The invention relates to a selective desulfurization absorbent,
system and process for
blast furnace gas with a
high carbon-
sulfur ratio. The absorbent comprises a main agent and an additional additive accounting for 0.01-0.8% of the total
mass of the main agent, the main agent comprises the following components in percentage by
mass: 5-15% of an
alcohol amine absorbent, 30-50% of a physical
solvent, 25-45% of a catalytic
promoter and the balance of water; wherein the physical
solvent contains a
sulfur-containing functional group or an
ether-containing functional group; the catalytic
promoter comprises a sterically hindered amine or a cyclic amine. According to the invention, the alkylol amine absorbent with stable performance is matched with the physical
solvent with similar compatibility characteristics and the catalytic
promoter with steric hindrance effect, and efficient
dissolution, intraphase
mass transfer and transfer
hydrolysis of organic
sulfur are remarkably promoted through a steric hindrance effect-group
synergy action mechanism; a synergistic
reaction path of
dissolution-transfer-
catalytic hydrolysis-chemical absorption is formed, so that the effects of selectively and highly desulfurizing and reducing the co-absorption amount of carbon are achieved, and the
energy consumption of a subsequent process is favorably reduced.