8104 results about "Prepolymer" patented technology

The invention provides a low-voltage cable, and relates to the technical field of cables, the low-voltage cable comprises a conductor layer, a support layer, a shielding layer and a sheath layer, the conductor layer is composed of multiple strands of fractal stranded conductors, and each fractal stranded conductor comprises an inner-layer superfine silver-plated copper wire, a middle-layer copper-clad aluminum wire and an outer-layer nickel-plated copper alloy wire; the supporting layer wraps the conductor layer and comprises an inner supporting layer, a dynamic framework layer and an outer restraint layer, the inner supporting layer is an obliquely wound aramid fiber woven belt, the dynamic framework layer is formed by alternately arranging shape memory polymers and carbon fiber composite belts, and the outer restraint layer is a spirally wound silica gel-glass fiber composite rope. The shielding layer comprises a tinned copper wire woven mesh; the sheath layer is a thermoplastic polyurethane matrix, a microcapsule self-repairing agent is dispersed in the thermoplastic polyurethane matrix, a microcapsule comprises a siloxane prepolymer, and the thermoplastic polyurethane matrix further comprises graphene nanosheets. Through collaborative design of the fractal stranded conductor layer, the dynamic skeleton support layer, the shielding layer and the self-repairing sheath, comprehensive improvement of cable performance is realized.

The invention belongs to the technical field of polyurethane, and particularly relates to a low-reaction-heat mine reinforcing material and a preparation method thereof. Comprising a component A and a component B, the component A comprises polyether polyol A, polyether polyol B, a flame retardant and a catalyst; the polyether polyol A takes a bisphenol compound and sorbitol as a mixed initiator; the polyether polyol B takes cane sugar and sorbitol as a mixed initiator; the component B comprises a prepolymer, a flame retardant and a viscosity reducer; the prepolymer is prepared by prepolymerizing polymerized MDI (Diphenyl Diisocyanate) and polyether polyol C; and the polyether polyol C takes tetrabromobisphenol A and dihydric alcohol as a mixed initiator. The bisphenol compound polyether polyol A and the high-functionality polyether polyol B which are used as specific initiators are mixed, so that the reaction heat is reduced, and the strength of the reinforcing material is improved; meanwhile, polyether polyol C starting from tetrabromobisphenol A is used, so that the flame retardance, the toughness and the strength of the prepolymer are enhanced; the prepared reinforcing material is high in compressive strength and low in reaction heat.

The invention discloses an embolism part for peripheral arteriovenous vessels, the embolism part comprises an anchoring part and a blocking part fixedly connected with the anchoring part, the blocking part adopts polyurethane shape memory foam, the expansion rate of the polyurethane shape memory foam is 50-100 times, and a preparation method of the polyurethane shape memory foam comprises the following steps: step 1, preparing a polyurethane shape memory foam material; the preparation method comprises the following steps: preparing a polyurethane acrylate prepolymer from macromolecular polyol, diisocyanate, a chain extender containing disulfide bonds, other micromolecular chain extenders and an acrylate end-capping reagent; and 2, uniformly mixing the polyurethane acrylate prepolymer, a foaming agent, a foaming promoter and a photoinitiator to obtain a foaming solution, and sequentially carrying out light curing and foaming on the foaming solution to obtain the polyurethane shape memory foam. According to the embolism part, the polyurethane shape memory foam is adopted as the blocking part, the blocking part applies radial acting force to the wall of the blood vessel all the time based on the expansion trend of the blocking part, and the blocking part and the anchoring part jointly act and can be stably maintained in the blood vessel.

The invention provides a gradient crosslinking process of photosensitive resin for photocuring 3D printing, and relates to the technical field of photocuring 3D printing materials. The gradient crosslinking process of the photosensitive resin for photocuring 3D printing comprises the following steps: S1, based on double-initiator system design, adopting molecular dynamics simulation screening, respectively adding a 405nm sensitive type TPO-L initiator and a 365nm sensitive type I TX initiator into an epoxy acrylate prepolymer, and verifying initiation energy barrier matching through quantum chemistry calculation, and generating a pre-initiation gradient resin formula. Through molecular dynamics simulation, initiator combinations are screened, energy barrier matching is verified, the ratio of dual-wavelength sensitive initiators is optimized, and accurate triggering of surface layer and deep layer cross-linking reaction is ensured. And a three-roller grinding and dispersing process is combined with ultrasonic oscillation to eliminate nanoparticle aggregation, so that the mechanical uniformity and light scattering effect of a resin system are improved.

The invention provides a preparation method of a gel semi-solid battery and the gel semi-solid battery, and belongs to the technical field of battery materials. The preparation method comprises the following steps: pre-mixing a gel monomer into a positive pole piece and a negative pole piece by adopting a dry electrode technology, then assembling the positive pole piece, the negative pole piece and a diaphragm into a dry battery cell, injecting a gel electrolyte prepolymer prepared from the gel monomer, an electrolyte, an initiator and the like into the dry battery cell, and standing and infiltrating; and heating and carrying out in-situ polymerization curing to obtain the gel semi-solid battery. According to the preparation method, a dry-method electrode technology and an in-situ curing technology are combined, on one hand, the curing uniformity of the gel electrolyte prepolymer is improved, on the other hand, it can be guaranteed that the cured gel electrolyte prepolymer makes closer contact with active material particles, the conductivity of gel and the active material is improved, and the conductivity of the active material is improved. Therefore, the overall electrical performance of the semi-solid battery is improved. The invention also provides a gel semi-solid battery which is prepared by the preparation method.

The preparation method comprises the following steps: adding a hydroxyl derivative of bis-spiro pentaerythritol diphosphate and hydroxyl-terminated polysiloxane into a three-neck flask which is provided with a mechanical stirrer and a thermometer together, uniformly stirring, adding an organic silicon catalyst, stirring, adding an organic silicon catalyst, stirring, adding an organic silicon catalyst, stirring, adding an organic silicon catalyst, stirring, adding an organic silicon catalyst, stirring, adding an organic silicon catalyst, and stirring to obtain the UV-cured polyurethane with the synergistic flame retardance of the bis-spiro phosphate and the organic silicon, thereby obtaining the UV-cured polyurethane with the synergistic flame retardance. Dibutyltin dilaurate and diisocyanate are dropwise added for a reaction, then hydroxypropyl methacrylate is added, the reaction continues to be conducted, and a polyurethane prepolymer containing bis-spiro phosphate and organic silicon is obtained; and then adding an ultraviolet light initiator, and carrying out UV curing to obtain the UV-cured polyurethane. The pencil hardness of the UV curing material is 2B-9H, the initial thermal decomposition temperature is 246.0-298.2 DEG C, the LOI is 26.0-33.2%, the flame retardant grade is V-1-V-0 grade, and the UV curing material can be used as an electronic flame retardant sealant, a flame retardant three-proofing paint, a flame retardant industrial paint, a flame retardant tent cloth coating and the like.

The invention relates to the technical field of macromolecules, and discloses a preparation method of modified polyurethane toughened epoxy resin, which comprises the following steps: by taking 4-(Boc-amino) phenylboronic acid, diethanol amine, 1, 3-bis (3-glycidyl ether oxypropyl) tetramethyldisiloxane and the like as raw materials, carrying out a series of chemical reactions to obtain a borate siloxane chain extender; the method comprises the following steps: adding a polyurethane prepolymer into the epoxy resin, participating in chain extension of polyurethane, and modifying the epoxy resin by using the polyurethane prepolymer to obtain the modified polyurethane toughened epoxy resin. A'soft segment 'and an Si-O structure in the modified polyurethane can also improve the flexibility of a curing network, effectively change the fracture mechanism of the resin, absorb a large amount of energy when the resin is fractured, and contribute to improving the toughness of the epoxy resin; on the basis of ensuring the strength of the epoxy resin, the toughness and flame retardant property of the epoxy resin are improved, and the epoxy resin can be applied to the fields of composite materials, coatings, adhesives and the like with higher toughness and flame retardant requirements, and has wide applicability.

The invention discloses a scratch repair coating and a preparation method thereof, and relates to the technical field of high polymer materials. When the scratch repair coating is prepared, hydroxylated boron nitride reacts with 1-(3-triethoxysilylpropyl)-2-imidazoline to prepare pre-modified boron nitride, and then the pre-modified boron nitride and 4-chloro-1-butene are subjected to quaternization to prepare modified boron nitride; the preparation method comprises the following steps: reacting styryl phosphonic dichloride with 4, 4, 5, 5, 6, 6, 7, 7, 7-nonafluoro-1, 2-heptanediol to prepare a hydroxyl-terminated phosphorus-fluorine-containing polymer; the preparation method comprises the following steps: reacting isophorone diisocyanate with a hydroxyl-terminated phosphorus and fluorine-containing polymer to prepare a polyurethane prepolymer; reacting the polyurethane prepolymer with hydroxyl-terminated coumarin to generate modified polyurethane; and uniformly mixing the modified polyurethane, the modified boron nitride and a photoinitiator to prepare the scratch repair coating. The scratch repairing coating prepared by the invention has good self-repairing performance, flame retardant property, corrosion resistance and mechanical property.

The invention provides anti-aging polyurethane-zirconium phosphate composite modified asphalt and a preparation method thereof, and belongs to the technical field of building material preparation. The anti-aging polyurethane-zirconium phosphate composite modified asphalt is prepared from the following components in parts by weight: 100 parts of matrix asphalt, 3 to 15 parts of an isocyanate prepolymer, 1 to 8 parts of organic zirconium phosphate, 0.001 to 0.1 part of a catalyst and 2 to 5 parts of a solubilizer, wherein the organic zirconium phosphate is prepared by carrying out ultrasonic intercalation treatment on zirconium phosphate by adopting organic molecules. Compared with the traditional polyurethane modified asphalt, the organic zirconium phosphate in the anti-aging polyurethane-zirconium phosphate composite modified asphalt has a polyurethane cross-linked network structure, can effectively improve the high and low temperature performance of the asphalt, has a layered structure, can absorb ultraviolet rays, and can effectively improve the anti-aging performance of the asphalt. Therefore, organic molecules in the polyurethane asphalt are protected from being oxidized, the anti-aging performance is excellent, and the service life of an asphalt pavement is prolonged.

The invention discloses a medium-temperature curing high-temperature-resistant high-adhesion epoxy structural adhesive film as well as a preparation method and application thereof. The preparation method comprises the following steps: reacting high-rigidity diisocyanate with polyether polyol to obtain a polyurethane prepolymer, then adding bisphenol epoxy resin to carry out grafting reaction, and then adding carboxyl-terminated nitrile rubber to react with an epoxy group to obtain the high-temperature-resistant high-adhesion epoxy resin. And finally, mixing with a curing system and coating to obtain the intermediate-temperature curing high-temperature-resistant high-adhesion epoxy structural adhesive film. The preparation process disclosed by the invention is reasonable, and the high-temperature resistance of the adhesive film is remarkably improved by introducing high-rigidity groups such as naphthalene ring, biphenyl or p-benzene while the excellent processing property of the adhesive film is ensured; and through the synergistic effect of the polyurethane flexible chain segment and the nitrile rubber, the toughness and the adhesive property of a resin system are improved, and the loss of the resin in the forming process is reduced.

The invention belongs to the technical field of ceramics and slurry thereof, and particularly relates to fiber-reinforced ceramic photocuring slurry, a preparation method and a reinforced ceramic material. The slurry provided by the invention consists of ceramic powder, ceramic composite short fibers, light-cured resin, a photoinitiator, a dispersing agent, a plasticizer and the like, wherein the ceramic composite short fibers are zirconium oxide and silicon oxide composite fibers; the light-cured resin contains a photosensitive resin monomer and a prepolymer; and the photoinitiator is compounded by a short-wavelength initiator and a long-wavelength initiator. The preparation method comprises the following steps: modifying the ceramic composite short fibers with a silane coupling agent, mixing the modified ceramic composite short fibers with all the materials, and carrying out ball milling and defoaming. The obtained slurry is subjected to 3D printing photocuring molding and degreasing sintering, and a reinforced ceramic material can be prepared. The slurry can be used for manufacturing a high-performance ceramic material through composite short fiber synergistic enhancement, long and short wavelength initiator synergistic curing and fiber surface modification, and the curing depth, the three-point bending strength and the fracture toughness are remarkably improved.

The invention discloses a bio-based polyurethane coating and a preparation method thereof, and belongs to the technical field of coatings. The bio-based polyurethane coating comprises the following raw materials in parts by weight: 100 parts of vegetable oil polyol, 70-120 parts of isocyanate, 10-25 parts of a flame retardant, 30-40 parts of an organic solvent, 1-5 parts of a catalyst, 10-30 parts of a hydrophilic chain extender, 10-30 parts of a neutralizer and 20-40 parts of deionized water. The preparation method comprises the following steps: adding plant polyol, isocyanate, a flame retardant, an organic solvent and a catalyst into a container, mixing and reacting to obtain a prepolymer mixed solution, then adding a hydrophilic chain extender, mixing and reacting to obtain a polymer mixed solution, cooling, then adding a neutralizer for neutralizing, then adding deionized water for emulsifying to form a polyurethane emulsion, and finally adding a curing agent for curing. And performing reduced pressure distillation to obtain the bio-based polyurethane coating. According to the invention, biomass-sourced acid reacts with the organosilicon compound to generate the flame retardant, and the prepared bio-based polyurethane coating has good flame retardant property.

The invention relates to the technical field of coatings, in particular to a mesoporous thermal insulation coating with an infrared heat shielding function and a preparation method thereof.The preparation method comprises the steps that polyurethane-organic silicon emulsion is selected as a base material of the coating, chain extension is conducted on polyurethane prepolymer through a hydroxyl-terminated ternary flame-retardant chain extender, and high-flame-retardant and self-repairing polyurethane-organic silicon emulsion is prepared; hollow silicon dioxide microspheres are selected as a mesoporous material, and the mesoporous material is prepared by a two-step method of performing hydrolytic condensation on phenyltrimethoxysilane and then calcining to remove impurities. The preparation method comprises the following steps: modifying hollow silicon dioxide microspheres to prepare composite hollow silicon dioxide microspheres as a filler, growing cesium-doped tungsten bronze nanoparticles on the surfaces of the hollow silicon dioxide microspheres in situ by adopting a solvothermal method to obtain pretreated hollow silicon dioxide microspheres, and treating the pretreated hollow silicon dioxide microspheres with an epoxy silane coupling agent to obtain epoxidized hollow silicon dioxide. And then grafting a hydroxyl-terminated ternary flame-retardant chain extender by utilizing an epoxy-hydroxyl reaction.

The invention belongs to antibacterial materials, and particularly relates to antibacterial modified waterborne polyurethane and a preparation method and application thereof.The preparation method of the antibacterial modified waterborne polyurethane comprises the following steps that polyol and diisocyanate are mixed and subjected to a prepolymerization reaction, and a polyurethane prepolymer is obtained; mixing the polyurethane prepolymer and a chain extender, and carrying out chain extension reaction; in the chain extension reaction, adding the graft and carrying out esterification reaction to obtain a first intermediate; mixing the first intermediate with triethylamine and carrying out neutralization reaction to obtain a second intermediate; and emulsifying the second intermediate in deionized water to obtain the antibacterial modified waterborne polyurethane. Compared with the prior art, the antibacterial waterborne polyurethane has the advantages that the problems of poor intermiscibility, low durability and the like in physical addition and the problems of limited binding objects and weak antibacterial effect in covalent binding in the antibacterial waterborne polyurethane in the prior art are solved. According to the scheme, arginine and chitosan are grafted to a molecular chain of waterborne polyurethane, so that the waterborne polyurethane is endowed with a synergistic antibacterial property.

The invention discloses a plant leaf imitating hydrogel composite material and a preparation method thereof, and belongs to the field of bionic composite materials. The preparation method comprises the following steps: firstly, preparing printing paste by compounding a coloring agent, printing a fabric to obtain a green fabric capable of simulating spectral characteristics of green peaks and red edges of plant leaves, and simulating fence tissues and skeletons in a leaf structure by using the green fabric; then taking a biological material polyvinyl alcohol (PVA) as a base material, adding a monomer with strong hygroscopicity, a cross-linking agent and an initiator, and blending to prepare a hydrogel prepolymer solution; and finally, pouring the hydrogel prepolymer solution into a mold containing the green fabric for copolymerizing, so that hydrogel is directly formed on the surface of the fabric and in pores, and the plant leaf imitating hydrogel composite material is obtained. The material gets rid of dependence on moisture absorption salt, and has the advantages of stable water absorption and simulation effects, good durability and the like.

The invention relates to the technical field of fertilizers, and discloses a coating material, a preparation method and application of the coating material in a trace element coating for potassium chloride particles. The preparation method comprises the following steps: reacting isophorone diisocyanate with polycaprolactone diol, tartaric acid and dimethylglyoxime to prepare a polyurethane prepolymer, continuously reacting the polyurethane prepolymer with chitosan oligosaccharide Schiff base to obtain chitosan oligosaccharide modified polyurethane, and mixing the chitosan oligosaccharide modified polyurethane, a cross-linking agent, silane modified isocyanate and a trace element solution to obtain the coating material. The coating material is good in mechanical property, contains trace elements, has a controlled release effect on the potassium chloride granulated fertilizer, and can be applied to the potassium chloride granulated fertilizer as a trace element coating.

The invention relates to a self-repairing high-mechanical-property film and a preparation method and application thereof, and the preparation method comprises the following steps: adding ureido pyrimidone and a chain extender into a solvent to obtain a mixed solution, adding the mixed solution into a polyurethane prepolymer, reacting, and drying to obtain the self-repairing high-mechanical-property film. UPy containing hydrogen bonds is introduced into the polymer to prepare the self-repairing high-mechanical-property film, and the hydrogen bond density can be adjusted by adjusting the UPy content of ureido pyrimidone, so that the composite material has excellent self-healing property; and density hydrogen bonds are introduced to construct a physical cross-linked network, so that the mechanical properties of the composite material can be remarkably improved.

The invention relates to a flexible aqueous binder for a lithium battery negative electrode and a preparation method thereof. The preparation method comprises the following steps: firstly, preparing a flexible polyurethane prepolymer containing vinyl by taking hydroxyl-terminated polybutadiene, isocyanate and hydroxyl acrylate as main raw materials; vinyl-containing compounds such as water-soluble acrylic acid (salt) or acrylamide, oil-soluble acrylic ester or acrylonitrile and the like are used as monomers and are combined with a flexible polyurethane prepolymer to prepare the negative water-based binder with flexible cross-linking points through free radical polymerization. The aqueous binder prepared by the technical method provided by the invention can realize point-to-point and point-to-line bonding modes with a pole piece active substance on a microstructure, so that the bonding strength of the active layer material and a copper foil is improved on the premise of not influencing the electrolyte resistance of the binder; and the flexibility of the negative pole piece and the subsequent processing stability are obviously improved.

The invention discloses a hydrophobic and oleophobic modified epoxy resin, which is prepared from the following components in parts by mass: 2 to 5 parts of thiolactone terminated fluorinated prepolymer, 15 to 16 parts of 4, 4 '-diaminodiphenylmethane, 0.13 to 0.14 part of base catalyst, 25 to 26.5 parts of epoxy resin and the balance of tetrahydrofuran solvent, wherein the thiolactone-terminated fluorinated prepolymer is prepared from thiolactone acrylamide, fluorinated acrylate and a photoinitiator in a mass ratio of (2-3): 1: (0.07-0.09) through a free radical polymerization copolymerization chemical reaction under the induction of ultraviolet light, and the thiolactone-terminated fluorinated prepolymer is obtained; wherein thiolactone acrylamide is prepared from DL-homocysteine thiolactone hydrochloride, a NaHCO3 solution and acryloyl chloride according to the mass ratio of 1: (1.3-1.5): (1.1-1.3), the oleophobic and hydrophobic modified epoxy resin provided by the invention effectively solves the problem that an epoxy resin coating in the prior art is poor in oleophobic performance and hydrophobic performance, and the oleophobic and hydrophobic modified epoxy resin has the advantages that the oleophobic and hydrophobic properties of the epoxy resin coating are improved; therefore, the oleophobic and hydrophobic properties of the epoxy resin coating are improved.

The invention provides a preparation method of a waterproof flame-retardant multifunctional fabric, and belongs to the technical field of functional textiles. The preparation method comprises the following steps: heating dihydric alcohol until the dihydric alcohol is completely melted, adding diisocyanate, a flame retardant and a catalyst, reacting to obtain a polyurethane prepolymer, adding a chain extender for chain extension, then adding an end-capping reagent for end capping, cooling, adding an emulsifier to obtain a waterproof flame retardant emulsion, adding water to form a finishing agent, soaking a polyacrylonitrile pre-oxidized fiber fabric in the finishing agent for treatment, and drying to obtain the waterproof flame retardant fabric. And pre-drying and baking to obtain the multifunctional fabric. Polyhydric alcohol with a long alkane chain is adopted to carry out chain extension on a polyurethane prepolymer, the obtained waterproof agent has good film-forming property, can be firmly fixed on the surface of a fiber without the help of a cross-linking agent or an adhesive during application, and endows a modified textile with excellent washing fastness.

The invention discloses a modified maleimide prepolymer, a resin composition and application thereof, the modified maleimide prepolymer is an amine compound modified maleimide prepolymer and is generated by a prepolymerization reaction of maleimide resin and an amine compound, and the weight ratio of the maleimide resin to the amine compound is 100: (1-120); according to the invention, the maleimide resin is modified by a compound containing a special aliphatic ring and aromatic amine structure, and due to the existence of the aliphatic ring or olefin structure, the dielectric property, the water absorption rate and the like of bismaleimide can be reduced; the structure has an excellent thermal expansion coefficient and can meet the requirement of high-order packaging; according to the present invention, the product has characteristics of high temperature resistance, no volatile low molecular substance generation during the reaction process, stable molecular structure and high thermal decomposition temperature, can completely meet the multi-chip assembly manufacturing process requirements in the large-scale integrated circuit, and can obtain the cured product with characteristics of high heat resistance, high toughness, low CTE, low dielectric property and low water absorption rate, and the obtained cured product has characteristics of high heat resistance, high toughness, low CTE, low dielectric property and low water absorption.

The invention relates to the technical field of thermal management material preparation, solves the technical problems of loose heat conduction network structure and non-uniform heat conduction direction of a flexible composite phase change material, and particularly relates to a magnetic polymer-based flexible composite phase change material and a preparation method thereof. Comprising the following steps: preparing a modified polydimethylsiloxane prepolymer from a carbon nanotube dispersion liquid and a polydimethylsiloxane prepolymer; adopting a Pickering emulsion method to mix 42 # paraffin, the modified polydimethylsiloxane prepolymer and nano cellulose to prepare a composite phase change material emulsion; silver mirror reaction is adopted to carry out surface silver plating on the magnetic neodymium iron boron particles; the magnetic polymer-based flexible composite phase change material is prepared from the composite phase change material emulsion and the surface-silvered magnetic neodymium iron boron particles. The high flexibility and magnetism of the prepared material in a normal temperature state endow the material with a more convenient installation mode and lower contact thermal resistance, the heat conduction network structure and component compatibility of the material are improved, and the application requirements of a phase change thermal management technology can be met.

The invention discloses a self-repairing wave-absorbing composite material as well as a preparation method and application thereof. The self-repairing wave-absorbing composite material provided by the invention comprises the following components in percentage by mass: 30-80% of a polyurethane matrix; 20%-70% of composite wave absorbing powder; the composite wave-absorbing powder is prepared by performing plasma ball milling on graphene oxide and soft magnetic metal powder. The preparation method of the self-repairing wave-absorbing composite material comprises the following steps: 1) preparing a polyurethane prepolymer solution; and 2) dispersing the composite wave-absorbing powder in a polyurethane prepolymer solution, injecting the solution into a mold, and carrying out curing molding to obtain the self-repairing wave-absorbing composite material. The self-repairing wave-absorbing composite material disclosed by the invention is excellent in wave-absorbing property and mechanical property, the material can realize quick self-repairing, the stability of the wave-absorbing property and the mechanical property is ensured, and the composite material is suitable for the fields of 5G communication, new energy automobiles, national defense and military industry and the like.

The invention belongs to the technical field of polyurethane materials, and provides a high-damping anti-fatigue and anti-aging polyurethane elastomer and a preparation method thereof. The high-temperature-resistant polyurethane elastomer is prepared from the following raw materials in parts by weight: 20 to 30 parts of poly (diethylene glycol adipate) glycol (PDA), 30 to 50 parts of polytetrahydrofuran ether glycol (PTMEG), 5 to 15 parts of chain extender, 0.1 to 0.3 part of A33, 0.1 to 0.2 part of organic tin catalyst, 2 to 5 parts of hindered phenol antioxidant, 1 to 3 parts of hindered amine light stabilizer, 3 to 8 parts of nano particles and 30 to 50 parts of isocyanate prepolymer. The isocyanate prepolymer is prepared from 1, 4-phenyl diisocyanate (PPDI) and branched chain-containing polytetrahydrofuran glycol PTXG according to a mass ratio of 1: (1.8 to 2.2). The polyurethane elastomer is excellent in damping performance and fatigue aging resistance, and meets the use requirements under complex working conditions.

The invention relates to the technical field of concrete, in particular to epoxy resin concrete for a catch basin and a preparation process thereof. The cement, the silica fume, the fine aggregate, the coarse aggregate, the water reducing agent, the fly ash, the modified epoxy resin, the curing agent, the diluent and the water are mixed to obtain epoxy concrete slurry, and the epoxy concrete with good mechanical property and ageing resistance for the catch basin is obtained through curing. A preparation process of the modified epoxy resin comprises the following steps: (1) preparing eugenol glycidyl ether by taking eugenol and epoxy chloropropane as raw materials; (2) enabling eugenol glycidyl ether to react with 1, 1, 3, 3-tetramethyldisiloxane, and then grafting 4-isopropylamino diphenylamine, so as to obtain silicon-containing dihydric alcohol; (3) mixing silicon-containing dihydric alcohol and polyethylene glycol, and reacting with isophorone diisocyanate to obtain a silicon-containing polyurethane prepolymer; and (4) mixing the silicon-containing polyurethane prepolymer with epoxy resin to obtain the modified epoxy resin.

The invention relates to the technical field of synthetic fibers, in particular to a high-elasticity textile fiber and a preparation process thereof. The high-elasticity textile fiber is prepared from the polyurethane-polyamide elastomer and the modified diatomite master batch through melt spinning, drafting and winding. According to the invention, hydroxyl-terminated polydimethylsiloxane is used as polyol, and the molar ratio of the polyurethane prepolymer to the polyamide prepolymer is controlled, so that the prepared polyamide-polyurethane elastomer slice has good heat resistance; the molar ratio of isocyanate to polyol and the molar mass ratio of caprolactam to adipic acid are controlled, so that the prepared textile fiber is excellent in mechanical property; 2, 2-dimethylolpropionic acid is used for a chain extension reaction, the molar ratio is controlled, the moisture regain of the prepared textile fiber is 8.58%, and the moisture absorption is high; the diatomite is modified by the quaternary ammonium salt compound, and the addition proportion is adjusted, so that the prepared spinning fiber has good antibacterial performance.

The invention discloses a temperature-resistant high-strength powder coating and a preparation method thereof, and belongs to the field of coatings. The invention relates to a temperature-resistant high-strength powder coating which is prepared from the following raw materials in percentage by weight: 40-50% of epoxy resin; 20-30% of polyester resin; 6-10% of a curing agent; 1-3% of a leveling agent; 1-2% of a filler; and the balance of pigment. According to the polyester resin, aliphatic diisocyanate reacts with polyether polyol and hydroxyl silicone oil to obtain a polyurethane prepolymer, and then the polyurethane prepolymer reacts with vinyl benzylamine, an acrylate monomer and an acrylic monomer to obtain the polyester resin. The powder coating has the advantage that the temperature resistance and the strength of the powder coating are improved.

The invention provides a polyurethane modified epoxy resin material for a prepreg and a preparation method of the polyurethane modified epoxy resin material. Comprising 10-35 parts by weight of polyester or polyether polyol, 1-10 parts by weight of isocyanate, 40-70 parts by weight of epoxy resin, 1-3 parts by weight of a light stabilizer, 1-2 parts by weight of an antioxidant, 1-2 parts by weight of an ultraviolet absorbent and 5-30 parts by weight of a chain extender and a curing agent. According to the invention, the intrinsic flexible epoxy resin is prepared by grafting modification of the polyurethane prepolymer, and is applied to a prepreg resin system and a medium-temperature cured carbon fiber prepreg, so that the brittleness of the epoxy resin is improved, and the elongation at break of the epoxy resin is improved, thereby realizing a toughening effect and a composite material forming process.

The invention relates to the technical field of coatings, in particular to a modified FEVE fluorocarbon resin coating and a preparation method thereof. The problem that the FEVE fluorocarbon coating is poor in durability is solved. The preparation method comprises the following steps: modifying FEVE fluorocarbon resin with linoleic acid to obtain a granular material; stirring the modified FEVE fluorocarbon resin, polyisocyanate, montmorillonite and a composite solvent to obtain a prepolymer; pre-dispersing and grinding silicon carbide, modified zinc oxide, a dispersing agent and a composite solvent, adding nano composite particles for ultrasonic dispersion, and adding a prepolymer and a flatting agent to obtain the modified FEVE fluorocarbon resin coating. Wherein the FEVE fluorocarbon resin is modified, so that the crosslinking speed, the coating strength and the adhesive force are improved, the stain resistance, the weather resistance and the corrosion resistance are improved through the nano composite particles and the like, and finally the durability of the FEVE fluorocarbon resin coating is improved.

The invention discloses a polyurethane composite material embedded with a liquid repair network and a preparation method thereof, and belongs to the technical field of high polymer materials, the polyurethane composite material comprises 40-60 parts of a polyurethane prepolymer, 5-20 parts of repair agent carrier particles, 10-30 parts of a liquid repair agent and 0.1-1 part of a dispersant. The composite material provided by the invention solves the problems that a polyurethane material is easy to damage and low in repair efficiency in long-term use. The composite material disclosed by the invention has rapid, efficient and self-adaptive repairing performance under large-scale damage and multiple damage, is suitable for complex environments such as acid-base and high temperature, and has important application prospects in the fields of various industrial equipment, flexible electronic equipment, automobiles, buildings and the like.