The method comprises the following steps: S1, putting a reaction solution into a high-
voltage electrode reaction kettle in which air is exhausted, filling
carbon dioxide gas, and sealing the high-
voltage electrode reaction kettle; s2, setting the initial
voltage, frequency and duty ratio of a direct-
current pulse power supply, starting a reaction, and adjusting the voltage in the reaction process to maintain stable
discharge plasma until the
system reaches a supercritical state; s3, in the supercritical state, continuously adjusting the voltage to maintain the target temperature or the target pressure intensity, then setting the target time, and stopping the reaction after the reaction reaches the target time; and S4, after the high-voltage
electrode reaction kettle is cooled, collecting a product, performing analysis and detection, adjusting reaction parameters based on an analysis and detection result, repeating the steps S1 to S4, and optimizing
reaction conditions. According to the method, directional conversion of
carbon dioxide to high-value
alcohol compounds can be realized, the selectivity of a main product is remarkably improved, and a novel and reliable means is provided for directional synthesis of high-
carbon chain hydrocarbon alcohol.