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273 results about "Sulfuric Acid Esters" patented technology

Method for preparing taurine by adopting sulfonation of ammonium sulfite

The invention discloses a method for preparing taurine by adopting sulfonation of ammonium sulfite. The method comprises the steps of: firstly carrying out esterification reaction to synthetize an intermediate 2-aminoethanol sulfate by taking concentrated sulfuric acid and ethanolamine as raw materials; carrying out sulfonation reaction to prepare taurine by taking ammonium sulfite and 2-aminoethyl sulfate as the raw materials, wherein ammonia is introduced to protect before the reaction, the temperature of the reaction solution is reduced after the sulfonation reaction is finished, and the conversion ratio of 2-aminoethyl sulfate is analyzed by adopting a sodium thiosulfate inverse titration method; cooling the reaction solution to room temperature, adding calcium hydroxide, heating, agitating and filtering to remove calcium sulfate, removing ammonia in mother liquor and repeatedly utilizing the mother liquor; then purifying the taurine by a cooling and crystallizing method to obtain crystal, carrying out suction filtration and baking the obtained crystal, and analyzing the taurine crystal by a thermal analysis method. The method disclosed by the invention is an integrated preparation method of combining the synthesis and separation of the taurine. The method is the preparation method of the taurine with simple operating process and mild reaction condition, wherein the primary conversion rate of 2-aminoethyl sulfate can be up to 79% and the desalination efficiency is 99.12%.
Owner:ZHENGZHOU UNIV

Electrolytic solution for high-temperature high-magnification type lithium ion battery

The invention discloses electrolytic solution for a high-temperature high-magnification type lithium ion battery. The electrolytic solution comprises an aprotic organic solvent, basic electrolyte lithium salt and a functional additive, wherein the aprotic organic solvent is one substance or a mixture of more of common carbonic ester, sulfite and sulfone compound and the like; the basic electrolyte lithium salt is 0.5-1.2mol/L of double-oxalate lithium borate or lithium difluoroborate or a mixture of the double-oxalate lithium borate and the lithium difluoroborate; the functional additive is sulfate difluoro lithium borate or sulfite difluoro lithium borate or a mixture of the sulfate difluoro lithium borate and the sulfite difluoro lithium borate. The electrolytic solution disclosed by the invention has the advantages that by optimization of components of the electrolytic solution, the electrical conductivity and the thermal decomposition temperature of the electrolytic solution are improved, the impedance of a solid electrolyte interfacial film formed by the electrolytic solution on the surface of the electrolyte material is greatly reduced, and further the high-temperature performance and the rate performance of the battery are improved.
Owner:LANZHOU UNIVERSITY OF TECHNOLOGY

Method for producing sulfuric acid fluorinated surfactants

The invention discloses a preparation method for a sulfuric acid ester salt fluorine surfactant. The method comprises the following steps: taking 4-perfluoro alkene oxygen group benzene sulfonyl chloride and 2-methylamino alcohol as raw materials, taking inorganic base or organic base as an acid-binding agent, and carrying out an amidation reaction in an organic solvent 1 to obtain N- ethoxyl-N-methyl-4-perfluoro alkene oxygen group benzene sulfonyl chloride; and carrying out the esterification reaction of N-ethoxyl-N-methyl-4-perfluoro alkene oxygen group benzene sulfonyl chloride and sulfur trioxide in an organic solvent 2 for 1.5 to 15 hours, carrying out distillation to remove the solvent when the esterification reaction is finished, adding water for dissolution, then adding inorganic base aqueous solution with the mass content of between 10 and 50 percent into the solution till the reaction system is neutral, stirring the reaction system for reaction, and finally obtaining sulphuric acid 2-( N-methyl-4- perfluoro alkene oxygen group benzene sulfonyl chloride)ethyl ester sodium. The preparation method has a convenient raw material source, a simple synthesis method and few wastes. In particular, sulfur trioxide (SO3) and N- ethoxyl-N-methyl-4- perfluoro alkene oxygen group benzene sulfonyl chloride are adopted to carry out the esterification reaction, thereby bringing about high reaction yield.
Owner:ZHEJIANG UNIV OF TECH

Preparation method of p-aminophenyl-beta-ethoxyl sulphone sulphate

The invention discloses a preparation method of p-aminophenyl-beta-ethoxyl sulphone sulphate. The preparation method comprises the following steps of: adding p-aminophenyl and mercaptoethanol into an N, N-dimethyl formamide solvent to dissolve, and adding NaOH to carry out reaction; filtering, distilling under reduced pressure to obtain p-aminophenyl-beta-ethoxyl thioether after reaction; adding the p-aminophenyl-beta-ethoxyl thioether and a catalyst into an oxidization kettle, adding hydrogen peroxide to carry out reaction, and cooling and separating out an oxidized and crystallized material after the reaction; washing the oxidized and crystallized material, adding water and a palladium-carbon catalyst after washing to carry out hydrogenation reaction, thus obtaining an hydrogenation product and water after the reaction; adding pure sulfuric acid to carry out esterification reaction, and crushing the obtained product to obtain the p-aminophenyl-beta-ethoxyl sulphone sulphate. In the preparation method disclosed by the invention, dosage of the adopted hydrogen peroxide and the palladium-carbon catalyst is less, especially, dosage of the palladium-carbon catalyst is greatly reduced, so that production cost is greatly lowered; and moreover, output of three wastes is lower, yield is higher, economical benefits and social benefits are remarkable.
Owner:XINXIANG RUICHENG TECH DEV
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