The invention discloses a process for preparing a V2O3 / ZnV2O3 total battery by simultaneously using
vanadium oxide in a
zinc ion battery as a positive
electrode material and a negative
electrode material, which comprises the following steps: reacting
ammonium metavanadate with absolute ethyl
alcohol by adopting a
solvothermal synthesis method, washing,
drying, and calcining in a tubular furnace to obtain V2O3; in the preparation process of the V2O3 positive
electrode material, only V2O3,
acetylene black serving as a conductive agent and PVDF serving as a binder are mixed in proportion and then are coated on
graphite paper, other
coating protection materials do not need to be introduced into a V2O3 / Zn negative electrode, and V2O3 is used as a
protection layer to inhibit growth of
zinc dendrites, relieve
hydrogen evolution
side reaction of the
zinc negative electrode and reduce
corrosion of zinc.
Vanadium oxide V2O3 is directly used as a core positive
electrode material, the zinc negative electrode
coating is developed by utilizing the characteristics of the
vanadium oxide V2O3, a material is formed, meanwhile, the performance optimization of the positive electrode and the negative electrode is realized, the used raw materials are simple and easy to obtain, the process is simple and easy to implement, and the preparation process is simple and easy to implement from V2O3
raw material synthesis to positive and negative electrode piece preparation to V2O3 / ZnV2O3 total battery
assembly. And comprehensive improvement of positive and negative electrode performances of zinc ions is simultaneously realized by a single material.