Solid chlorine dioxide sustained-release material and preparation method thereof
A chlorine dioxide, slow-release material technology, applied in the fields of botanical equipment and methods, oxidized water/sewage treatment, chemicals for biological control, etc., can solve the problem of inconvenient gas storage, transportation and use, poor air purification effect problems such as good quality and danger, to achieve stable and reliable production process, excellent air purification effect, and the effect of removing air pollutants
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[0033] The present invention also provides a preparation method of solid chlorine dioxide slow-release material, the steps comprising:
[0034] 1. Preparation of the silica airgel micropowder:
[0035] 1) Prepare a mixed solution of ethyl orthosilicate, hydrochloric acid, water, and ethanol solution, and reflux at 120°C for 2-4 hours to obtain a prepolymer; the concentration of hydrochloric acid is 1mol / L, and ethyl orthosilicate, hydrochloric acid, water , The volume ratio of ethanol solution is 10:0.01-0.5:0.5-5:200-500;
[0036] 2) Take the prepolymer and dilute it with n-hexane, add ammonia water dropwise under stirring conditions at room temperature, and then let it stand for 2 hours to obtain a gel; the concentration of ammonia water is 1mol / L, and the volume ratio of prepolymer, n-hexane and ammonia water is 100:500-1000:1-5;
[0037] 3) Stir again to pulverize the gel, replace it with n-hexane solvent, and dry it under normal pressure at 120-150° C. to obtain silica ...
Embodiment 1
[0044] A solid chlorine dioxide slow-release material, its raw materials include: sodium chlorite, solid acid, carrier material, coating agent and auxiliary agent; the carrier material is silica airgel micropowder; the auxiliary agent includes Accelerators, stabilizers and binders. The accelerator is one or more of anhydrous ferric chloride, potassium persulfate, sodium dichloroisocyanurate, glucose, potassium permanganate, and sodium chloride. The solid acid is one of citric acid, sulfamic acid, tartaric acid, oxalic acid, sodium bisulfate; the coating agent is gelatin, acacia powder, rosin, paraffin, polyvinylpyrrolidone, acrylic acid and methacrylic acid One of the copolymers; the stabilizer is anhydrous calcium chloride or anhydrous magnesium sulfate, and the composition of the binder includes silica gel. The mass ratio of described sodium chlorite, solid acid, carrier material, coating agent and auxiliary agent is 10:15:10:10:40; The mass ratio of described accelerator, ...
Embodiment 2
[0054] A solid chlorine dioxide slow-release material, its raw materials include: sodium chlorite, solid acid, carrier material, coating agent and auxiliary agent; the carrier material is silica airgel micropowder; the auxiliary agent includes Accelerators, stabilizers and binders. The accelerator is one or more of anhydrous ferric chloride, potassium persulfate, sodium dichloroisocyanurate, glucose, potassium permanganate, and sodium chloride. The solid acid is one of citric acid, sulfamic acid, tartaric acid, oxalic acid, sodium bisulfate; the coating agent is gelatin, acacia powder, rosin, paraffin, polyvinylpyrrolidone, acrylic acid and methacrylic acid One of the copolymers; the stabilizer is anhydrous calcium chloride or anhydrous magnesium sulfate, and the composition of the binder includes silica gel. The mass ratio of described sodium chlorite, solid acid, carrier material, coating agent and auxiliary agent is 10:15:15:12:50; The mass ratio of described promotor, sta...
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