be treated with a reducing agent such as sodium borohydride. In the case of cellulose the method results in a high percentage of carboxyl groups located at the fiber surface. The product is especially useful as a papermaking fiber where it contributes strength and has a higher attraction for cationic additives. The product is also useful as an additive to recycled fiber to increase strength. The method can be used to improve properties of either virgin or recycled fiber. It does not require high α-cellulose fiber but is suitable for regular market pulps.
Owner:INT PAPER CANADA PULP HLDG ULC

Slow-release chlorine dioxide solid disinfectant

The invention relates to a slow-release chlorine dioxide solid disinfectant, which is formed by mixing sodium chlorite microcapsules and solid acid microcapsules according to a weigh ratio being 1:(1-2), core materials of the sodium chlorite microcapsules are sodium chlorite, a water-soluble organic matter layer and a water-insoluble high polymer material layer are sequentially covered outside the core materials, core materials of the solid acid microcapsules are solid acid or salts capable of releasing hydrogen ions, a water-soluble organic matter layer and a water-insoluble high polymer material layer are sequentially covered outside the core materials, the water-soluble organic matter is selected from polyvinyl alcohol, polyethylene glycol or polyacrylamide, and the water-insoluble high polymer materials are selected from polymethyl methacrylate, ethylene-vinyl acetate or polylactic acid. The disinfectant cannot be easily deliquesced, and the stability is high. After the slow-release chlorine dioxide solid disinfectant is placed into water, sodium chlorite and solid acid are respectively and slowly released onto the surfaces of the microcapsules, chlorine dioxide is generated through the reaction, the contact between the sodium chlorite and the solid acid is retarded, and good slow release performance is realized.
Owner:吕永生 +5
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