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79 results about "Tetramethylammonium" patented technology

Tetramethylammonium (TMA) or (Me₄N⁺) is the simplest quaternary ammonium cation, consisting of four methyl groups attached to a central nitrogen atom, and is isoelectronic with neopentane. It is positively charged and can only be isolated in association with a counter-ion. Common salts include tetramethylammonium chloride and tetramethylammonium hydroxide. Tetramethylammonium salts are used in chemical synthesis and are widely employed in pharmacological research.

Method for preparing electronic grade tetramethylammonium hydroxide by continuous method

The invention discloses a method for preparing electronic grade tetramethylammonium hydroxide by a continuous method. The method comprises the following steps of: sequentially dividing an electrolytic cell into a cathode chamber, a first cathode middle chamber, a second cathode middle chamber and an anode chamber, wherein the two adjacent chambers are partitioned by a cation exchange membrane and connected by using a circulating pump and a filter connected in series, and the anode chamber is connected with the circulating pump and the filter connected in series; putting a 5 to 50 percent aqueous solution of a tetramethyl ammonium salt into the anode chamber, wherein (CH3)4N<+>, H<+> and metal cation R<+> in the solution enter the two cathode middle chambers and the cathode chamber through the cation exchange membranes; and removing the sediment generated by partial metal cation R<+> and OH<-> by using the filter, pumping the filtrate for reaction by using the circulating pump, and discharging the 5 to 30 percent tetramethylammonium hydroxide from the cathode chamber, wherein the concentration of each metal ion is less than 10ppb, the concentration of each anion is less than 500ppb, and the tetramethylammonium hydroxide has high purity. The current efficiency of the tetramethylammonium hydroxide is 70 to 80 percent, the tetramethylammonium hydroxide has high utilization rate, and the method has no pollution and can be used for large-scale production.
Owner:镇江润晶高纯化工科技股份有限公司

Ionic additives for extreme low dielectric constant chemical formulations

A process for depositing porous silicon oxide-based films using a sol-gel approach utilizing a precursor solution formulation which includes a purified nonionic surfactant and an additive among other components, where the additive is either an ionic additive or an amine additive which forms an ionic ammonium type salt in the acidic precursor solution. Using this precursor solution formulation enables formation of a film having a dielectric constant less than 2.5, appropriate mechanical properties, and minimal levels of alkali metal impurities. In one embodiment, this is achieved by purifying the surfactant and adding ionic or amine additives such as tetraalkylammonium salts and amines to the stock precursor solution. In some embodiments, the ionic additive is a compound chosen from a group of cationic additives of the general composition [NR(CH3)3]+A−, where R is a hydrophobic ligand of chain length 1 to 24, including tetramethylammonium and cetyltrimethylammonium, and A− is an anion, which may be chosen from the group consisting essentially of formate, nitrate, oxalate, acetate, phosphate, carbonate, and hydroxide and combinations thereof. Tetramethylammonium salts, or more generally tetraalkylammonium salts, or tetraorganoammonium salts or organoamines in acidic media are added to surfactant templated porous oxide precursor formulations to increase the ionic content, replacing alkali ion impurities (sodium and potassium) removed during surfactant purification, but which are found to exhibit beneficial effects in promoting the formation of the resulting dielectric.
Owner:VERSUM MATERIALS US LLC

Novel sulfonate salts and derivatives, photoacid generators, resist compositions, and patterning process

Sulfonate salts have the formula: CF3—CH(OH)—CF2SO3−M+ wherein M+ is a Li, Na, K, ammonium or tetramethylammonium ion. Because of inclusion within the molecule of a hydroxyl group which is a polar group, the sulfonic acids are effective for restraining the length of acid diffusion through hydrogen bond or the like. The photoacid generators that generate these sulfonic acids perform well during the device fabrication process including coating, pre-baking, exposure, post-exposure baking, and developing steps. The photoacid generators are little affected by water left on the wafer during the ArF immersion lithography.
Owner:SHIN ETSU CHEM IND CO LTD

Amino acid intercalation manganese dioxide and its preparation method

The invention discloses a manganese dioxide composite material of amino intercalation and making method of planar assembly, wherein the chemical composition of composite material is (A<+>)a(Amino+)bMnO2mH2O ( A<+> is inorganic or organic cation, such as one, two or three of sodium ion, hydrogen ion and tetramethyl ammonium ion; Amino is one of L- lysine, L- arginine and L-histidine; a and b is the quantity of A<+> and Amino<+> separately; a+b<=0.4; m is the quantity of crystallinic water; 0.1 and A<+> in the middle; the stratified structure Delta-MnO2 is prepared by hot water, which is stripped by tetramethyl ammonium hydroxide to form plywood with negative electricity; the plywood and amino cation are self-assembly by electrostatic action, which produces the composite material of intercalation-structured amino acid-manganese dioxide. The invention possesses potential appliance value in the chiral catalysis, electrochemical catalysis and electrochemical biological sensor domain.
Owner:BEIJING UNIV OF CHEM TECH

Method for Enhancing High Temperature and Low Temperature Resistance of Aluminum Electrolytic Capacitors

The invention discloses a method for enhancing the high temperature resistance and low temperature resistance of an aluminum electrolytic capacitor, which includes the preparation of an electrolyte, and the electrolyte includes the following raw materials in parts by weight: main solvent: 48-80%; auxiliary solvent: 10-32%, solute : 15-30%, additives: 0.3-3.2%, wherein, the solvent composed of the main solvent and the auxiliary solvent is a liquid with low saturated vapor pressure; the solute is tetramethylammonium maleate, ammonium adipate, triethylamine, One or more of 1,2-dimethylimidazolium phosphoric acid and phosphorous acid. Due to the selection of solvents with low saturated vapor pressure, the ratio of solutes is increased to ensure that the electrolyte does not condense at low temperature and the solutes do not precipitate; adding hydrogen absorbing agents and water suppressing agents reduces the internal pressure of the product; adding inhibitors and low leakage agents, The occurrence of high-temperature characteristic defects such as too fast recovery of electric leakage is prevented; the invention can also effectively ensure the low-temperature stability of the electrolyte, and provide guarantee for the stable operation of the LED driving power supply.
Owner:ZHAOQING BERYL ELECTRONICS TECH

Octakis (acetylenyl dimethyl siloxane) polysilsesquioxane and synthetic method thereof

The invention relates to a synthetic method of octakis (acetylenyl dimethyl siloxane) polysilsesquioxane. The synthetic method comprises the steps that (1) 1,3-acetylene-1,1,3,3-tetramethyldisiloxane is synthesized by Grignard reaction; (2) 1,3-acetylene-1,1,3,3-tetramethyldisiloxane is hydrolyzed to obtain ethinyl dimethyl silicon alcohol, and a chloridizing agent is used for chloridizing silicon hydroxyl to obtain acetenyl dimethylchlorosilane; (3) tetraethoxysilane is used, hydrolytic condensation is performed under an alkaline condition provided by tetramethylammonium hydroxide, and octamer tetramethylammonium silicate is obtained; (4) the octamer tetramethylammonium silicate and the acetenyl dimethylchlorosilane react to obtain the octakis (acetylenyl dimethyl siloxane) polysilsesquioxane. The prepared octakis (acetylenyl dimethyl siloxane) polysilsesquioxane has end alkynyl and excellent high temperature resistance and high reactivity, and can be used for preparing nanometer POSS (polyhedral oligomeric silsesquioxane) materials; the octakis(acetylenyl dimethyl siloxane)polysilsesquioxane can be applied in spatial and medical functional materials and the like and has an excellent development and application prospect.
Owner:EAST CHINA UNIV OF SCI & TECH

Tetramethylammonium dizinc-vanadium oxygen-cluster catalyst as well as preparation method and application thereof

The invention discloses a preparation method of a tetramethylammonium dizinc-dcavanadium oxygen-cluster single-component catalyst. Such a method comprises the following steps of putting zinc acetate, vanadium pentoxide, tetramethylammonium hydroxide and water into a beaker to carry out a reaction, after the reaction is finished, carrying out filtration, and slowly volatilizing filtrate, so as to obtain a crystal of the tetramethylammonium dizinc-dcavanadium oxygen-cluster single-component catalyst. The method provided by the invention has the advantages that a reaction speed is quick, a reaction process is simple, an obtained product is high in purity, and the post treatment is simple. In a cycloaddition reaction of carbon dioxide, the conversation ratio is up to 94.7 percent, and the selectivity is up to 95.6 percent.
Owner:LIAOCHENG UNIV
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