494 results about "Ammonium sulfite" patented technology

The recovering process includes the steps of: the reaction of the S containing fume with water solution of ammonia, with ammonia-to-sulphur molar ratio of 1.3-1.8 and gas-to-liquid ratio of 2000-5000, to produce ammonium sulfite solution; the oxidation of ammonium sulfite solution with air to obtain ammonium sulfate solution; the contact of the ammonium sulfate solution with hot fume to evaporatewater and the crystallization of ammonium sulfate in a crystallizer to produce commercial ammonium sulfate fertilizer. The equipment includes one desulfurizing tower with SO2 absorbing section, one ammonium sulfite oxidizing section, ammonium sulfate solution concentration section, one water washing section and mist elimianting section. The present invention can lower cost and steam consumption, reduce fume density and produce ammonium sulfate fertilizer.

The invention belongs to flue gas desulphurization technology of the environmental protection field. To solve the problems of large energy consumption, lower product quality and large investment in recovering ammonia sulfate by an ammonia desulphurization technique, the invention provides an energy-saving and high-quality ammonia desulphurization process for ammonia sulfate recovery. The process adopts ammonia water as a desulfurizer, ammonium sulfite is produced after the ammonia water and flue gas are decarbolized completely, and ammonia sulfate is produced after the ammonium sulfite is forcibly oxidized in a tower; impurities in the ammonia sulfate solution is removed by filtering, the filtrate is contacted with high-temperature flue gas in a desulfurizing tower for heat exchange, and when flue gas is cooled, the ammonia sulfate solution is heated and saturated; and then after crystallization of the saturated ammonia sulfate solution for a period of time, high-quality ammonia sulfate is produced after centrifugal drying. By adopting the technical proposal of the invention, not only thermal energy of an ammonia sulfate product which is produced by drying process can be greatly saved, high-quality ammonia sulfate fertilizer can be recovered, occupation area can be reduced and investment can be save, but also flue gas emission can meet the standard, without resulting in secondary pollution such as waste water and the like.

A segment-based ammonia flue gas desulfurization process and a device thereof combine traditional absorption towers with a crystallization tower. A regeneration tank is arranged at the outside of the tower. The processes of absorption of SO2, sulfite oxidation, regeneration of desulfurization solution, crystallization of ammonium sulphate and ammonia volatilization are carried out respectively. The process system effectively improves the removal rate of SO2, improves the oxidation of the sulfite, strengthens the crystallization of the ammonium sulphate and reduces the escape of ammonia in outlet smoke. The standard discharge of the smoke can be realized after the smoke is processed by the system. The removal rate of SO2 is above 95 percent. The whole system process is simple and has no secondary pollution. And the by-product ammonium sulphate has high economic value and can be especially configured by enterprises with fixed ammonium sources.

The invention discloses a deep desulfurization method of sulfate acid tail gas. The method additionally arranges a desulfurization tower behind a second adsorption tower of a sulphuric acid device; after the waste gas discharged from the second adsorption tower enters the desulfurization tower, an ammoniation absorbent is used for adsorbing SO2 in the waste gas to generate ammonium sulfite; the tail gas after the desulfurization passes through a demisting layer in the tower to eliminate acid fog; the purified tail gas is discharged through a chimney at high altitude; the ammonium sulfite in the absorbent is aerated and oxidized to be ammonium sulfate solution at the bottom of the tower; and after the concentration of circulation liquid ammonium sulfate meets the requirement, the circulation liquid ammonium sulfate is sent to a follow-up process to be processed and used. The deep desulfurization method of sulfate acid tail gas can cause the concentration of the SO2 in the tail gas to be lower than 100mg/m<3> in a standard state, greatly reduces the emission of the SO2 in the tail gas, is beneficial to the improvement of the atmospheric environment quality, meets the construction principles of energy conservation, emission reduction and sustainable development and has good social benefits; in addition, the deep desulfurization method can increase the recovery amount of the ammonium sulfate, and has certain economic benefits.

The invention discloses a method used for producing sulfur-based urea compound fertilizer from ammonia desulphurization by-products. The method comprises following steps: sulfur dioxide-containing tail gas is delivered into a desulfurizing tower; ammonium hydroxide or liquid ammonia is sprayed so as to absorb sulfur dioxide, ammonium sulfite is oxidized with air, and an obtained product is subjected to concentration so as to obtain an ammonium sulfate slurry, and the ammonium sulfate slurry is subjected to solid-liquid separation so as to obtain an ammonium sulfate wet material; the ammonium sulfate wet material is delivered into a molten urea groove via a conveyor, solid urea is delivered into the molten urea groove via another hopper, and an obtained mixture is subjected to heating melting, or liquid urea is added directly; fluidization granulation is carried out, wherein dried seed crystal is delivered into a fluidized bed through one end, and is driven to flow to the other end of the fluidized bed in the fluidized bed; a mixed ammonium sulfate-urea composite solution is pumped into the fluidized bed, and multistage spraying is carried out; the sulfur dioxide-containing tail gas is delivered into the fluidized bed or/and fluidized drying with hot air is carried out, and semi-finished product sulfur-based urea compound fertilizer is obtained via seed crystal growth; and a obtained fluidization tail gas is subjected to dust separation, and is delivered into an ammonia desulphurization tower. According to the method, ammonium sulfate low in additional value is changed into sulfur-based urea high in additional value at low investment and operation cost.

The invention discloses a low-temperature plasma smoke compound pollutant control method. By discharging at a high voltage to generate low-temperature plasmas in a dry reactor and a wet reactor, the method controls pollutants and oxidized by-products in the smoke, such as smoke dusts, sulfur dioxide, oxynitride, hydrogen sulfide, hydrogen chloride, heavy metal and the like, by combination with the conventional dedusting method, the ammonia method desulfuration, the limestone/gypsum wet method, the rotary atomization drying method and the like, wherein the dry plasma reactor is used together with a dedusting device to improve the dedusting efficiency and oxidize the nitric oxide; and an absorbing device is used together with the wet plasma reactor to remove gaseous pollutants, oxidize ammonium sulfite, namely a desulfurized product of an ammonia absorber, demist and purify the tail gas. The method can be used for controlling smoke compound pollutants of boilers or incinerators.

The invention provides a method for desulfurization of a sulfur recovery tail gas by using a boiler flue gas ammonia method. The method comprises the following steps: (1) burning the sulfur recovery tail gas, wherein sulfide in the sulfur recovery tail gas is converted into sulfur dioxide; (2) converging the burnt sulfur recovery tail gas with the boiler flue gas to form merged flue gas, feeding the merged flue gas to an absorption tower, and discharging the merged flue gas after being absorbed by absorption liquid in a countercurrent manner in the absorption tower, wherein the absorption liquid is a water solution containing an ammonium salt, and the ammonium salt is a mixture of ammonium sulfate and ammonium sulfite. By adopting the method disclosed by the invention, not only can the sulfur recovery rate be better ensured, but also emission of the tail gas achieves the environmental protection requirements; meanwhile, investment and operative difficulty are reduced; the floor area is reduced; the comprehensive utilization efficiency of energy is improved; a good effect of treatment of waste by waste can also be achieved.

The invention discloses a method for automatically controlling desulphurization and denitration by flue gas based on pH value and ORP value and an apparatus thereof. The method comprises the following steps: dedusting and preoxidazing flue gas, oxidizing NO to NO2, precleaning and processing flue gas by a prewashing system, then taking ammonium sulfite as a absorption liquid, absorbing SO2 and NOx(x is 1 or 2) in flue gas, keeping the pH value and ORP value of the absorption liquid in a set scope during the absorption process for ensuring the absorption efficiency of desulphurization and denitration as well as operation stability, passing the flue gas through an electric demister, and removing the ammonia mist in the flue gas for preventing the ammonia leakage. When the concentration ratio of the absorption liquid (NH4)2SO3/NH4HSO3 decreases to 0.9, a part of the absorption liquid in a washing tower reservoir is introduced into an ammonium sulfate byproduct treatment system, and the resource and recovery utilization can be realized. The provided desulphurization and denitration method has desulphurization efficiency with more than 95% and denitration efficiency with more than 85%, the ammonia escape amount is lower than 5mg/m<3>, and the sulfur resource can be simultaneously recovered.

The invention relates to a method for electroforming hard gold products. The method comprises the following steps: template picking, mould pouring, wax repairing and electric conducting layer coating are carried out to obtain a wax mould of a gold product to be processed, and a layer of electric conductive oil is coated on the surface of the wax mould; and a titanium net is taken as anode in the gold electroforming step, the wax mould coated with the electric conductive oil is put in an electrotyping bath as cathode, the electroforming solution is put in the electrotyping bath and includes sulfurous acid gold potassium, ammonium sulfite and potassium citrate, wherein the sulfurous acid gold potassium is combined with the ammonium sulfite, a trivalent gold ion is reduced into a univalent gold ion, the univalent gold ion generates close crystal grains, the close crystal grains are combined through the potassium citrate to form complexing gold through PH buffer solution, the gold is deposited on the wax mould to form a casting gold layer, and the half-finished product is prepared; and the wax film in the half-finished product and the electric conductive layer are removed in the wax removal step and the electric conductive layer removal step to obtain the finished product. The volume and the hardness of the gold product are changed by using the variation of the chemical structure of the gold ion, so that the hardness, the volume and the toughness of the gold product meet the standards simultaneously.

The invention relates to polyvinylidene fluoride resin compositions comprising 100 parts by weight of a polyvinylidene fluoride resin, and 0.03 to 10 parts by weight of at least one compound selected from the group consisting of alkyl quaternary ammonium sulfates and alkyl quaternary ammonium sulfites.

The invention discloses a method for recovering thiocyanate from coke oven gas desulfuration and decyanation wastewater. The method comprises the steps of: adding persulfate or sulfuric acid to polyamine salt wastewater for reacting with ammonium thiosulfate so as to generate ammonium sulfate and ammonium sulfite, and further oxidizing into ammonium sulfate and sulfur, thus the wastewater is changed into a two-component mixed liquid which contains ammonium thiocyanate and ammonium sulfate and is easy to separate by crystallization from a three-component mixed liquid, and high-efficiency separation is realized. The purity of the obtained ammonium thiocyanate crystal can reach 99%.

The invention relates to an ammonia desulfurization system for sintering flue gas, and the system comprises a gasifying equipment, a absorbing equipment, an oxidation equipment, a concentration equipment and filter equipment etc. The ammonia desulfurization system for sintering flue gas of the invention can removes the SO2 in the flue gas effectively, but also can desulfurizate by reacting with SO2 in the flue gas using carbonization waste water (liquid ammonia gasified). The product of ammonium sulfite is oxidated in a low concentration at the common pressure, and then is concentrated by evaporation by the quantity of heat of the flue gas to greatly save the heat dissipation of concentration by evaporation to arrive at the aim of economize on energy. The ammonia sulfate solution in high concentration is filtrated, and then is send to the ammiaonia sulfate plant to produce chemical fertilizer. The flue gas desulfurization system of the invention has a reasonable process, makes the discharge of the flue gas reach the standard, forms without secondary pollution, treatment the waste gas by waste carbonization waste water, and produces the byproduct-chemical fertilizer.

The invention relates to a method for leaching metals in an anode material of a waste lithium ion battery. The method for leaching the metals in the anode material of the waste lithium ion battery comprises the steps that anode active substances are obtained after the waste lithium ion battery is pretreated, then the anode active substances are made to react with an ammonium salt solution containing a reducing agent, solid-liquid separation is conducted after the reaction, and thus, leachate and filter residues are obtained. According to the method, the process is simple, the metal leaching rate is high, and the metal selectivity is high; by controlling the type and quantity of the reducing agent used in the leaching process, selective leaching of the metals can be achieved, for instance,when the anode material contains metals such as Li, Co and Mn, the reducing agent is ammonium sulfite, the leaching rate of Mn is 90% when the concentration of the reducing agent is 0.75 mol/L, and the leaching rate of Mn is 4% when the concentration of the reducing agent is 1.5 mol/L; the impurity content of the leachate is low, so that the cost for the subsequent impurity removal procedure is low; and the leaching process is conducted in a high-pressure kettle, emission of poisonous gas is avoided in the operation process, and the operation environment is good.

The invention relates to a method for boiling high concentration pulping in normal pressure or low pressure by an alkaline method with zero residual alkaline, and the method comprises adding accelerating agent in the boiling process and utilizing a double screw to rub and squeeze a pulper, leading pulp making and boiling process with an alkaline method to go on in normal pressure or low pressure, and leaving no residual alkaline in black liquor, leading pulp to always keep a higher density in the pulping process of boiling, washing and bleaching, and the pulp which is prepared can meets the requirement of paper making. Accelerating agent chooses one or a plurality of magnesium hydrate, potassium hydrate, sodium metasilicate, sodium sulfide, sodium sulfite, ammonium sulfite and carbamide. Special-purpose pulping boiling equipment and high-pressure boilers are not needed by pulping paper mills through utilizing the invention, in the process of pulping, pulp always keeps higher density, and black liquid has high density, little numbers and low energy consumption, alkaline recovery project with great investment is not needed to be built, and the invention enables black liquid to prepare fertilizer or other chemical products with high quality, and the invention is suitable for popularizing and applying.

The invention relates to a new material with air cleaning function and a preparation method thereof. The artware material comprises the following compositions in percent by weight: 10-50% of a plant active raw material, 0.4-4% of an antiseptic, 0.1-5% of water-soluble essence, 0.1-5% of a fixative, 0.3%-2% of sodium sulfite, 0.5%-3% of sodium sulfite, 1%-10% of aluminium sulfate, 0.15%-1% of sodium hypochlorite, 0.2%-1% of a pigment, 20%-60% of a solid porous adsorbent, 10%-30% of an active catalyst, 5%-15% of flocculent fiber, and 10%-35% of a binder. A prepared artware possesses unique artistry, natural plant delicate fragrance and strong effects of removing formaldehyde and other harmful gases, performing sterilization and disinfection and purifying air, long-acting infrared ray can guarantee health of family members, and prevention and treatment of diseases are integrated. Also, the manufacture cost is low, operation is simple, and the material and the preparation method are suitable for industrialized production, and are beneficial for the nation and the people. The additive and the chemical reagents added during preparation do not contain harmful substances, and environment pollution is not caused during usage of the new material.

The invention discloses a method for recycling iron waste for the fenton technology. The method comprises the following steps that hydrogen peroxide, the iron waste and an activating agent are added to waste water to be treated, stirring is conducted so that the iron waste can be dispersed in a reaction system, a reaction is conducted, and then solid and liquid separation is conducted, wherein the activating agent is any one or a mixture of sodium sulfite, potassium sulfite, magnesium sulfite, calcium sulfite, sodium thiosulfate, potassium thiosulfate, calcium thiosulfate, magnesium thiosulfate, sodium borohydride, potassium borohydride, hydroxylamine hydrochloride and ascorbic acid. By means of the method, various kinds of iron waste are recycled, meanwhile, zero iron mud emission is achieved, and thus pollution to the environment is effectively reduced. The invention further provides a water treating device capable of achieving the method. By means of the method and the water treating device, the reaction speed of the iron waste in the fenton system is greatly increased, the effective pH range of the fenton system is expanded, meanwhile zero iron mud emission is achieved, and thus pollution to the environment can be easily reduced.

A method is disclosed for the production of taurine in high yield by a cyclic process of reacting monoethanolamine, sulfuric acid, and ammonium sulfite in the presence of additives to inhibit the hydrolysis of 2-aminoethyl hydrogen sulfate intermediate. The cyclic process is economical and little waste is generated.

The invention discloses a process for continuous preparation of caramel pigment by an ammonium sulfite method, which comprises the following steps of: (1) adding a catalyst for the first time, and mixing with syrup; (2) performing two-stage pre-heating; (3) increasing temperature; (4) performing secondary multi-stage catalyst feeding and caramelization; (5) flashing and reducing temperature; (6) diluting and regulating pH value; (7) filtering; (8) condensing; (9) performing two-stage cooling, and (10) quality regulating which can be further comprised. The process for continuous preparation of the caramel pigment by the ammonium sulfite method disclosed by the invention can realize continuous and sealed preparation of the caramel pigment by the ammonium sulfite method, improve production efficiency and output, improve safety of the product and reduce the energy consumption; the produced caramel pigment is stable in quality, and is capable of simultaneously meeting high color index and high red index, being ideal caramel pigment in many fields, particularly in soy sauce.