678results about "Amino compound purification/separation" patented technology

The invention discloses a green preparation process of a microwave-assisted synthesized perovskite semiconductor material, which aims at solving the problems of long reaction period, large reagent dosage, heavy pollution and the like of the traditional perovskite preparation process, adopts a novel organic-inorganic hybrid precursor and green solvent system, and accelerates the reaction by microwave radiation. The rapid and environment-friendly synthesis of the material is realized by accurately regulating and controlling microwave parameters and combining multiple processes such as intermittent and collaborative ultrasonic processes. Novel compounds such as nitrogen-containing heterocyclic borate and organic phosphonate are introduced to optimize the performance of the material. The process significantly shortens the preparation period, reduces reagent consumption, improves photoelectric properties, and enhances material stability.

The invention relates to a degradable epoxy resin composite material with an adjustable curing speed, and a preparation method and a mild total recycling method thereof. Existing degradable epoxy resin has the problems of high cost, harsh degradation conditions and the like, and is difficult to meet the requirements of different application scenes on curing speed and temperature at the same time. The invention provides an epoxy resin composite material which comprises curing agent components (an epoxy resin amine curing agent and an ester-containing polythiol curing agent) and epoxy resin components (glycidyl ether epoxy resin, glycidyl amine epoxy resin and glycidyl ester epoxy resin). The cured composite material can be fully recycled through catalytic degradation under mild conditions by using a lewis acid and an amino group breaking ester bond mechanism, and the degradation product can be directly used as a curing agent, a toughening agent and a chain extender. The epoxy resin composite material disclosed by the invention not only has adjustable curing speed and high use performance, but also realizes environmental friendliness and resource recycling, and provides a new solution for sustainable development of epoxy resin.

The invention discloses a method for joint production of cyclohexylamine and dicyclohexylamine, which comprises the following steps: 1) feeding aniline tail gas of a nitrobenzene catalytic hydrogenation production device into a gas-liquid separator for gas-liquid separation to obtain aniline tail hydrogen and aniline condensate; 2) mixing aniline tail hydrogen and new hydrogen as a raw material A, and mixing defective aniline and fresh aniline in proportion as a raw material B; (3) feeding the vaporized raw material B and the vaporized raw material A into a fixed bed reactor according to a certain hydrogen-oil ratio, and carrying out hydrogenation reaction; a hydrogenation reaction product is subjected to heat exchange condensation and then enters a gas-liquid separator for gas-liquid separation, a gas phase serves as recycle hydrogen to be mixed with the raw material A, and a liquid phase is fed into a distillation device; and 4) carrying out primary distillation and rectification purification in sequence to obtain cyclohexylamine and dicyclohexylamine. According to the method, aniline tail gas resources and defective aniline are fully utilized, the three-waste treatment cost is reduced, product benefits can be improved, pollution to the environment can be reduced, and economic benefits and social benefits are remarkable.

The invention relates to a method and a system for synthesizing N-methylaniline and co-producing N, N-dimethylaniline by a gas phase method, and belongs to the technical field of chemical engineering. The system comprises a raw material gasification unit, a reaction unit, a separation and rectification unit and a hydrogen recovery unit which are connected through pipelines. The method comprises the following steps of: firstly, mainly synthesizing N-methylaniline from raw materials aniline and part of methanol in a first-methylaniline reactor, then partially or completely feeding first-methylaniline reaction gas into a second-methylaniline reactor, adding methanol steam, and further reacting to generate N, N-dimethylaniline. And after the product gas is subjected to heat exchange energy recovery, a liquid phase and a gas phase respectively enter the separation and rectification unit and the hydrogen recovery unit. The purification of N-methylaniline and N, N-dimethylaniline and the recovery of byproduct hydrogen are realized. The yield of N, N-dimethylaniline (in terms of aniline) can be adjusted in a range of 5-30% by adjusting reaction conditions and a feeding ratio.

A method for continuously producing m-xylylenediamine belongs to the technical field of organic synthesis and comprises the following steps: (1) mixing isophthalonitrile, toluene and liquid ammonia according to a mass ratio of 1: (3-5): (13-17) in a nitrogen atmosphere to form a reaction mixture; (2) heating the interior of a reaction bed containing a catalyst to 90-95 DEG C, continuously introducing hydrogen into the reaction bed, introducing the reaction mixture after the pressure intensity of the reaction bed is stable, and carrying out a catalytic hydrogenation reaction to generate a reaction product; and (3) carrying out gas-liquid separation on the reaction product, removing liquid ammonia from the liquid-phase product through an ammonia distillation process, and separating toluene and m-xylylenediamine through a rectification process to obtain m-xylylenediamine. According to the method, isophthalonitrile and hydrogen are used as raw materials, liquid ammonia and methylbenzene are used as reaction solvents, the raw materials and the reaction solvents are heated to 90-95 DEG C under the catalytic action of a catalyst for an exothermic reaction, m-xylylenediamine is generated through the reaction, and the reaction yield is larger than 99%.

The invention discloses a crystallization process of o-chloro-p-nitroaniline, which comprises the following steps: feeding a material into a crystallization kettle to crystallize the o-chloro-p-nitroaniline, regulating and controlling the temperature in the kettle body in the crystallization process, cooling to a metastable region of the o-chloro-p-nitroaniline, preserving the heat in the metastable region for a first preset time length, and then cooling to a second preset time length; continuously cooling to a first temperature lower than the melting point of the o-chloro-p-nitroaniline, keeping the temperature at the first temperature for a second preset duration, continuously cooling to a second temperature, and outputting the material out of the crystallization kettle for filtration and separation; in the cooling process, the cooling speed in the kettle body is controlled to be 0.1-0.2 DEG C / min. According to the invention, the interior of the kettle body can be slowly cooled, and the cooling speed of each part in the kettle body can be more uniform, so that the crystallization purity and the product quality of o-chloro-p-nitroaniline are finally improved.

The invention discloses methylamine rectification equipment, a separation and purification assembly and a purification process, and relates to the technical field of methylamine processing.The methylamine rectification equipment comprises a tower body, a skirt is arranged at the bottom of the tower body, a manhole is formed in the side face of the skirt, a drain pipe is arranged at the bottom of the tower body, a ventilation hole is formed in the side face of the skirt, and a steam ingress pipe is arranged at the bottom of the side face of the tower body; a liquid inlet pipe is arranged on the side face of the tower body, a backflow pipe and a tower body top hanging column are arranged on the two sides of the top of the side face of the tower body respectively, a steam guide-out pipe is arranged at the top end of the tower body, a gas-liquid separator is arranged on the top side of the interior of the tower body, and tower plate assemblies are vertically arranged in the tower body in a staggered mode. Moreover, when the tower plate leaks liquid, monitoring is carried out in time, process parameters are adjusted in time, in addition, the flow speed of liquid on the tower plate can be adjusted conveniently according to production requirements, and blockage clearing can be intervened in time conveniently when the tower plate is blocked.

The invention relates to the technical field of gas separation, in particular to an amine recovery monitoring method and system for polyurethane synthesis tail gas. The method comprises the following steps: preliminarily separating to obtain a triethylamine solution; collecting parameter values of different parameters for distillation of the triethylamine solution; acquiring a parameter sequence in a preset time period; decomposing the parameter sequence to obtain a periodic sequence and a trend sequence; obtaining periodic saliency values of different parameters based on the periodic sequence, and obtaining a fluctuation consistency coefficient based on the trend sequence; a distillation interference coefficient is obtained after weighting; pure triethylamine is obtained based on the distillation interference coefficient control system; collecting attribute values of different attributes, constructing a change characteristic value sequence through differences between data values and predicted values of the attributes in the sliding window, and obtaining a dehydration steady-state index based on sequence similarity and vapor pressure differences; and recycling and monitoring of triethylamine are realized based on the dehydration steady-state index. According to the method, the dehydration efficiency of the triethylamine is improved, and the purity of the recovered triethylamine is further improved.

The invention discloses a preparation method and application of a metal sulfide adsorbent for adsorbing iodine and methyl iodide. The preparation method comprises the following steps: uniformly mixing an antimony source, a sulfur source, a deep eutectic solvent, polyamine and water to obtain a mixed solution; and transferring the mixed solution into a high-pressure reaction kettle, sealing, carrying out hydrothermal reaction at 110-220 DEG C for 2-9 days, cooling to room temperature to separate out crystals, and filtering, washing and drying to obtain the metal sulfide adsorbent. The invention also discloses application of the metal sulfide adsorbent in adsorption of iodine and methyl iodide. The metal sulfide adsorbent disclosed by the invention has a good adsorption effect on iodine and methyl iodide, and compared with an ethylenediamine-oriented metal sulfide adsorbent, the diethylenetriamine-oriented metal sulfide adsorbent has higher adsorption capacity on iodine and methyl iodide.

The invention relates to the technical field of catalysis, in particular to a green preparation process for synthesizing 4 '-chloro-2-aminobiphenyl through a membrane method.A palladium-based catalytic membrane is prepared through an impregnation method, by means of the multi-pore-channel advantage of a ceramic membrane, active components can be well distributed on the surface and in the membrane, contact of a reaction substrate and active sites is promoted, and the catalytic activity of 4'-chloro-2-aminobiphenyl is improved. The reaction effect is enhanced, the reaction efficiency is improved, the preparation process is simple, the preparation environment is mild, and large-scale production can be realized; meanwhile, the 4 '-chloro-2-aminobiphenyl is prepared by adopting a method for carrying out Suzuki-Miyaura coupling reaction by adopting the catalytic membrane, tedious steps in the traditional industry are omitted, compared with a traditional heterogeneous catalyst, the trouble of recovery is avoided, the cost is saved, the harm to the environment is greatly reduced, and compared with the prior art, the 4'-chloro-2-aminobiphenyl has a wide application prospect.

The invention provides a low-energy-consumption preparation process of tetramethylammonium bicarbonate, and relates to the technical field of chemical synthesis. The preparation process comprises the following steps: inputting trimethylamine, dimethyl carbonate and a solvent methanol into a reactive distillation tower, carrying out a quaternization reaction to generate methyl carbonate tetramethylammonium, and carrying out a hydrolysis reaction on a first liquid phase obtained by rectification and water vapor to generate TMAB; the reacted material is input into a methanol removal tower for rectification, an obtained second gas phase is heated and pressurized, one part of the second gas phase is input into a subsequent methanol recovery tower, the other part of the second gas phase exchanges heat with water to generate steam, the steam is input into a tower kettle of the methanol removal tower, and high-purity methanol is extracted from the side of the methanol recovery tower. The number of reaction equipment is reduced, and the energy utilization rate is increased; the steam grade is improved by utilizing a heat pump technology, and steam latent heat is integrated between the methanol removal tower and the methanol recovery tower through thermal coupling, so that the overall process energy consumption is remarkably reduced while the product quality is ensured.

The invention discloses an activated carbon modification method which comprises the following steps: activating activated carbon through plasma, and then performing graft modification by using 3-amino-5-sulfydryl-1, 2, 4-triazole (AMT) to obtain the activated carbon. The method aims at solving the problems that in an existing modification process, the grafting rate is low, the adsorption performance is poor, and pores are prone to being damaged, and the method is suitable for continuous treatment of the m-phenylenediamine (MPD) oxidation color development aqueous solution. According to the process, the AMT grafting rate of the modified activated carbon is 1.0-1.2 mmol / g, the specific surface area is 950-1100 m < 2 > / g, the pore volume ratio of activated mesopores is increased to 43%, the decolorization rate is greatly increased, the saturated adsorption period of the activated carbon is prolonged, and the solution can be kept basically colorless within 120 hours by using 0.5 wt% of activated carbon under a static adsorption condition.

The invention relates to the field of anti-aging agents DTPD, and particularly discloses a preparation method of the anti-aging agent DTPD. The preparation method of the anti-aging agent DTPD comprises the following steps: mixing aniline and o-toluidine, stirring, heating to 50-60 DEG C, adding hydroquinone and a catalyst, carrying out condensation reaction at 100-250 DEG C, removing evaporated water in the reaction process, and stopping the reaction until water cannot be evaporated; cooling to 100-140 DEG C, filtering while the mixture is hot, and distilling to remove impurities, so as to obtain the anti-aging agent DTPD; the catalyst is selected from one or more of benzene sulfonic acid, benzene disulfonic acid, p-toluenesulfonic acid, p-aminobenzene sulfonic acid, aniline trisulfonic acid and sulfonated halloysite. The preparation method disclosed by the invention has the advantages of high content of effective components in the product, simplicity and convenience in operation and safety.

To provide a fluorinated aniline derivative that is suitable for use as a material for forming charge-transporting thin films for electronic components such as organic EL elements.SOLUTION: For example, fluorinated aniline derivatives are represented by the following formulae (H1) and (H2).SELECTED DRAWING: None

The invention discloses a method for extracting and separating N-methylaniline and N, N-dimethylaniline, and relates to the technical field of organic compound separation.The method comprises the steps that a reaction product of aniline and methyl alcohol is taken and fed into an adsorption refiner to be adsorbed, and a mixture A is obtained; feeding the mixture A into a light component removal tower for light component removal, collecting at the top of the light component removal tower to obtain light components, feeding the light component removal tower into a heavy component removal tower for heavy component removal, and collecting at the top of the heavy component removal tower to obtain a mixture B; taking the mixture B, feeding from the middle part of an extractive distillation tower, taking an extracting agent, feeding from the upper part of the extractive distillation tower, and performing extractive distillation; collecting the N, N-dimethylaniline at the top of the extractive distillation tower to obtain N, N-dimethylaniline, and collecting the N, N-dimethylaniline at the bottom of the extractive distillation tower to obtain an N-methylaniline mixed solution; feeding the N-methylaniline mixed solution into a desorption tower for desorption; collecting at the top of the desorption tower to obtain N-methylaniline, and collecting at the bottom of the desorption tower to obtain the extracting agent.

The invention discloses an organic-inorganic hybrid zero-dimensional halide perovskite single crystal material and a preparation method thereof. The chemical formula of the organic-inorganic hybrid zero-dimensional halide perovskite single crystal material is PMA4InCl7.H2O, and the chemical formula of the antimony-doped single crystal material is PMA4InCl7.H2O: Sb, the corresponding single crystal material is obtained through the steps of raw material adding, cooling crystallization, suction filtration, drying and the like. The optical band gap of the PMA4InCl7. H2O is determined to be 4-5 eV through an ultraviolet-visible spectrophotometer, and when the PMA4InCl7. H2O is irradiated by a 365 nm portable ultraviolet lamp, the PMA4InCl7. H2O shows light blue; the optical band gap of the PMA4InCl7. H2O: Sb is determined to be 3-4 eV through an ultraviolet-visible spectrophotometer, and when the PMA4InCl7. H2O: Sb is irradiated by a 365 nm portable ultraviolet lamp, the PMA4InCl7. H2O: Sb shows bright yellow. The maximum quantum yield measured by an absolute fluorescence quantum yield spectrometer can reach 72%.

This invention relates to the field of synthesis and discloses a method for synthesizing hexamethylenediamine and co-producing cyclohexylimine. The method includes: (1) ammonolysis: bis(hexamethylene)triamine undergoes an ammonolysis reaction in the presence of an ammonolysis catalyst, ammonia, and hydrogen; wherein the ammonolysis catalyst contains active components Ni, La, and In; (2) the material obtained from the ammonolysis reaction is sequentially subjected to cyclohexylimine separation and hexamethylenediamine separation. This method can simultaneously obtain hexamethylenediamine and cyclohexylimine, and exhibits high reactivity, high conversion rate, and high selectivity.

A preparation method for diamines and polyamines of the diphenylmethane series. By means of controlling a preparation process for diamines and polyamines of the diphenylmethane series to satisfy that the neutralization phase-separation coefficient M≤1.0, the method can improve the phase separation effect after neutralization while not introducing other substances, thus facilitating stable phase separation, and improving the phase separation efficiency. The preparation method controls the preparation process for the diamines and polyamines of the diphenylmethane series to satisfy that the neutralization phase-separation coefficient M≤1.0, preferably M≤0.8, and more preferably M≤0.5, the neutralization phase-separation coefficient M being calculated according to following equation (I), and R in equation (I) being an aqueous-phase concentration index and being calculated according to following equation (II).

A process for the manufacture of isophorone diamine (IPDA), comprising the steps of:a) providing a feed stream comprising trans-IPDA, cis-IPDA, isophorone nitrile amine (IPNA), components having a lower boiling point than trans-IPDA and components having a higher boiling point than IPNA, including isophorone amino alcohol (IPAA) and components having a higher boiling point than IPAA;b) separating the feed stream into(i) a fraction (ii) comprising a higher mass fraction of cis-IPDA content, compared to the feed stream;(ii) a fraction (iii) comprising a higher mass fraction of IPNA compared to the feed stream and a higher mass fraction of components having a boiling point higher than the boiling point of IPNA, including IPAA and components having a higher boiling point than IPAA, compared to the feed stream and optionally IPDA;c) further separating fraction (iii) into(iii) a fraction (iii-1) comprising a higher mass fraction of IPDA, compared to fraction (iii); and / or(iv) a fraction (iii-3) comprising a higher mass fraction of IPAA, compared to fraction (iii).

The invention discloses a method for preparing electronic grade tetramethyl ammonium bicarbonate. The method comprises the following steps: respectively pumping dimethyl carbonate and trimethylamine as raw materials and methanol as a solvent into a modified ion exchange resin tower for demetalization, mixing in a mixing kettle, and then entering a tandem reaction kettle; reaction materials are fed from the bottom of the previous stage, discharged from the upper part of the reactor and fed into the next stage of reactor, and are catalyzed and dehydrated in the last stage of reactor to further remove metal ions; feeding into a flash tank after passing through a multi-stage reaction kettle, separating excessive methanol and dimethyl carbonate, and refluxing to the mixing kettle; materials at the bottom of the flash tank enter a hydrolysis rectifying tower, methanol at the top partially flows back, and the product tetramethyl ammonium bicarbonate is obtained at the bottom of the rectifying tower. The reaction is stable, the reaction is driven by pressure difference, the number of moving equipment is minimum, continuous operation and automatic control are achieved, meanwhile, metal ion control in the raw material and synthesis process is achieved, and the quality of the electronic-grade tetramethylammonium bicarbonate is improved.

The invention provides a method for reversibly regulating and controlling the water solubility of long-chain alkyl trimethyl ammonium bromide, which comprises the following steps of: mixing sodium benzyl selenopropionate serving as an auxiliary agent with long-chain alkyl trimethyl ammonium bromide, adding water for dissolving, reducing the Krafft temperature of the long-chain alkyl trimethyl ammonium bromide to 10 DEG C or below, and then adding sodium benzyl selenopropionate, according to the method, benzyl selenium sodium propionate is oxidized into benzyl selenium oxygen sodium propionate by adding an oxidizing agent, so that the KT of long-chain alkyl trimethyl ammonium bromide is increased, and the water solubility of the long-chain alkyl trimethyl ammonium bromide is reduced, so that the long-chain alkyl trimethyl ammonium bromide is crystallized and separated out from an aqueous solution, and the separation, recovery and reutilization of the long-chain alkyl trimethyl ammonium bromide are realized; the residual water phase solution after the long-chain alkyl trimethyl ammonium bromide is recovered can be used as the plant leaf selenium fertilizer.

The invention relates to a high-performance copper (I)-based glass scintillator material and a preparation method thereof, and particularly discloses a Cu (I)-based hybrid metal halide optimized based on halogen engineering (Cl, Br, I), and the X-ray absorption cross section and the light output performance are remarkably improved. The light yield of the material reaches 79, 770 photons MeV <-1 > and is improved by 180% compared with that before optimization. The transparent glass scintillation screen (optical transmittance gt; the material has excellent X-ray imaging resolution (20.5 lp mm <-1 >), and also shows good thermal stability (stable luminescence performance at a high temperature of 150 DEG C) and anti-radiation durability. The material has the advantages of high light yield, low detection limit, high spatial resolution and the like, provides a breakthrough solution for application of the zero-dimensional halogenated cuprous-based scintillator in the fields of X-ray detection and imaging, and is particularly suitable for the fields of medical diagnosis, industrial nondestructive testing, high-energy physical detection and the like.

The invention belongs to the technical field of automatic control, and discloses a cyclopropylamine (R)-mandelate crystallization process feedback control method, which comprises the following steps: acquiring the concentration, solvent temperature, stirring speed and pH value of cyclopropylamine (R)-mandelate in a solvent in real time, and forming a state parameter set reflecting the real-time state of a cyclopropylamine (R)-mandelate crystallization system; based on the state parameter set, deriving a solute supersaturation degree change rate, a nucleation rate and a crystal growth rate by adopting an explicit kinetic relationship to obtain a kinetic feature set of the cyclopropylamine (R)-mandelate; collecting the grain size, the shape and the crystallization uniformity of the crystal, and constructing a corresponding crystal quality prediction function in combination with the kinetic feature set of the cyclopropylamine (R)-mandelate to obtain a predicted crystal quality index; comparing the actually detected crystal morphology index with the predicted crystal quality index, and calculating to obtain a deviation value; the crystal quality of the cyclopropylamine (R)-mandelate is improved.

The invention discloses a vinylene carbonate production waste treatment method, which comprises: dispersing triethylamine hydrochloride waste residue in water, filtering, adding excess alkali into the filtrate to carry out an alkaline hydrolysis reaction, and standing for layering to obtain an oil phase and a water phase, the oil phase containing triethylamine; adding calcium peroxide into the water phase, mixing and stirring to obtain a pretreatment solution; performing electrochemical catalytic oxidation treatment on the pretreatment solution, wherein a graphite felt electrode modified by a specific iron-based activated carbon catalyst is used as a cathode in the electrochemical catalytic oxidation treatment; the method is simple to operate, easy to implement, high in continuity, low in cost, free of high-temperature and high-pressure processes and excellent in treatment effect.

The present invention describes a new crystalline form of triethylenetetramine tetrachloride which has improved room temperature stability over known forms and over the dichloride salt. The new crystalline form is characterised by having peaks in an XRPD spectrum at 22.9, 25.4, 25.8, 26.6, 34.6 and 35.3±0.1°2θ and Raman shifts 943, 1173, 1527 and 1612±5 cm−1. The crystalline form of triethylenetetramine tetrachloride is useful in the treatment of Wilson's disease.

The present invention relates to a production process for synthesizing hexamethylenediamine by catalytic hydrogenation of adiponitrile. The process comprises the following steps: 1) preparing a catalyst precursor; 2) calcining the catalyst precursor to obtain a catalyst; 3) catalytic hydrogenation of adiponitrile under the condition of the catalyst to synthesize crude hexamethylenediamine; 4) separating hexamethylenediamine from the discharge of a fluidized bed reactor containing crude hexamethylenediamine. The present invention uses Ni(NO3)2 and / or Mg(NO3)2 as main raw materials, doped with transition metal oxides, and then performs ultrasonic adsorption using Al2O3 as a catalyst carrier to load Ni(NO3)2 and / or Mg(NO3)2 and transition metal oxides on Al2O3, and obtains a catalyst through high-temperature calcination. The doping of transition metal oxides can improve the basicity of the catalyst, eliminating the need to add a strong basic co-catalyst in the catalytic reaction stage, reducing by-product formation. Moreover, it increases the specific surface area of the catalyst, thereby reducing the adsorption of the reaction product hexamethylenediamine on the catalyst, extending the service life of the catalyst, and saving the energy consumption for catalyst regeneration.

The application discloses a kind of purification devices for diphenylamine production, it is related to chemical purification technical field, including purification tank body, stirring mixing assembly and lifting mixed flow component are equipped in the purification tank body, stirring mixing assembly and lifting mixed flow component are jointly connected comprehensive drive component;The lifting mixed flow component includes multiple dispersion pipes arranged in the purification tank body, multiple dispersion pipes are evenly distributed in the circumferential of purification tank body, lifting column is slidably connected in each dispersion pipe, the top end of lifting column is fixedly connected with traction rope, the diphenylamine solution in the purification tank body can be mixed as a whole by being equipped with stirring mixing assembly, the diphenylamine solution can be fine flow mixing by being equipped with lifting mixed flow component using pressure-driven mode, stirring mixing assembly and lifting mixed flow component are jointly used to effectively ensure that the diphenylamine solution in the purification tank body is efficiently mixed, so that diphenylamine is more efficiently purified, and the use effect is good.

The invention relates to the technical field of product selectivity adjustment in a vinylamine production process, in particular to a piperazine and diethylenetriamine high-selectivity co-production system and process, the piperazine and diethylenetriamine high-selectivity co-production system comprises a raw material storage unit, a reaction unit, an ammonia recovery unit, a product refining unit and a product storage unit, the raw material storage unit is provided with an NH3 storage area and an MEA storage area, a mass flow meter I, a mass flow meter II and a flow proportion control module I are arranged; a stream I is connected between the ammonia recovery unit and the NH3 storage area; the product storage unit comprises an MEA product intermediate tank, an EDA product intermediate tank and an AEA product intermediate tank which are connected with a second stream, a third stream and a fourth stream respectively, and a third mass flow meter, a fourth mass flow meter, a second flow proportion control module and a third flow proportion control module are arranged on the third stream and the fourth stream respectively. The selectivity of piperazine and diethylenetriamine is improved, and the operation benefit of the device is maximized.

The invention belongs to the technical field of materials, and particularly relates to an efficient yellow light-emitting perovskite material, a preparation method thereof and a light-emitting device. Wherein the chemical formula of the hybrid perovskite yellow light-emitting material is (C4H12N) 2In1-xCl5. DMF: Sbx, and x is more than 0 and less than or equal to 0.05. According to the antimony ion doped organic-inorganic hybrid perovskite yellow light-emitting material, the perovskite matrix material provides a suitable crystal field environment for doping of Sb, perovskite doping is achieved by replacing an In site with Sb, efficient yellow light emission of Sb can be achieved under the structure, the light-emitting efficiency is high and is close to 100%, and the structure is stable. In addition, the luminescent material does not contain heavy metal lead, so that the harm of the material to human bodies and the environment can be avoided.

The invention belongs to the technical field of organic synthetic chemistry, and particularly relates to a synthesis process of N-methylaniline. By adopting the special biomass porous carbon loaded nickel-copper bimetallic catalyst, the selectivity and the conversion rate of the reaction are improved, and the generation of byproducts is reduced, so that the burden of subsequent separation is reduced, the utilization rate of the raw materials is improved, and the yield is increased by introducing the micro-channel reactor and combining a microwave heating technology. Compared with the prior art, the method has the advantages that the mixing efficiency and the heat mass transfer rate of materials are improved, the reaction time is shortened, in the separation and purification process, a membrane separation and rectification combined technology and an efficient phase splitter are adopted, salt water is not needed, salt-containing wastewater is avoided, meanwhile, the recovery efficiency of methanol and aniline is improved, and cyclic utilization of a solvent is achieved. The whole process reduces the energy consumption, improves the production efficiency, reduces the emission of pollutants and meets the requirements of green chemistry through waste heat recovery, heating mode optimization and separation process.