The invention relates to the technical field of surfactants, and particularly discloses a high-stability reactive high-molecular surfactant and a preparation method thereof. The surfactant is prepared from the following raw materials in parts by
mass: 50 to 60 parts of allyl
polyoxyethylene ether, 20 to 30 parts of dodecyl
acrylate, 5 to 10 parts of trifluoroethyl
methacrylate, 50 to 60 parts of SO3 compound, 0.5 to 1 part of
chain transfer agent, 0.1 to 0.3 part of initiator, 0.2 to 0.5 part of synergist and 15 to 20 parts of deionized water. According to the invention, the
reaction type high-molecular surfactant with the amphiphilic
block structure is formed, so that the water molecule penetration is reduced, the
water resistance of the
emulsion is obviously improved, the water molecule penetration is reduced, and the
water resistance of the
emulsion is obviously improved. Moreover, the
viscosity of the
emulsion is kept stable under high
shear force, so that the
mechanical stability of the emulsion can be improved.