243 results about "Gas to liquids" patented technology

The recovering process includes the steps of: the reaction of the S containing fume with water solution of ammonia, with ammonia-to-sulphur molar ratio of 1.3-1.8 and gas-to-liquid ratio of 2000-5000, to produce ammonium sulfite solution; the oxidation of ammonium sulfite solution with air to obtain ammonium sulfate solution; the contact of the ammonium sulfate solution with hot fume to evaporatewater and the crystallization of ammonium sulfate in a crystallizer to produce commercial ammonium sulfate fertilizer. The equipment includes one desulfurizing tower with SO2 absorbing section, one ammonium sulfite oxidizing section, ammonium sulfate solution concentration section, one water washing section and mist elimianting section. The present invention can lower cost and steam consumption, reduce fume density and produce ammonium sulfate fertilizer.

A process is disclosed for the conversion of lower molecular weight hydrocarbons, such as methane, into higher molecular weight hydrocarbon products, such as hydrocarbons having between 4 and 29 carbons. The process includes forming hydrated electrons, such as by mixing the lower molecular weight hydrocarbons with water and contacting the mixture with an energy source to form hydrated electrons. The hydrated electrons react with the methane to form hydrogen and higher molecular weight hydrocarbon products. Also disclosed is a related process for converting higher molecular weight hydrocarbons to lower molecular weight hydrocarbons by forming a mixture of higher molecular weight hydrocarbons and water and contacting the mixture with an energy source to form hydrated electrons that react with the higher molecular weight hydrocarbons to form hydrogen and lower molecular weight hydrocarbon products.

A high strength, flexible crosslinked polyethylene (PEX) material is provided wherein the base polymer is intermixed with a polymer modifier which affects the amorphous region of the polymer, leaving the crystalline portion of the base polymer virtually unaffected. Consequently, the amorphous region's density is lowered, resulting in a more flexible final product, while the crosslinked molecular structure and / or crystalline portion of the polymer, which controls the strength of the base polymer, remains strong. The polymer modifier can comprise a hydrocarbon fluid such as PAO, Group III basestocks, or a gas-to-liquid hydrocarbon. A method for producing the plastic material is also provided. The plastic material has particular utility in the production of tubing, piping, and conduits for transporting gases, liquids, and the like, as well as wire and cable coatings such as jacketing and insulation.

The present invention relates to thermally stable supports and catalysts for use in high temperature operation, and methods of preparing such supports and catalysts, which includes adding a rare earth metal to an aluminum-containing precursor prior to calcining. The present invention can be more specifically seen as a support, process and catalyst wherein the thermally stable support comprises two rare earth aluminates of different molar ratios of aluminum to rare earth metal, and optionally, alumina and / or a rare earth oxide. More particularly, the invention relates to the use of noble metal catalysts comprising the thermally stable support for synthesis gas production via partial oxidation of light hydrocarbon (e.g., methane) with minimal deactivation over long-term operations and further relates to gas-to-liquids conversion processes.

A system and apparatus is provided that maximizes mass and energy conversion efficiencies in an integrated thermochemical process for the conversion of fossil fuel or renewable biomass to synthesis gas. The system combines gasification, catalytic conversion of gas to liquid, electricity generation, steam and chilled water generation with a system controller to maximize the conversion efficiency from syngas to merchantable products over the efficiency of syngas alone burned as a fuel. A clean synthesis gas stream is introduced into a catalytic reactor that utilizes specially formulated catalysts to generate liquid fuel from CO and H2 while concentrating CH4 and other combustible, but non-reactive gases in the syngas product stream. The methane rich stream is introduced into an engine for the production of electricity and heat while the unreacted CO and H2 can be recycled to produce additional liquid fuel. Excess heat can be used for other co-located processes and facilities.

The present invention discloses a system for converting methanol or synthesis gas to liquid hydrocarbons with comparable energy content to gasoline within a mixed bed single reactor or double reactor systems. Varying catalyst composition and temperature profiles allow for significant tailoring of reaction conditions to the specific feedstocks or the desired products.

The invention relates to methods for creating high value liquid fuels such as gasoline, diesel, jet and alcohols using carbon dioxide and water as the starting raw materials and a system for using the same. These methods combine a novel solid oxide electrolytic cell (SOEC) for the efficient and clean conversion of carbon dioxide and water to hydrogen and carbon monoxide, uniquely integrated with a gas-to-liquid fuels producing method.

A serial, dual piston high pressure fluid pumping system that overcomes the difficulties of gas in the fluid stream without the need for added mechanical valves or fluid paths. A bubble detection and recovery mechanism monitors compression and decompression volumes of the serially configured dual pump head pump, and the overall system delivery pressure. Bubble detection is effected by sensing a ratio of compression to decompression volume and determining if the ratio exceeds an empirical threshold that suggests the ratio of gas-to-liquid content of eluent or fluid in the system is beyond the pump's ability to accurately meter a solvent mixture. The magnitude of the ratio of compression to decompression volume indicates that either the intake stroke has a bubble or that the eluent has a higher-than-normal gas content. Once a bubble has been detected, recovery is effected by forcing the pump into a very high stroke volume with the compression and decompression stroke limits constrained to obtain the largest delivery stroke compression ratio that will expel a bubble or solvent that has detrimental quantities of gas.

A compact evaporation apparatus includes an evaporator vessel with a sloped, bottom chamber. A combustion chamber is mounted to a top of the vessel, with a burner mounted to a top of the combustion chamber, the combustion chamber sized to achieve total combustion of an air / gas mixture supplied to the burner before being released below a liquid surface in the vessel. At least one turbulence diverter plate is located within the vessel beneath the liquid surface, the diverter plate being a submerged perforated plate extending horizontally from the combustion chamber, such that hot combustion gasses are released below the diverter plate, and as large gas bubbles rise to the surface they pass through small perforations in the diverter plate, thereby breaking large, hot gas bubbles into small bubbles, the gas to liquid contact area being maximized to increase system efficiency.

A liquid to gas converter to convert liquids (1) to gas (2) that can include a liquid pressurization element (3), a liquid preheating element (5), and a nozzle (10) to disperse liquids into energy (7) generated by an energy source (8). The gas to liquid converter can be located inside an enclosure (17) and substances dissolved in the liquid can accumulate as solids (13) on deposition surface (12) of the enclosure as the liquid (1) converts to gas Cis (2). Condensation of a portion of the gas (2) generated can be combined with the solids (13) for continuous removal of such solids (13) from the enclosure (17). A gas expansion compensator can generate a pressure gradient (24) to move the volume of gas generated from the liquid from the enclosure (17).

Novel methods of providing fuels to a gas-to-liquids facility are disclosed. A gas-to-liquids facility typically operates in a remote location and therefore must supply its own energy needs. These facilities are often sustained by fuels having different heating values, and for smooth operation while transitioning from one fuel to another, (such as during startup, shut down, and emergencies) the Wobble Indices of the two fuels cannot greatly vary from one another. According to embodiments of the present invention, the Wobble Index of either or both of the fuels is adjusted such that their ratio is less than or equal to about 3. The fuel having the higher Wobble Index may be natural gas, and materials such as nitrogen, carbon dioxide and flue gas may be added to lower its Wobble Index. The fuel having the lower Wobble Index may be the tail gas of a Fischer-Tropsch synthesis, and materials such as methane, ethane, LPG, or natural gas may be added to raise its Wobble Index. Alternatively, carbon dioxide may be removed from the tail gas to raise its Wobble Index.

A method and apparatus for converting natural gas from a remote source into hydrocarbon liquid stable at room temperature, comprising a skid or trailer-mounted portable gas-to-liquids reactor. The reactor includes a preprocessor which desulfurizes and dehydrates the natural gas, a first-stage reactor which transforms the preprocessed natural gas into synthesis gas, and a liquid productions unit using a Fisher-Tropsch or similar polymerization process. The hydrocarbon liquid may be stored in a portable tank for later transportation or further processed on site in a portable hydrocarbon cracking unit to yield fuel or lubricating oils.

A system having a movable platform including synthesis gas production, synthetic crude production and product upgrading is provided. The system may include one or more movable platforms on which the various production and / or upgrading facilities are located. A process for converting natural gas to hydrocarbon products is also provided where the process occurs on a movable platform. The process may occur on one or more operationally connected vessels. The movable platform may be any of a number of movable or transportable bases on which process equipment may be placed and / or in which hydrocarbon products may be stored.

The invention relates to a foam system suitable for profile control and oil displacement of an oil field and an oil displacement method, in particular to a foam system formula used for profile control and oil displacement of the oil field after polymer flooding and a foam profile control oil displacement method. The foam system formula comprises in percentages by weight: 0.1-0.5 wt% of surfactant, 0.05-0.4 wt% of foam stabilizer, 0.08-0.4% of thickening agent, 0.05-1.2 wt% of inorganic salt and the balance of water. In the foam profile control oil displacement method, a ratio of gas to liquid of the foam system is as follows: the volume ratio of gas to liquid is 0.4: 1-1: 1 under an injection pressure. The foam system, provided by the invention, has super strong foam performance and ultra-low interface tension. The foam profile control effect is remarkable after polymer flooding, the yield is improved for more than 20%, and the economic benefit is remarkable.

The present invention provides a process for natural gas in the form, e.g., of stranded gas or associated gas to transportable liquids. More particularly, the present invention provides a process in which the gas is non-oxidatively converted to aromatic liquid, preferably in proximity to the welihead, which may be onshore or offshore. In one aspect, the present invention provides integration of separation of wellhead fluids into associated gas and crude with blending of the aromatic liquid derived from the gas with the crude. Alternatively, or in combination, in another aspect, the present invention provides integration of conversion of byproduct hydrogen to power with non-oxidative conversion of gas to aromatic liquid.

An oral care appliance comprises: a fluid pump assembly (46); a source of liquid (50); and a source of gas (12), wherein the pump is in operative communication with the sources of liquid and gas to produce a series of gas-injected fluid pulses, directed to a nozzle assembly (80) from which the resulting pulses are directed to the teeth. The individual pulses have a pulse width in the range of 0.001-0.5 seconds, a pulse height from 0.1-10 Newtons, and a rise / fall time range of 0.5-250 ms, a repetition rate in the range of 2 Hz to 20 Hz. The gas / liquid mixture range from 40-95% volume to volume, gas to liquid.

The present invention relates to improved catalyst compositions, as well as methods of making and using such compositions. In particular, preferred embodiments of the present invention comprise rare earth catalyst supports, catalyst compositions having rare earth supports, and methods of preparing and using the catalysts and supports. Accordingly, the present invention also encompasses an improved method for converting a hydrocarbon containing gas and an oxygen containing gas to a gas mixture comprising hydrogen and carbon monoxide, i.e., syngas, using the rare earth catalyst supports in accordance with the present invention. In addition, the present invention contemplates an improved method for converting hydrocarbon gas to liquid hydrocarbons using the novel syngas catalyst supports and compositions described herein.

A premixing device includes an air inlet to introduce compressed air into a mixing chamber and a fuel plenum to provide fuel to the mixing chamber via at least one slot and over a pre-determined wall profile to form a fuel boundary layer, the mixing chamber including a surface treatment disposed on at least a portion of an inside wall thereof to aerodynamically enhance the mixing of fuel from the boundary layer with the compressed air, without causing a boundary layer flow separation and flame holding in the mixing chamber. Low-emission combustors, gas turbine combustors, methods for premixing a fuel and an oxidizer in a combustion system, a gas turbine, and a gas-to-liquid system using the premixing device are also disclosed.

Disclosed are a gas to liquids (GTL)-floating production, storage and offloading (FPSO) system that can be used in offshore oil fields or stranded gas fields and a method for producing synthetic fuel using the same. More particularly, the disclosure relates to a GTL-FPSO system capable of producing liquid synthetic fuel from gas extracted from stranded gas fields or associated gas extracted from oil fields, including a reforming reactor and a liquid hydrocarbon producer, and a method for producing the same.

A transportable GTL processing facility constructed on an inland barge is provided. Also provided is a process for producing liquid hydrocarbons from natural gas utilizing a transportable GTL processing facility. The facility and process may be used to access and convert stranded natural gas in an economical fashion into liquid hydrocarbons. Further provided is a transportable GTL processing facility and process for producing liquid hydrocarbons wherein the liquid hydrocarbons are upgraded into transportation fuels and other locally usable materials.

A method and system of producing hydrocarbons from a hydrocarbon containing subterranean hydrate reservoir is disclosed. Waste heat is captured and transferred to a hydrocarbon bearing hydrate formation to dissociate hydrates into natural gas and water. The waste heat can be heat generated from surface facilities such as a Gas To Liquids (GTL) plant, a Liquefied Natural Gas (LNG) plant, an electric or power generation plant, and an onshore or offshore facility producing other conventional or unconventional hydrocarbons from a subterranean reservoir. Alternatively, the waste heat can be obtained from subterranean reservoirs such as hydrocarbon containing producing wells and geothermal wells producing heated water.

This invention relates to one gas to liquid separation integral current device, which comprises shell set with sealed separation chamber with top side set with water guide tube and the guide tube and guide flow outer tube are connected; the shell down part is set with liquid collection guide tube through shell into separation chamber; the liquid collection guide tube orderly comprises guide section, liquid mixture section, gas and liquid mixture section, exit one; the separation chamber top is set with gas guide tube connected with gas and liquid mixture section; guide flow tube is connected to gas guide tube vertical section; the liquid collection tube exit section is set with main gas liquid even integral mixture device.

A lubricating base oil is disclosed comprising a mixture of gas-to-liquids (GTL) base stock / base oil, hydrodewaxed or hydroisomerized / catalytic (and / or solvent) dewaxed wax derived base stock / base oil and from about 1 to 95% by weight of an alkylated naphthalene or alkylated benzene synthetic oil having a pour point of 0° C. or less. The pour point of the base oil is dramatically lowered by the addition of the synthetic oil.

Herein disclosed is a method of producing synthesis gas from carbonaceous material, the method comprising: (a) providing a mixture comprising carbonaceous material and a liquid medium; (b) subjecting the mixture to high shear under gasification conditions whereby a high shear-treated stream comprising synthesis gas is produced; and (c) separating a product comprising synthesis gas from the high shear-treated stream. Herein also disclosed is a method for producing a liquid product. The method comprises forming a dispersion comprising gas bubbles dispersed in a liquid phase in a high shear device, wherein the average gas bubble diameter is less than about 1.5 μm; contacting the dispersion with a multifunctional catalyst to form the liquid product; and recovering the liquid product. In an embodiment, the liquid product is selected from the group consisting of C2+ hydrocarbons, C2+ oxygenates, and combinations thereof.

A phase change cooler of the present invention includes: a plurality of heat receiving units that cause a refrigerant to change phase from liquid to gas by heat received from a heat generating body; one heat radiating unit that causes the refrigerant to change phase from gas to liquid by radiating heat to surrounding area; a plurality of vapor tubes that respectively transport the refrigerant in a vapor state from each of the heat receiving units to the heat radiating unit; a liquid tube that respectively circulates the refrigerant in a liquid state from the heat radiating unit to each of the heat receiving units; and a bypass tube that connects each of the heat receiving units to each other.

The present invention is a process for removing waxy haze from and improving the filterability of base stocks including heavy mineral oil base stocks, gas-to-liquids (GTL) and hydrodewaxed or hydroisomerized waxy feed basestocks by filtering the waxy haze causing particles out of the base stock employing a filter characterized by a high surface area of pores accessible to the haze wax particles which have particles dimensions of no more than about 5 microns.

A method and system of producing hydrocarbons from a hydrocarbon containing subterranean hydrate reservoir is disclosed. Waste heat is captured and transferred to a hydrocarbon bearing hydrate formation to dissociate hydrates into natural gas and water. The waste heat can be heat generated from surface facilities such as a Gas To Liquids (GTL) plant, a Liquefied Natural Gas (LNG) plant, an electric or power generation plant, and an onshore or offshore facility producing other conventional or unconventional hydrocarbons from a subterranean reservoir. Alternatively, the waste heat can be obtained from subterranean reservoirs such as hydrocarbon containing producing wells and geothermal wells producing heated water.