The invention discloses a reactive polymer waterproofing coiled material which comprises a fetal membrane layer, a reactive composite rubber layer and an anti-sticking isolation film layer; the reactive composite rubber layer is covered on the surface of the fetal membrane layer, and the anti-sticking isolation film layer is covered on the other surface of the reactive composite rubber layer; thereactive composite rubber comprises the following components in percentage by weight: 85.0 to 92.0 percent of SIS hot melt adhesive, 3.0 to 5.0 percent of talcum powder, 2.0 to 3.5 percent of composite ore powder, 1.0 to 2.5 percent of gaseous silica, 0.5 to 2.0 percent of silane coupling agent, and 0.5 to 2.0 percent of nano calcium carbonate. The waterproofing coiled material can have chemical cross-linking reaction and be cured with a cast-concrete matrix, fundamentally avoids 'watermoving between layer', and has the advantages of high strength, high toughness, aging resistance, long service life and the like.