The invention discloses a method for preparing
polyoxymethylene dimethyl ether by using an
ethylene glycol and
glycerol extraction technology, and belongs to the technical field of preparation of
new energy synthetic fuels and environment-friendly solvents. Aiming at the problems of rectification
tower blockage, low product yield and environmental
pollution caused by an
impurity removal process due to the fact that a synthetic product contains impurities such as
formaldehyde, water and
formic acid in an existing process, the invention adopts the following technical scheme:
formaldehyde and methylal are used as raw materials, and a DMM2-5 product mixture is synthesized under the
catalysis of a
solid acid catalyst;
ethylene glycol or
glycerol is adopted as a single extraction agent, strong polar impurities are removed through 5-10 stages of extraction, and a target product and methylal are enriched in a light phase; and carrying out multi-
tower continuous rectification and purification to obtain high-purity DMM2 and DMM3-5 products. The extraction agent and unreacted raw materials can be recycled and reused, so that closed-loop production is realized. The process is green and waste-free, impurities are thoroughly removed (
formaldehyde is less than 0.5%, and water is less than 0.1%), the product purity is more than or equal to 99.1%, the yield is 85-95%, the operation is mild and safe, the adaptability is high, and the process conforms to the
coal clean and efficient utilization policy and is suitable for production of environment-friendly solvents and national VI standard clean diesel components.